RU2010101711A - Способ и устройство для получения спиртов из синтетического газа - Google Patents
Способ и устройство для получения спиртов из синтетического газа Download PDFInfo
- Publication number
- RU2010101711A RU2010101711A RU2010101711/04A RU2010101711A RU2010101711A RU 2010101711 A RU2010101711 A RU 2010101711A RU 2010101711/04 A RU2010101711/04 A RU 2010101711/04A RU 2010101711 A RU2010101711 A RU 2010101711A RU 2010101711 A RU2010101711 A RU 2010101711A
- Authority
- RU
- Russia
- Prior art keywords
- specified
- reaction zone
- catalyst
- methanol
- synthetic gas
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract 70
- 150000001298 alcohols Chemical class 0.000 title claims abstract 14
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract 87
- 238000006243 chemical reaction Methods 0.000 claims abstract 51
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract 49
- 239000003054 catalyst Substances 0.000 claims abstract 31
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract 24
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims abstract 21
- 230000015572 biosynthetic process Effects 0.000 claims abstract 12
- 238000003786 synthesis reaction Methods 0.000 claims abstract 12
- 239000000203 mixture Substances 0.000 claims 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 11
- 239000013067 intermediate product Substances 0.000 claims 9
- 239000000126 substance Substances 0.000 claims 9
- 229910004298 SiO 2 Inorganic materials 0.000 claims 7
- 239000000047 product Substances 0.000 claims 7
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims 6
- 239000002808 molecular sieve Substances 0.000 claims 6
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims 6
- 238000001035 drying Methods 0.000 claims 5
- 239000000446 fuel Substances 0.000 claims 5
- 239000012528 membrane Substances 0.000 claims 5
- 239000012264 purified product Substances 0.000 claims 5
- 238000004821 distillation Methods 0.000 claims 4
- 239000012071 phase Substances 0.000 claims 4
- 239000011148 porous material Substances 0.000 claims 4
- 239000007790 solid phase Substances 0.000 claims 4
- 229910021536 Zeolite Inorganic materials 0.000 claims 3
- 239000002274 desiccant Substances 0.000 claims 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 3
- 239000010457 zeolite Substances 0.000 claims 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- 229910052799 carbon Inorganic materials 0.000 claims 2
- 238000002485 combustion reaction Methods 0.000 claims 2
- 239000007788 liquid Substances 0.000 claims 2
- 239000007858 starting material Substances 0.000 claims 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
- C07C27/04—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by reduction of oxygen-containing compounds
- C07C27/06—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by reduction of oxygen-containing compounds by hydrogenation of oxides of carbon
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/32—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/26—Chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/19—Catalysts containing parts with different compositions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/20—Sulfiding
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1516—Multisteps
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1516—Multisteps
- C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US94865707P | 2007-07-09 | 2007-07-09 | |
| US94865007P | 2007-07-09 | 2007-07-09 | |
| US60/948,650 | 2007-07-09 | ||
| US60/948,657 | 2007-07-09 | ||
| US12/166,203 | 2008-07-01 | ||
| US12/166,212 US9227895B2 (en) | 2007-07-09 | 2008-07-01 | Methods and apparatus for producing alcohols from syngas |
| US12/166,212 | 2008-07-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2010101711A true RU2010101711A (ru) | 2011-08-20 |
Family
ID=41580944
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2010101711/04A RU2010101711A (ru) | 2007-07-09 | 2008-07-02 | Способ и устройство для получения спиртов из синтетического газа |
Country Status (12)
| Country | Link |
|---|---|
| EP (1) | EP2173694B1 (pt) |
| CN (4) | CN104725186A (pt) |
| AU (1) | AU2008275349B2 (pt) |
| BR (1) | BRPI0812602A2 (pt) |
| CA (1) | CA2693476C (pt) |
| DK (1) | DK2173694T3 (pt) |
| ES (1) | ES2616306T3 (pt) |
| HU (1) | HUE031684T2 (pt) |
| MX (1) | MX2010000233A (pt) |
| PL (1) | PL2173694T3 (pt) |
| RU (1) | RU2010101711A (pt) |
| WO (1) | WO2009009389A2 (pt) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8614257B2 (en) | 2010-02-08 | 2013-12-24 | Fulcrum Bioenergy, Inc. | Product recycle loops in process for converting municipal solid waste into ethanol |
| US11525097B2 (en) | 2010-02-08 | 2022-12-13 | Fulcrum Bioenergy, Inc. | Feedstock processing systems and methods for producing fischer-tropsch liquids and transportation fuels |
| BR112013025081A2 (pt) * | 2011-04-01 | 2017-02-14 | Dow Global Technologies Llc | catalisador para conversão de gás de síntese e processo para produzir um ou mais alcoóis c2-c4 |
| CN104870413B (zh) * | 2012-12-20 | 2017-07-28 | 托普索公司 | 生产高级醇的方法和设备 |
| US9290425B2 (en) * | 2013-06-20 | 2016-03-22 | Standard Alcohol Company Of America, Inc. | Production of mixed alcohols from synthesis gas |
| US10875820B2 (en) | 2013-06-20 | 2020-12-29 | Standard Alcohol Company Of America, Inc. | Catalyst for converting syngas to mixed alcohols |
| CN104892361A (zh) * | 2014-03-04 | 2015-09-09 | 中国科学院大连化学物理研究所 | 一种催化转化甲醇制备丙醇的方法 |
| CN104892362A (zh) * | 2014-03-04 | 2015-09-09 | 中国科学院大连化学物理研究所 | 一种催化转化甲醇制备丁醇的方法 |
| CN104892360A (zh) * | 2014-03-04 | 2015-09-09 | 中国科学院大连化学物理研究所 | 一种催化转化甲醇制备乙醇的新方法 |
| DE102016006710A1 (de) * | 2016-06-01 | 2017-12-07 | Linde Aktiengesellschaft | Verfahren und Anlage zur Herstellung von Ethanol |
| DE102016006709A1 (de) * | 2016-06-01 | 2017-12-07 | Linde Aktiengesellschaft | Verfahren und Anlage zur Herstellung von Ethanol |
| DE102016006713A1 (de) * | 2016-06-01 | 2017-12-07 | Linde Aktiengesellschaft | Verfahren und Anlage zur Herstellung von Ethanol |
| CA3104273A1 (en) * | 2018-06-29 | 2020-01-02 | Dow Global Technologies Llc | Hybrid catalysts comprising a mixed metal oxide component for production of c2 and c3 hydrocarbons |
| CN109126818B (zh) * | 2018-08-17 | 2021-12-07 | 新奥科技发展有限公司 | 一种复合催化剂及其制备方法 |
| CN109503324A (zh) * | 2019-01-09 | 2019-03-22 | 珠海经济特区方源有限公司 | 一种回收甲醇不合格品处理方法 |
| CN112898123B (zh) * | 2019-11-19 | 2022-02-11 | 中国科学院大连化学物理研究所 | 一种制备丙醇的方法 |
| BR112023002922A2 (pt) * | 2020-09-25 | 2023-04-04 | China Petroleum & Chem Corp | Processo para a produção de isobutanol |
| WO2024194205A1 (en) | 2023-03-17 | 2024-09-26 | Basf Se | Process for producing 2-propanol |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3375175A (en) * | 1965-01-21 | 1968-03-26 | Fmc Corp | Pyrolysis of coal |
| IT1140947B (it) * | 1980-05-16 | 1986-10-10 | Snam Progetti | Processo per la produzione di una miscela di metanolo ed alcoli superiori "grado carburante" |
| US4692432A (en) * | 1981-07-15 | 1987-09-08 | Georgia Tech Research Corporation | Two cycle process for producing fuel-grade ethanol from dilute aqueous mixtures |
| US4405343A (en) * | 1982-09-01 | 1983-09-20 | Othmer Donald F | Methanol dehydration |
| CN1008087B (zh) * | 1984-02-02 | 1990-05-23 | 金属股份有限公司 | 甲醇和高级醇类混合物的生产方法 |
| US4725626A (en) * | 1985-08-05 | 1988-02-16 | The Standard Oil Company | Manufacture of alcohols from synthesis gas |
| US4670473A (en) * | 1985-08-09 | 1987-06-02 | Amoco Corporation | Syn gas conversion |
| US6316683B1 (en) * | 1999-06-07 | 2001-11-13 | Exxonmobil Chemical Patents Inc. | Protecting catalytic activity of a SAPO molecular sieve |
| US6723886B2 (en) * | 1999-11-17 | 2004-04-20 | Conocophillips Company | Use of catalytic distillation reactor for methanol synthesis |
| JP2003528067A (ja) * | 2000-03-22 | 2003-09-24 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | オレフィンからアルコールを調製するための方法 |
| US6863878B2 (en) * | 2001-07-05 | 2005-03-08 | Robert E. Klepper | Method and apparatus for producing synthesis gas from carbonaceous materials |
| CN1167502C (zh) * | 2001-11-23 | 2004-09-22 | 中国科学院山西煤炭化学研究所 | 一种由合成气制低碳混合醇的催化剂及其制备方法 |
| CA2469653C (en) * | 2001-12-18 | 2011-10-25 | Jerrel Dale Branson | System and method for extracting energy from agricultural waste |
| ITTO20020643A1 (it) * | 2002-07-23 | 2004-01-23 | Fiat Ricerche | Pila a combustibile ad alcool diretto e relativo metodo di realizzazione |
| US7288689B2 (en) * | 2003-11-19 | 2007-10-30 | Exxonmobil Chemical Patents Inc. | Methanol and fuel alcohol production for an oxygenate to olefin reaction system |
| US7196239B2 (en) * | 2003-11-19 | 2007-03-27 | Exxonmobil Chemical Patents Inc. | Methanol and ethanol production for an oxygenate to olefin reaction system |
| US7384987B2 (en) * | 2004-06-01 | 2008-06-10 | Syntec Biofuel, Inc. | Catalysts and processes for the manufacture of lower aliphatic alcohols from syngas |
| CN1974732A (zh) * | 2006-12-13 | 2007-06-06 | 太原理工大学 | 气化煤气和热解煤气共制合成气工艺 |
-
2008
- 2008-07-02 AU AU2008275349A patent/AU2008275349B2/en not_active Ceased
- 2008-07-02 ES ES08772376.3T patent/ES2616306T3/es active Active
- 2008-07-02 RU RU2010101711/04A patent/RU2010101711A/ru unknown
- 2008-07-02 CN CN201510026198.5A patent/CN104725186A/zh active Pending
- 2008-07-02 HU HUE08772376A patent/HUE031684T2/en unknown
- 2008-07-02 MX MX2010000233A patent/MX2010000233A/es active IP Right Grant
- 2008-07-02 CA CA2693476A patent/CA2693476C/en not_active Expired - Fee Related
- 2008-07-02 PL PL08772376T patent/PL2173694T3/pl unknown
- 2008-07-02 DK DK08772376.3T patent/DK2173694T3/en active
- 2008-07-02 CN CN2012104742355A patent/CN103121922A/zh active Pending
- 2008-07-02 EP EP08772376.3A patent/EP2173694B1/en active Active
- 2008-07-02 CN CN201810939088.1A patent/CN109160872A/zh active Pending
- 2008-07-02 BR BRPI0812602A patent/BRPI0812602A2/pt not_active IP Right Cessation
- 2008-07-02 CN CN200880024056A patent/CN101730674A/zh active Pending
- 2008-07-02 WO PCT/US2008/069071 patent/WO2009009389A2/en active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| PL2173694T3 (pl) | 2017-06-30 |
| CN109160872A (zh) | 2019-01-08 |
| AU2008275349B2 (en) | 2013-12-19 |
| WO2009009389A3 (en) | 2009-03-12 |
| EP2173694A2 (en) | 2010-04-14 |
| EP2173694A4 (en) | 2013-08-14 |
| CA2693476C (en) | 2017-11-28 |
| AU2008275349A1 (en) | 2009-01-15 |
| CN104725186A (zh) | 2015-06-24 |
| MX2010000233A (es) | 2010-06-02 |
| HUE031684T2 (en) | 2017-07-28 |
| CN103121922A (zh) | 2013-05-29 |
| WO2009009389A2 (en) | 2009-01-15 |
| ES2616306T3 (es) | 2017-06-12 |
| EP2173694B1 (en) | 2016-11-23 |
| CA2693476A1 (en) | 2009-01-15 |
| DK2173694T3 (en) | 2017-03-06 |
| CN101730674A (zh) | 2010-06-09 |
| BRPI0812602A2 (pt) | 2019-09-24 |
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