RU2017137626A - Покрывающий агент, покрывающая пленка, ламинат и изделие с защищенной поверхностью - Google Patents

Покрывающий агент, покрывающая пленка, ламинат и изделие с защищенной поверхностью Download PDF

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RU2017137626A
RU2017137626A RU2017137626A RU2017137626A RU2017137626A RU 2017137626 A RU2017137626 A RU 2017137626A RU 2017137626 A RU2017137626 A RU 2017137626A RU 2017137626 A RU2017137626 A RU 2017137626A RU 2017137626 A RU2017137626 A RU 2017137626A
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fluorine
resin
film
agent according
laminate
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RU2017137626A
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RU2699632C2 (ru
RU2017137626A3 (ru
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Киоко КОНДО
Кениа ИТО
Хироюки ИИЗУКА
Аки КУРОМАЦУ
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ДжейЭнСи КОРПОРЭЙШН
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    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/44—Polycarbonates
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    • C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
    • C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C08G81/024—Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G
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    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/26—Layered products comprising a layer of synthetic resin characterised by the use of special additives using curing agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
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    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
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    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
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    • C08G18/81—Unsaturated isocyanates or isothiocyanates
    • C08G18/8108—Unsaturated isocyanates or isothiocyanates having only one isocyanate or isothiocyanate group
    • C08G18/8116—Unsaturated isocyanates or isothiocyanates having only one isocyanate or isothiocyanate group esters of acrylic or alkylacrylic acid having only one isocyanate or isothiocyanate group
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    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/22—Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring
    • C08G65/223—Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring containing halogens
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    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Paints Or Removers (AREA)
  • Laminated Bodies (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Adhesive Tapes (AREA)

Claims (20)

1. Покрывающий агент, содержащий смолу на основе уретанового (мет)акрилата (а), фторсодержащее соединение (b) и инициатор фотополимеризации (d),
в котором средневесовая молекулярная масса смолы на основе уретанового (мет)акрилата (а) составляет от 10000 до 800000 и
фторсодержащее соединение (b) содержит по меньшей мере две полимеризуемые функциональные группы.
2. Покрывающий агент по п. 1, отличающийся тем, что фторсодержащее соединение (b) представляет собой перфторполиэфир, содержащий (мет)акрилоильную группу.
3. Покрывающий агент по п. 1 или 2, отличающийся тем, что покрывающий агент содержит от 1 до 9 масс. % фторсодержащего соединения (b) в расчете на общее количество смолы на основе уретанового (мет)акрилата (а) и фторсодержащего соединения (b).
4. Покрывающий агент по любому из пп. 1-3, дополнительно содержащий производное фторсилсесквиоксана (с),
в котором производное фторсилсесквиоксана (с) содержит по меньшей мере одну полимеризуемую функциональную группу.
5. Покрывающий агент по п. 4, отличающийся тем, что производное фторсилсесквиоксана (с) представляет собой фторсилсесквиоксан клеточной структуры.
6. Покрывающий агент по п. 4 или 5, отличающийся тем, что покрывающий агент содержит от 0,1 до 10 масс. % производного фторсилсесквиоксана (с) в расчете на общее количество смолы на основе уретанового (мет)акрилата (а), фторсодержащего соединения (b) и производного фторсилсесквиоксана (с).
7. Покрывающая пленка, полученная путем отверждения покрывающего агента по любому из пп. 1-6.
8. Ламинат, содержащий:
пленку основного материала, полученную из термопластичного полиуретана; и
поверхностный слой, полученный путем отверждения покрывающего агента по любому из пп. 1-6 на первой стороне поверхности пленки основного материала.
9. Ламинат по п. 8, содержащий:
адгезионный слой на стороне, противоположной первой стороне поверхности пленки основного материала; и
антиадгезионную пленку на поверхности, противоположной пленке основного материала с адгезионным слоем,
где адгезионный слой содержит по меньшей мере одну смолу, выбранную из акриловой смолы, уретановой смолы, каучуковой смолы и силиконовой смолы, и на поверхность антиадгезионной пленки, обращенной к адгезионному слою, нанесен по меньшей мере один антиадгезионный агент, выбранный из фторсодержащей смолы, силиконовой смолы и длинноцепочечного карбамата.
10. Изделие с защищенной поверхностью, содержащее:
ламинат по п. 8 или 9, от которого отделена антиадгезионная пленка; и
изделие, к поверхности которого за счет адгезионного слоя прикреплен ламинат, от которого отделена антиадгезионная пленка.
RU2017137626A 2015-03-31 2016-03-29 Покрывающий агент, покрывающая пленка, ламинат и изделие с защищенной поверхностью RU2699632C2 (ru)

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JP2015074274 2015-03-31
JP2015-074274 2015-03-31
PCT/JP2016/060270 WO2016159023A1 (ja) 2015-03-31 2016-03-29 コーティング剤、皮膜、積層体、表面保護物品

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RU2017137626A true RU2017137626A (ru) 2019-05-06
RU2017137626A3 RU2017137626A3 (ru) 2019-05-06
RU2699632C2 RU2699632C2 (ru) 2019-09-06

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US (2) US10513586B2 (ru)
EP (1) EP3279282A4 (ru)
JP (1) JP6241571B2 (ru)
KR (1) KR20170132817A (ru)
CN (1) CN107429113A (ru)
MX (1) MX2017012451A (ru)
RU (1) RU2699632C2 (ru)
TW (1) TWI697528B (ru)
WO (1) WO2016159023A1 (ru)

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JP6607510B2 (ja) * 2015-08-11 2019-11-20 エルジー・ケム・リミテッド 光硬化性コーティング組成物、低屈折層および反射防止フィルム
EP3312209B1 (en) * 2016-10-20 2023-09-27 Samsung Electronics Co., Ltd. Self-healing composition, self-healing film, and device including the self-healing film
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