MXPA04011464A - Revestimientos curados al ambiente y productos de hule revestidos con los mismos. - Google Patents

Info

Publication number

MXPA04011464A

MXPA04011464A MXPA04011464A MXPA04011464A MXPA04011464A MX PA04011464 A MXPA04011464 A MX PA04011464A MX PA04011464 A MXPA04011464 A MX PA04011464A MX PA04011464 A MXPA04011464 A MX PA04011464A MX PA04011464 A MXPA04011464 A MX PA04011464A

Authority

MX

Mexico

Prior art keywords

group

film

polymer

acrylate

acid

Prior art date

2002-07-25

Links

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• 229920000642 polymer Polymers 0.000 claims abstract description 158
• 239000011248 coating agent Substances 0.000 claims abstract description 39
• 239000000203 mixture Substances 0.000 claims abstract description 27
• 239000002245 particle Substances 0.000 claims abstract description 17
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• 239000000178 monomer Substances 0.000 claims description 86
• 125000000524 functional group Chemical group 0.000 claims description 79
• 238000000034 method Methods 0.000 claims description 72
• 229920000459 Nitrile rubber Polymers 0.000 claims description 61
• 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 49
• 239000000806 elastomer Substances 0.000 claims description 45
• 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 32
• 239000003795 chemical substances by application Substances 0.000 claims description 32
• 150000001993 dienes Chemical class 0.000 claims description 31
• 239000001257 hydrogen Substances 0.000 claims description 31
• 229910052739 hydrogen Inorganic materials 0.000 claims description 31
• 239000012948 isocyanate Substances 0.000 claims description 30
• ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 29
• 150000002148 esters Chemical class 0.000 claims description 28
• 150000002513 isocyanates Chemical class 0.000 claims description 28
• KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 26
• 150000001412 amines Chemical class 0.000 claims description 24
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 21
• 239000002904 solvent Substances 0.000 claims description 20
• 239000005977 Ethylene Substances 0.000 claims description 17
• 150000002825 nitriles Chemical class 0.000 claims description 17
• 229910000077 silane Inorganic materials 0.000 claims description 17
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 16
• BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 16
• 239000002253 acid Chemical group 0.000 claims description 16
• 150000008064 anhydrides Chemical class 0.000 claims description 15
• OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 14
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• VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 13
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• 150000002430 hydrocarbons Chemical class 0.000 claims description 8
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• WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 6
• 229920001400 block copolymer Polymers 0.000 claims description 6
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• 229930195734 saturated hydrocarbon Natural products 0.000 claims description 6
• IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 claims description 5
• XLYMOEINVGRTEX-ARJAWSKDSA-N Ethyl hydrogen fumarate Chemical compound CCOC(=O)\C=C/C(O)=O XLYMOEINVGRTEX-ARJAWSKDSA-N 0.000 claims description 5
• XLYMOEINVGRTEX-UHFFFAOYSA-N fumaric acid monoethyl ester Natural products CCOC(=O)C=CC(O)=O XLYMOEINVGRTEX-UHFFFAOYSA-N 0.000 claims description 5
• PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 claims description 5
• 230000003647 oxidation Effects 0.000 claims description 5
• 238000007254 oxidation reaction Methods 0.000 claims description 5
• FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical group [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 claims description 5
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• SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 claims description 4
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• 150000002762 monocarboxylic acid derivatives Chemical class 0.000 claims description 4
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• 229920001451 polypropylene glycol Polymers 0.000 claims description 4
• 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims description 4
• 229920001567 vinyl ester resin Polymers 0.000 claims description 4
• ZYAASQNKCWTPKI-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propan-1-amine Chemical compound CO[Si](C)(OC)CCCN ZYAASQNKCWTPKI-UHFFFAOYSA-N 0.000 claims description 3
• 244000043261 Hevea brasiliensis Species 0.000 claims description 3
• 125000005250 alkyl acrylate group Chemical group 0.000 claims description 3
• 230000001747 exhibiting effect Effects 0.000 claims description 3
• 150000002763 monocarboxylic acids Chemical class 0.000 claims description 3
• KBJFYLLAMSZSOG-UHFFFAOYSA-N n-(3-trimethoxysilylpropyl)aniline Chemical compound CO[Si](OC)(OC)CCCNC1=CC=CC=C1 KBJFYLLAMSZSOG-UHFFFAOYSA-N 0.000 claims description 3
• DVYVMJLSUSGYMH-UHFFFAOYSA-N n-methyl-3-trimethoxysilylpropan-1-amine Chemical compound CNCCC[Si](OC)(OC)OC DVYVMJLSUSGYMH-UHFFFAOYSA-N 0.000 claims description 3
• 229920003052 natural elastomer Polymers 0.000 claims description 3
• 229920001194 natural rubber Polymers 0.000 claims description 3
• WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical group CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims description 3
• VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical class CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 claims description 2
• 230000001680 brushing effect Effects 0.000 claims description 2
• LNDKRVOOYMEYTC-UHFFFAOYSA-N buta-1,3-dien-1-ol Chemical class OC=CC=C LNDKRVOOYMEYTC-UHFFFAOYSA-N 0.000 claims description 2
• 238000007033 dehydrochlorination reaction Methods 0.000 claims description 2
• 238000007598 dipping method Methods 0.000 claims description 2
• INJVFBCDVXYHGQ-UHFFFAOYSA-N n'-(3-triethoxysilylpropyl)ethane-1,2-diamine Chemical compound CCO[Si](OCC)(OCC)CCCNCCN INJVFBCDVXYHGQ-UHFFFAOYSA-N 0.000 claims description 2
• 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 claims description 2
• 229920000346 polystyrene-polyisoprene block-polystyrene Polymers 0.000 claims description 2
• 238000005507 spraying Methods 0.000 claims description 2
• 229920006132 styrene block copolymer Polymers 0.000 claims description 2
• 150000003512 tertiary amines Chemical class 0.000 claims description 2
• KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 claims 1
• 239000002174 Styrene-butadiene Substances 0.000 claims 1
• QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims 1
• OCWCVKQSJSKTHM-UHFFFAOYSA-N [bis(3-aminopropyl)-ethoxysilyl] triethyl silicate Chemical compound NCCC[Si](OCC)(CCCN)O[Si](OCC)(OCC)OCC OCWCVKQSJSKTHM-UHFFFAOYSA-N 0.000 claims 1
• MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical class C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims 1
• XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 claims 1
• 239000013536 elastomeric material Substances 0.000 claims 1
• 150000002431 hydrogen Chemical class 0.000 claims 1
• DOUHZFSGSXMPIE-UHFFFAOYSA-N hydroxidooxidosulfur(.) Chemical compound [O]SO DOUHZFSGSXMPIE-UHFFFAOYSA-N 0.000 claims 1
• 229920003049 isoprene rubber Polymers 0.000 claims 1
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• 229920002755 poly(epichlorohydrin) Chemical group 0.000 claims 1
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• 150000007934 α,β-unsaturated carboxylic acids Chemical class 0.000 claims 1
• 229910052751 metal Inorganic materials 0.000 abstract description 14
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• 150000003254 radicals Chemical class 0.000 description 33
• 125000004432 carbon atom Chemical group C* 0.000 description 31
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• 125000004435 hydrogen atom Chemical class [H]* 0.000 description 29
• 229920001973 fluoroelastomer Polymers 0.000 description 28
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• 125000000217 alkyl group Chemical group 0.000 description 22
• 239000000243 solution Substances 0.000 description 22
• 150000001252 acrylic acid derivatives Chemical class 0.000 description 21
• NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 21
• 239000003054 catalyst Substances 0.000 description 21
• 239000000758 substrate Substances 0.000 description 19
• VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 18
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• RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 16
• 239000003999 initiator Substances 0.000 description 16
• HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 15
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• CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 15
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• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
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• 125000003277 amino group Chemical group 0.000 description 8
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• 239000000047 product Substances 0.000 description 7
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• SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 6
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• 238000009833 condensation Methods 0.000 description 6
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• 125000003700 epoxy group Chemical group 0.000 description 6
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 6
• 238000010438 heat treatment Methods 0.000 description 6
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• 229920001568 phenolic resin Polymers 0.000 description 6
• 239000005011 phenolic resin Substances 0.000 description 6
• BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 6
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• CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 5
• ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
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• 239000002841 Lewis acid Substances 0.000 description 5
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• 125000005843 halogen group Chemical group 0.000 description 5
• HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 5
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• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
• 230000005855 radiation Effects 0.000 description 5
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