RU2017104449A - Слоистый материал, изделия с защищенной поверхностью и способ получения слоистого материала - Google Patents

Слоистый материал, изделия с защищенной поверхностью и способ получения слоистого материала Download PDF

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RU2017104449A
RU2017104449A RU2017104449A RU2017104449A RU2017104449A RU 2017104449 A RU2017104449 A RU 2017104449A RU 2017104449 A RU2017104449 A RU 2017104449A RU 2017104449 A RU2017104449 A RU 2017104449A RU 2017104449 A RU2017104449 A RU 2017104449A
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adhesive layer
base film
curable resin
layered material
resin composition
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RU2017104449A3 (ru
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Соитиро ХИРАКИ
Кодзи ОГУМА
Микио ЯМАХИРО
Сигетака ИКЕМОТО
Таро МАГАТАНИ
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ДжейЭнСи КОРПОРЭЙШН
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    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
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    • B05D1/00—Processes for applying liquids or other fluent materials
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    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
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    • C09D151/085—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds on to polysiloxanes
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    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
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Claims (26)

1. Слоистый материал, содержащий:
пленку-основу, полученную из термопластичного полиуретана; и
адгезивный слой, полученный на первой поверхностной стороне пленки-основы, при этом
пленка-основа имеет поверхностный слой на стороне, противоположной первой поверхности, в поверхностном слое присутствует смесь термопластичного полиуретана и отверждаемой смоляной композиции,
относительное содержание отверждаемой смоляной композиции выполнено с возможностью постепенного снижения в направлении от поверхности поверхностного слоя к внутренней части пленки-основы,
отверждаемая смоляная композиция содержит по меньшей мере одно фторсодержащее соединение, выбранное из группы, состоящей из фторсилсесквиоксана и фторсилсесквиоксановых полимеров, и отверждаемую смолу, и
адгезивный слой имеет шероховатость поверхности 350-750 нм.
2. Слоистый материал по п. 1, отличающийся тем, что фторсодержащее соединение имеет структуру «клетки»,
отверждаемая смола содержит по меньшей мере соединение, содержащее (мет)акрилоильную группу, и
адгезивный слой образован с применением по меньшей мере смолы, выбранной из группы, состоящей из акриловой смолы, уретановой смолы, каучуковой смолы и кремнийорганической смолы.
3. Слоистый материал по п. 1 или 2, отличающийся тем, что
фторсилсесквиоксановый полимер представляет собой аддитивный полимер фторсилсесквиоксана, содержащего по меньшей мере одну аддитивно полимеризуемую функциональную группу, или аддитивный сополимер фторсилсесквиоксана, содержащего одну аддитивно полимеризуемую функциональную группу, с аддитивно полимеризуемым мономером.
4. Слоистый материал по пп. 1-3, содержащий отслаиваемую пленку, обеспеченную на поверхности адгезивного слоя, противоположной пленке-основе, где
поверхность отслаиваемой пленки, обращенная в сторону адгезивного слоя, имеет шероховатость поверхности 350-800 нм.
5. Слоистый материал по п. 4, отличающийся тем, что адгезивный слой сохраняет неровности, демонстрирующие шероховатость поверхности, в течение от 10 до 120 минут после отрыва отслаиваемой пленки.
6. Слоистый материал по п. 4 или 5, отличающийся тем, что поверхность отслаиваемой пленки, обращенная в сторону адгезивного слоя, покрыта по меньшей мере отслаивающим агентом, выбранным из фторсодержащих каучуков, кремнийорганических каучуков и длинноцепочечных карбаматов.
7. Изделие с защищенной поверхностью, содержащее:
слоистый материал по любому из пп. 1-3; и
изделие, в котором слоистый материал прикреплен к его поверхности посредством адгезивного слоя, при этом
неровности адгезивного слоя, демонстрирующие шероховатость поверхности, исчезли.
8. Способ получения слоистого материала, включающий:
стадию обеспечения пленки-основы, полученной из термопластичного полиуретана;
стадию получения адгезивного слоя на первой поверхностной стороне пленки-основы, где поверхность адгезивного слоя, противоположная пленке-основе, имеет шероховатость 350-750 нм;
стадию нанесения отверждаемой смоляной композиции на вторую поверхность пленки-основы, противоположную первой поверхности, для проникновения отверждаемой смоляной композиции в пленку-основу; и
стадию облучения отверждаемой смоляной композиции УФ лучами, при этом
отверждаемая смоляная композиция содержит по меньшей мере одно фторсодержащее соединение, выбранное из группы, состоящей из фторсилсесквиоксана и фторсилсесквиоксановых полимеров, и отверждаемую смолу.
RU2017104449A 2014-07-15 2015-07-14 Слоистый материал, изделия с защищенной поверхностью и способ получения слоистого материала RU2693168C2 (ru)

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JP2014-145465 2014-07-15
JP2014145465 2014-07-15
PCT/JP2015/070168 WO2016010041A1 (ja) 2014-07-15 2015-07-14 積層体、表面保護物品、積層体の製造方法

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EP (1) EP3170659B1 (ru)
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KR (1) KR20170033333A (ru)
CN (1) CN106794678B (ru)
MX (1) MX2017000469A (ru)
RU (1) RU2693168C2 (ru)
TW (1) TWI682855B (ru)
WO (1) WO2016010041A1 (ru)

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JP6780647B2 (ja) * 2015-09-18 2020-11-04 Jnc株式会社 プラスチック修復用フィルム、表面保護物品、プラスチック修復用フィルムの製造方法
JP6700542B2 (ja) * 2016-09-30 2020-05-27 Jnc株式会社 積層フィルム
JP6673128B2 (ja) * 2016-09-30 2020-03-25 Jnc株式会社 積層フィルム
JP7140099B2 (ja) * 2017-02-14 2022-09-21 王子ホールディングス株式会社 剥離性フィルム
KR20200016280A (ko) * 2017-05-31 2020-02-14 제이엔씨 주식회사 적층 필름
JP6393384B1 (ja) * 2017-10-06 2018-09-19 日本ペイント・オートモーティブコーティングス株式会社 防眩ハードコート層の形成方法
CN111032235B (zh) * 2017-10-23 2021-06-22 Mec株式会社 膜形成基材的制造方法、膜形成基材及表面处理剂
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US20170226385A1 (en) 2017-08-10
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TWI682855B (zh) 2020-01-21
EP3170659A1 (en) 2017-05-24
RU2017104449A3 (ru) 2019-01-29
CN106794678B (zh) 2019-02-01
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