RU2017146613A - Каталитические смеси - Google Patents
Каталитические смеси Download PDFInfo
- Publication number
- RU2017146613A RU2017146613A RU2017146613A RU2017146613A RU2017146613A RU 2017146613 A RU2017146613 A RU 2017146613A RU 2017146613 A RU2017146613 A RU 2017146613A RU 2017146613 A RU2017146613 A RU 2017146613A RU 2017146613 A RU2017146613 A RU 2017146613A
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- RU
- Russia
- Prior art keywords
- molecular sieve
- catalyst composition
- extra
- lattice
- composition according
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims 11
- 230000003197 catalytic effect Effects 0.000 title 1
- 239000002808 molecular sieve Substances 0.000 claims 15
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims 15
- 239000003054 catalyst Substances 0.000 claims 9
- 229910052751 metal Inorganic materials 0.000 claims 9
- 239000002184 metal Substances 0.000 claims 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 3
- 229910052802 copper Inorganic materials 0.000 claims 3
- 239000010949 copper Substances 0.000 claims 3
- 150000002739 metals Chemical class 0.000 claims 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- 229910000323 aluminium silicate Inorganic materials 0.000 claims 2
- 239000013078 crystal Substances 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 2
- 239000000377 silicon dioxide Substances 0.000 claims 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
- 229910052787 antimony Inorganic materials 0.000 claims 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims 1
- 229910052797 bismuth Inorganic materials 0.000 claims 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims 1
- 229910052792 caesium Inorganic materials 0.000 claims 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims 1
- 229910052804 chromium Inorganic materials 0.000 claims 1
- 239000011651 chromium Substances 0.000 claims 1
- 229910017052 cobalt Inorganic materials 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 1
- HSMPDPBYAYSOBC-UHFFFAOYSA-N khellin Chemical compound O1C(C)=CC(=O)C2=C1C(OC)=C1OC=CC1=C2OC HSMPDPBYAYSOBC-UHFFFAOYSA-N 0.000 claims 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 1
- 229910052750 molybdenum Inorganic materials 0.000 claims 1
- 239000011733 molybdenum Substances 0.000 claims 1
- 229910052758 niobium Inorganic materials 0.000 claims 1
- 239000010955 niobium Substances 0.000 claims 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims 1
- 229910052718 tin Inorganic materials 0.000 claims 1
- 239000011135 tin Substances 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 1
- 229910052721 tungsten Inorganic materials 0.000 claims 1
- 239000010937 tungsten Substances 0.000 claims 1
- 229910052720 vanadium Inorganic materials 0.000 claims 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 claims 1
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- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
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- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
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- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
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- F01N3/2839—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration
- F01N3/2842—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration specially adapted for monolithic supports, e.g. of honeycomb type
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- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
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- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
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- F01N3/033—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
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- Combustion & Propulsion (AREA)
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- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Processes For Solid Components From Exhaust (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Claims (9)
1. Композиция катализатора, включающая смесь двух молекулярных сит с каркасом СНА, при этом первое молекулярное сито характеризуется средним размером кристалла от около 0,01 до около 1 мкм, а второе молекулярное сито характеризуется средним размером кристалла от около 1 до около 5 мкм, и при этом первое молекулярное сито содержит первый внерешеточный металл, а второе молекулярное сито содержит второй внерешеточный металл, и при этом указанные первый и второй внерешеточные металлы независимо выбраны из группы, включающей в себя цезий, медь, никель, цинк, железо, олово, вольфрам, молибден, кобальт, висмут, титан, цирконий, сурьму, марганец, хром, ванадий, ниобий и их сочетания.
2. Композиция катализатора по п.1, в которой упомянутые два молекулярных сита представляют собой алюмосиликаты.
3. Композиция катализатора по п.1, в которой упомянутое первое молекулярное сито представляет собой алюмосиликат, а упомянутое второе молекулярное сито представляет собой кремнийалюмофосфат.
4. Композиция катализатора по п.1, в которой упомянутые первый и второй внерешеточные металлы независимо выбирают из группы, включающей в себя медь и железо.
5. Композиция катализатора по п.1, в которой упомянутые первый и второй замещенные металлы представляют собой медь.
6. Композиция катализатора по п.1, в которой соотношение диоксида кремния к оксиду алюминия в указанном первом молекулярном сите составляет от около 10 до около 25, а соотношение диоксида кремния к оксиду алюминия в указанном втором молекулярном сите составляет от около 20 до около 25.
7. Композиция катализатора по п.1, в которой по меньшей мере одно из указанных первого молекулярного сита и второго молекулярного сита представляет собой экструдат.
8. Композиция катализатора по п.1, в которой упомянутый первый внерешеточный металл присутствует в количестве от около 1 до около 5 масс.%, из расчета на общую массу упомянутого молекулярного сита, а второй внерешеточный металл присутствует в количестве, достаточном для достижения массового соотношения первого внерешеточного металла и второго внерешеточного металла от около 0,4:1,0 до около 1,5:1,0.
9. Композиция катализатора по п.1, в которой упомянутые первое молекулярное сито и второе молекулярное сито присутствуют в молярном соотношении от около 0,5:1,0 до около 1,5:1,0.
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EP (2) | EP3326714A1 (ru) |
JP (2) | JP6293676B2 (ru) |
KR (1) | KR20140124387A (ru) |
CN (2) | CN106040292A (ru) |
BR (1) | BR112014018506A8 (ru) |
GB (2) | GB2514945B (ru) |
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- 2013-01-28 CN CN201610371797.5A patent/CN106040292A/zh active Pending
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US20150375215A1 (en) | 2015-12-31 |
CN104159667A (zh) | 2014-11-19 |
GB201721108D0 (en) | 2018-01-31 |
US20180297016A1 (en) | 2018-10-18 |
US9610571B2 (en) | 2017-04-04 |
BR112014018506A2 (ru) | 2017-06-20 |
BR112014018506A8 (pt) | 2017-07-11 |
GB201415093D0 (en) | 2014-10-08 |
US20170182482A1 (en) | 2017-06-29 |
US9126180B2 (en) | 2015-09-08 |
CN106040292A (zh) | 2016-10-26 |
RU2642443C2 (ru) | 2018-01-25 |
EP3326714A1 (en) | 2018-05-30 |
JP6293676B2 (ja) | 2018-03-14 |
US20150190791A1 (en) | 2015-07-09 |
GB2514945A (en) | 2014-12-10 |
RU2014135450A (ru) | 2016-03-27 |
JP2018140387A (ja) | 2018-09-13 |
EP2809441A1 (en) | 2014-12-10 |
WO2013114172A1 (en) | 2013-08-08 |
CN104159667B (zh) | 2017-02-08 |
JP2015510448A (ja) | 2015-04-09 |
GB2514945B (en) | 2018-01-31 |
US9999876B2 (en) | 2018-06-19 |
KR20140124387A (ko) | 2014-10-24 |
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