RO86842B - Procedeu de preparare a unor fosforoditionati - Google Patents
Procedeu de preparare a unor fosforoditionatiInfo
- Publication number
- RO86842B RO86842B RO110794A RO11079483A RO86842B RO 86842 B RO86842 B RO 86842B RO 110794 A RO110794 A RO 110794A RO 11079483 A RO11079483 A RO 11079483A RO 86842 B RO86842 B RO 86842B
- Authority
- RO
- Romania
- Prior art keywords
- carbon atoms
- alkyl group
- general formula
- phosphorodithioates
- preparation
- Prior art date
Links
- NAGJZTKCGNOGPW-UHFFFAOYSA-N dithiophosphoric acid Chemical class OP(O)(S)=S NAGJZTKCGNOGPW-UHFFFAOYSA-N 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000001309 chloro group Chemical group Cl* 0.000 abstract 2
- AFINAILKDBCXMX-PBHICJAKSA-N (2s,3r)-2-amino-3-hydroxy-n-(4-octylphenyl)butanamide Chemical compound CCCCCCCCC1=CC=C(NC(=O)[C@@H](N)[C@@H](C)O)C=C1 AFINAILKDBCXMX-PBHICJAKSA-N 0.000 abstract 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 1
- 150000001447 alkali salts Chemical class 0.000 abstract 1
- 125000001589 carboacyl group Chemical group 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/17—Esters of thiophosphoric acids with hydroxyalkyl compounds without further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/177—Esters of thiophosphoric acids with cycloaliphatic alcohols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Dentistry (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Inventia se refera la un procedeu de preparare a unor fosforoditionati cu formula generala I: (vezi formula) în care R este o grupa alchil cu 4...8 atomi de carbon alfa-ramificata sau cicloalchil cu 5...8 atomi carbon, R1 este o grupa alchil cu 1...8atomi de carbon liniara sau ramificata, R2 este o grupa alchil cu 1...4 atomi de carbon, care consta în aceea ca se trateaza un derivat de acid fosforic cu formula generala II.(vezi formula) în care R2 are semnificatiile de mai sus si Z este o grupa-SR1 în care R1 are semnificatiile de mai sus sau un atom de clor, cu o sare alcalina a unui alcantiol cu formula generala III: (vezi formula) în care R are semnificatiile de mai sus, raportul molar între reactanti fiind 1:1 cînd Z este -SR1 si 1:2cînd Z este clor si R are aceleasi semnificatii cu R1, reactia avînd loc la o temperatura între 0 degree C si la temperatura camerei, în mediu de tetrahidrofuran, dupa care produsul se izoleaza în mod în sine cunoscut.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US29743781A | 1981-08-28 | 1981-08-28 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RO86842A RO86842A (ro) | 1985-05-20 |
| RO86842B true RO86842B (ro) | 1985-06-01 |
Family
ID=23146312
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RO110794A RO86842B (ro) | 1981-08-28 | 1983-04-27 | Procedeu de preparare a unor fosforoditionati |
Country Status (22)
| Country | Link |
|---|---|
| EP (1) | EP0086826B1 (ro) |
| JP (1) | JPS58501378A (ro) |
| KR (1) | KR850001920B1 (ro) |
| AR (1) | AR242216A1 (ro) |
| AU (1) | AU550206B2 (ro) |
| BR (1) | BR8207835A (ro) |
| CA (1) | CA1213605A (ro) |
| DD (1) | DD204028A5 (ro) |
| DE (1) | DE3268671D1 (ro) |
| DK (1) | DK160504C (ro) |
| ES (1) | ES8400447A1 (ro) |
| GR (1) | GR77244B (ro) |
| HU (1) | HU186981B (ro) |
| IE (1) | IE53185B1 (ro) |
| IL (1) | IL66628A (ro) |
| IT (1) | IT1203691B (ro) |
| MX (1) | MX6975E (ro) |
| OA (1) | OA08301A (ro) |
| PH (1) | PH20379A (ro) |
| RO (1) | RO86842B (ro) |
| WO (1) | WO1983000870A1 (ro) |
| ZA (1) | ZA826300B (ro) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4535077A (en) * | 1981-08-28 | 1985-08-13 | Fmc Corporation | O-ethyl S,S-dialkyl phosphorodithioates for use as pesticides |
| JPS5978198A (ja) * | 1982-10-25 | 1984-05-04 | Sumitomo Chem Co Ltd | ジチオ−ルりん酸エステル、その製造法およびそれを有効成分とする土壌害虫防除剤 |
| US4596796A (en) * | 1983-09-12 | 1986-06-24 | Sumitomo Chemical Company, Limited | Dithiolphosphoric acid ester as a soil pesticide |
| JPS6089490A (ja) * | 1983-10-12 | 1985-05-20 | Sumitomo Chem Co Ltd | トリチオリン酸エステル、その製造法およびそれを有効成分とする土壌害虫防除剤 |
| AU565903B2 (en) * | 1983-11-04 | 1987-10-01 | Sumitomo Chemical Company, Limited | Trithiophosphoric acid ester |
| DE102007045955A1 (de) | 2007-09-26 | 2009-04-09 | Bayer Cropscience Ag | Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften |
| ES2527833T3 (es) | 2009-03-25 | 2015-01-30 | Bayer Cropscience Ag | Combinaciones de principios activos nematicidas que comprenden fluopiram y otro principio activo |
| EP2410847A1 (de) | 2009-03-25 | 2012-02-01 | Bayer CropScience AG | Wirkstoffkombinationen mit insektiziden und akariziden eigenschaften |
| MX2017010115A (es) * | 2015-02-06 | 2017-11-01 | Ishihara Sangyo Kaisha | Composicion pesticida y metodo para controlar plagas. |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1238013B (de) * | 1965-07-08 | 1967-04-06 | Bayer Ag | Verfahren zur Herstellung von Dithiolphosphorsaeureestern |
| BE786068A (fr) * | 1971-07-12 | 1973-01-10 | Bayer Ag | Nouveaux esters d'acides organophosphoriques, leur preparation et leur application comme insecticides et nematicides |
| JPS55141495A (en) * | 1979-04-20 | 1980-11-05 | Sumitomo Chem Co Ltd | O-ethyl s-alkyl s-isopropylphosphorodithiolate and nematocide comprising it as active constituent |
| US4383991A (en) * | 1981-06-23 | 1983-05-17 | Rhone-Poulenc Agrochimie | O-Alkyl-S-alkyl-S-branched alkylphosphorodithioate soil insecticides |
-
1982
- 1982-08-06 CA CA000408947A patent/CA1213605A/en not_active Expired
- 1982-08-10 AR AR82290262A patent/AR242216A1/es active
- 1982-08-13 EP EP82902845A patent/EP0086826B1/en not_active Expired
- 1982-08-13 BR BR8207835A patent/BR8207835A/pt not_active IP Right Cessation
- 1982-08-13 DE DE8282902845T patent/DE3268671D1/de not_active Expired
- 1982-08-13 HU HU823333A patent/HU186981B/hu not_active IP Right Cessation
- 1982-08-13 PH PH27730A patent/PH20379A/en unknown
- 1982-08-13 WO PCT/US1982/001102 patent/WO1983000870A1/en active IP Right Grant
- 1982-08-13 AU AU89508/82A patent/AU550206B2/en not_active Expired
- 1982-08-13 JP JP57502909A patent/JPS58501378A/ja active Granted
- 1982-08-23 IL IL66628A patent/IL66628A/xx not_active IP Right Cessation
- 1982-08-26 IT IT23007/82A patent/IT1203691B/it active
- 1982-08-26 IE IE2073/82A patent/IE53185B1/en not_active IP Right Cessation
- 1982-08-27 KR KR8203878A patent/KR850001920B1/ko active
- 1982-08-27 ZA ZA826300A patent/ZA826300B/xx unknown
- 1982-08-27 ES ES515305A patent/ES8400447A1/es not_active Expired
- 1982-08-27 GR GR69137A patent/GR77244B/el unknown
- 1982-08-27 MX MX8210259U patent/MX6975E/es unknown
- 1982-08-27 DD DD82242851A patent/DD204028A5/de not_active IP Right Cessation
- 1982-11-25 OA OA57851A patent/OA08301A/xx unknown
-
1983
- 1983-04-27 RO RO110794A patent/RO86842B/ro unknown
- 1983-04-27 DK DK186683A patent/DK160504C/da not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| DK186683D0 (da) | 1983-04-27 |
| AR242216A1 (es) | 1993-03-31 |
| IL66628A0 (en) | 1982-12-31 |
| JPH0219840B2 (ro) | 1990-05-07 |
| AU550206B2 (en) | 1986-03-06 |
| EP0086826A4 (en) | 1983-12-23 |
| GR77244B (ro) | 1984-09-11 |
| DK160504B (da) | 1991-03-18 |
| IT8223007A0 (it) | 1982-08-26 |
| EP0086826B1 (en) | 1986-01-22 |
| JPS58501378A (ja) | 1983-08-18 |
| OA08301A (fr) | 1987-10-30 |
| KR850001920B1 (ko) | 1985-12-31 |
| IE53185B1 (en) | 1988-08-17 |
| DK186683A (da) | 1983-04-27 |
| DK160504C (da) | 1991-08-26 |
| BR8207835A (pt) | 1983-09-06 |
| KR840000874A (ko) | 1984-03-26 |
| DE3268671D1 (en) | 1986-03-06 |
| EP0086826A1 (en) | 1983-08-31 |
| IE822073L (en) | 1983-02-28 |
| DD204028A5 (de) | 1983-11-16 |
| IT1203691B (it) | 1989-02-15 |
| ES515305A0 (es) | 1983-10-16 |
| MX6975E (es) | 1987-01-14 |
| RO86842A (ro) | 1985-05-20 |
| HU186981B (en) | 1985-10-28 |
| IL66628A (en) | 1987-10-30 |
| ZA826300B (en) | 1983-07-27 |
| PH20379A (en) | 1986-12-08 |
| AU8950882A (en) | 1983-03-28 |
| ES8400447A1 (es) | 1983-10-16 |
| CA1213605A (en) | 1986-11-04 |
| WO1983000870A1 (en) | 1983-03-17 |
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