MXPA04004942A - Proceso para preparacion de catalizador de niquel/ligando fosforos para hidrocianacion de olefinas. - Google Patents
Proceso para preparacion de catalizador de niquel/ligando fosforos para hidrocianacion de olefinas.Info
- Publication number
- MXPA04004942A MXPA04004942A MXPA04004942A MXPA04004942A MXPA04004942A MX PA04004942 A MXPA04004942 A MX PA04004942A MX PA04004942 A MXPA04004942 A MX PA04004942A MX PA04004942 A MXPA04004942 A MX PA04004942A MX PA04004942 A MXPA04004942 A MX PA04004942A
- Authority
- MX
- Mexico
- Prior art keywords
- nickel
- preparation
- phosphorus ligand
- ligand catalyst
- olefin hydrocyanation
- Prior art date
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title abstract 4
- 239000003054 catalyst Substances 0.000 title abstract 2
- 238000005669 hydrocyanation reaction Methods 0.000 title abstract 2
- 239000003446 ligand Substances 0.000 title abstract 2
- 229910052759 nickel Inorganic materials 0.000 title abstract 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title 1
- 150000001336 alkenes Chemical class 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title 1
- 229910052698 phosphorus Inorganic materials 0.000 title 1
- 239000011574 phosphorus Substances 0.000 title 1
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 abstract 2
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 abstract 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
- B01J31/30—Halides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/08—Halides; Oxyhalides
- C01G53/09—Chlorides; Oxychlorides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/04—Nickel compounds
- C07F15/045—Nickel compounds without a metal-carbon linkage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
- C01P2002/88—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by thermal analysis data, e.g. TGA, DTA, DSC
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
- C01P2006/82—Compositional purity water content
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Nanotechnology (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Composite Materials (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/994,102 US6893996B2 (en) | 2001-11-26 | 2001-11-26 | Process for the preparation of a nickel/phosphorous ligand catalyst for olefin hydrocyanation |
| PCT/US2002/036468 WO2003045555A2 (en) | 2001-11-26 | 2002-11-14 | Process for the preparation of a nickel/phosphorus ligand catalyst for olefin hydrocyanation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MXPA04004942A true MXPA04004942A (es) | 2004-08-11 |
Family
ID=25540279
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MXPA04004942A MXPA04004942A (es) | 2001-11-26 | 2002-11-14 | Proceso para preparacion de catalizador de niquel/ligando fosforos para hidrocianacion de olefinas. |
Country Status (17)
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030100803A1 (en) * | 2001-11-26 | 2003-05-29 | Lu Helen S.M. | 3-Alkylated-5,5',6,6',7,7,'8,8'-octahydro-2,2'-binaphthols and 3,3'-dialkylated-5,5',6,6',7,7',8,8'-octahydro-2,2'-binaphthols and processes for making them |
| FR2849027B1 (fr) * | 2002-12-23 | 2005-01-21 | Rhodia Polyamide Intermediates | Procede de synthese de composes comprenant des fonctions nitriles a partir de composes a insaturations ethyleniques |
| US6897329B2 (en) * | 2003-01-14 | 2005-05-24 | Invista North America S.A.R.L. | Process for the preparation of nickel/phosphorous ligand catalyst for olefin hydrocyanation |
| FR2850966B1 (fr) | 2003-02-10 | 2005-03-18 | Rhodia Polyamide Intermediates | Procede de fabrication de composes dinitriles |
| FR2854891B1 (fr) | 2003-05-12 | 2006-07-07 | Rhodia Polyamide Intermediates | Procede de preparation de dinitriles |
| FR2854892B1 (fr) * | 2003-05-12 | 2005-06-24 | Rhodia Polyamide Intermediates | Procede de fabrication de dinitriles |
| DE10351002A1 (de) * | 2003-10-30 | 2005-05-25 | Basf Ag | Einsatz von azeotrop-getrockneten Nickel(II)-halogeniden |
| DE10351003A1 (de) * | 2003-10-30 | 2005-05-25 | Basf Ag | Verfahren zur Herstellung von Nickel-Phosphorligand-Komplexen |
| DE10351000A1 (de) * | 2003-10-30 | 2005-06-09 | Basf Ag | Verfahren zur Herstellung von Nickel(O)-Phosphorligand-Komplexen |
| DE102004004718A1 (de) * | 2004-01-29 | 2005-08-18 | Basf Ag | Verfahren zur Hydrocyanierung |
| EP1825914A1 (de) * | 2006-02-22 | 2007-08-29 | Basf Aktiengesellschaft | Verbessertes Verfahren zur Herstellung von Nickel(0)-Phophorligand-Komplexen |
| CA2644961A1 (en) * | 2006-03-17 | 2007-09-27 | Invista Technologies S.A.R.L. | Method for the purification of triorganophosphites by treatment with a basic additive |
| US7659422B2 (en) * | 2006-07-14 | 2010-02-09 | Invista North America S.A.R.L. | Hydrocyanation process with reduced yield losses |
| US7709673B2 (en) * | 2006-07-14 | 2010-05-04 | Invista North America S.A R.L. | Process for making 3-pentenenitrile by hydrocyanation of butadiene |
| US7709674B2 (en) * | 2006-07-14 | 2010-05-04 | Invista North America S.A R.L | Hydrocyanation process with reduced yield losses |
| US7919646B2 (en) * | 2006-07-14 | 2011-04-05 | Invista North America S.A R.L. | Hydrocyanation of 2-pentenenitrile |
| US7880028B2 (en) * | 2006-07-14 | 2011-02-01 | Invista North America S.A R.L. | Process for making 3-pentenenitrile by hydrocyanation of butadiene |
| JP5295512B2 (ja) * | 2007-03-29 | 2013-09-18 | 三井化学株式会社 | ゼロ価ニッケルの有機ホスフィン錯体の製造方法 |
| US7977502B2 (en) * | 2008-01-15 | 2011-07-12 | Invista North America S.A R.L. | Process for making and refining 3-pentenenitrile, and for refining 2-methyl-3-butenenitrile |
| EP2229353B1 (en) * | 2008-01-15 | 2018-01-03 | INVISTA Textiles (U.K.) Limited | Hydrocyanation of pentenenitriles |
| WO2011075494A1 (en) | 2009-12-18 | 2011-06-23 | Invista Technologies S.A.R.L. | Nickel metal compositions and nickel complexes derived from basic nickel carbonates |
| EP2574191B1 (en) | 2010-07-07 | 2013-11-20 | Invista Technologies S.a r.l. | Process for making nitriles |
| WO2012033555A1 (en) | 2010-09-07 | 2012-03-15 | Invista Technologies S.A.R.L. | Nickel compositions for preparing nickel metal and nickel complexes |
| EP2718015A2 (en) * | 2011-06-10 | 2014-04-16 | Invista Technologies S.à.r.l. | Improvement in nickel metal-ligand catalyst formation |
| EP2763960B1 (en) | 2011-10-07 | 2017-03-01 | Invista Technologies S.à.r.l. | Process for making nitriles |
| US10759741B2 (en) | 2013-07-17 | 2020-09-01 | Invista North America S.A R.L. | Separating a solvent from a nickel catalyst by distillation |
| EP3406568A4 (en) * | 2016-01-21 | 2019-08-21 | JX Nippon Mining & Metals Corporation | ANHYDRIC NICKEL CHLORIDE AND METHOD FOR THE PRODUCTION THEREOF |
| CN114212836A (zh) * | 2021-12-31 | 2022-03-22 | 金川集团镍盐有限公司 | 一种无水氯化镍粉体材料的制备方法 |
| CN114835176A (zh) * | 2022-05-30 | 2022-08-02 | 金川集团镍盐有限公司 | 一种球形无水氯化镍产品的制备方法 |
| JP7798365B2 (ja) * | 2023-01-06 | 2026-01-14 | レアメタルリサイクル環境合同会社 | 無水塩化ニッケル粉末の製造方法 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3631191A (en) | 1970-04-08 | 1971-12-28 | Du Pont | Synthesis of zero valent nickel-tetrakis triaryl phosphite complexes |
| US3847959A (en) | 1972-10-25 | 1974-11-12 | Du Pont | Process of preparing a zerovalent nickel complex with organic phosphorus compounds |
| US3846461A (en) | 1972-10-25 | 1974-11-05 | Du Pont | Process of preparing a zerovalent nickel complex with organic phosphorus compounds |
| SU1096223A1 (ru) | 1981-11-16 | 1984-06-07 | Ленинградский Ордена Октябрьской Революции И Ордена Трудового Красного Знамени Технологический Институт Им.Ленсовета | Способ получени безводного хлорида никел |
| US5061669A (en) | 1988-11-30 | 1991-10-29 | Eastman Kodak Company | Preparation of biaryl compounds |
| DE4109743C2 (de) * | 1991-03-25 | 1995-03-23 | Escher Wyss Gmbh | Verfahren zur thermischen Behandlung von feuchten Hydraten |
| US5175335A (en) | 1991-11-12 | 1992-12-29 | E. I. Du Pont De Nemours And Company | Enantioselective hydrocyanation of aromatic vinyl compounds |
| EP0723477B1 (en) * | 1993-10-12 | 2000-04-26 | E.I. Du Pont De Nemours And Company | Improved synthesis of nickel phosphine and phosphite catalysts |
| DE69412635T2 (de) | 1993-11-23 | 1999-04-15 | E.I. Du Pont De Nemours And Co., Wilmington, Del. | Verfahren und katalysator-zusammensetzungen für die anlagerung von cyanwassenstoff an monoolefine |
| DE4344159A1 (de) | 1993-12-23 | 1995-06-29 | Bayer Ag | Verfahren zur Herstellung von Dimethylcarbonat |
| ATE196745T1 (de) * | 1994-04-14 | 2000-10-15 | Du Pont | Nickel und phosphinebidentat enthaltende katalysatorzusammen- setzungen zur hydrocyanierung von monoolefinen |
| US5512695A (en) | 1994-04-14 | 1996-04-30 | E. I. Du Pont De Nemours And Company | Bidentate phosphite and nickel catalyst compositions for hydrocyanation of monoolefins |
| US5512696A (en) | 1995-07-21 | 1996-04-30 | E. I. Du Pont De Nemours And Company | Hydrocyanation process and multidentate phosphite and nickel catalyst composition therefor |
| TW315370B (cg-RX-API-DMAC10.html) | 1994-10-07 | 1997-09-11 | Du Pont | |
| US5523453A (en) * | 1995-03-22 | 1996-06-04 | E. I. Du Pont De Nemours And Company | Process for hydrocyanation |
| FR2739378B1 (fr) * | 1995-09-29 | 1997-10-31 | Rhone Poulenc Fibres | Procede d'hydrocyanation de composes organiques a insaturation ethylenique |
| US5693843A (en) | 1995-12-22 | 1997-12-02 | E. I. Du Pont De Nemours And Company | Process for hydrocyanation of diolefins and isomerization of nonconjugated 2 alkyl-3-monoalkenenitriles |
| JPH1088205A (ja) * | 1996-09-10 | 1998-04-07 | Sumitomo Metal Mining Co Ltd | 金属ニッケル粉末の製造方法 |
| JPH11263625A (ja) | 1998-03-19 | 1999-09-28 | Sumitomo Metal Mining Co Ltd | 無水塩化ニッケルの製造方法 |
| JP4918194B2 (ja) * | 2001-03-22 | 2012-04-18 | Ｊｆｅミネラル株式会社 | 無水塩化ニッケルの製造方法 |
-
2001
- 2001-11-26 US US09/994,102 patent/US6893996B2/en not_active Expired - Fee Related
-
2002
- 2002-08-29 TW TW091119674A patent/TW592817B/zh not_active IP Right Cessation
- 2002-11-14 CA CA002468293A patent/CA2468293A1/en not_active Abandoned
- 2002-11-14 AT AT02803976T patent/ATE307669T1/de not_active IP Right Cessation
- 2002-11-14 CN CNB2006101054979A patent/CN100445210C/zh not_active Expired - Lifetime
- 2002-11-14 AU AU2002356942A patent/AU2002356942A1/en not_active Abandoned
- 2002-11-14 MX MXPA04004942A patent/MXPA04004942A/es active IP Right Grant
- 2002-11-14 EP EP05075636A patent/EP1604954A1/en not_active Withdrawn
- 2002-11-14 DE DE60206958T patent/DE60206958T2/de not_active Expired - Lifetime
- 2002-11-14 WO PCT/US2002/036468 patent/WO2003045555A2/en not_active Ceased
- 2002-11-14 KR KR1020097006558A patent/KR20090048517A/ko not_active Ceased
- 2002-11-14 PL PL02371463A patent/PL371463A1/xx not_active Application Discontinuation
- 2002-11-14 RU RU2004116079/04A patent/RU2301704C2/ru not_active IP Right Cessation
- 2002-11-14 ES ES02803976T patent/ES2250748T3/es not_active Expired - Lifetime
- 2002-11-14 CN CNB028235339A patent/CN1293944C/zh not_active Expired - Lifetime
- 2002-11-14 EP EP02803976A patent/EP1450949B1/en not_active Expired - Lifetime
- 2002-11-14 KR KR1020047007924A patent/KR100912331B1/ko not_active Expired - Fee Related
- 2002-11-14 BR BRPI0214260-0A patent/BR0214260B1/pt not_active IP Right Cessation
- 2002-11-14 JP JP2003547049A patent/JP2005510346A/ja active Pending
- 2002-11-26 MY MYPI20024421A patent/MY129876A/en unknown
-
2008
- 2008-11-05 JP JP2008284604A patent/JP2009035482A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JP2005510346A (ja) | 2005-04-21 |
| RU2301704C2 (ru) | 2007-06-27 |
| BR0214260B1 (pt) | 2014-07-29 |
| EP1450949A2 (en) | 2004-09-01 |
| RU2004116079A (ru) | 2005-03-27 |
| DE60206958T2 (de) | 2006-08-03 |
| JP2009035482A (ja) | 2009-02-19 |
| EP1450949B1 (en) | 2005-10-26 |
| CN1293944C (zh) | 2007-01-10 |
| AU2002356942A1 (en) | 2003-06-10 |
| BR0214260A (pt) | 2004-09-21 |
| KR100912331B1 (ko) | 2009-08-14 |
| EP1604954A1 (en) | 2005-12-14 |
| WO2003045555A3 (en) | 2003-11-06 |
| MY129876A (en) | 2007-05-31 |
| US6893996B2 (en) | 2005-05-17 |
| PL371463A1 (en) | 2005-06-13 |
| KR20090048517A (ko) | 2009-05-13 |
| CN100445210C (zh) | 2008-12-24 |
| CN1596152A (zh) | 2005-03-16 |
| WO2003045555A2 (en) | 2003-06-05 |
| DE60206958D1 (de) | 2005-12-01 |
| US20030100442A1 (en) | 2003-05-29 |
| TW592817B (en) | 2004-06-21 |
| KR20040060989A (ko) | 2004-07-06 |
| ES2250748T3 (es) | 2006-04-16 |
| ATE307669T1 (de) | 2005-11-15 |
| CA2468293A1 (en) | 2003-06-05 |
| CN1899972A (zh) | 2007-01-24 |
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