NO312889B1 - Fremgangsmåte for fremstilling av en höytetthets cesium- og rubidiumsaltopplösning - Google Patents
Fremgangsmåte for fremstilling av en höytetthets cesium- og rubidiumsaltopplösning Download PDFInfo
- Publication number
- NO312889B1 NO312889B1 NO19951845A NO951845A NO312889B1 NO 312889 B1 NO312889 B1 NO 312889B1 NO 19951845 A NO19951845 A NO 19951845A NO 951845 A NO951845 A NO 951845A NO 312889 B1 NO312889 B1 NO 312889B1
- Authority
- NO
- Norway
- Prior art keywords
- cesium
- rubidium
- solution
- acid
- digestion
- Prior art date
Links
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 229910052792 caesium Inorganic materials 0.000 title claims abstract description 24
- 239000012266 salt solution Substances 0.000 title claims description 18
- 150000003297 rubidium Chemical class 0.000 title claims description 12
- 238000004519 manufacturing process Methods 0.000 title abstract description 8
- 239000000706 filtrate Substances 0.000 claims abstract description 19
- 239000000725 suspension Substances 0.000 claims abstract description 12
- 229910001744 pollucite Inorganic materials 0.000 claims abstract description 10
- 229910052701 rubidium Inorganic materials 0.000 claims abstract description 9
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims abstract description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052629 lepidolite Inorganic materials 0.000 claims abstract description 7
- 239000007787 solid Substances 0.000 claims abstract description 7
- 239000002253 acid Substances 0.000 claims abstract description 6
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims abstract description 5
- 238000001914 filtration Methods 0.000 claims abstract description 5
- 150000008065 acid anhydrides Chemical class 0.000 claims abstract description 4
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims abstract description 4
- 239000000920 calcium hydroxide Substances 0.000 claims abstract description 4
- 235000011116 calcium hydroxide Nutrition 0.000 claims abstract description 4
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 4
- 230000029087 digestion Effects 0.000 claims description 37
- 239000000243 solution Substances 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 21
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 13
- 239000011707 mineral Substances 0.000 claims description 13
- 235000010755 mineral Nutrition 0.000 claims description 13
- FAWNVSNJFDIJRM-UHFFFAOYSA-N [Rb].[Cs] Chemical compound [Rb].[Cs] FAWNVSNJFDIJRM-UHFFFAOYSA-N 0.000 claims description 11
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 10
- JAAGVIUFBAHDMA-UHFFFAOYSA-M rubidium bromide Chemical compound [Br-].[Rb+] JAAGVIUFBAHDMA-UHFFFAOYSA-M 0.000 claims description 8
- ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten trioxide Chemical compound O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 claims description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- 239000011575 calcium Substances 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 5
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 5
- 235000019253 formic acid Nutrition 0.000 claims description 5
- 229910052744 lithium Inorganic materials 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- WGEFECGEFUFIQW-UHFFFAOYSA-L calcium dibromide Chemical class [Ca+2].[Br-].[Br-] WGEFECGEFUFIQW-UHFFFAOYSA-L 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 2
- 150000001450 anions Chemical class 0.000 claims description 2
- SXDBWCPKPHAZSM-UHFFFAOYSA-N bromic acid Chemical compound OBr(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 2
- WFIZEGIEIOHZCP-UHFFFAOYSA-M potassium formate Chemical class [K+].[O-]C=O WFIZEGIEIOHZCP-UHFFFAOYSA-M 0.000 claims description 2
- ZIMBPNXOLRMVGV-UHFFFAOYSA-M rubidium(1+);formate Chemical compound [Rb+].[O-]C=O ZIMBPNXOLRMVGV-UHFFFAOYSA-M 0.000 claims description 2
- 239000012047 saturated solution Substances 0.000 claims description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 5
- 238000001704 evaporation Methods 0.000 abstract description 4
- 230000008020 evaporation Effects 0.000 abstract description 4
- 238000005406 washing Methods 0.000 abstract description 4
- 229910052681 coesite Inorganic materials 0.000 abstract description 3
- 229910052906 cristobalite Inorganic materials 0.000 abstract description 3
- 229910052682 stishovite Inorganic materials 0.000 abstract description 3
- 229910052905 tridymite Inorganic materials 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 2
- 239000000377 silicon dioxide Substances 0.000 abstract description 2
- 235000012239 silicon dioxide Nutrition 0.000 abstract description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 2
- 239000011780 sodium chloride Substances 0.000 abstract 2
- 238000007664 blowing Methods 0.000 abstract 1
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 abstract 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 abstract 1
- 229910052808 lithium carbonate Inorganic materials 0.000 abstract 1
- 238000009835 boiling Methods 0.000 description 4
- VCGRFBXVSFAGGA-UHFFFAOYSA-N (1,1-dioxo-1,4-thiazinan-4-yl)-[6-[[3-(4-fluorophenyl)-5-methyl-1,2-oxazol-4-yl]methoxy]pyridin-3-yl]methanone Chemical compound CC=1ON=C(C=2C=CC(F)=CC=2)C=1COC(N=C1)=CC=C1C(=O)N1CCS(=O)(=O)CC1 VCGRFBXVSFAGGA-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- CPRMKOQKXYSDML-UHFFFAOYSA-M rubidium hydroxide Chemical compound [OH-].[Rb+] CPRMKOQKXYSDML-UHFFFAOYSA-M 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 241000220317 Rosa Species 0.000 description 1
- LIHHHYMOABTJCZ-UHFFFAOYSA-N [Rb].[W] Chemical compound [Rb].[W] LIHHHYMOABTJCZ-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000009530 blood pressure measurement Methods 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- FJDQFPXHSGXQBY-UHFFFAOYSA-L caesium carbonate Chemical compound [Cs+].[Cs+].[O-]C([O-])=O FJDQFPXHSGXQBY-UHFFFAOYSA-L 0.000 description 1
- 229910000024 caesium carbonate Inorganic materials 0.000 description 1
- HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Inorganic materials [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 238000005188 flotation Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- -1 hydrides carbon monoxide Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical class [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 229910052642 spodumene Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D17/00—Rubidium, caesium or francium compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Measurement Of Radiation (AREA)
- Inorganic Insulating Materials (AREA)
- Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
- Compounds Of Unknown Constitution (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4237954A DE4237954C1 (de) | 1992-11-11 | 1992-11-11 | Verfahren zur Herstellung einer Cäsium- und Rubidiumsalzlösung mit einer Dichte von 1,6 bis 3,3 g/cm ·3· |
| PCT/EP1993/003143 WO1994011303A1 (de) | 1992-11-11 | 1993-11-10 | Verfahren zur herstellung einer hochdichten cäsium- und rubidiumsalzlösung |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO951845D0 NO951845D0 (no) | 1995-05-10 |
| NO951845L NO951845L (no) | 1995-06-30 |
| NO312889B1 true NO312889B1 (no) | 2002-07-15 |
Family
ID=6472548
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO19951845A NO312889B1 (no) | 1992-11-11 | 1995-05-10 | Fremgangsmåte for fremstilling av en höytetthets cesium- og rubidiumsaltopplösning |
Country Status (23)
| Country | Link |
|---|---|
| US (1) | US5593650A (zh) |
| EP (1) | EP0668845B1 (zh) |
| JP (1) | JP3378007B2 (zh) |
| KR (1) | KR0160829B1 (zh) |
| CN (1) | CN1038668C (zh) |
| AT (1) | ATE152430T1 (zh) |
| AU (1) | AU669770B2 (zh) |
| BR (1) | BR9307423A (zh) |
| CA (1) | CA2149138C (zh) |
| CZ (1) | CZ120895A3 (zh) |
| DE (2) | DE4237954C1 (zh) |
| DK (1) | DK0668845T3 (zh) |
| EE (1) | EE9400163A (zh) |
| FI (1) | FI952278A (zh) |
| GR (1) | GR3023856T3 (zh) |
| HU (1) | HU213321B (zh) |
| LT (1) | LT3450B (zh) |
| LV (1) | LV10844B (zh) |
| NO (1) | NO312889B1 (zh) |
| PL (1) | PL171649B1 (zh) |
| SK (1) | SK61495A3 (zh) |
| WO (1) | WO1994011303A1 (zh) |
| ZA (1) | ZA938429B (zh) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4339062C1 (de) * | 1993-11-16 | 1995-02-23 | Metallgesellschaft Ag | Verfahren zur Herstellung einer Cäsium- und Rubidiumsalzlösung |
| US6390395B1 (en) | 1998-12-16 | 2002-05-21 | Versitech, Inc. | Heavy liquids for use in separation processes |
| CN103820633B (zh) * | 2014-02-28 | 2015-12-09 | 金川集团股份有限公司 | 一种含铷矿石的处理方法 |
| CN104108731A (zh) * | 2014-07-15 | 2014-10-22 | 天津市化学试剂研究所有限公司 | 一种优级纯溴化铯的制备方法 |
| AU2015302219B2 (en) | 2014-08-13 | 2019-05-16 | Albemarle Corporation | High density aqueous well fluids |
| MY188299A (en) | 2016-11-17 | 2021-11-25 | Albemarle Corp | High density aqueous well fluids |
| CN106631764B (zh) * | 2016-12-21 | 2018-05-08 | 江西东鹏新材料有限责任公司 | 一种甲酸铷铯生产工艺 |
| CN113337734B (zh) * | 2021-04-25 | 2022-09-09 | 武汉科技大学 | 从含铷矿石中超声强化提取铷的方法 |
| CN115124054A (zh) * | 2022-06-20 | 2022-09-30 | 萍乡市拓源实业有限公司 | 从锂云母沉锂母液中分离提取铷、铯盐的方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3207571A (en) * | 1962-04-09 | 1965-09-21 | San Antonio Chemicals Inc | Process for preparing cesium compounds from cesium alum |
| US3489509A (en) * | 1967-05-18 | 1970-01-13 | Kewanee Oil Co | Process for recovery of cesium compounds of high purity |
| US4141373A (en) | 1977-09-28 | 1979-02-27 | Rjr Archer, Inc. | Method for deoiling metal scrap |
| FR2588847B1 (fr) * | 1985-10-18 | 1988-01-08 | Rhone Poulenc Spec Chim | Procede de preparation d'une solution aqueuse de fluorure de metal alcalin |
-
1992
- 1992-11-11 DE DE4237954A patent/DE4237954C1/de not_active Expired - Fee Related
-
1993
- 1993-11-10 PL PL93308990A patent/PL171649B1/pl unknown
- 1993-11-10 BR BR9307423-9A patent/BR9307423A/pt not_active IP Right Cessation
- 1993-11-10 AT AT94901785T patent/ATE152430T1/de not_active IP Right Cessation
- 1993-11-10 HU HU9501381A patent/HU213321B/hu not_active IP Right Cessation
- 1993-11-10 DE DE59306347T patent/DE59306347D1/de not_active Expired - Lifetime
- 1993-11-10 WO PCT/EP1993/003143 patent/WO1994011303A1/de not_active Application Discontinuation
- 1993-11-10 KR KR1019950701863A patent/KR0160829B1/ko not_active IP Right Cessation
- 1993-11-10 US US08/436,260 patent/US5593650A/en not_active Expired - Lifetime
- 1993-11-10 CA CA002149138A patent/CA2149138C/en not_active Expired - Lifetime
- 1993-11-10 DK DK94901785.9T patent/DK0668845T3/da active
- 1993-11-10 SK SK614-95A patent/SK61495A3/sk unknown
- 1993-11-10 AU AU56237/94A patent/AU669770B2/en not_active Expired
- 1993-11-10 CZ CZ951208A patent/CZ120895A3/cs unknown
- 1993-11-10 EP EP94901785A patent/EP0668845B1/de not_active Expired - Lifetime
- 1993-11-10 JP JP51170294A patent/JP3378007B2/ja not_active Expired - Lifetime
- 1993-11-10 LT LTIP1454A patent/LT3450B/lt not_active IP Right Cessation
- 1993-11-11 ZA ZA938429A patent/ZA938429B/xx unknown
- 1993-11-11 CN CN93114368A patent/CN1038668C/zh not_active Expired - Lifetime
-
1994
- 1994-11-16 EE EE9400163A patent/EE9400163A/xx unknown
-
1995
- 1995-05-10 NO NO19951845A patent/NO312889B1/no not_active IP Right Cessation
- 1995-05-10 FI FI952278A patent/FI952278A/fi unknown
- 1995-05-11 LV LVP-95-128A patent/LV10844B/lv unknown
-
1997
- 1997-06-20 GR GR970401495T patent/GR3023856T3/el unknown
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MK1K | Patent expired |