RU2011103676A - Высокоэффективный газофазный способ модификации и функционализации углеродных нановолокон парами азотной кислоты - Google Patents

Высокоэффективный газофазный способ модификации и функционализации углеродных нановолокон парами азотной кислоты Download PDF

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RU2011103676A
RU2011103676A RU2011103676/05A RU2011103676A RU2011103676A RU 2011103676 A RU2011103676 A RU 2011103676A RU 2011103676/05 A RU2011103676/05 A RU 2011103676/05A RU 2011103676 A RU2011103676 A RU 2011103676A RU 2011103676 A RU2011103676 A RU 2011103676A
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Prior art keywords
carbon fibers
range
reactor
carbon
nitric acid
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RU2011103676/05A
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English (en)
Russian (ru)
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Мартин МУЛЕР (DE)
Мартин МУЛЕР
Вей КСИА (DE)
Вей КСИА
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Байер МатириальСайенс АГ (DE)
Байер Матириальсайенс Аг
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Publication of RU2011103676A publication Critical patent/RU2011103676A/ru

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    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
    • D01F11/10—Chemical after-treatment of artificial filaments or the like during manufacture of carbon
    • D01F11/12—Chemical after-treatment of artificial filaments or the like during manufacture of carbon with inorganic substances ; Intercalation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • B01J20/205—Carbon nanostructures, e.g. nanotubes, nanohorns, nanocones, nanoballs
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B01J20/28007—Sorbent size or size distribution, e.g. particle size with size in the range 1-100 nanometers, e.g. nanosized particles, nanofibers, nanotubes, nanowires or the like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28023—Fibres or filaments
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B01J20/28059—Surface area, e.g. B.E.T specific surface area being less than 100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B01J20/28061—Surface area, e.g. B.E.T specific surface area being in the range 100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B01J21/185—Carbon nanotubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
    • C08J5/043—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with glass fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/64—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with nitrogen oxides; with oxyacids of nitrogen or their salts
    • D06M11/65—Salts of oxyacids of nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Textile Engineering (AREA)
  • Composite Materials (AREA)
  • General Physics & Mathematics (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Fibers (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Catalysts (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
RU2011103676/05A 2008-07-03 2009-06-27 Высокоэффективный газофазный способ модификации и функционализации углеродных нановолокон парами азотной кислоты RU2011103676A (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102008031579.6 2008-07-03
DE102008031579A DE102008031579A1 (de) 2008-07-03 2008-07-03 Ein hocheffizientes Gasphasenverfahren zur Modifizierung und Funktionalisierung von Kohlenstoff-Nanofasern mit Salpetersäuredampf

Publications (1)

Publication Number Publication Date
RU2011103676A true RU2011103676A (ru) 2012-08-10

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RU2011103676/05A RU2011103676A (ru) 2008-07-03 2009-06-27 Высокоэффективный газофазный способ модификации и функционализации углеродных нановолокон парами азотной кислоты

Country Status (11)

Country Link
US (1) US20110104492A1 (https=)
EP (1) EP2297386A2 (https=)
JP (1) JP2011526331A (https=)
KR (1) KR20110027723A (https=)
CN (1) CN102099515A (https=)
AU (1) AU2009266063A1 (https=)
BR (1) BRPI0915597A2 (https=)
CA (1) CA2729693A1 (https=)
DE (1) DE102008031579A1 (https=)
RU (1) RU2011103676A (https=)
WO (1) WO2010000424A2 (https=)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8333900B1 (en) * 2008-06-27 2012-12-18 E I Du Pont De Nemours And Company Selective etching of single walled carbon nanotubes
CN102153069B (zh) * 2011-02-25 2012-12-19 中国科学院长春应用化学研究所 一种纳米碳材料的处理方法
KR20120105827A (ko) * 2011-03-16 2012-09-26 삼성전자주식회사 정착장치용 발열체, 이를 구비한 정착장치 및 화상형성장치
CN102424379B (zh) * 2011-09-20 2013-11-20 奇瑞汽车股份有限公司 一种高分散性碳纳米管的制备方法
CN102424973A (zh) * 2011-12-26 2012-04-25 昆山全亚冠环保科技有限公司 一种鎳銅合金金相腐蚀剂
CN104018340B (zh) * 2014-06-12 2015-12-09 航天精工股份有限公司 一种连续碳纤维表面改性方法
CN117385630A (zh) * 2014-12-09 2024-01-12 国立大学法人 东京大学 表面处理碳纤维、表面处理碳纤维束及它们的制造方法
CN106215949A (zh) * 2016-08-02 2016-12-14 上海应用技术学院 一种低温选择性催化还原脱硝催化剂及其制备方法
JP6857806B2 (ja) 2016-12-05 2021-04-14 パナソニックＩｐマネジメント株式会社 燃料電池用の金属粒子担持触媒およびその製造方法、およびその触媒を用いた燃料電池
CN109847706A (zh) * 2019-02-12 2019-06-07 广州大学 一种表面官能团功能化水热炭吸附剂及其制备方法与应用
CN111139646A (zh) * 2020-01-14 2020-05-12 贵州大学 一种改性碳纤维及其与尼龙6复合材料的制备

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4729820A (en) * 1986-05-30 1988-03-08 Amoco Corporation Multielectrolyte shear treatment of carbon fibers
JPH02118121A (ja) * 1988-10-25 1990-05-02 Osaka Gas Co Ltd ピッチ系活性炭素繊維およびその製造方法
JPH06166953A (ja) * 1992-11-25 1994-06-14 Osaka Gas Co Ltd 炭素繊維の表面処理方法および炭素繊維
EP1061042A1 (en) * 1999-06-15 2000-12-20 Iljin Nanotech Co., Ltd. Method for gas phase purification of carbon nanotubes by thermal treatment in diffusion furnace
KR100382878B1 (ko) * 1999-06-15 2003-05-09 일진나노텍 주식회사 고순도 탄소나노튜브의 합성 방법
JP2002177702A (ja) 2000-12-08 2002-06-25 Sony Corp カーボンナノ構造体の一段階精製用の超音波還流システム
HU230180B1 (hu) * 2001-02-21 2015-09-28 Basf Ag Eljárás D-pantoténsav és/vagy sói előállítására állati takarmányadalékként
WO2003040446A2 (en) * 2001-06-15 2003-05-15 The Pennsylvania State Research Foundation Method of purifying nanotubes and nanofibers using electromagnetic radiation
JP2005001980A (ja) * 2003-04-23 2005-01-06 Samsung Corning Co Ltd 流動化方式を用いた炭素ナノ構造体の処理方法
US7144949B2 (en) * 2003-12-11 2006-12-05 The Aerospace Corporation Synthetic method for conducting polymer nanofibers
KR100533414B1 (ko) * 2004-05-12 2005-12-02 한국전력공사 활성탄소섬유의 질산 표면처리장치 및 표면처리방법
US20080031802A1 (en) * 2004-10-22 2008-02-07 Hyperion Catalysis International, Inc. Ozonolysis of carbon nanotubes
DE102004054959A1 (de) * 2004-11-13 2006-05-18 Bayer Technology Services Gmbh Katalysator zur Herstellung von Kohlenstoffnanoröhrchen durch Zersetzung von gas-förmigen Kohlenverbindungen an einem heterogenen Katalysator
DE102006007147A1 (de) * 2006-02-16 2007-08-23 Bayer Technology Services Gmbh Verfahren zur kontinuierlichen Herstellung von Katalysatoren
DE102007044031A1 (de) * 2007-09-14 2009-03-19 Bayer Materialscience Ag Kohlenstoffnanoröhrchenpulver, Kohlenstoffnanoröhrchen und Verfahren zu ihrer Herstellung
KR101001385B1 (ko) * 2008-04-23 2010-12-14 한화케미칼 주식회사 탄소나노튜브의 연속적인 표면처리 방법 및 장치

Also Published As

Publication number Publication date
AU2009266063A1 (en) 2010-01-07
EP2297386A2 (de) 2011-03-23
BRPI0915597A2 (pt) 2019-08-27
WO2010000424A3 (de) 2010-12-29
US20110104492A1 (en) 2011-05-05
CA2729693A1 (en) 2010-01-07
KR20110027723A (ko) 2011-03-16
CN102099515A (zh) 2011-06-15
WO2010000424A2 (de) 2010-01-07
DE102008031579A1 (de) 2010-01-07
JP2011526331A (ja) 2011-10-06

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