RU2016152664A - Разделение и хранение текучих сред с использованием itq-55 - Google Patents

Разделение и хранение текучих сред с использованием itq-55 Download PDF

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RU2016152664A
RU2016152664A RU2016152664A RU2016152664A RU2016152664A RU 2016152664 A RU2016152664 A RU 2016152664A RU 2016152664 A RU2016152664 A RU 2016152664A RU 2016152664 A RU2016152664 A RU 2016152664A RU 2016152664 A RU2016152664 A RU 2016152664A
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fluid
component
adsorbent
itq
value
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RU2016152664A
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RU2675874C2 (ru
RU2016152664A3 (ru
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Эдвард У. Мл. КОРКОРАН
Павел КОРТУНОВ
Чаранжит С. ПАУР
Питер И. РАВИКОВИТЧ
Юй ВАН
Канос Авелино Корма
Валенсия Сусана Валенсия
ГАРСИЯ Фернандо РЭЙ
САНС Анхель КАНТИН
РОКА Мигель ПАЛОМИНО
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ЭкссонМобил Рисерч энд Энджиниринг Компани
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Claims (60)

1. Способ адсорбции и хранения текучих сред, включающий:
пропускание входящего потока текучей среды, содержащего первый компонент текучей среды, через адсорбент, содержащий цеолит ITQ-55, при первом давлении и первой температуре,
удерживание адсорбента при втором давлении и второй температуре в течение срока хранения,
образование выходящего потока адсорбированной текучей среды, содержащего первый компонент текучей среды, и
сбор выходящего потока адсорбированной текучей среды,
где цеолит ITQ-55 имеет каркас из тетраэдрических (Т) атомов, соединенных мостиковыми атомами, при этом тетраэдрический атом определяют его соединениями с ближайшими Т атомами, как описано в следующей таблице:
Соединения тетраэдрических атомов в ITQ-55 Т атом Соединен с Т1 Т6, Т7, Т55, Т73 Т2 Т3, Т5, Т9, Т56 Т3 Т2, Т7, Т21, Т27 Т4 Т8, Т9, Т58, Т73 Т5 Т2, Т8, Т52, Т59 Т6 Т1, Т8, Т53, Т60 Т7 Т1, Т3, Т50, Т61 Т8 Т4, Т5, Т6, Т51 Т9 Т2, Т4, Т21, Т63 Т10 Т15, Т16, Т64, Т74 Т11 Т12, Т14, Т18, Т65
Т12 Т11, Т16, Т30, Т36 Т13 Т17, Т18, Т67, Т74 Т14 Т11, Т17, Т43, Т68 Т15 Т10, Т17, Т44, Т69 Т16 Т10, Т12, Т41, Т70 Т17 Т13, Т14, Т15, Т42 Т18 Т11, Т13, Т30, Т72 Т19 Т24, Т25, Т37, Т73 Т20 Т21, Т23, Т27, Т38 Т21 Т3, Т9, Т20, Т25 Т22 Т26, Т27, Т40, Т73 Т23 Т20, Т26, Т41, Т70 Т24 Т19, Т26, Т42, Т71 Т25 T19, T21, T43, T68 Т26 Т22, Т23, Т24, Т69 Т27 Т3, Т20, Т22, Т45 Т28 Т33, Т34, Т46, Т74 Т29 Т30, Т32, Т36, Т47 Т30 Т12, Т18, Т29, Т34 Т31 Т35, Т36, Т49, Т74 Т32 Т29, Т35, Т50, Т61 Т33 Т28, Т35, Т51, Т62 Т34 Т28, Т30, Т52, Т59 Т35 Т31, Т32, Т33, Т60 Т36 Т12, Т29, Т31, Т54 Т37 Т19, Т42, Т43, Т75 Т38 Т20, Т39, Т41, Т45
Т39 Т38, Т43, Т57, Т63 Т40 Т22, Т44, Т45, Т75 Т41 Т16, Т23, Т38, Т44 Т42 Т17, Т24, Т37, Т44 Т43 Т14, Т25, Т37, Т39 Т44 Т15, Т40, Т41, Т42 Т45 Т27, Т38, Т40, Т57 Т46 Т28, Т51, Т52, Т76 Т47 Т29, Т48, Т50, Т54 Т48 Т47, Т52, Т66, Т72 Т49 Т31, Т53, Т54, Т76 Т50 Т7, Т32, Т47, Т53 Т51 Т8, Т33, Т46, Т53 Т52 Т5, Т34, Т46, Т48 Т53 Т6, Т49, Т50, Т51 Т54 Т36, Т47, Т49, Т66 Т55 Τ1, Τ60, Τ61, Τ75 Т56 Т2, Т57, Т59, Т63 Т57 Т39, Т45, Т56, Т61 Т58 Т4, Т62, Т63, Т75 Т59 Т5, Т34, Т56, Т62 Т60 Т6, Т35, Т55, Т62 Т61 Т7, Т32, Т55, Т57 Т62 Т33, Т58, Т59, Т60 Т63 Т9, Т39, Т56, Т58 Т64 Т10, Т69, Т70, Т76 Т65 Т11, Т66, Т68, Т72
Т66 Т48, Т54, Т65, Т70 Т67 Т13, Т71, Т72, Т76 Т68 Т14, Т25, Т65, Т71 Т69 T15, T26, Т64, Т71 Т70 Т16, Т23, Т64, Т66 Т71 Т24, Т67, Т68, Т69 Т72 Т18, Т48, Т65, Т67 Т73 Т1, Т4, Т19, Т22 Т74 Т10, Т13, Т28, Т31 Т75 Т37, Т40, Т55, Т58 Т76 Т46, Т49, Т64, Т67
2. Способ адсорбции и хранения текучих сред, включающий:
пропускание входящего потока текучей среды, содержащего первый компонент текучей среды, через адсорбент, содержащий цеолит ITQ-55, при первом давлении и первой температуре,
удерживание адсорбента при втором давлении и второй температуре в течение срока хранения,
образование выходящего потока адсорбированной текучей среды, содержащего первый компонент текучей среды, и
сбор выходящего потока адсорбированной текучей среды,
где цеолит ITQ-55 в только что синтезированном состоянии имеет рентгеновскую дифрактограмму, по меньшей мере, со значениями угла 2θ (градусы) и относительными интенсивностями (I/I0):
2θ (градусы)±0,5 Интенсивность (I/I0) 5,8 w 7,7 w 8,9 w 9,3 mf
9,9 w 10,1 w 13,2 m 13,4 w 14,7 w 15,1 m 15,4 w 15,5 w 17,4 m 17,7 m 19,9 m 20,6 m 21,2 f 21,6 f 22,0 f 23,1 mf 24,4 m 27,0 m
где I0 является интенсивностью наиболее интенсивного пика, которой присваивают значение 100,
w является слабой относительной интенсивностью от 0 до 20%,
m является средней относительной интенсивностью от 20 до 40%,
f является сильной относительной интенсивностью от 40 до 60% и
mf является очень сильной относительной интенсивностью от 60 до 100%.
3. Способ по п. 1 или 2, в котором цеолит ITQ-55 имеет в обожженном состоянии и в отсутствии дефектов в его кристаллической матрице, проявляющихся путем присутствия силанолов, эмпирическую формулу
х (M1/nXO2) : y YO2 : g GeO2 : (1 - g) SiO2
в которой
М выбран из Н+, по меньшей мере одного неорганического катиона с зарядом +n и смеси обоих,
X является по меньшей мере одним химическим элементом в степени окисления +3,
Y является по меньшей мере одним химическим элементом в степени окисления +4, отличным от Si,
х имеет значение от 0 до 0,2, оба граничных значения включены,
y имеет значение от 0 до 0,1, оба граничных значения включены,
g имеет значение от 0 до 0,5, оба граничных значения включены.
4. Способ по п. 3, в котором х имеет значение по существу ноль, у имеет значение по существу ноль и g имеет значение по существу ноль.
5. Способ по п. 3, в котором а) х имеет значение больше ноля, б) у имеет значение по существу ноль, в) g имеет значение по существу ноль или г) сочетание этого.
6. Способ по любому из предшествующих пунктов, в котором пропускание входящего потока текучей среды через адсорбент включает пропускание входящего потока текучей среды через адсорбент в сосуде для короткоцикловой адсорбции.
7. Способ по любому из предшествующих пунктов, в котором первая температура и вторая температура являются одинаковыми, первое давление и второе давление являются одинаковыми, или сочетание этого.
8. Способ по любому из предшествующих пунктов, в котором образование выходящего потока адсорбированной текучей среды включает изменение второй температуры адсорбента, или образование выходящего потока адсорбированной текучей среды включает пропускание потока текучей среды, содержащего третий компонент, через адсорбент, содержащий цеолит ITQ-55, причем по меньшей мере часть третьего компонента адсорбируется адсорбентом, содержащим цеолит ITQ-55, или сочетание этого.
9. Способ по любому из предшествующих пунктов, в котором адсорбент имеет менее примерно 20% объема открытых пор в порах, имеющих диаметры более примерно 20
Figure 00000001
и менее примерно 1 мкм.
10. Способ по любому из предшествующих пунктов, в котором удерживание адсорбента при втором давлении и второй температуре в течение срока хранения включает подвергание адсорбента воздействию окружающей среды, имеющей парциальное давление первого компонента текучей среды, составляющее примерно 0,1 МПа абс. или менее.
11. Способ по любому из предшествующих пунктов, в котором входящий поток текучей среды дополнительно содержит второй компонент, при этом молярное отношение первого компонента ко второму компоненту в выходящем потоке адсорбированной текучей среды больше молярного отношения первого компонента ко второму компоненту во входящем потоке текучей среды.
12. Способ по п. 10, в котором второй компонент текучей среды представляет собой метан, этан, метанол, диметиловый эфир, органическое соединение, содержащее 3 или более тяжелых атомов, или их сочетание.
13. Способ по п. 11, в котором первый компонент текучей среды представляет собой CO2.
14. Способ по п. 10, в котором первый компонент текучей среды представляет собой Н2, а второй компонент текучей среды представляет собой оксид азота, оксид серы, углеводород, оксид углерода или их сочетание, при этом возможно входящий поток текучей среды содержит синтез-газ.
15. Способ по п. 10, в котором первый компонент текучей среды представляет собой Н2, а второй компонент текучей среды представляет собой H2S, NH3 или их сочетание.
16. Способ по любому из пп. 1-10, в котором первый компонент текучей среды представляет собой CO2, Н2 или их сочетание.
17. Способ по любому из пп. 1-10, в котором первый компонент текучей среды представляет собой этилен, ацетилен, формальдегид или их сочетание.
18. Способ по любому из пп. 1-10, в котором первый компонент текучей среды представляет собой благородный газ, молекулярный галоген, галогеноводород или их сочетание.
19. Способ по любому из пп. 1-10, в котором первый компонент текучей среды представляет собой метан, этилен, этан, метанол, диметиловый эфир или их сочетание.
20. Способ по любому из п. 1 или 3-8, в котором цеолит ITQ-55 в только что синтезированном состоянии имеет рентгеновскую дифрактограмму, по меньшей мере, со значениями угла 2θ (градусы) и относительными интенсивностями (I/I0):
2θ (градусы)±0,5 Интенсивность (I/I0) 5,8 w 7,7 w 8,9 w 9,3 mf 9,9 w 10,1 w 13,2 m
13,4 w 14,7 w 15,1 m 15,4 w 15,5 w 17,4 m 17,7 m 19,9 m 20,6 m 21,2 f 21,6 f 22,0 f 23,1 mf 24,4 m 27,0 m
где I0 является интенсивностью наиболее интенсивного пика, которой присваивают значение 100,
w является слабой относительной интенсивностью от 0 до 20%,
m является средней относительной интенсивностью от 20 до 40%,
f является сильной относительной интенсивностью от 40 до 60% и
mf является очень сильной относительной интенсивностью от 60 до 100%.
21. Способ по любому из пп. 2-18, в котором ITQ-55 имеет каркас из тетраэдрических (Т) атомов, соединенных мостиковыми атомами, при этом тетраэдрический атом определяют его соединениями с ближайшими Т атомами, как описано в следующей таблице:
Соединения тетраэдрических атомов в ITQ-55 Т атом Соединен с Т1 Т6, T7, Т55, Т73 T2 Т3, Т5, Т9, Т56 Т3 Т2, Т7, Т21, Т27 Т4 Т8, Т9, Т58, Т73 Т5 Т2, Т8, Т52, Т59 Т6 Т1, Т8, Т53, Т60 T7 Т1, Т3, Т50, Т61 Т8 Т4, Т5, Т6, Т51 Т9 T2, T4, T21, T63 Т10 Т15, Т16, Т64, Т74 Т11 Т12, Т14, Т18, Т65 Т12 Т11, Т16, Т30, Т36 Т13 Т17, Т18, Т67, Т74 Т14 T11, T17, T43, T68 Т15 Т10, Т17, Т44, Т69 Т16 Т10, Т12, Т41, Т70 Т17 Т13, Т14, Т15, Т42 Т18 Т11, Т13, Т30, Т72 Т19 Т24, Т25, Т37, Т73 Т20 Т21, Т23, Т27, Т38 Т21 Т3, Т9, Т20, Т25 Т22 Т26, Т27, Т40, Т73 Т23 T20, T26, T41, T70 Т24 Т19, Т26, Т42, Т71
Т25 Т19, Т21, Т43, Т68 Т26 Т22, Т23, Т24, Т69 Т27 Т3, Т20, Т22, Т45 Т28 Т33, Т34, Т46, Т74 Т29 Т30, Т32, Т36, Т47 Т30 Т12, Т18, Т29, Т34 Т31 Т35, Т36, Т49, Т74 Т32 Т29, Т36, Т50, Т61 Т33 Т28, Т35, Т51, Т62 Т34 Т28, Т30, Т52, Т59 Т35 Т31, Т32, Т33, Т60 Т36 Т12, Т29, Т31, Т54 Т37 Т19, Т42, Т43, Т75 Т38 Т20, Т39, Т41, Т45 Т39 Т38, Т43, Т57, Т63 Т40 Т22, Т44, Т45, Т75 Т41 Т16, Т23, Т38, Т44 Т42 Т17, Т24, Т37, Т44 Т43 Т14, Т25, Т37, Т39 Т44 Т15, Т40, Т41, Т42 Т45 Т27, Т38, Т40, Т57 Т46 Т28, Т51, Т52, Т76 Т47 Т29, Т48, Т50, Т54 Т48 Т47, Т52, Т66, Т72 Т49 Т31, Т53, Т54, Т76 Т50 Т7, Т32, Т47, Т53 Т51 Т8, Т33, Т46, Т53
Т52 Т5, Т34, Т46, Т48 Т53 Т6, Т49, Т50, Т51 Т54 Т36, Т47, Т49, Т66 Т55 Т1, Т60, Т61, Т75 Т56 Т2, Т57, Т59, Т63 Т57 Т39, Т45, Т56, Т61 Т58 Т4, Т62, Т63, Т75 Т59 Т5, Т34, Т56, Т62 Т60 Т6, Т35, Т55, Т62 Т61 Т7, Т32, Т55, Т57 Т62 Т33, Т58, Т59, Т60 Т63 Т9, Т39, Т56, Т58 Т64 Т10, Т69, Т70, Т76 Т65 Т11, Т66, Т68 Т72 Т66 Т48, Т54, Т65, Т70 Т67 Т13, Т71, Т72, Т76 Т68 Т14, Т25, Т65, Т71 Т69 Т15, Т26, Т64, Т71 Т70 Т16, Т23, Т64, Т66 Т71 Т24, Т67, Т68, Т69 Т72 Т18, Т48, Т65, Т67 Т73 Т1, Т4, Т19, Т22 Т74 Т10, Т13, Т28, Т31 Т75 Т37, Т40, Т55, Т58 Т76 Т46, Т49, Т64, Т67
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