NO128713B - - Google Patents
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- Publication number
- NO128713B NO128713B NO02624/68A NO262468A NO128713B NO 128713 B NO128713 B NO 128713B NO 02624/68 A NO02624/68 A NO 02624/68A NO 262468 A NO262468 A NO 262468A NO 128713 B NO128713 B NO 128713B
- Authority
- NO
- Norway
- Prior art keywords
- tributyltin
- copper
- weight
- parts
- paint
- Prior art date
Links
- 239000003973 paint Substances 0.000 claims description 23
- 239000000203 mixture Substances 0.000 claims description 15
- 230000003373 anti-fouling effect Effects 0.000 claims description 12
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 11
- -1 tributyltin carboxylate Chemical class 0.000 claims description 11
- 230000002195 synergetic effect Effects 0.000 claims description 7
- 239000010949 copper Substances 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 5
- OBLNWSCLAYSJJR-UHFFFAOYSA-N Quinoclamin Chemical compound C1=CC=C2C(=O)C(N)=C(Cl)C(=O)C2=C1 OBLNWSCLAYSJJR-UHFFFAOYSA-N 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- YABTYYUIWFCMDW-SRTAMGJPSA-L bis(tributylstannyl) (e)-but-2-enedioate Chemical group CCCC[Sn](CCCC)(CCCC)OC(=O)\C=C\C(=O)O[Sn](CCCC)(CCCC)CCCC YABTYYUIWFCMDW-SRTAMGJPSA-L 0.000 claims description 2
- 229940120693 copper naphthenate Drugs 0.000 claims description 2
- SEVNKWFHTNVOLD-UHFFFAOYSA-L copper;3-(4-ethylcyclohexyl)propanoate;3-(3-ethylcyclopentyl)propanoate Chemical compound [Cu+2].CCC1CCC(CCC([O-])=O)C1.CCC1CCC(CCC([O-])=O)CC1 SEVNKWFHTNVOLD-UHFFFAOYSA-L 0.000 claims description 2
- ZKXWKVVCCTZOLD-UHFFFAOYSA-N copper;4-hydroxypent-3-en-2-one Chemical compound [Cu].CC(O)=CC(C)=O.CC(O)=CC(C)=O ZKXWKVVCCTZOLD-UHFFFAOYSA-N 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims description 2
- 230000002401 inhibitory effect Effects 0.000 claims description 2
- DFNPRTKVCGZMMC-UHFFFAOYSA-M tributyl(fluoro)stannane Chemical group CCCC[Sn](F)(CCCC)CCCC DFNPRTKVCGZMMC-UHFFFAOYSA-M 0.000 claims description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 7
- 239000005749 Copper compound Substances 0.000 description 6
- 150000001880 copper compounds Chemical class 0.000 description 6
- 239000013535 sea water Substances 0.000 description 6
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 5
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 5
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- UKWHYYKOEPRTIC-UHFFFAOYSA-N mercury(ii) oxide Chemical compound [Hg]=O UKWHYYKOEPRTIC-UHFFFAOYSA-N 0.000 description 4
- 229920000915 polyvinyl chloride Polymers 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 3
- 239000005751 Copper oxide Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 229910000431 copper oxide Inorganic materials 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- 229920003002 synthetic resin Polymers 0.000 description 3
- 239000000057 synthetic resin Substances 0.000 description 3
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- 230000002942 anti-growth Effects 0.000 description 2
- 239000002519 antifouling agent Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 229940101209 mercuric oxide Drugs 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 150000003606 tin compounds Chemical class 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 241001523707 Balanidae Species 0.000 description 1
- 239000005739 Bordeaux mixture Substances 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 229930192627 Naphthoquinone Natural products 0.000 description 1
- 241001523579 Ostrea Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- 241000251577 Styela Species 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 229910052933 brochantite Inorganic materials 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229940108928 copper Drugs 0.000 description 1
- 229940116318 copper carbonate Drugs 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- NJVOZLGKTAPUTQ-UHFFFAOYSA-M fentin chloride Chemical compound C=1C=CC=CC=1[Sn](C=1C=CC=CC=1)(Cl)C1=CC=CC=C1 NJVOZLGKTAPUTQ-UHFFFAOYSA-M 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- LITQZINTSYBKIU-UHFFFAOYSA-F tetracopper;hexahydroxide;sulfate Chemical class [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Cu+2].[Cu+2].[Cu+2].[Cu+2].[O-]S([O-])(=O)=O LITQZINTSYBKIU-UHFFFAOYSA-F 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4266567 | 1967-07-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO128713B true NO128713B (fr) | 1974-01-02 |
Family
ID=12642296
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO02624/68A NO128713B (fr) | 1967-07-03 | 1968-07-01 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3615744A (fr) |
| DE (1) | DE1769717A1 (fr) |
| GB (1) | GB1212247A (fr) |
| NL (1) | NL6809326A (fr) |
| NO (1) | NO128713B (fr) |
| SE (1) | SE337961B (fr) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4058402A (en) * | 1969-09-25 | 1977-11-15 | Phillips Petroleum Company | Water soluble rodent repellent composition for protecting a buried material such as a cable |
| FR2189444B1 (fr) * | 1972-06-19 | 1977-12-30 | Balsacq Guy | |
| US4012347A (en) * | 1975-11-03 | 1977-03-15 | M & T Chemicals Inc. | Antifouling composition |
| US4270953A (en) * | 1978-03-09 | 1981-06-02 | Kansai Paint Co., Ltd. | Two component antifouling paint |
| US4197233A (en) * | 1978-03-15 | 1980-04-08 | Kennecott Copper Corporation | Anti-fouling and anti-sliming coating material |
| US4314851A (en) * | 1979-02-09 | 1982-02-09 | Ogly Shakhtakhtinsky Togrul N | Antifouling coating compositions |
| DK149187B (da) * | 1979-05-10 | 1986-03-10 | M & T Chemicals Inc | Begroningshaemmende overtraeksmateriale indeholdende en phenyltinforbindelse |
| US4282126A (en) * | 1979-08-24 | 1981-08-04 | The United States Of America As Represented By The Secretary Of The Navy | Polyisobutylene rubber antifouling paint |
| US4482652A (en) * | 1980-12-01 | 1984-11-13 | Grow Group, Inc. | Marine anti-fouling paints |
| US5057153A (en) * | 1990-05-03 | 1991-10-15 | Olin Corporation | Paint containing high levels of a pyrithione salt plus a copper salt |
| US5098473A (en) * | 1991-03-04 | 1992-03-24 | Olin Corporation | Process for stabilizing zinc pyrithione plus cuprous oxide in paint |
| US5112397A (en) * | 1991-06-17 | 1992-05-12 | Olin Corporation | Process for stabilizing zinc pyrithione plus cuprous oxide in paint |
| WO1992015647A1 (fr) * | 1991-03-04 | 1992-09-17 | Olin Corporation | Procede de stabilisation de zinc pyrithione et d'oxyde cuivreux dans de la peinture |
| US5366004A (en) * | 1991-08-30 | 1994-11-22 | General Motors Corporation | Biostatic/biocidal coatings for air conditioner cores |
| US5137569A (en) * | 1991-10-10 | 1992-08-11 | Olin Corporation | Process for stabilizing zinc pyrithione plus cuprous oxide in paint |
| US5185033A (en) * | 1992-09-01 | 1993-02-09 | Olin Corporation | Gel-free paint containing copper pyrithione or pyrithione disulfide plus cuprous oxide |
| US5232493A (en) * | 1992-09-01 | 1993-08-03 | Olin Corporation | Process for stabilizing zinc pyrithione plus cuprous oxide in paint |
| US5238490A (en) * | 1992-09-04 | 1993-08-24 | Olin Corporation | Process for generating copper pyrithione in-situ in a paint formulation |
| US5246489A (en) * | 1992-09-04 | 1993-09-21 | Olin Corporation | Process for generating copper pyrithione in-situ in a paint formulation |
| US5298061A (en) * | 1993-05-14 | 1994-03-29 | Olin Corporation | Gel-free paint containing zinc pyrithione, cuprous oxide, and amine treated rosin |
| US5342437A (en) * | 1993-10-15 | 1994-08-30 | Olin Corporation | Gel-free paint containing zinc pyrithione cuprous oxide and carboxylic acid |
| US5403390A (en) * | 1994-03-11 | 1995-04-04 | Spera; Richard J. | Cuprous sulfide marine antifoulant paint |
| EP1035174A3 (fr) * | 1999-03-12 | 2000-10-18 | Josef Becker | Peinture applicable sous l'eau pour des navires |
| DE502004005077D1 (de) * | 2004-04-30 | 2007-11-08 | Ligrufa Ag | Wärmetauscher und Installation zur Entnahme von Wärme aus Abwasser |
| US7893047B2 (en) * | 2006-03-03 | 2011-02-22 | Arch Chemicals, Inc. | Biocide composition comprising pyrithione and pyrrole derivatives |
| EP2275466A1 (fr) | 2009-07-16 | 2011-01-19 | Bayer MaterialScience AG | Adhésif tissulaire à base de polyurée |
| US8541493B2 (en) * | 2010-02-19 | 2013-09-24 | Arch Chemicals, Inc. | Synthesis of zinc acrylate copolymer from acid functional copolymer, zinc pyrithione, and copper compound |
| JP2014524443A (ja) | 2011-08-17 | 2014-09-22 | アーチ・ケミカルズ・インコーポレーテッド | 亜鉛ピリチオンおよび銅化合物からの銅ピリチオンの合成 |
| CN102618137B (zh) * | 2012-04-01 | 2014-09-17 | 海洋化工研究院有限公司 | 绿色环保渔船防污漆及挂板实验方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2829082A (en) * | 1958-04-01 | Fungicidal composition comprising | ||
| US3111456A (en) * | 1961-06-08 | 1963-11-19 | Hochman Harry | Wood preservatives |
| US3214279A (en) * | 1961-06-09 | 1965-10-26 | M & T Chemicals Inc | Novel coating composition |
| US3266913A (en) * | 1962-11-14 | 1966-08-16 | Internat Mineral & Chemical Co | Marine antifouling composition and method of treating surfaces |
-
1968
- 1968-07-01 NO NO02624/68A patent/NO128713B/no unknown
- 1968-07-01 SE SE09068/68A patent/SE337961B/xx unknown
- 1968-07-02 NL NL6809326A patent/NL6809326A/xx unknown
- 1968-07-02 GB GB31451/68A patent/GB1212247A/en not_active Expired
- 1968-07-02 DE DE19681769717 patent/DE1769717A1/de active Pending
- 1968-07-03 US US742187A patent/US3615744A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| SE337961B (fr) | 1971-08-23 |
| NL6809326A (fr) | 1969-01-07 |
| US3615744A (en) | 1971-10-26 |
| GB1212247A (en) | 1970-11-11 |
| DE1769717A1 (de) | 1971-07-15 |
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