MXPA04011464A

MXPA04011464A - Revestimientos curados al ambiente y productos de hule revestidos con los mismos.

Revestimientos curados al ambiente y productos de hule revestidos con los mismos.

Info

Publication number: MXPA04011464A
Authority: MX; Mexico
Prior art keywords: group; film; polymer; acrylate; acid
Prior art date: 2002-07-25

Application number

MXPA04011464A

Other languages

English (en)

Spanish (es)

Inventor

R Halladay James

Original Assignee

Lord Corp

Priority date

2002-07-25

Filing date

2003-07-24

Publication date

2005-02-14

2002-07-25 Priority claimed from US10/205,178 external-priority patent/US6844412B2/en

2002-10-07 Priority claimed from US10/265,576 external-priority patent/US6777026B2/en

2003-07-24 Application filed by Lord Corp filed Critical Lord Corp

2005-02-14 Publication of MXPA04011464A publication Critical patent/MXPA04011464A/es

Links

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238000000576 coating method Methods 0.000 title claims abstract description 62
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239000011248 coating agent Substances 0.000 claims abstract description 39
239000000203 mixture Substances 0.000 claims abstract description 27
239000002245 particle Substances 0.000 claims abstract description 17
239000008199 coating composition Substances 0.000 claims abstract description 11
239000007787 solid Substances 0.000 claims abstract description 9
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239000000178 monomer Substances 0.000 claims description 86
125000000524 functional group Chemical group 0.000 claims description 79
238000000034 method Methods 0.000 claims description 72
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239000000806 elastomer Substances 0.000 claims description 45
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 32
239000003795 chemical substances by application Substances 0.000 claims description 32
150000001993 dienes Chemical class 0.000 claims description 31
239000001257 hydrogen Substances 0.000 claims description 31
229910052739 hydrogen Inorganic materials 0.000 claims description 31
239000012948 isocyanate Substances 0.000 claims description 30
ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 29
150000002148 esters Chemical class 0.000 claims description 28
150000002513 isocyanates Chemical class 0.000 claims description 28
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 26
150000001412 amines Chemical class 0.000 claims description 24
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239000002904 solvent Substances 0.000 claims description 20
239000005977 Ethylene Substances 0.000 claims description 17
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239000002253 acid Chemical group 0.000 claims description 16
150000008064 anhydrides Chemical class 0.000 claims description 15
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150000003141 primary amines Chemical class 0.000 claims description 10
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238000007254 oxidation reaction Methods 0.000 claims description 5
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239000007795 chemical reaction product Substances 0.000 claims description 4
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238000006385 ozonation reaction Methods 0.000 claims description 4
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ZYAASQNKCWTPKI-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propan-1-amine Chemical compound CO[Si](C)(OC)CCCN ZYAASQNKCWTPKI-UHFFFAOYSA-N 0.000 claims description 3
244000043261 Hevea brasiliensis Species 0.000 claims description 3
125000005250 alkyl acrylate group Chemical group 0.000 claims description 3
230000001747 exhibiting effect Effects 0.000 claims description 3
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KBJFYLLAMSZSOG-UHFFFAOYSA-N n-(3-trimethoxysilylpropyl)aniline Chemical compound CO[Si](OC)(OC)CCCNC1=CC=CC=C1 KBJFYLLAMSZSOG-UHFFFAOYSA-N 0.000 claims description 3
DVYVMJLSUSGYMH-UHFFFAOYSA-N n-methyl-3-trimethoxysilylpropan-1-amine Chemical compound CNCCC[Si](OC)(OC)OC DVYVMJLSUSGYMH-UHFFFAOYSA-N 0.000 claims description 3
229920003052 natural elastomer Polymers 0.000 claims description 3
229920001194 natural rubber Polymers 0.000 claims description 3
WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical group CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims description 3
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230000001680 brushing effect Effects 0.000 claims description 2
LNDKRVOOYMEYTC-UHFFFAOYSA-N buta-1,3-dien-1-ol Chemical class OC=CC=C LNDKRVOOYMEYTC-UHFFFAOYSA-N 0.000 claims description 2
238000007033 dehydrochlorination reaction Methods 0.000 claims description 2
238000007598 dipping method Methods 0.000 claims description 2
INJVFBCDVXYHGQ-UHFFFAOYSA-N n'-(3-triethoxysilylpropyl)ethane-1,2-diamine Chemical compound CCO[Si](OCC)(OCC)CCCNCCN INJVFBCDVXYHGQ-UHFFFAOYSA-N 0.000 claims description 2
229920002587 poly(1,3-butadiene) polymer Polymers 0.000 claims description 2
229920000346 polystyrene-polyisoprene block-polystyrene Polymers 0.000 claims description 2
238000005507 spraying Methods 0.000 claims description 2
229920006132 styrene block copolymer Polymers 0.000 claims description 2
150000003512 tertiary amines Chemical class 0.000 claims description 2
KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 claims 1
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QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims 1
OCWCVKQSJSKTHM-UHFFFAOYSA-N [bis(3-aminopropyl)-ethoxysilyl] triethyl silicate Chemical compound NCCC[Si](OCC)(CCCN)O[Si](OCC)(OCC)OCC OCWCVKQSJSKTHM-UHFFFAOYSA-N 0.000 claims 1
MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical class C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims 1
XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 claims 1
239000013536 elastomeric material Substances 0.000 claims 1
150000002431 hydrogen Chemical class 0.000 claims 1
DOUHZFSGSXMPIE-UHFFFAOYSA-N hydroxidooxidosulfur(.) Chemical compound [O]SO DOUHZFSGSXMPIE-UHFFFAOYSA-N 0.000 claims 1
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239000002841 Lewis acid Substances 0.000 description 5
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238000005755 formation reaction Methods 0.000 description 5
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MNMVKGDEKPPREK-UHFFFAOYSA-N trimethyl(prop-2-enoxy)silane Chemical compound C[Si](C)(C)OCC=C MNMVKGDEKPPREK-UHFFFAOYSA-N 0.000 description 1
HYWCXWRMUZYRPH-UHFFFAOYSA-N trimethyl(prop-2-enyl)silane Chemical compound C[Si](C)(C)CC=C HYWCXWRMUZYRPH-UHFFFAOYSA-N 0.000 description 1
UYPYRKYUKCHHIB-UHFFFAOYSA-N trimethylamine N-oxide Chemical compound C[N+](C)(C)[O-] UYPYRKYUKCHHIB-UHFFFAOYSA-N 0.000 description 1
PGQNYIRJCLTTOJ-UHFFFAOYSA-N trimethylsilyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)O[Si](C)(C)C PGQNYIRJCLTTOJ-UHFFFAOYSA-N 0.000 description 1
CWMFRHBXRUITQE-UHFFFAOYSA-N trimethylsilylacetylene Chemical group C[Si](C)(C)C#C CWMFRHBXRUITQE-UHFFFAOYSA-N 0.000 description 1
DSROZUMNVRXZNO-UHFFFAOYSA-K tris[(1-naphthalen-1-yl-3-phenylnaphthalen-2-yl)oxy]alumane Chemical compound C=1C=CC=CC=1C=1C=C2C=CC=CC2=C(C=2C3=CC=CC=C3C=CC=2)C=1O[Al](OC=1C(=C2C=CC=CC2=CC=1C=1C=CC=CC=1)C=1C2=CC=CC=C2C=CC=1)OC(C(=C1C=CC=CC1=C1)C=2C3=CC=CC=C3C=CC=2)=C1C1=CC=CC=C1 DSROZUMNVRXZNO-UHFFFAOYSA-K 0.000 description 1
239000005050 vinyl trichlorosilane Substances 0.000 description 1
229920003249 vinylidene fluoride hexafluoropropylene elastomer Polymers 0.000 description 1
UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical compound [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 1
238000004073 vulcanization Methods 0.000 description 1
239000004636 vulcanized rubber Substances 0.000 description 1
125000005023 xylyl group Chemical group 0.000 description 1
XKMZOFXGLBYJLS-UHFFFAOYSA-L zinc;prop-2-enoate Chemical compound [Zn+2].[O-]C(=O)C=C.[O-]C(=O)C=C XKMZOFXGLBYJLS-UHFFFAOYSA-L 0.000 description 1