RU2017146613A - Каталитические смеси - Google Patents

Каталитические смеси Download PDF

Info

Publication number
RU2017146613A
RU2017146613A RU2017146613A RU2017146613A RU2017146613A RU 2017146613 A RU2017146613 A RU 2017146613A RU 2017146613 A RU2017146613 A RU 2017146613A RU 2017146613 A RU2017146613 A RU 2017146613A RU 2017146613 A RU2017146613 A RU 2017146613A
Authority
RU
Russia
Prior art keywords
molecular sieve
catalyst composition
extra
lattice
composition according
Prior art date
Application number
RU2017146613A
Other languages
English (en)
Inventor
Джозеф М. ФЕДЕЙКО
Хай-Ин ЧЭНЬ
Гай Ричард ЧЭНДЛЕР
Александр Николас Майкл ГРИН
Дебнатх ДЕ
Шадаб МУЛЛА
Уэнди МЭННИНГ
Филип Джеральд БЛЭЙКМАН
Original Assignee
Джонсон Мэтти Паблик Лимитед Компани
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Джонсон Мэтти Паблик Лимитед Компани filed Critical Джонсон Мэтти Паблик Лимитед Компани
Publication of RU2017146613A publication Critical patent/RU2017146613A/ru

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/005Mixtures of molecular sieves comprising at least one molecular sieve which is not an aluminosilicate zeolite, e.g. from groups B01J29/03 - B01J29/049 or B01J29/82 - B01J29/89
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76Iron group metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8621Removing nitrogen compounds
    • B01D53/8625Nitrogen oxides
    • B01D53/8628Processes characterised by a specific catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404Removing only nitrogen compounds
    • B01D53/9409Nitrogen oxides
    • B01D53/9413Processes characterised by a specific catalyst
    • B01D53/9418Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42Platinum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76Iron group metals or copper
    • B01J29/763CHA-type, e.g. Chabazite, LZ-218
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/82Phosphates
    • B01J29/84Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85Silicoaluminophosphates [SAPO compounds]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/19Catalysts containing parts with different compositions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/50Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0814Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents combined with catalytic converters, e.g. NOx absorption/storage reduction catalysts
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0828Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents characterised by the absorbed or adsorbed substances
    • F01N3/0842Nitrogen oxides
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • F01N3/2066Selective catalytic reduction [SCR]
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2839Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration
    • F01N3/2842Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration specially adapted for monolithic supports, e.g. of honeycomb type
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2062Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/10Noble metals or compounds thereof
    • B01D2255/102Platinum group metals
    • B01D2255/1021Platinum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/10Noble metals or compounds thereof
    • B01D2255/102Platinum group metals
    • B01D2255/1023Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20738Iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20761Copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/209Other metals
    • B01D2255/2092Aluminium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/30Silica
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/50Zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/90Physical characteristics of catalysts
    • B01D2255/91NOx-storage component incorporated in the catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/90Physical characteristics of catalysts
    • B01D2255/915Catalyst supported on particulate filters
    • B01D2255/9155Wall flow filters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/40Nitrogen compounds
    • B01D2257/404Nitrogen oxides other than dinitrogen oxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7015CHA-type, e.g. Chabazite, LZ-218
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2610/00Adding substances to exhaust gases
    • F01N2610/02Adding substances to exhaust gases the substance being ammonia or urea
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/033Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices
    • F01N3/035Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices with catalytic reactors, e.g. catalysed diesel particulate filters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Toxicology (AREA)
  • Catalysts (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Processes For Solid Components From Exhaust (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Claims (9)

1. Композиция катализатора, включающая смесь двух молекулярных сит с каркасом СНА, при этом первое молекулярное сито характеризуется средним размером кристалла от около 0,01 до около 1 мкм, а второе молекулярное сито характеризуется средним размером кристалла от около 1 до около 5 мкм, и при этом первое молекулярное сито содержит первый внерешеточный металл, а второе молекулярное сито содержит второй внерешеточный металл, и при этом указанные первый и второй внерешеточные металлы независимо выбраны из группы, включающей в себя цезий, медь, никель, цинк, железо, олово, вольфрам, молибден, кобальт, висмут, титан, цирконий, сурьму, марганец, хром, ванадий, ниобий и их сочетания.
2. Композиция катализатора по п.1, в которой упомянутые два молекулярных сита представляют собой алюмосиликаты.
3. Композиция катализатора по п.1, в которой упомянутое первое молекулярное сито представляет собой алюмосиликат, а упомянутое второе молекулярное сито представляет собой кремнийалюмофосфат.
4. Композиция катализатора по п.1, в которой упомянутые первый и второй внерешеточные металлы независимо выбирают из группы, включающей в себя медь и железо.
5. Композиция катализатора по п.1, в которой упомянутые первый и второй замещенные металлы представляют собой медь.
6. Композиция катализатора по п.1, в которой соотношение диоксида кремния к оксиду алюминия в указанном первом молекулярном сите составляет от около 10 до около 25, а соотношение диоксида кремния к оксиду алюминия в указанном втором молекулярном сите составляет от около 20 до около 25.
7. Композиция катализатора по п.1, в которой по меньшей мере одно из указанных первого молекулярного сита и второго молекулярного сита представляет собой экструдат.
8. Композиция катализатора по п.1, в которой упомянутый первый внерешеточный металл присутствует в количестве от около 1 до около 5 масс.%, из расчета на общую массу упомянутого молекулярного сита, а второй внерешеточный металл присутствует в количестве, достаточном для достижения массового соотношения первого внерешеточного металла и второго внерешеточного металла от около 0,4:1,0 до около 1,5:1,0.
9. Композиция катализатора по п.1, в которой упомянутые первое молекулярное сито и второе молекулярное сито присутствуют в молярном соотношении от около 0,5:1,0 до около 1,5:1,0.
RU2017146613A 2012-01-31 2013-01-28 Каталитические смеси RU2017146613A (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261593030P 2012-01-31 2012-01-31
US61/593,030 2012-01-31

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
RU2014135450A Division RU2642443C2 (ru) 2012-01-31 2013-01-28 Каталитические смеси

Publications (1)

Publication Number Publication Date
RU2017146613A true RU2017146613A (ru) 2018-10-17

Family

ID=47754888

Family Applications (2)

Application Number Title Priority Date Filing Date
RU2014135450A RU2642443C2 (ru) 2012-01-31 2013-01-28 Каталитические смеси
RU2017146613A RU2017146613A (ru) 2012-01-31 2013-01-28 Каталитические смеси

Family Applications Before (1)

Application Number Title Priority Date Filing Date
RU2014135450A RU2642443C2 (ru) 2012-01-31 2013-01-28 Каталитические смеси

Country Status (9)

Country Link
US (4) US9126180B2 (ru)
EP (2) EP3326714A1 (ru)
JP (2) JP6293676B2 (ru)
KR (1) KR20140124387A (ru)
CN (2) CN106040292A (ru)
BR (1) BR112014018506A8 (ru)
GB (2) GB2514945B (ru)
RU (2) RU2642443C2 (ru)
WO (1) WO2013114172A1 (ru)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2642443C2 (ru) * 2012-01-31 2018-01-25 Джонсон Мэтти Паблик Лимитед Компани Каталитические смеси
JP5873562B2 (ja) * 2012-10-03 2016-03-01 イビデン株式会社 ハニカム構造体
KR102186666B1 (ko) * 2012-10-19 2020-12-04 바스프 코포레이션 혼합된 금속 8-고리 소 공극 분자체 촉매 조성물, 촉매성 물품, 시스템 및 방법
CN104837557B (zh) 2012-12-12 2018-06-01 巴斯夫公司 使用大颗粒分子筛的催化剂组合物、催化制品、系统和方法
JP6245896B2 (ja) * 2013-08-27 2017-12-13 イビデン株式会社 ハニカム触媒及び排ガス浄化装置
WO2015028805A1 (en) 2013-08-30 2015-03-05 Johnson Matthey Public Limited Company Zeolite blend catalysts for treating exhaust gas containing nox
US9889437B2 (en) 2015-04-15 2018-02-13 Basf Corporation Isomorphously substituted catalyst
JP6615794B2 (ja) * 2014-06-18 2019-12-04 ビーエーエスエフ コーポレーション モレキュラーシーブ触媒組成物、触媒複合体、システム、及び方法
US10850265B2 (en) 2014-06-18 2020-12-01 Basf Corporation Molecular sieve catalyst compositions, catalytic composites, systems, and methods
US9764313B2 (en) * 2014-06-18 2017-09-19 Basf Corporation Molecular sieve catalyst compositions, catalyst composites, systems, and methods
JP5732170B1 (ja) * 2014-07-07 2015-06-10 イビデン株式会社 ゼオライト、ハニカム触媒及び排ガス浄化装置
RU2710595C2 (ru) * 2014-10-30 2019-12-30 Басф Корпорейшн Смешанные каталитические композиции металлических крупнокристаллических молекулярных сит, каталитические изделия, системы и способы
US20160131001A1 (en) * 2014-11-06 2016-05-12 GM Global Technology Operations LLC Catalyst design for selective-catalytic-reduction (scr) filters
JP6469457B2 (ja) * 2015-01-22 2019-02-13 日野自動車株式会社 排気浄化装置
GB2540832B (en) * 2015-02-20 2019-04-17 Johnson Matthey Plc Bi-metal molecular sieve catalysts
KR20170121185A (ko) * 2015-02-26 2017-11-01 존슨 맛쎄이 퍼블릭 리미티드 컴파니 수동 NOx 흡착제
DE102015205843A1 (de) * 2015-03-31 2016-10-06 Johnson Matthey Catalysts (Germany) Gmbh Katalysator insbesondere zur Abgasreinigung
JP2016222505A (ja) * 2015-06-01 2016-12-28 イビデン株式会社 ゼオライトの製造方法
CA2996032C (en) * 2015-08-21 2023-09-26 Basf Corporation Exhaust gas treatment catalysts
JP6718137B2 (ja) * 2016-03-17 2020-07-08 三菱自動車工業株式会社 排気浄化装置
EP3448810A1 (en) * 2016-04-28 2019-03-06 Johnson Matthey Public Limited Company Sta-20, a novel molecular sieve framework type, methods of preparation and use
CN107774303B (zh) * 2016-08-30 2020-02-28 中国石油化工股份有限公司 多孔金属/分子筛复合催化剂、其制备方法及在合成气制备低碳烯烃中的用途
JP2018038978A (ja) * 2016-09-08 2018-03-15 トヨタ自動車株式会社 Scr触媒
CN109996765A (zh) * 2016-10-03 2019-07-09 巴斯夫公司 铝梯度硅铝酸盐沸石组合物
CN106577643A (zh) * 2016-11-05 2017-04-26 徐州乐泰机电科技有限公司 适用于公共场合的纳米改性y‑ssz‑13/sapo‑34抗菌材料
RU2020120226A (ru) * 2017-12-13 2021-12-20 Джонсон Мэттей Паблик Лимитед Компани Улучшенное снижение выброса nh3 с большей селективностью в отношении n2
WO2019135182A1 (en) * 2018-01-03 2019-07-11 Basf Corporation Surface-treated silicoaluminophosphate molecular sieve
GB201805312D0 (en) * 2018-03-29 2018-05-16 Johnson Matthey Plc Catalyst article for use in emission treatment system
US11541379B2 (en) * 2018-08-31 2023-01-03 Johnson Matthey Public Limited Company Bimetallic Cu/Mn catalysts for selective catalytic reduction
US11278874B2 (en) * 2018-11-30 2022-03-22 Johnson Matthey Public Limited Company Enhanced introduction of extra-framework metal into aluminosilicate zeolites
CN113301993A (zh) * 2019-03-14 2021-08-24 庄信万丰股份有限公司 Jmz-1s,含cha的分子筛及制备方法
JP7194431B2 (ja) * 2019-05-15 2022-12-22 株式会社 Acr 触媒、触媒製品および触媒の製造方法
CN110433855B (zh) * 2019-08-13 2021-07-20 华南理工大学 一种用于净化燃煤烟气中挥发性有机物的负载型催化剂及其制备方法与应用
US20220331782A1 (en) * 2019-09-19 2022-10-20 Basf Corporation Selective catalytic reduction catalyst composition, catalytic article comprising the same and method for preparing the cataytic article
KR20210087743A (ko) * 2020-01-03 2021-07-13 현대자동차주식회사 촉매 및 촉매의 제조 방법

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4544538A (en) 1982-07-09 1985-10-01 Chevron Research Company Zeolite SSZ-13 and its method of preparation
US4440871A (en) 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
US4992160A (en) * 1983-05-02 1991-02-12 Uop Conversion of crude oil feeds by catalytic cracking
US5314612A (en) * 1992-11-30 1994-05-24 Exxon Research And Engineering Company Fluid catalytic cracking process for producing low emissions fuels
CN1102075C (zh) * 1996-05-29 2003-02-26 埃克森美孚化学专利公司 沸石催化剂及其在烃转化上的用途
GB9805815D0 (en) 1998-03-19 1998-05-13 Johnson Matthey Plc Manufacturing process
US6858556B2 (en) * 2002-02-25 2005-02-22 Indian Oil Corporation Limited Stabilized dual zeolite single particle catalyst composition and a process thereof
RU2328445C2 (ru) * 2002-05-23 2008-07-10 Консехо Супериор Де Инвестигасьонес Сьентификас Микропористый кристаллический цеолитный материал (цеолит itq-22), способ его получения и применение в качестве катализатора
CN1329296C (zh) 2002-05-24 2007-08-01 三菱瓦斯化学株式会社 具八元氧环微孔的结晶硅铝磷酸盐分子筛、其制备方法和以此为催化剂生产甲胺的方法
US7375050B2 (en) * 2003-04-28 2008-05-20 Exxonmobil Chemical Patents Inc. Synthesis and use of aluminophosphates and silicoaluminophosphates
US7122500B2 (en) * 2003-09-22 2006-10-17 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst composition, its making and use in conversion processes
WO2008118434A1 (en) * 2007-03-26 2008-10-02 Pq Corporation Novel microporous crystalline material comprising a molecular sieve or zeolite having an 8-ring pore opening structure and methods of making and using same
CA2939726C (en) * 2007-04-26 2019-06-18 Johnson Matthey Public Limited Company Transition metal/zeolite scr catalysts
US20090196812A1 (en) * 2008-01-31 2009-08-06 Basf Catalysts Llc Catalysts, Systems and Methods Utilizing Non-Zeolitic Metal-Containing Molecular Sieves Having the CHA Crystal Structure
US20100092397A1 (en) 2008-10-14 2010-04-15 Activaero Gmbh Method For Treatment of COPD and Other Pulmonary Diseases
GB2464478A (en) 2008-10-15 2010-04-21 Johnson Matthey Plc Aluminosilicate zeolite catalyst and use thereof in exhaust gas after-treatment
JP5482179B2 (ja) 2008-12-22 2014-04-23 東ソー株式会社 チャバザイト型ゼオライト及びその製造方法
US9662611B2 (en) * 2009-04-03 2017-05-30 Basf Corporation Emissions treatment system with ammonia-generating and SCR catalysts
JP5560158B2 (ja) * 2009-11-19 2014-07-23 イビデン株式会社 ハニカム構造体及び排ガス浄化装置
GB2475740B (en) * 2009-11-30 2017-06-07 Johnson Matthey Plc Catalysts for treating transient NOx emissions
CN102869427B (zh) * 2010-03-11 2016-11-09 约翰逊马西有限公司 用于选择性催化还原NOx的无序分子筛载体
US9352307B2 (en) * 2010-04-08 2016-05-31 Basf Corporation Cu-CHA/Fe-MFI mixed zeolite catalyst and process for the treatment of NOx in gas streams
JP2014530097A (ja) * 2011-10-05 2014-11-17 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se ガス流中のNOxを処理するためのCu−CHA/Fe−BEA混合ゼオライト触媒および方法
EP2771111A1 (en) * 2011-10-24 2014-09-03 Haldor Topsøe A/S Catalyst composition and method for use in selective catalytic reduction of nitrogen oxides
RU2642443C2 (ru) * 2012-01-31 2018-01-25 Джонсон Мэтти Паблик Лимитед Компани Каталитические смеси
JP5873562B2 (ja) * 2012-10-03 2016-03-01 イビデン株式会社 ハニカム構造体
KR102186666B1 (ko) * 2012-10-19 2020-12-04 바스프 코포레이션 혼합된 금속 8-고리 소 공극 분자체 촉매 조성물, 촉매성 물품, 시스템 및 방법
JP6377086B2 (ja) * 2013-03-14 2018-08-22 ジョンソン、マッセイ、パブリック、リミテッド、カンパニーJohnson Matthey Public Limited Company 排ガスを処理するための触媒としてのアルミノ珪酸塩又はシリコアルミノホスフェートモレキュラーシーブ/マンガン八面体モレキュラーシーブ
JP6245896B2 (ja) * 2013-08-27 2017-12-13 イビデン株式会社 ハニカム触媒及び排ガス浄化装置
WO2015028805A1 (en) * 2013-08-30 2015-03-05 Johnson Matthey Public Limited Company Zeolite blend catalysts for treating exhaust gas containing nox
JP6562866B2 (ja) * 2016-03-31 2019-08-21 日本碍子株式会社 ハニカム構造体の製造方法

Also Published As

Publication number Publication date
US20150375215A1 (en) 2015-12-31
CN104159667A (zh) 2014-11-19
GB201721108D0 (en) 2018-01-31
US20180297016A1 (en) 2018-10-18
US9610571B2 (en) 2017-04-04
BR112014018506A2 (ru) 2017-06-20
BR112014018506A8 (pt) 2017-07-11
GB201415093D0 (en) 2014-10-08
US20170182482A1 (en) 2017-06-29
US9126180B2 (en) 2015-09-08
CN106040292A (zh) 2016-10-26
RU2642443C2 (ru) 2018-01-25
EP3326714A1 (en) 2018-05-30
JP6293676B2 (ja) 2018-03-14
US20150190791A1 (en) 2015-07-09
GB2514945A (en) 2014-12-10
RU2014135450A (ru) 2016-03-27
JP2018140387A (ja) 2018-09-13
EP2809441A1 (en) 2014-12-10
WO2013114172A1 (en) 2013-08-08
CN104159667B (zh) 2017-02-08
JP2015510448A (ja) 2015-04-09
GB2514945B (en) 2018-01-31
US9999876B2 (en) 2018-06-19
KR20140124387A (ko) 2014-10-24

Similar Documents

Publication Publication Date Title
RU2017146613A (ru) Каталитические смеси
RU2016152441A (ru) Способ получения акриловой кислоты с использованием не содержащего алюминий цеолитного материала
JP2015510448A5 (ru)
JP2015528856A5 (ru)
MX2018007396A (es) Catalizador para reduccion catalitica selectiva (scr) que comprende un oxido compuesto que contiene v y sb, proceso de preparacion del mismo, y su utilizacion para la eliminacion de oxidos de nitrogeno.
RU2016152439A (ru) Способ получения акриловой кислоты с использованием свободного от щелочных металлов и щелочно-земельных металлов цеолитного материала
JP2012036444A5 (ru)
WO2014081491A3 (en) Cobalt alloys
JP2012143751A5 (ru)
JP2014210229A5 (ru)
JP2014523967A5 (ru)
JP2011088925A5 (ru)
WO2012084276A3 (en) Process for preparing an industrial hydroconversion catalyst, catalyst thus obtained and use thereof in a hydroconversion process
WO2013096069A3 (en) Uzm-39 aluminosilicate zeolite
MY154913A (en) Mixed metal oxide catalysts and catalytic conversions of lower alkane hydrocarbons
JP2013534146A5 (ru)
WO2014093110A3 (en) Uzm-44 aluminosilicate zeolite
JP2014517770A5 (ru)
RU2019100524A (ru) Каталитическая композиция, содержащая цеолит типа con и цеолит типа zsm-5, получение и способ применения указанной композиции
HRP20190864T1 (hr) Feritni nehrđajući čelik s odličnom otpornošću na oksidaciju, dobrom otpornošću na visoke temperature i dobrom formabilnošću
JP2017014077A5 (ru)
RU2019108803A (ru) Алкилароматический катализатор конверсии
MY168923A (en) Catalyst support materials, cataylysts, methods of making them and uses thereof
JP2013102002A5 (ru)
WO2014057358A8 (en) Low binder, wear resistant hard metal

Legal Events

Date Code Title Description
FA93 Acknowledgement of application withdrawn (no request for examination)

Effective date: 20201229