NO331854B1 - Ekspanderbare styrenpolymerperler som inneholder karbonpartikler, fremgangsmate for fremstilling og anvendelse av disse - Google Patents
Ekspanderbare styrenpolymerperler som inneholder karbonpartikler, fremgangsmate for fremstilling og anvendelse av disse Download PDFInfo
- Publication number
- NO331854B1 NO331854B1 NO20033119A NO20033119A NO331854B1 NO 331854 B1 NO331854 B1 NO 331854B1 NO 20033119 A NO20033119 A NO 20033119A NO 20033119 A NO20033119 A NO 20033119A NO 331854 B1 NO331854 B1 NO 331854B1
- Authority
- NO
- Norway
- Prior art keywords
- weight
- eps
- beads
- pentane
- water
- Prior art date
Links
- 239000002245 particle Substances 0.000 title claims abstract description 33
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 20
- 239000011324 bead Substances 0.000 title claims description 54
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title claims description 44
- 229920000642 polymer Polymers 0.000 title claims description 19
- 238000000034 method Methods 0.000 title claims description 8
- 229910052799 carbon Inorganic materials 0.000 title description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims abstract description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 17
- 239000010439 graphite Substances 0.000 claims abstract description 17
- 239000006229 carbon black Substances 0.000 claims abstract description 13
- 239000006260 foam Substances 0.000 claims description 15
- 238000005187 foaming Methods 0.000 claims description 13
- 239000004604 Blowing Agent Substances 0.000 claims description 9
- 239000003063 flame retardant Substances 0.000 claims description 6
- 238000006116 polymerization reaction Methods 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 239000000178 monomer Substances 0.000 claims description 5
- 150000005526 organic bromine compounds Chemical class 0.000 claims description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052794 bromium Inorganic materials 0.000 claims description 3
- 150000002894 organic compounds Chemical class 0.000 claims description 3
- 239000007900 aqueous suspension Substances 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 6
- 239000004794 expanded polystyrene Substances 0.000 description 32
- 239000004793 Polystyrene Substances 0.000 description 11
- 229920002223 polystyrene Polymers 0.000 description 10
- 150000002978 peroxides Chemical class 0.000 description 9
- 238000010557 suspension polymerization reaction Methods 0.000 description 7
- 238000009413 insulation Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 3
- 239000004584 polyacrylic acid Substances 0.000 description 3
- 229920006327 polystyrene foam Polymers 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- DEIGXXQKDWULML-UHFFFAOYSA-N 1,2,5,6,9,10-hexabromocyclododecane Chemical compound BrC1CCC(Br)C(Br)CCC(Br)C(Br)CCC1Br DEIGXXQKDWULML-UHFFFAOYSA-N 0.000 description 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 229920006248 expandable polystyrene Polymers 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000002667 nucleating agent Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- WYKYCHHWIJXDAO-UHFFFAOYSA-N tert-butyl 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(C)C WYKYCHHWIJXDAO-UHFFFAOYSA-N 0.000 description 2
- HGTUJZTUQFXBIH-UHFFFAOYSA-N (2,3-dimethyl-3-phenylbutan-2-yl)benzene Chemical group C=1C=CC=CC=1C(C)(C)C(C)(C)C1=CC=CC=C1 HGTUJZTUQFXBIH-UHFFFAOYSA-N 0.000 description 1
- AUTSLLHNWAZVLE-UHFFFAOYSA-N 1,1,2,2,3-pentabromo-3-chlorocyclohexane Chemical compound ClC1(Br)CCCC(Br)(Br)C1(Br)Br AUTSLLHNWAZVLE-UHFFFAOYSA-N 0.000 description 1
- VCNJVIWFSMCZPE-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-prop-2-enoxybenzene Chemical compound BrC1=C(Br)C(Br)=C(OCC=C)C(Br)=C1Br VCNJVIWFSMCZPE-UHFFFAOYSA-N 0.000 description 1
- JJRDRFZYKKFYMO-UHFFFAOYSA-N 2-methyl-2-(2-methylbutan-2-ylperoxy)butane Chemical compound CCC(C)(C)OOC(C)(C)CC JJRDRFZYKKFYMO-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241000872198 Serjania polyphylla Species 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- -1 aromatic bromine compounds Chemical class 0.000 description 1
- 229910021383 artificial graphite Inorganic materials 0.000 description 1
- JPNZKPRONVOMLL-UHFFFAOYSA-N azane;octadecanoic acid Chemical class [NH4+].CCCCCCCCCCCCCCCCCC([O-])=O JPNZKPRONVOMLL-UHFFFAOYSA-N 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910021382 natural graphite Inorganic materials 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- VWIJWLZJWWCDSY-UHFFFAOYSA-N pentyl 2-ethylhexaneperoxoate Chemical compound CCCCCOOC(=O)C(CC)CCCC VWIJWLZJWWCDSY-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001955 polyphenylene ether Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- KXYJPVZMZBJJBZ-UHFFFAOYSA-N tert-butyl 2-ethylbutaneperoxoate Chemical compound CCC(CC)C(=O)OOC(C)(C)C KXYJPVZMZBJJBZ-UHFFFAOYSA-N 0.000 description 1
- PFBLRDXPNUJYJM-UHFFFAOYSA-N tert-butyl 2-methylpropaneperoxoate Chemical compound CC(C)C(=O)OOC(C)(C)C PFBLRDXPNUJYJM-UHFFFAOYSA-N 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/16—Making expandable particles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F112/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F112/02—Monomers containing only one unsaturated aliphatic radical
- C08F112/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F112/06—Hydrocarbons
- C08F112/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/127—Mixtures of organic and inorganic blowing agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/141—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/16—Making expandable particles
- C08J9/20—Making expandable particles by suspension polymerisation in the presence of the blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/10—Water or water-releasing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10101432A DE10101432A1 (de) | 2001-01-13 | 2001-01-13 | Kohlenstoffpartikel enthaltende expandierbare Styrolpolymerisate |
| PCT/EP2002/000212 WO2002055594A1 (de) | 2001-01-13 | 2002-01-11 | Kohlenstoffpartikel enthaltende expandierbare styrolpolymerisate |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO20033119D0 NO20033119D0 (no) | 2003-07-08 |
| NO20033119L NO20033119L (no) | 2003-09-12 |
| NO331854B1 true NO331854B1 (no) | 2012-04-23 |
Family
ID=7670512
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO20033119A NO331854B1 (no) | 2001-01-13 | 2003-07-08 | Ekspanderbare styrenpolymerperler som inneholder karbonpartikler, fremgangsmate for fremstilling og anvendelse av disse |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US20040039073A1 (ko) |
| EP (1) | EP1366110B1 (ko) |
| JP (1) | JP2005506390A (ko) |
| KR (1) | KR100822579B1 (ko) |
| CN (1) | CN1194033C (ko) |
| AT (1) | ATE334164T1 (ko) |
| AU (1) | AU2002234613A1 (ko) |
| CA (1) | CA2434051A1 (ko) |
| CZ (1) | CZ298607B6 (ko) |
| DE (2) | DE10101432A1 (ko) |
| ES (1) | ES2269648T3 (ko) |
| MX (1) | MXPA03005785A (ko) |
| NO (1) | NO331854B1 (ko) |
| PL (1) | PL206009B1 (ko) |
| RU (1) | RU2302432C2 (ko) |
| WO (1) | WO2002055594A1 (ko) |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE543893T1 (de) | 2002-12-18 | 2012-02-15 | Synbra Tech Bv | Feuerbeständige materialien |
| ITMI20030627A1 (it) * | 2003-03-31 | 2004-10-01 | Polimeri Europa Spa | Polimeri vinilaromatici espandibili e procedimento per la loro preparazione. |
| DE102004028768A1 (de) * | 2004-06-16 | 2005-12-29 | Basf Ag | Styrolpolymer-Partikelschaumstoffe mit verringerter Wärmeleitfähigkeit |
| WO2006005901A1 (en) * | 2004-07-13 | 2006-01-19 | Ineos Europe Limited | Expandable polystyrene composition and process for making same |
| DE102004034514A1 (de) * | 2004-07-15 | 2006-02-16 | Basf Ag | Synergistische Flammschutzmischungen für Polystyrolschaumstoffe |
| ITMI20050666A1 (it) * | 2005-04-15 | 2006-10-16 | Polimeri Europa Spa | Procedimento per il migoioramento del potere isolante di polimeri vinilaromatici espansi e prodotti cosi'ottenuti |
| US20060266707A1 (en) * | 2005-05-26 | 2006-11-30 | Fisher Jon R | Drying method for macroporous polymers, and method of preparation and use of macroporous polymers made using the method |
| IT1366567B (it) | 2005-10-18 | 2009-10-06 | Polimeri Europa Spa | Granulati espandibili a basemdi polimeri vinilaromatici dotati di migliorata espansibilita'e procedimento per la loro preparazione |
| MY143939A (en) * | 2006-03-07 | 2011-07-29 | Basf Se | Process for preparing expandable styrene polymers |
| WO2007114529A1 (en) * | 2006-03-31 | 2007-10-11 | Korea Kumho Petrochemical Co., Ltd | Method for manufacturing expandable polystyrene particles with excellent thermal insulation capability |
| KR100750626B1 (ko) * | 2006-12-29 | 2007-08-20 | 주식회사 벽산 | 단열성이 우수한 압출 스티렌 폼 제조방법 |
| US20090030095A1 (en) * | 2007-07-24 | 2009-01-29 | Laverdure Kenneth S | Polystyrene compositions and methods of making and using same |
| KR101096798B1 (ko) | 2007-10-15 | 2011-12-22 | 현대이피 주식회사 | 발포성 폴리스티렌 비드 및 그 제조방법 |
| PL2274369T5 (pl) * | 2008-05-02 | 2023-08-07 | Basf Se | Polistyrenowe tworzywa piankowe o małej zawartości metali |
| ITMI20080823A1 (it) * | 2008-05-07 | 2009-11-08 | Polimeri Europa Spa | Composizioni di polimeri vinilaromatici espansibili a migliorata capacita' di isolamento termico, procedimento per la loro preparazione ed articoli espansi da esse ottenuti |
| IT1392391B1 (it) * | 2008-12-19 | 2012-03-02 | Polimeri Europa Spa | Composizioni di polimeri vinilaromatici espansibili a migliorata capacita' di isolamento termico, procedimento per la loro preparazione ed articoli espansi da loro ottenuti |
| CN101560308B (zh) * | 2009-06-02 | 2011-08-31 | 吉林大学 | 一步法合成黑色可发性聚苯乙烯粒子的制备方法 |
| JP5632926B2 (ja) * | 2009-12-10 | 2014-11-26 | アクゾ ノーベル ケミカルズ インターナショナル ベスローテン フエンノートシャップＡｋｚｏ Ｎｏｂｅｌ Ｃｈｅｍｉｃａｌｓ Ｉｎｔｅｒｎａｔｉｏｎａｌ Ｂ．Ｖ． | スチレンの重合方法 |
| NL2004588C2 (nl) * | 2010-04-21 | 2011-10-24 | Synbra Tech Bv | Deeltjesvormig, expandeerbaar polymeer, werkwijze ter vervaardiging hiervan, alsmede de toepassing. |
| IT1401950B1 (it) | 2010-09-21 | 2013-08-28 | Polimeri Europa Spa | Composizioni di (co)polimeri vinilaromatici espansibili autoestinguenti e procedimento per la loro preparazione. |
| KR101168268B1 (ko) | 2011-10-04 | 2012-07-30 | 금호석유화학 주식회사 | 흑연을 함유하는 폴리스티렌 압출 보드의 간편한 제조 방법 |
| US20140364524A1 (en) * | 2011-12-21 | 2014-12-11 | Basf Se | Method for producing expandable styrene polymers containing graphite and flame retardant |
| JP5810007B2 (ja) * | 2012-02-29 | 2015-11-11 | 積水化成品工業株式会社 | スチレン系樹脂粒子、その製造方法、発泡性粒子、発泡粒子及び発泡成形体 |
| CN102977239B (zh) * | 2012-12-05 | 2014-12-03 | 新疆蓝山屯河新材料有限公司 | 难燃型可发性聚苯乙烯树脂材料及其生产方法 |
| FR3009561B1 (fr) * | 2013-08-06 | 2017-12-22 | Arkema France | Procede de preparation de polystyrene expansible noir |
| WO2015045885A1 (ja) * | 2013-09-30 | 2015-04-02 | 積水化成品工業株式会社 | カーボンブラック含有複合樹脂予備発泡粒子とその製造方法及び発泡成形体 |
| MA41342A (fr) | 2015-01-14 | 2017-11-21 | Synthos Sa | Procédé pour la production de granulés de polymère vinylique aromatique expansible ayant une conductivité thermique réduite |
| PT3245242T (pt) | 2015-01-14 | 2018-12-05 | Synthos Sa | Utilização de um mineral com estrutura de perovskita em espuma de polímero de vinilo aromático |
| PT3245172T (pt) | 2015-01-14 | 2019-04-23 | Synthos Sa | Granulado de polímero vinílico aromático expansível e espuma de polímero vinílico aromático expandida compreendendo compósito geopolimérico e a sua utilização aí |
| MA41344B1 (fr) | 2015-01-14 | 2019-01-31 | Synthos Sa | Combinaison de silice et de graphite et son utilisation pour réduire la conductivité thermique d'une mousse de polymère aromatique vinylique |
| CA2998094C (en) | 2015-09-09 | 2022-12-13 | Kaneka Corporation | Expandable styrene resin particles, pre-expanded particles of styrene resin, styrene resin foam molded body, and method for producing expandable resin particles |
| CN105504115B (zh) * | 2015-12-18 | 2018-05-18 | 武汉轻工大学 | 消除炭黑或石墨在聚苯乙烯保温材料合成中阻聚效应的原位微胶囊方法 |
| CN105949360A (zh) * | 2016-05-30 | 2016-09-21 | 日照新三明化工有限公司 | 含鳞片石墨的阻燃可发性聚苯乙烯及其本体聚合制备方法 |
| CN107141384B (zh) * | 2016-08-16 | 2020-07-14 | 新疆蓝山屯河新材料有限公司 | 一种高黑度石墨可发性聚苯乙烯颗粒的生产方法 |
| CN111393549B (zh) * | 2018-12-28 | 2022-06-24 | 青岛海林港工业有限公司 | 一种eps泡粒的制备方法及其应用 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH510703A (de) * | 1966-06-23 | 1971-07-31 | Basf Ag | Schwerentflammbare thermoplastische Formmasse |
| AU4754090A (en) * | 1988-11-25 | 1990-06-26 | Dow Chemical Company, The | Polystyrene foam containing carbon black |
| DE3842305A1 (de) * | 1988-12-16 | 1990-06-21 | Basf Ag | Verfahren zur herstellung von styrolpolymerisat-schaumstoffpartikeln |
| DE4014261A1 (de) * | 1990-05-04 | 1991-11-07 | Basf Ag | Expandierbare styrolpolymerisate |
| US5112875A (en) * | 1990-11-26 | 1992-05-12 | Basf Corporation | Polystyrene having high degree of expandability, and formulation having a highly-expandable polymer therein |
| DE59702327D1 (de) * | 1997-05-14 | 2000-10-12 | Basf Ag | Graphitpartikel enthaltende expandierbare styrolpolymerisate |
| DE59702388D1 (de) * | 1997-05-14 | 2000-10-26 | Basf Ag | Verfahren zur herstellung graphitpartikel enthaltender expandierbarer styrolpolymerisate |
| DE19742910A1 (de) * | 1997-09-29 | 1999-04-01 | Basf Ag | Verfahren zur Herstellung von expandierbaren Styrolpolymerisaten |
| DE19812856A1 (de) * | 1998-03-24 | 1999-09-30 | Basf Ag | Verfahren zur Herstellung wasserexpandierbarer Styrolpolymerisate |
| EP0987293A1 (en) * | 1998-09-16 | 2000-03-22 | Shell Internationale Researchmaatschappij B.V. | Porous polymer particles |
| MXPA03004908A (es) * | 2000-12-04 | 2004-05-24 | Nova Chem Inc | Particulas celulares espumadas de composicion polimerica extendida. |
-
2001
- 2001-01-13 DE DE10101432A patent/DE10101432A1/de not_active Withdrawn
-
2002
- 2002-01-11 CZ CZ20031877A patent/CZ298607B6/cs not_active IP Right Cessation
- 2002-01-11 AU AU2002234613A patent/AU2002234613A1/en not_active Abandoned
- 2002-01-11 MX MXPA03005785A patent/MXPA03005785A/es active IP Right Grant
- 2002-01-11 ES ES02701251T patent/ES2269648T3/es not_active Expired - Lifetime
- 2002-01-11 JP JP2002556656A patent/JP2005506390A/ja active Pending
- 2002-01-11 CA CA002434051A patent/CA2434051A1/en not_active Abandoned
- 2002-01-11 EP EP02701251A patent/EP1366110B1/de not_active Expired - Lifetime
- 2002-01-11 PL PL369135A patent/PL206009B1/pl unknown
- 2002-01-11 AT AT02701251T patent/ATE334164T1/de active
- 2002-01-11 RU RU2003125175/04A patent/RU2302432C2/ru not_active IP Right Cessation
- 2002-01-11 KR KR1020037009280A patent/KR100822579B1/ko active IP Right Grant
- 2002-01-11 DE DE50207638T patent/DE50207638D1/de not_active Expired - Lifetime
- 2002-01-11 WO PCT/EP2002/000212 patent/WO2002055594A1/de active IP Right Grant
- 2002-01-11 CN CNB028034570A patent/CN1194033C/zh not_active Expired - Fee Related
- 2002-01-11 US US10/451,736 patent/US20040039073A1/en not_active Abandoned
-
2003
- 2003-07-08 NO NO20033119A patent/NO331854B1/no not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| DE50207638D1 (de) | 2006-09-07 |
| PL369135A1 (en) | 2005-04-18 |
| WO2002055594A1 (de) | 2002-07-18 |
| KR20040073277A (ko) | 2004-08-19 |
| CN1484666A (zh) | 2004-03-24 |
| KR100822579B1 (ko) | 2008-04-16 |
| CZ20031877A3 (cs) | 2003-12-17 |
| RU2003125175A (ru) | 2005-01-10 |
| JP2005506390A (ja) | 2005-03-03 |
| CN1194033C (zh) | 2005-03-23 |
| CZ298607B6 (cs) | 2007-11-21 |
| CA2434051A1 (en) | 2002-07-18 |
| NO20033119D0 (no) | 2003-07-08 |
| PL206009B1 (pl) | 2010-06-30 |
| US20040039073A1 (en) | 2004-02-26 |
| ES2269648T3 (es) | 2007-04-01 |
| EP1366110A1 (de) | 2003-12-03 |
| DE10101432A1 (de) | 2002-07-18 |
| AU2002234613A1 (en) | 2002-07-24 |
| ATE334164T1 (de) | 2006-08-15 |
| RU2302432C2 (ru) | 2007-07-10 |
| EP1366110B1 (de) | 2006-07-26 |
| MXPA03005785A (es) | 2003-09-10 |
| NO20033119L (no) | 2003-09-12 |
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