RU2008142366A - Гидрирование ароматических соединений - Google Patents

Гидрирование ароматических соединений Download PDF

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RU2008142366A
RU2008142366A RU2008142366/04A RU2008142366A RU2008142366A RU 2008142366 A RU2008142366 A RU 2008142366A RU 2008142366/04 A RU2008142366/04 A RU 2008142366/04A RU 2008142366 A RU2008142366 A RU 2008142366A RU 2008142366 A RU2008142366 A RU 2008142366A
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hydrogenated cyclic
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Дж Юн РЮ (US)
Дж Юн РЮ
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Каталитик Дистиллейшн Текнолоджиз (Us)
Каталитик Дистиллейшн Текнолоджиз
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Abstract

1. Способ гидрирования ароматических соединений в реакционном потоке, включающий контактирование указанного реакционного потока с водородом в условиях давления и температуры для реагирования водорода и ароматических соединений в присутствии катализатора, включающего от 4 до 14 мас.% Ni и от 0,0 до около 0,9 мас.% Cu, нанесенных на носитель из переходного оксида алюминия, имеющий удельную площадь поверхности по методу ВЕТ от около 40 до 180 м2/г и объем пор от около 0,3 до около 0,8 см3/г, для получения гидрированного циклического соединения. ! 2. Способ по п.1, в котором содержание Cu составляет от около 0,2 до 0,4 мас.%. ! 3. Способ по п.2, в котором содержание Ni в катализаторе составляет от около 9 до 10 мас.% и. ! 4. Способ по п.2, в котором катализатор содержит один или более модифицирующих компонентов, выбранных из группы, состоящей из Ag, Ru, Re, Zn, Mo и Pd. ! 5. Способ по п.1, в котором бензол присутствует в реакционном потоке в количестве от 1 до 60 мас.%, и гидрированное циклическое соединение включает циклогексан. ! 6. Способ по п.1, который проводят в присутствии растворителя, имеющего температуру кипения по меньшей мере на 10°F выше, чем у гидрируемого ароматического соединения и гидрированного циклического соединения. ! 7. Способ по п.6, в котором содержание Cu составляет от около 0,2 до 0,4 мас.%. ! 8. Способ по п.7, в котором содержание Ni в катализаторе составляет от около 9 до 10 мас.% и. ! 9. Способ по п.7, в котором катализатор содержит один или более модифицирующих компонентов, выбранных из группы, состоящей из Ag, Ru, Re, Zn, Mo и Pd. ! 10. Способ по п.6, в котором бензол присутствует в реакционном потоке в количестве от 1 до 60 мас.%, и гидрированное циклическое соединение вк�

Claims (12)

1. Способ гидрирования ароматических соединений в реакционном потоке, включающий контактирование указанного реакционного потока с водородом в условиях давления и температуры для реагирования водорода и ароматических соединений в присутствии катализатора, включающего от 4 до 14 мас.% Ni и от 0,0 до около 0,9 мас.% Cu, нанесенных на носитель из переходного оксида алюминия, имеющий удельную площадь поверхности по методу ВЕТ от около 40 до 180 м2/г и объем пор от около 0,3 до около 0,8 см3/г, для получения гидрированного циклического соединения.
2. Способ по п.1, в котором содержание Cu составляет от около 0,2 до 0,4 мас.%.
3. Способ по п.2, в котором содержание Ni в катализаторе составляет от около 9 до 10 мас.% и.
4. Способ по п.2, в котором катализатор содержит один или более модифицирующих компонентов, выбранных из группы, состоящей из Ag, Ru, Re, Zn, Mo и Pd.
5. Способ по п.1, в котором бензол присутствует в реакционном потоке в количестве от 1 до 60 мас.%, и гидрированное циклическое соединение включает циклогексан.
6. Способ по п.1, который проводят в присутствии растворителя, имеющего температуру кипения по меньшей мере на 10°F выше, чем у гидрируемого ароматического соединения и гидрированного циклического соединения.
7. Способ по п.6, в котором содержание Cu составляет от около 0,2 до 0,4 мас.%.
8. Способ по п.7, в котором содержание Ni в катализаторе составляет от около 9 до 10 мас.% и.
9. Способ по п.7, в котором катализатор содержит один или более модифицирующих компонентов, выбранных из группы, состоящей из Ag, Ru, Re, Zn, Mo и Pd.
10. Способ по п.6, в котором бензол присутствует в реакционном потоке в количестве от 1 до 60 мас.%, и гидрированное циклическое соединение включает циклогексан.
11. Способ по п.6, в котором растворитель составляет от 10 до 90 мас.% реакционного потока.
12. Модифицированный медью никелевый катализатор для применения в гидрировании ароматического соединения с получением гидрированного циклического соединения, включающий от 4 до 14 мас.% Ni и от около 0,2 до 0,4 мас.% Cu, нанесенных на носитель из переходного оксида алюминия, имеющего удельную площадь поверхности по методу ВЕТ от около 40 до 180 м2/г и объем пор от около 0,3 до около 0,8 см3/г.
RU2008142366/04A 2006-03-27 2006-11-22 Гидрирование ароматических соединений RU2391326C1 (ru)

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US11/389,955 US7348463B2 (en) 2006-03-27 2006-03-27 Hydrogenation of aromatic compounds
US11/389,955 2006-03-27

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US (2) US7348463B2 (ru)
EP (1) EP1999101A4 (ru)
JP (1) JP2009531426A (ru)
KR (1) KR20080108140A (ru)
CN (2) CN101045669B (ru)
RU (1) RU2391326C1 (ru)
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TW200736209A (en) 2007-10-01
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US20080139383A1 (en) 2008-06-12
RU2391326C1 (ru) 2010-06-10
CN101045669B (zh) 2011-07-13
JP2009531426A (ja) 2009-09-03
US7348463B2 (en) 2008-03-25
KR20080108140A (ko) 2008-12-11
EP1999101A1 (en) 2008-12-10
WO2007126421A1 (en) 2007-11-08

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