PT2274412E - Um aparelho e um método para hidrólise térmica contínua de material biológico - Google Patents
Um aparelho e um método para hidrólise térmica contínua de material biológico Download PDFInfo
- Publication number
- PT2274412E PT2274412E PT09727008T PT09727008T PT2274412E PT 2274412 E PT2274412 E PT 2274412E PT 09727008 T PT09727008 T PT 09727008T PT 09727008 T PT09727008 T PT 09727008T PT 2274412 E PT2274412 E PT 2274412E
- Authority
- PT
- Portugal
- Prior art keywords
- reactor
- zone
- temperature
- feed zone
- biological material
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 34
- 238000009283 thermal hydrolysis Methods 0.000 title claims abstract description 19
- 239000012620 biological material Substances 0.000 title claims description 61
- 239000010802 sludge Substances 0.000 claims abstract description 58
- 238000001816 cooling Methods 0.000 claims abstract description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002002 slurry Substances 0.000 claims description 41
- 239000002699 waste material Substances 0.000 claims description 35
- 239000007787 solid Substances 0.000 claims description 30
- 239000000498 cooling water Substances 0.000 claims description 25
- 239000011368 organic material Substances 0.000 claims description 18
- 239000000126 substance Substances 0.000 claims description 16
- 238000011144 upstream manufacturing Methods 0.000 claims description 13
- 238000009835 boiling Methods 0.000 claims description 7
- 238000006460 hydrolysis reaction Methods 0.000 claims description 6
- 230000007062 hydrolysis Effects 0.000 claims description 5
- 239000013043 chemical agent Substances 0.000 claims description 4
- 241000269821 Scombridae Species 0.000 claims 2
- 235000020640 mackerel Nutrition 0.000 claims 2
- 230000003028 elevating effect Effects 0.000 abstract 1
- 238000011282 treatment Methods 0.000 description 13
- 230000014759 maintenance of location Effects 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 230000003068 static effect Effects 0.000 description 5
- 239000013589 supplement Substances 0.000 description 5
- 230000008021 deposition Effects 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000002028 Biomass Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- 238000004065 wastewater treatment Methods 0.000 description 2
- QHZSDTDMQZPUKC-UHFFFAOYSA-N 3,5-dichlorobiphenyl Chemical compound ClC1=CC(Cl)=CC(C=2C=CC=CC=2)=C1 QHZSDTDMQZPUKC-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- CKMXBZGNNVIXHC-UHFFFAOYSA-L ammonium magnesium phosphate hexahydrate Chemical compound [NH4+].O.O.O.O.O.O.[Mg+2].[O-]P([O-])([O-])=O CKMXBZGNNVIXHC-UHFFFAOYSA-L 0.000 description 1
- 230000000721 bacterilogical effect Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 239000002551 biofuel Substances 0.000 description 1
- 229920001222 biopolymer Polymers 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 210000003850 cellular structure Anatomy 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000007071 enzymatic hydrolysis Effects 0.000 description 1
- 238000006047 enzymatic hydrolysis reaction Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 238000009928 pasteurization Methods 0.000 description 1
- 239000010908 plant waste Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 150000003071 polychlorinated biphenyls Chemical class 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000010909 process residue Substances 0.000 description 1
- 239000010822 slaughterhouse waste Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 229910052567 struvite Inorganic materials 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/18—Treatment of sludge; Devices therefor by thermal conditioning
Landscapes
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatment Of Sludge (AREA)
- Processing Of Solid Wastes (AREA)
- Biological Treatment Of Waste Water (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP08153824A EP2107108A1 (en) | 2008-03-31 | 2008-03-31 | An apparatus and a method for continuous thermal hydrolysis of biological material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PT2274412E true PT2274412E (pt) | 2012-08-22 |
Family
ID=39730673
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PT09727008T PT2274412E (pt) | 2008-03-31 | 2009-03-31 | Um aparelho e um método para hidrólise térmica contínua de material biológico |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US20110114570A1 (cg-RX-API-DMAC7.html) |
| EP (2) | EP2107108A1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP5665731B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR101591031B1 (cg-RX-API-DMAC7.html) |
| CN (1) | CN101981175B (cg-RX-API-DMAC7.html) |
| AU (1) | AU2009231506B2 (cg-RX-API-DMAC7.html) |
| BR (1) | BRPI0909262A2 (cg-RX-API-DMAC7.html) |
| CA (1) | CA2719527C (cg-RX-API-DMAC7.html) |
| DK (1) | DK2274412T3 (cg-RX-API-DMAC7.html) |
| ES (1) | ES2390496T3 (cg-RX-API-DMAC7.html) |
| IL (1) | IL208157A (cg-RX-API-DMAC7.html) |
| MX (1) | MX2010010420A (cg-RX-API-DMAC7.html) |
| PL (1) | PL2274412T3 (cg-RX-API-DMAC7.html) |
| PT (1) | PT2274412E (cg-RX-API-DMAC7.html) |
| RU (1) | RU2509730C2 (cg-RX-API-DMAC7.html) |
| WO (1) | WO2009121873A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5329369B2 (ja) * | 2009-11-03 | 2013-10-30 | 株式会社テクノプラン | 汚泥可溶化装置及び汚泥可溶化方法 |
| JP5733683B2 (ja) * | 2011-04-13 | 2015-06-10 | 熱研産業株式会社 | 余剰汚泥移送管の洗浄装置 |
| KR101110870B1 (ko) * | 2011-06-27 | 2012-02-15 | 주식회사 미래지앤씨 | 하수 슬러지 처리장치 |
| WO2013117686A1 (en) | 2012-02-08 | 2013-08-15 | Veolia Water Solutions & Technologies Support | An apparatus for continuous hydrolysis |
| WO2013163998A1 (en) * | 2012-05-03 | 2013-11-07 | Haarslev Industries A/S | Method for continuous treatment of biological material |
| FR2992308B1 (fr) * | 2012-06-20 | 2017-05-12 | Degremont | Procede de traitement de dechets organiques, en particulier de boues de stations d'epuration, et installation pour la mise en œuvre de ce procede |
| CN102775031B (zh) * | 2012-06-26 | 2015-02-25 | 深圳市环源科技发展有限公司 | 污泥加碱加酸催化双热水解处理方法 |
| EP2774894B1 (en) | 2013-03-08 | 2015-07-22 | Aquatec, Proyectos Para El Sector Del Agua, S.A.U. | Continuously operating method for the thermal hydrolysis of organic material and installation for implementing the method |
| US9527760B2 (en) * | 2013-03-09 | 2016-12-27 | Veolia Water Solutions & Technologies Support | Energy efficient system and process for treating sludge |
| FR3003558B1 (fr) | 2013-03-25 | 2015-04-24 | Veolia Water Solutions & Tech | Procede et dispositif d’hydrolyse thermique en continu |
| JP6159573B2 (ja) * | 2013-05-13 | 2017-07-05 | 三菱化工機株式会社 | 有機性廃棄物の処理装置 |
| FR3010403B1 (fr) * | 2013-09-06 | 2017-01-13 | Veolia Water Solutions & Tech | Procede et dispositif d'hydrolyse thermique en continu avec recirculation de vapeur de recuperation |
| FR3015971B1 (fr) * | 2013-12-26 | 2016-01-01 | Veolia Water Solutions & Tech | Procede d'hydrolyse thermique en continu de boues a forte siccite. |
| DE102014108682A1 (de) * | 2014-02-28 | 2015-09-03 | Harnisch Gmbh Filter-, Apparate- Und Anlagenbau | Thermische Hydrolyse von Biomasse |
| DE102014013813A1 (de) * | 2014-09-23 | 2016-03-24 | Bma Braunschweigische Maschinenbauanstalt Ag | Verfahren und Anordnung zur Abwasserbehandlung |
| GB201419096D0 (en) * | 2014-10-27 | 2014-12-10 | Firmenich & Cie | Improved apparatus and method for hydrolysing a product |
| FR3027895B1 (fr) * | 2014-10-31 | 2018-11-09 | Veolia Water Solutions & Technologies Support | Procede et installation pour l'hydrolyse thermique des boues. |
| CN105347637A (zh) * | 2015-12-14 | 2016-02-24 | 北京洁绿科技发展有限公司 | 一种连续式污泥热水解系统及方法 |
| RU2643976C1 (ru) * | 2016-11-08 | 2018-02-06 | Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук (ИК СО РАН) | Реактор для проведения реакций гидролиза |
| CN110650810A (zh) * | 2017-03-15 | 2020-01-03 | 碧奥新能源有限公司 | 用于将进料至沼气反应器的原料卫生化的卫生化单元和方法 |
| EP3782725A1 (en) * | 2019-08-21 | 2021-02-24 | Nederlandse Organisatie voor toegepast- natuurwetenschappelijk Onderzoek TNO | Reactor for the hydrothermal treatment of biomass |
| SE545274C2 (en) * | 2020-06-08 | 2023-06-13 | Valmet Oy | A pre-hydrolysis pressure vessel system comprising a cleaning arrangement |
| JP7638076B2 (ja) * | 2020-09-28 | 2025-03-03 | 三菱重工業株式会社 | 廃棄物処理システム及び廃棄物処理方法 |
Family Cites Families (36)
| Publication number | Priority date | Publication date | Assignee | Title |
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| AT378531B (de) * | 1983-11-11 | 1985-08-26 | Voest Alpine Ag | Verfahren zur herstellung von organischen stoffen oder hydrolysaten aus abwasserschlaemmen zur gewinnung von biotechnisch verwertbaren substraten |
| DK71987D0 (da) * | 1987-02-13 | 1987-02-13 | Nordiske Kabel Traad | Fremgangsmaade til rensning af olie- og kemikalieforurenet jord |
| US4874509A (en) * | 1987-04-24 | 1989-10-17 | Donald Bullock | Oxidation saturation device |
| US4822497A (en) * | 1987-09-22 | 1989-04-18 | Modar, Inc. | Method for solids separation in a wet oxidation type process |
| JPH0779999B2 (ja) * | 1988-01-26 | 1995-08-30 | 日本パーカライジング株式会社 | シアン含有液の処理方法 |
| IT1232670B (it) * | 1989-09-15 | 1992-03-02 | Snam Progetti | Procedimento per la purificazione delle acque reflue prodotte dagli impianti di produzione dell'urea. |
| US5160637A (en) * | 1990-10-19 | 1992-11-03 | Alcan International Limited | Apparatus and method for hydrolysis of cyanide-containing liquids |
| US5556445A (en) * | 1991-04-08 | 1996-09-17 | Mark K. Quinn | Steam treatment of municipal solid waste |
| US5188741A (en) * | 1992-04-01 | 1993-02-23 | Texaco Inc. | Treatment of sewage sludge |
| NO300094B1 (no) * | 1994-09-28 | 1997-04-07 | Cambi As | Fremgangsmate og anordning ved hydrolyse av organisk materiale under reduserende betingelser |
| US5525229A (en) * | 1994-09-14 | 1996-06-11 | North Carolina State University | Process and apparatus for anaerobic digestion |
| US5560823A (en) * | 1994-12-21 | 1996-10-01 | Abitibi-Price, Inc. | Reversible flow supercritical reactor and method for operating same |
| RU2108997C1 (ru) * | 1996-06-18 | 1998-04-20 | Есиев Сергей Саладинович | Технологическая линия для переработки органических материалов и/или отходов, содержащих органические материалы |
| GB9700015D0 (en) * | 1997-01-02 | 1997-02-19 | R3 Management Limited | Treating sewage or like sludge |
| US6077491A (en) * | 1997-03-21 | 2000-06-20 | Ec&C Technologies | Methods for the production of ammonia from urea and/or biuret, and uses for NOx and/or particulate matter removal |
| JP3464897B2 (ja) * | 1997-11-11 | 2003-11-10 | オルガノ株式会社 | 超臨界水酸化方法及び装置 |
| NO310717B1 (no) * | 1999-05-31 | 2001-08-20 | Cambi As | Fremgangsmate og anordning for kontinuerlig hydrolyse av avlopsvann |
| US6325935B1 (en) * | 1999-08-02 | 2001-12-04 | Kruger A/S | System and method for reducing the pathogen concentration of sludge |
| JP2001259696A (ja) * | 2000-03-23 | 2001-09-25 | General Atomics Inc | し尿および／または浄化槽汚泥の処理方法および装置 |
| JP2002066507A (ja) * | 2000-08-25 | 2002-03-05 | Ishikawajima Harima Heavy Ind Co Ltd | 有機性固形物の処理方法および有機性固形物の処理装置 |
| JP2002224681A (ja) * | 2001-02-02 | 2002-08-13 | Shinko Pantec Co Ltd | 有機性被処理液の酸化処理方法及び装置 |
| FR2820735B1 (fr) * | 2001-02-14 | 2004-05-14 | Vivendi Water Systems | Procede et installation pour l'hydrolyse thermique des boues |
| JP2002292267A (ja) * | 2001-03-30 | 2002-10-08 | Shinko Pantec Co Ltd | 有機性被処理液の酸化処理方法及び装置 |
| JP2002355697A (ja) * | 2001-05-31 | 2002-12-10 | Japan Sewage Works Agency | 超臨界水酸化分解装置および超臨界水酸化分解方法 |
| JP3869240B2 (ja) * | 2001-10-11 | 2007-01-17 | 木村化工機株式会社 | 油脂含有物質処理装置 |
| AU2002348166A1 (en) * | 2001-11-16 | 2003-06-10 | Ch2M Hill, Inc. | Method and apparatus for the treatment of particulate biodegradable organic waste |
| JP2003170037A (ja) * | 2001-12-06 | 2003-06-17 | Kimura Chem Plants Co Ltd | 油分分離装置 |
| JP2003236568A (ja) * | 2002-02-12 | 2003-08-26 | Kurita Water Ind Ltd | 水熱反応処理方法 |
| JP2003251306A (ja) * | 2002-03-07 | 2003-09-09 | Ishikawajima Harima Heavy Ind Co Ltd | 食品の廃棄処理方法及び廃棄処理装置 |
| KR20030074966A (ko) * | 2002-03-15 | 2003-09-22 | 주식회사 태영 | 슬러지 전처리 및 고농도 막분리 생물반응조를 이용한슬러지 처리방법 |
| JP3963124B2 (ja) * | 2002-06-06 | 2007-08-22 | 日立造船株式会社 | 有機性廃棄物の処理方法 |
| JP2005052706A (ja) * | 2003-08-07 | 2005-03-03 | Ishikawajima Harima Heavy Ind Co Ltd | 廃棄物処理方法及び装置 |
| JP4726035B2 (ja) * | 2004-01-20 | 2011-07-20 | 独立行政法人森林総合研究所 | バイオマスを原料とする糖類および固形燃料の製造方法 |
| CN2771778Y (zh) * | 2005-03-18 | 2006-04-12 | 东南大学 | 污泥过热蒸汽干燥装置 |
| US20070000172A1 (en) * | 2005-06-28 | 2007-01-04 | Michael Boe | Compact reforming reactor |
| JP2008000645A (ja) * | 2006-06-20 | 2008-01-10 | Shigeki Matsumoto | 湿式酸化法を用いた有機性廃棄物の処理方法及び装置 |
-
2008
- 2008-03-31 EP EP08153824A patent/EP2107108A1/en not_active Ceased
-
2009
- 2009-03-31 WO PCT/EP2009/053802 patent/WO2009121873A1/en not_active Ceased
- 2009-03-31 KR KR1020107024603A patent/KR101591031B1/ko not_active Expired - Fee Related
- 2009-03-31 EP EP09727008A patent/EP2274412B1/en not_active Not-in-force
- 2009-03-31 JP JP2011502371A patent/JP5665731B2/ja not_active Expired - Fee Related
- 2009-03-31 PL PL09727008T patent/PL2274412T3/pl unknown
- 2009-03-31 CN CN200980111189.9A patent/CN101981175B/zh not_active Expired - Fee Related
- 2009-03-31 ES ES09727008T patent/ES2390496T3/es active Active
- 2009-03-31 DK DK09727008.6T patent/DK2274412T3/da active
- 2009-03-31 AU AU2009231506A patent/AU2009231506B2/en not_active Ceased
- 2009-03-31 CA CA2719527A patent/CA2719527C/en not_active Expired - Fee Related
- 2009-03-31 BR BRPI0909262A patent/BRPI0909262A2/pt not_active IP Right Cessation
- 2009-03-31 US US12/934,357 patent/US20110114570A1/en not_active Abandoned
- 2009-03-31 MX MX2010010420A patent/MX2010010420A/es active IP Right Grant
- 2009-03-31 PT PT09727008T patent/PT2274412E/pt unknown
- 2009-03-31 RU RU2010144526/10A patent/RU2509730C2/ru not_active IP Right Cessation
-
2010
- 2010-09-15 IL IL208157A patent/IL208157A/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| AU2009231506B2 (en) | 2013-08-29 |
| ES2390496T3 (es) | 2012-11-13 |
| CN101981175B (zh) | 2014-04-16 |
| MX2010010420A (es) | 2011-03-02 |
| US20110114570A1 (en) | 2011-05-19 |
| DK2274412T3 (da) | 2012-09-03 |
| IL208157A0 (en) | 2010-12-30 |
| KR20110003515A (ko) | 2011-01-12 |
| IL208157A (en) | 2014-12-31 |
| EP2107108A1 (en) | 2009-10-07 |
| AU2009231506A1 (en) | 2009-10-08 |
| WO2009121873A1 (en) | 2009-10-08 |
| JP5665731B2 (ja) | 2015-02-04 |
| KR101591031B1 (ko) | 2016-02-03 |
| JP2011516246A (ja) | 2011-05-26 |
| CA2719527A1 (en) | 2009-10-08 |
| PL2274412T3 (pl) | 2012-10-31 |
| RU2010144526A (ru) | 2012-05-10 |
| CN101981175A (zh) | 2011-02-23 |
| BRPI0909262A2 (pt) | 2016-05-24 |
| CA2719527C (en) | 2016-08-09 |
| RU2509730C2 (ru) | 2014-03-20 |
| HK1153500A1 (en) | 2012-03-30 |
| EP2274412B1 (en) | 2012-05-16 |
| EP2274412A1 (en) | 2011-01-19 |
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