MY132853A - PROCESSES FOR PREPARING GLUFOSINATE AND PHOSPHORUS-CONTAINING a- AMINONITRILES AS INTERMEDIATES - Google Patents
PROCESSES FOR PREPARING GLUFOSINATE AND PHOSPHORUS-CONTAINING a- AMINONITRILES AS INTERMEDIATESInfo
- Publication number
- MY132853A MY132853A MYPI98003746A MYPI9803746A MY132853A MY 132853 A MY132853 A MY 132853A MY PI98003746 A MYPI98003746 A MY PI98003746A MY PI9803746 A MYPI9803746 A MY PI9803746A MY 132853 A MY132853 A MY 132853A
- Authority
- MY
- Malaysia
- Prior art keywords
- aminonitriles
- phosphorus
- glufosinate
- intermediates
- processes
- Prior art date
Links
- IAJOBQBIJHVGMQ-UHFFFAOYSA-N 2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid Chemical compound CP(O)(=O)CCC(N)C(O)=O IAJOBQBIJHVGMQ-UHFFFAOYSA-N 0.000 title abstract 3
- 239000005561 Glufosinate Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 239000000543 intermediate Substances 0.000 title 1
- -1 KETO COMPOUNDS Chemical class 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 229930194542 Keto Natural products 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 238000007059 Strecker synthesis reaction Methods 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 230000007062 hydrolysis Effects 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000007040 multi-step synthesis reaction Methods 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/657163—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms the ring phosphorus atom being bound to at least one carbon atom
- C07F9/657172—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms the ring phosphorus atom being bound to at least one carbon atom the ring phosphorus atom and one oxygen atom being part of a (thio)phosphinic acid ester: (X = O, S)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
- C07F9/301—Acyclic saturated acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
- C07F9/32—Esters thereof
- C07F9/3205—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/3211—Esters of acyclic saturated acids which can have further substituents on alkyl
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19736125A DE19736125A1 (de) | 1997-08-20 | 1997-08-20 | Verfahren zur Herstellung von Glufosinate und phosphorhaltige alpha-Aminonitrile als Zwischenprodukte |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MY132853A true MY132853A (en) | 2007-10-31 |
Family
ID=7839559
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MYPI98003746A MY132853A (en) | 1997-08-20 | 1998-08-18 | PROCESSES FOR PREPARING GLUFOSINATE AND PHOSPHORUS-CONTAINING a- AMINONITRILES AS INTERMEDIATES |
Country Status (27)
| Country | Link |
|---|---|
| US (1) | US6359162B1 (OSRAM) |
| EP (1) | EP1005475B1 (OSRAM) |
| JP (1) | JP4519316B2 (OSRAM) |
| KR (1) | KR100674326B1 (OSRAM) |
| CN (1) | CN1261442C (OSRAM) |
| AR (1) | AR015932A1 (OSRAM) |
| AT (1) | ATE258180T1 (OSRAM) |
| AU (1) | AU756471B2 (OSRAM) |
| BR (1) | BR9811971B1 (OSRAM) |
| CA (1) | CA2301181C (OSRAM) |
| CO (1) | CO5031316A1 (OSRAM) |
| CZ (1) | CZ2000593A3 (OSRAM) |
| DE (2) | DE19736125A1 (OSRAM) |
| DK (1) | DK1005475T3 (OSRAM) |
| ES (1) | ES2214727T3 (OSRAM) |
| HU (1) | HUP0003501A3 (OSRAM) |
| IL (1) | IL134633A0 (OSRAM) |
| MY (1) | MY132853A (OSRAM) |
| PH (1) | PH11998002119A1 (OSRAM) |
| PL (1) | PL191587B1 (OSRAM) |
| PT (1) | PT1005475E (OSRAM) |
| RU (1) | RU2275376C2 (OSRAM) |
| TR (1) | TR200000456T2 (OSRAM) |
| TW (1) | TW530063B (OSRAM) |
| UA (1) | UA66806C2 (OSRAM) |
| WO (1) | WO1999009039A1 (OSRAM) |
| ZA (1) | ZA987465B (OSRAM) |
Families Citing this family (48)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2323223C2 (ru) * | 2002-03-21 | 2008-04-27 | Шеринг Акциенгезельшафт | Ингибиторы карбоксипептидазы b плазмы (крови) |
| US7795464B2 (en) | 2006-09-20 | 2010-09-14 | Meiji Seika Kaisha Ltd. | Method for producing α-amino acid including phosphorus and production intermediates thereof |
| BR112012026205A2 (pt) | 2010-04-14 | 2015-11-03 | Strategic Enzyme Applic Inc | processo para produção enzimática de um produto de fosfinotricina ou um precursor do mesmo |
| CN102372738B (zh) * | 2010-08-14 | 2017-11-10 | 武汉工程大学 | Lj反应在制备维蒂希试剂和草铵膦中的应用 |
| MY167395A (en) | 2011-09-30 | 2018-08-16 | Meiji Seika Pharma Co Ltd | Method for producing glufosinate p free acid |
| CN102372739B (zh) * | 2011-12-05 | 2017-06-16 | 河北威远生化农药有限公司 | 一种草铵膦的合成方法 |
| CN102399240A (zh) * | 2011-12-27 | 2012-04-04 | 江苏优士化学有限公司 | 一种改进的草铵膦及类似物的合成方法 |
| CN102399239A (zh) * | 2011-12-27 | 2012-04-04 | 江苏优士化学有限公司 | 一种草铵膦及类似物的合成方法 |
| CN103183707B (zh) * | 2011-12-30 | 2016-06-15 | 中化蓝天集团有限公司 | 一种草胺膦的制备方法 |
| CN102584893B (zh) * | 2012-02-07 | 2015-03-04 | 浙江工业大学 | 一种草铵膦的制备方法 |
| CN103374030B (zh) * | 2012-04-13 | 2016-03-23 | 浙江新安化工集团股份有限公司 | 一种制备草铵膦的方法及其中间体的制备方法 |
| CN103483379A (zh) * | 2013-09-26 | 2014-01-01 | 江苏辉丰农化股份有限公司 | 一种草铵膦酸的制备方法 |
| CN113264958A (zh) * | 2014-05-13 | 2021-08-17 | 拜耳作物科学股份公司 | 制备含磷羟腈的方法 |
| CN104558033B (zh) * | 2014-12-19 | 2016-05-18 | 浙江工业大学 | 一种l-草铵膦-n-羧酸酐及其制备和应用 |
| EP3288381A1 (en) | 2015-04-27 | 2018-03-07 | Bayer CropScience Aktiengesellschaft | Herbicide combinations comprising glufosinate and indaziflam |
| US10611785B2 (en) | 2015-09-02 | 2020-04-07 | Basf Se | Process for producing phosphorus-containing cyanohydrin esters |
| CN108026122B (zh) | 2015-09-02 | 2021-03-09 | 拜耳作物科学股份公司 | 制备含磷氰醇酯的方法 |
| CN108137628B (zh) | 2015-09-02 | 2020-10-09 | 拜耳农作物科学股份公司 | 制备含磷的氰醇酯的方法 |
| US10196410B2 (en) | 2015-09-02 | 2019-02-05 | Bayer Cropscience Aktiengesellschaft | Process for producing phosphorus-containing cyanohydrin esters |
| TWI721019B (zh) | 2015-09-29 | 2021-03-11 | 德商拜耳作物科學股份有限公司 | 製造膦酸酯之方法 |
| CN107236001A (zh) * | 2016-04-06 | 2017-10-10 | 四川省乐山市福华通达农药科技有限公司 | 一种膦醛的合成方法 |
| CN107417721B (zh) * | 2016-05-24 | 2019-05-28 | 四川福思达生物技术开发有限责任公司 | 一种氢氰酸加成工艺 |
| WO2018108797A1 (de) | 2016-12-15 | 2018-06-21 | Bayer Cropscience Aktiengesellschaft | Verfahren zur herstellung von l-glufosinat oder dessen salzen unter verwendung von ephedrin |
| WO2018108794A1 (de) | 2016-12-15 | 2018-06-21 | Bayer Cropscience Aktiengesellschaft | Verfahren zur herstellung von d-glufosinat oder dessen salzen unter verwendung von ephedrin |
| EP3392237B1 (de) | 2017-04-21 | 2019-10-02 | Evonik Degussa GmbH | Verfahren zur herstellung von acroleincyanhydrinen |
| CN111065270A (zh) * | 2017-07-18 | 2020-04-24 | 阿格里麦蒂斯有限责任公司 | L-草胺膦的生产方法 |
| KR102644410B1 (ko) | 2017-07-21 | 2024-03-06 | 바스프 에스이 | N-부틸(3-아미노-3-시아노프로필)메틸포스피네이트 및 (3-아미노-3-시아노프로필)메틸포스핀산 암모늄 염의 혼합물을 제공하기 위한 3-[n-부톡시(메틸)포스포릴]-1-시아노프로필 아세테이트의 반응에 의한 글루포시네이트의 제조 |
| US11220520B2 (en) | 2017-12-19 | 2022-01-11 | Basf Se | Method for preparing phosphorus-containing α-aminonitriles |
| CN109134534B (zh) * | 2018-08-08 | 2020-09-08 | 江苏好收成韦恩农化股份有限公司 | 一种3,3-二烷氧基丙基甲基膦酸酯简易制备方法 |
| KR102131687B1 (ko) * | 2018-09-10 | 2020-07-08 | 주식회사 휴런 | 파킨슨 병 진단 장치 및 방법 |
| BR112021013271B1 (pt) | 2019-01-11 | 2024-02-20 | Cj Cheiljedang Corporation | Método de preparação de intermediário de l-glufosinato e de lglufosinato |
| CN111662326B (zh) * | 2019-03-05 | 2023-03-24 | 利尔化学股份有限公司 | 一种制备l-草铵膦的方法 |
| CN111662325B (zh) * | 2019-03-05 | 2023-03-24 | 利尔化学股份有限公司 | 一种制备l-草铵膦的方法 |
| CN111662324B (zh) * | 2019-03-05 | 2023-02-24 | 利尔化学股份有限公司 | 一种制备l-草铵膦的方法 |
| CN110003269B (zh) * | 2019-04-29 | 2022-04-05 | 利尔化学股份有限公司 | 低能耗生产草铵膦的方法 |
| CN110590836B (zh) * | 2019-09-30 | 2022-07-26 | 江苏七洲绿色化工股份有限公司 | 一种草铵膦中间体的合成方法 |
| CN112898338A (zh) * | 2019-12-04 | 2021-06-04 | 利尔化学股份有限公司 | 草铵膦中间体及草铵膦的制备方法 |
| CN111659330B (zh) * | 2020-04-23 | 2021-05-07 | 河北威远生物化工有限公司 | 一种连续化生产草铵膦的工艺与设备 |
| CN112358499A (zh) * | 2020-11-12 | 2021-02-12 | 江苏春江润田农化有限公司 | 一种草铵膦的合成方法 |
| PE20241062A1 (es) | 2021-04-01 | 2024-05-13 | Evonik Operations Gmbh | Procedimiento enzimatico para la produccion de l-glufosinato y sus fosfoesteres |
| EP4105335A1 (en) | 2021-06-16 | 2022-12-21 | Evonik Operations GmbH | Enzymatic method for the production of l-glufosinate p-alkyl esters |
| HUE068217T2 (hu) * | 2021-07-20 | 2024-12-28 | Lier Chemical Co Ltd | Glufozinát vagy analógjának elõállítására szolgáló eljárás |
| EP4151643A1 (en) | 2021-09-16 | 2023-03-22 | Evonik Operations GmbH | Improved process for production of phosphoesters of glufosinate precursors |
| CN114163472B (zh) * | 2021-11-27 | 2024-08-09 | 永农生物科学有限公司 | 醇溶剂下合成α-氨基腈的方法及草铵膦的合成方法 |
| WO2023174511A1 (en) | 2022-03-14 | 2023-09-21 | Evonik Operations Gmbh | Enzymatic method for the production of l-glufosinate p-esters |
| CN116789695B (zh) * | 2022-11-17 | 2024-03-29 | 永农生物科学有限公司 | 一种草铵膦的制备方法 |
| WO2024175643A1 (en) | 2023-02-23 | 2024-08-29 | Basf Se | A process for preparing l-glufosinate from cyanhydrine or cyanhydrine derivatives |
| WO2024256370A1 (en) | 2023-06-13 | 2024-12-19 | Basf Se | Synthesis of glufosinate using an amidase-based process |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5484529A (en) * | 1977-12-19 | 1979-07-05 | Meiji Seika Kaisha Ltd | Production of d,l-2-amino-4-methylphosphinobutyric acid |
| DE2849003A1 (de) * | 1978-11-11 | 1980-08-21 | Hoechst Ag | Phosphorhaltige cyanhydrinderivate und verfahren zu ihrer herstellung |
| DE3508573A1 (de) * | 1985-03-11 | 1986-09-11 | Hoechst Ag, 6230 Frankfurt | Phosphorhaltige (alpha)-aminonitrile und verfahren zu ihrer herstellung |
| JP2615777B2 (ja) * | 1987-05-26 | 1997-06-04 | 日産化学工業株式会社 | ホスフィニルアミノ酸誘導体の製造方法 |
| RU2024536C1 (ru) * | 1992-01-09 | 1994-12-15 | Институт элементоорганических соединений РАН | 4-триметилсилоксиметилфосфинил -2- триметилсилокси -2-бутеннитрил в качестве полупродукта синтеза 4-метилгидроксифосфинил-2- кетобутановой кислоты, обладающей гербицидной активностью, и способы его получения |
-
1997
- 1997-08-20 DE DE19736125A patent/DE19736125A1/de not_active Withdrawn
-
1998
- 1998-08-08 PL PL338855A patent/PL191587B1/pl not_active IP Right Cessation
- 1998-08-08 WO PCT/EP1998/005053 patent/WO1999009039A1/de not_active Ceased
- 1998-08-08 BR BRPI9811971-0A patent/BR9811971B1/pt not_active IP Right Cessation
- 1998-08-08 AT AT98945195T patent/ATE258180T1/de not_active IP Right Cessation
- 1998-08-08 US US09/486,031 patent/US6359162B1/en not_active Expired - Lifetime
- 1998-08-08 EP EP98945195A patent/EP1005475B1/de not_active Expired - Lifetime
- 1998-08-08 CN CNB988082616A patent/CN1261442C/zh not_active Expired - Lifetime
- 1998-08-08 JP JP2000509718A patent/JP4519316B2/ja not_active Expired - Lifetime
- 1998-08-08 CZ CZ2000593A patent/CZ2000593A3/cs unknown
- 1998-08-08 ES ES98945195T patent/ES2214727T3/es not_active Expired - Lifetime
- 1998-08-08 DK DK98945195T patent/DK1005475T3/da active
- 1998-08-08 AU AU92598/98A patent/AU756471B2/en not_active Ceased
- 1998-08-08 PT PT98945195T patent/PT1005475E/pt unknown
- 1998-08-08 RU RU2000107139/04A patent/RU2275376C2/ru not_active IP Right Cessation
- 1998-08-08 CA CA002301181A patent/CA2301181C/en not_active Expired - Fee Related
- 1998-08-08 IL IL13463398A patent/IL134633A0/xx not_active IP Right Cessation
- 1998-08-08 DE DE59810636T patent/DE59810636D1/de not_active Expired - Lifetime
- 1998-08-08 HU HU0003501A patent/HUP0003501A3/hu unknown
- 1998-08-08 UA UA2000031510A patent/UA66806C2/uk unknown
- 1998-08-08 TR TR2000/00456T patent/TR200000456T2/xx unknown
- 1998-08-08 KR KR1020007001687A patent/KR100674326B1/ko not_active Expired - Lifetime
- 1998-08-18 MY MYPI98003746A patent/MY132853A/en unknown
- 1998-08-18 CO CO98046950A patent/CO5031316A1/es unknown
- 1998-08-18 AR ARP980104072A patent/AR015932A1/es active IP Right Grant
- 1998-08-18 TW TW087113567A patent/TW530063B/zh not_active IP Right Cessation
- 1998-08-19 ZA ZA987465A patent/ZA987465B/xx unknown
- 1998-08-19 PH PH11998002119A patent/PH11998002119A1/en unknown
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