NO319881B1 - Fremgangsmate for in-situ syntese av krystallint mikroporost metalloaluminofosfat i faste legemer samt anvendelse av de faste legemer - Google Patents
Fremgangsmate for in-situ syntese av krystallint mikroporost metalloaluminofosfat i faste legemer samt anvendelse av de faste legemer Download PDFInfo
- Publication number
- NO319881B1 NO319881B1 NO20022608A NO20022608A NO319881B1 NO 319881 B1 NO319881 B1 NO 319881B1 NO 20022608 A NO20022608 A NO 20022608A NO 20022608 A NO20022608 A NO 20022608A NO 319881 B1 NO319881 B1 NO 319881B1
- Authority
- NO
- Norway
- Prior art keywords
- solid bodies
- elapo
- bodies
- sapo
- solid
- Prior art date
Links
- 238000011065 in-situ storage Methods 0.000 title claims abstract description 14
- 239000007787 solid Substances 0.000 title claims description 91
- 238000000034 method Methods 0.000 title claims description 34
- 238000003786 synthesis reaction Methods 0.000 title description 50
- 230000015572 biosynthetic process Effects 0.000 title description 48
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 22
- 239000011230 binding agent Substances 0.000 claims abstract description 21
- 238000002425 crystallisation Methods 0.000 claims abstract description 21
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims abstract description 19
- 239000003054 catalyst Substances 0.000 claims abstract description 19
- 229910001868 water Inorganic materials 0.000 claims abstract description 19
- 238000004519 manufacturing process Methods 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000003463 adsorbent Substances 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 31
- 230000008025 crystallization Effects 0.000 claims description 20
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 18
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 18
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 claims description 18
- 229940073455 tetraethylammonium hydroxide Drugs 0.000 claims description 18
- LRGJRHZIDJQFCL-UHFFFAOYSA-M tetraethylazanium;hydroxide Chemical compound [OH-].CC[N+](CC)(CC)CC LRGJRHZIDJQFCL-UHFFFAOYSA-M 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 15
- 239000011541 reaction mixture Substances 0.000 claims description 12
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 11
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 10
- 229910052710 silicon Inorganic materials 0.000 claims description 10
- 239000010703 silicon Substances 0.000 claims description 10
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- 150000001336 alkenes Chemical class 0.000 claims description 7
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- 239000013078 crystal Substances 0.000 claims description 6
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 claims description 6
- 229940043279 diisopropylamine Drugs 0.000 claims description 6
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 claims description 6
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 4
- -1 C4-C20 -alcohols Chemical compound 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 239000011651 chromium Substances 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 3
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 241000269350 Anura Species 0.000 claims description 2
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 claims description 2
- XOBKSJJDNFUZPF-UHFFFAOYSA-N Methoxyethane Chemical compound CCOC XOBKSJJDNFUZPF-UHFFFAOYSA-N 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 2
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims 1
- 239000002994 raw material Substances 0.000 claims 1
- 229910019142 PO4 Inorganic materials 0.000 abstract description 5
- 229940001007 aluminium phosphate Drugs 0.000 abstract 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 2
- 235000021317 phosphate Nutrition 0.000 abstract 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 37
- 239000000463 material Substances 0.000 description 22
- 239000000047 product Substances 0.000 description 22
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 13
- 239000002808 molecular sieve Substances 0.000 description 13
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 13
- 239000000377 silicon dioxide Substances 0.000 description 12
- 230000003197 catalytic effect Effects 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical group O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 7
- 229910052698 phosphorus Inorganic materials 0.000 description 7
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 6
- 239000000499 gel Substances 0.000 description 6
- 239000011574 phosphorus Substances 0.000 description 6
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 6
- 229910000391 tricalcium phosphate Inorganic materials 0.000 description 6
- 238000002441 X-ray diffraction Methods 0.000 description 5
- 229910021536 Zeolite Inorganic materials 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 239000006069 physical mixture Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000010457 zeolite Substances 0.000 description 5
- 239000003153 chemical reaction reagent Substances 0.000 description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
- 235000019731 tricalcium phosphate Nutrition 0.000 description 4
- 229910017119 AlPO Inorganic materials 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 150000004706 metal oxides Chemical group 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000013074 reference sample Substances 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 230000004580 weight loss Effects 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910000389 calcium phosphate Inorganic materials 0.000 description 2
- 239000001506 calcium phosphate Substances 0.000 description 2
- 235000011010 calcium phosphates Nutrition 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 238000000386 microscopy Methods 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 238000004876 x-ray fluorescence Methods 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 101100011518 Arabidopsis thaliana ELP1 gene Proteins 0.000 description 1
- 241000640882 Condea Species 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 101100501248 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) ELO2 gene Proteins 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 229910001408 cation oxide Inorganic materials 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- IPZJQDSFZGZEOY-UHFFFAOYSA-N dimethylmethylene Chemical compound C[C]C IPZJQDSFZGZEOY-UHFFFAOYSA-N 0.000 description 1
- YWEUIGNSBFLMFL-UHFFFAOYSA-N diphosphonate Chemical compound O=P(=O)OP(=O)=O YWEUIGNSBFLMFL-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000000635 electron micrograph Methods 0.000 description 1
- 238000001493 electron microscopy Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000000017 hydrogel Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000010335 hydrothermal treatment Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 150000002736 metal compounds Chemical group 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- DLYUQMMRRRQYAE-UHFFFAOYSA-N phosphorus pentoxide Inorganic materials O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 1
- 229960005235 piperonyl butoxide Drugs 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 239000012690 zeolite precursor Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0248—Compounds of B, Al, Ga, In, Tl
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
- B01J20/0292—Phosphates of compounds other than those provided for in B01J20/048
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
- B01J29/85—Silicoaluminophosphates (SAPO compounds)
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
- C01B37/08—Silicoaluminophosphates (SAPO compounds), e.g. CoSAPO
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/54—Phosphates, e.g. APO or SAPO compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/60—Synthesis on support
- B01J2229/64—Synthesis on support in or on refractory materials
Priority Applications (12)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NO20022608A NO319881B1 (no) | 2002-05-31 | 2002-05-31 | Fremgangsmate for in-situ syntese av krystallint mikroporost metalloaluminofosfat i faste legemer samt anvendelse av de faste legemer |
| CN038125455A CN1656017B (zh) | 2002-05-31 | 2003-05-23 | 用于在成型物体中原位合成结晶态微孔金属磷酸铝的方法 |
| PT03756129T PT1513770E (pt) | 2002-05-31 | 2003-05-23 | Processo para sintese in situ de metaloaluminofosfato microporoso cristalino num corpo formado |
| EP03756129A EP1513770B1 (en) | 2002-05-31 | 2003-05-23 | Method for in-situ synthesis of crystalline microporous metalloaluminophosphate in a formed body |
| RU2004139073/15A RU2317253C2 (ru) | 2002-05-31 | 2003-05-23 | Способ in-situ синтеза кристаллического микропористого металлоалюмофосфата в виде формованного материала |
| DE60305698T DE60305698T2 (de) | 2002-05-31 | 2003-05-23 | Verfahren zur in-situ-synthese von kristallinem mikroporösem metalloaluminophosphat in einem formkörper |
| AT03756129T ATE327966T1 (de) | 2002-05-31 | 2003-05-23 | Verfahren zur in-situ-synthese von kristallinem mikroporösem metalloaluminophosphat in einem formkörper |
| AU2003232693A AU2003232693A1 (en) | 2002-05-31 | 2003-05-23 | Method for in-situ synthesis of crystalline microporous metalloaluminophosphate in a formed body |
| ES03756129T ES2264000T3 (es) | 2002-05-31 | 2003-05-23 | Metodo para la sintesis in situ de metaloaluminofosfato cristalino microporoso en un cuerpo conformado. |
| DK03756129T DK1513770T3 (da) | 2002-05-31 | 2003-05-23 | Fremgangsmåde til in situ syntese af krystallinsk, mikroporöst metalloaluminophosphat i et formgivet legeme |
| US10/515,502 US7341707B2 (en) | 2002-05-31 | 2003-05-23 | Method for in-situ synthesis of crystalline microporous metalloaluminophosphate in a formed body |
| PCT/NO2003/000170 WO2003101892A1 (en) | 2002-05-31 | 2003-05-23 | Method for in-situ synthesis of crystalline microporous metalloaluminophosphate in a formed body |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NO20022608A NO319881B1 (no) | 2002-05-31 | 2002-05-31 | Fremgangsmate for in-situ syntese av krystallint mikroporost metalloaluminofosfat i faste legemer samt anvendelse av de faste legemer |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO20022608D0 NO20022608D0 (no) | 2002-05-31 |
| NO20022608L NO20022608L (no) | 2003-12-01 |
| NO319881B1 true NO319881B1 (no) | 2005-09-26 |
Family
ID=19913681
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO20022608A NO319881B1 (no) | 2002-05-31 | 2002-05-31 | Fremgangsmate for in-situ syntese av krystallint mikroporost metalloaluminofosfat i faste legemer samt anvendelse av de faste legemer |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US7341707B2 (ru) |
| EP (1) | EP1513770B1 (ru) |
| CN (1) | CN1656017B (ru) |
| AT (1) | ATE327966T1 (ru) |
| AU (1) | AU2003232693A1 (ru) |
| DE (1) | DE60305698T2 (ru) |
| DK (1) | DK1513770T3 (ru) |
| ES (1) | ES2264000T3 (ru) |
| NO (1) | NO319881B1 (ru) |
| PT (1) | PT1513770E (ru) |
| RU (1) | RU2317253C2 (ru) |
| WO (1) | WO2003101892A1 (ru) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4271400B2 (ja) * | 2002-02-14 | 2009-06-03 | 株式会社デンソー | 触媒体 |
| WO2007134094A2 (en) * | 2006-05-15 | 2007-11-22 | The Regents Of The University Of Colorado, A Body Corporate | High flux and selectivity sapo-34 membranes for co2/ch4 separations |
| TW200904752A (en) * | 2007-03-09 | 2009-02-01 | Univ Colorado Regents | Synthesis of zeolites and zeolite membranes using multiple structure directing agents |
| EP2161243A1 (en) * | 2008-08-29 | 2010-03-10 | Total Petrochemicals Research Feluy | Method for preparing metalloaluminophosphate (MeAPO) molecular sieves |
| EP2161242A1 (en) * | 2008-08-29 | 2010-03-10 | Total Petrochemicals Research Feluy | Method for Preparing Crystalline Metalloaluminophosphate (MeAPO) Molecular Sieve from Amorphous Materials |
| JP5756461B2 (ja) | 2009-06-12 | 2015-07-29 | アルベマール・ユーロプ・エスピーアールエル | Ｓａｐｏ分子篩触媒と、その調製および使用 |
| AU2011245307B2 (en) | 2010-04-29 | 2014-10-09 | The Regents Of The University Of Colorado, A Body Corporate | High flux SAPO-34 membranes for CO2/CH4 separation and template removal method |
| DE102010055677B4 (de) * | 2010-12-22 | 2018-09-20 | Clariant Produkte (Deutschland) Gmbh | Wärmetauscher-Modul mit Wärmemanagement mit einem Titano-Silico-Alumo-Phosphat als Adsorptionsmittel und dessen Verwendung |
| US20140171713A1 (en) * | 2012-12-14 | 2014-06-19 | Uop Llc | Nano sapo-35 and method of making |
| CN107074571B (zh) | 2014-08-22 | 2022-09-27 | 格雷斯公司 | 使用一异丙醇胺合成磷酸硅铝-34分子筛的方法 |
| WO2017204993A1 (en) | 2016-05-25 | 2017-11-30 | Uop Llc | High charge density metallophosphate molecular sieves |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4973785A (en) * | 1984-04-13 | 1990-11-27 | Uop | Molecular sieve compositions |
| US4861743A (en) * | 1987-11-25 | 1989-08-29 | Uop | Process for the production of molecular sieves |
| US5514362A (en) * | 1994-05-03 | 1996-05-07 | Chevron U.S.A. Inc. | Preparation of non-zeolitic molecular sieves |
| US6004527A (en) * | 1997-09-29 | 1999-12-21 | Abb Lummus Global Inc. | Method for making molecular sieves and novel molecular sieve compositions |
| US6207872B1 (en) * | 1997-12-09 | 2001-03-27 | Uop Llc | Metallo aluminophosphate molecular sieve with cubic crystal morphology and methanol to olefin process using the sieve |
| NO318680B1 (no) * | 2001-11-07 | 2005-04-25 | Polymers Holding As | Metode for a fremstille krystallinsk, mikroporost metalloaluminofosfat fra et fast legeme og anvendelse derav |
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2002
- 2002-05-31 NO NO20022608A patent/NO319881B1/no not_active IP Right Cessation
-
2003
- 2003-05-23 RU RU2004139073/15A patent/RU2317253C2/ru not_active IP Right Cessation
- 2003-05-23 US US10/515,502 patent/US7341707B2/en not_active Expired - Fee Related
- 2003-05-23 DE DE60305698T patent/DE60305698T2/de not_active Expired - Lifetime
- 2003-05-23 DK DK03756129T patent/DK1513770T3/da active
- 2003-05-23 AU AU2003232693A patent/AU2003232693A1/en not_active Abandoned
- 2003-05-23 CN CN038125455A patent/CN1656017B/zh not_active Expired - Fee Related
- 2003-05-23 WO PCT/NO2003/000170 patent/WO2003101892A1/en not_active Application Discontinuation
- 2003-05-23 ES ES03756129T patent/ES2264000T3/es not_active Expired - Lifetime
- 2003-05-23 EP EP03756129A patent/EP1513770B1/en not_active Expired - Lifetime
- 2003-05-23 PT PT03756129T patent/PT1513770E/pt unknown
- 2003-05-23 AT AT03756129T patent/ATE327966T1/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| NO20022608D0 (no) | 2002-05-31 |
| DE60305698T2 (de) | 2007-02-22 |
| DK1513770T3 (da) | 2006-10-02 |
| WO2003101892A1 (en) | 2003-12-11 |
| CN1656017A (zh) | 2005-08-17 |
| EP1513770B1 (en) | 2006-05-31 |
| RU2004139073A (ru) | 2005-06-10 |
| PT1513770E (pt) | 2006-09-29 |
| US7341707B2 (en) | 2008-03-11 |
| EP1513770A1 (en) | 2005-03-16 |
| AU2003232693A1 (en) | 2003-12-19 |
| ES2264000T3 (es) | 2006-12-16 |
| US20050171394A1 (en) | 2005-08-04 |
| CN1656017B (zh) | 2010-04-28 |
| RU2317253C2 (ru) | 2008-02-20 |
| DE60305698D1 (de) | 2006-07-06 |
| ATE327966T1 (de) | 2006-06-15 |
| NO20022608L (no) | 2003-12-01 |
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