ATE494954T1 - Organometallische übergangsmetallverbindung, biscyclopentadienylligandsystem, katalysatorsystem und herstellung von polyolefinen - Google Patents
Organometallische übergangsmetallverbindung, biscyclopentadienylligandsystem, katalysatorsystem und herstellung von polyolefinenInfo
- Publication number
- ATE494954T1 ATE494954T1 AT02792805T AT02792805T ATE494954T1 AT E494954 T1 ATE494954 T1 AT E494954T1 AT 02792805 T AT02792805 T AT 02792805T AT 02792805 T AT02792805 T AT 02792805T AT E494954 T1 ATE494954 T1 AT E494954T1
- Authority
- AT
- Austria
- Prior art keywords
- polyolefins
- production
- transition metal
- metal compound
- organometallic transition
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title 1
- 239000003446 ligand Substances 0.000 title 1
- 229920000098 polyolefin Polymers 0.000 title 1
- 150000003623 transition metal compounds Chemical class 0.000 title 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/48—Zirconium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/941—Synthetic resins or natural rubbers -- part of the class 520 series having the transition metal bonded directly to carbon
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10158656A DE10158656A1 (de) | 2001-11-30 | 2001-11-30 | Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen |
| PCT/EP2002/013296 WO2003045551A1 (en) | 2001-11-30 | 2002-11-26 | Organometallic transition metal compound, biscyclopentadienyl ligand system, catalyst system and preparation of polyolefins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE494954T1 true ATE494954T1 (de) | 2011-01-15 |
Family
ID=7707431
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT02792805T ATE494954T1 (de) | 2001-11-30 | 2002-11-26 | Organometallische übergangsmetallverbindung, biscyclopentadienylligandsystem, katalysatorsystem und herstellung von polyolefinen |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7109278B2 (de) |
| EP (1) | EP1455938B1 (de) |
| JP (1) | JP4416507B2 (de) |
| AR (1) | AR037470A1 (de) |
| AT (1) | ATE494954T1 (de) |
| AU (1) | AU2002358541A1 (de) |
| DE (2) | DE10158656A1 (de) |
| WO (1) | WO2003045551A1 (de) |
Families Citing this family (56)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10200422A1 (de) * | 2002-01-08 | 2003-07-17 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von Dialkyl-ansa-Metallocenen |
| WO2004022613A1 (en) * | 2002-09-06 | 2004-03-18 | Basell Polyolefine Gmbh | Process for the copolymerization of ethylene |
| US8058371B2 (en) | 2002-09-20 | 2011-11-15 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization |
| US8008412B2 (en) | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
| ATE423784T1 (de) * | 2003-05-28 | 2009-03-15 | Basell Polyolefine Gmbh | Bisindenyl-zirconium-komplexe zur olefinpolymerisation |
| JP2007505175A (ja) * | 2003-09-11 | 2007-03-08 | バセル ポリオレフィン ジーエムビーエイチ | ヘテロ相プロピレンコポリマーを製造するための多段方法 |
| DE10358082A1 (de) | 2003-12-10 | 2005-07-14 | Basell Polyolefine Gmbh | Organübergangsmetallverbindung, Bscyclopentadienyligandsystem, Katalysatorsystem und Hertellung von Polyolefinen |
| ATE445650T1 (de) * | 2004-05-04 | 2009-10-15 | Basell Polyolefine Gmbh | Verfahren zur herstellung von ataktischen 1- butenpolymeren |
| DE102004027332A1 (de) * | 2004-06-04 | 2005-12-22 | Basell Polyolefine Gmbh | Übergangsmetallverbindung, Ligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen |
| DE102004056104A1 (de) * | 2004-11-19 | 2006-05-24 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von niedermolekularen Olefinpolymeren, Organoübergangsmetallverbindungen, Biscyclopentadienylligandsysteme und Katalysatorsysteme |
| WO2006065844A2 (en) | 2004-12-16 | 2006-06-22 | Exxonmobil Chemical Patents Inc. | Process for producing substituted metallocene compounds for olefin polymerization |
| RU2008101445A (ru) * | 2005-06-13 | 2009-07-20 | Базелль Полиолефине Гмбх (De) | Способ сополимеризации пропилена |
| US20090227748A1 (en) * | 2005-09-06 | 2009-09-10 | Basell Polyolefine Gmbh | Process for Preparing Olff in Polymers in the Presence of Catalyst Systems Having Photochromic Groups |
| US8034886B2 (en) | 2005-11-04 | 2011-10-11 | Ticona Gmbh | Process for manufacturing high to ultra high molecular weight polymers using novel bridged metallocene catalysts |
| DE102005052654A1 (de) * | 2005-11-04 | 2007-05-16 | Ticona Gmbh | Verfahren zur Herstellung von ultrahochmolekularen Polymeren unter Verwendung von speziellen verbrückten Metallocen-Katalysatoren |
| US7598329B2 (en) * | 2005-11-04 | 2009-10-06 | Ticona Gmbh | Process for manufacturing ultra high molecular weight polymers using novel bridged metallocene catalysts |
| EP1963347B1 (de) | 2005-12-14 | 2011-10-19 | ExxonMobil Chemical Patents Inc. | Halogensubstituierte metallocenverbindungen für die olefinpolymerisation |
| US7538168B2 (en) | 2005-12-14 | 2009-05-26 | Exxonmobil Chemical Patents Inc. | Halogen substituted metallocene compounds for olefin polymerization |
| US7868197B2 (en) | 2005-12-14 | 2011-01-11 | Exxonmobil Chemical Patents Inc. | Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization |
| US7667064B2 (en) * | 2005-12-14 | 2010-02-23 | Exxonmobil Chemical Patents Inc. | Halogen substituted metallocene compounds for olefin polymerization |
| US7550544B2 (en) | 2005-12-14 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Halogen substituted metallocene compounds for olefin polymerization |
| JP2010500418A (ja) * | 2006-04-21 | 2010-01-07 | バーゼル・ポリオレフィン・ゲーエムベーハー | エチレンプロピレンコポリマーの製造方法 |
| JP5295098B2 (ja) | 2006-04-21 | 2013-09-18 | バーゼル・ポリオレフィン・ゲーエムベーハー | エチレンコポリマーの製造方法 |
| US8242237B2 (en) | 2006-12-20 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Phase separator and monomer recycle for supercritical polymerization process |
| EP2235071A2 (de) | 2007-10-25 | 2010-10-06 | Novolen Technology Holdings, C.V. | Metallocenverbindungen, katalysatoren, die diese enthalten, verfahren zur herstellung eines olefinpolymers unter verwendung der katalysatoren und olefinhomo- und copolymere |
| MX2010004418A (es) * | 2007-10-25 | 2010-08-09 | Lummus Novolen Technology Gmbh | Compuestos de metaloceno, catalizadores que comprenden los mismos, proceso para producir un polimero de olefina mediante el uso de los catalizadores y homo- y copolimeros de olefina. |
| US7812104B2 (en) * | 2008-01-18 | 2010-10-12 | Exxonmobil Chemical Patents Inc. | Production of propylene-based polymers |
| US8318875B2 (en) | 2008-01-18 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization and polypropylenes made therefrom |
| US7544825B1 (en) * | 2008-06-12 | 2009-06-09 | Basell Polyolefine Gmbh | Preparation of siloxy-bridged metallocenes |
| WO2013007664A1 (en) | 2011-07-08 | 2013-01-17 | Borealis Ag | Heterophasic copolymers |
| JP6176015B2 (ja) | 2012-11-01 | 2017-08-09 | 日本ポリプロ株式会社 | メタロセン錯体およびオレフィンの重合方法 |
| EP2746289B1 (de) | 2012-12-21 | 2017-09-27 | Borealis AG | Katalysatoren |
| CN104918948B (zh) | 2012-12-21 | 2018-09-18 | 博里利斯股份公司 | 催化剂 |
| ES2674576T3 (es) * | 2012-12-21 | 2018-07-02 | Borealis Ag | Catalizador |
| JP5710035B2 (ja) | 2013-02-27 | 2015-04-30 | 日本ポリエチレン株式会社 | メタロセン化合物およびオレフィン重合体の製造方法 |
| JP5695687B2 (ja) | 2013-03-05 | 2015-04-08 | 日本ポリエチレン株式会社 | エチレン／α−オレフィン共重合体の製造方法 |
| EP3301119B1 (de) | 2013-07-17 | 2021-03-17 | ExxonMobil Chemical Patents Inc. | Isotaktische propylenpolymere |
| EP3022238B1 (de) | 2013-07-17 | 2017-09-20 | ExxonMobil Chemical Patents Inc. | Metallocene und katalysatorzusammensetzungen daraus |
| CN110845546A (zh) | 2013-07-17 | 2020-02-28 | 埃克森美孚化学专利公司 | 取代的茂金属催化剂 |
| WO2015009472A1 (en) | 2013-07-17 | 2015-01-22 | Exxonmobil Chemcal Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
| US9938364B2 (en) | 2013-07-17 | 2018-04-10 | Exxonmobil Chemical Patents Inc. | Substituted metallocene catalysts |
| SG11201508750SA (en) | 2013-07-17 | 2015-11-27 | Exxonmobil Chem Patents Inc | Cyclopropyl substituted metallocene catalysts |
| KR101785764B1 (ko) | 2014-07-16 | 2017-10-16 | 주식회사 엘지화학 | 신규한 리간드 화합물 및 전이금속 화합물의 제조방법 |
| KR101743327B1 (ko) | 2014-07-16 | 2017-06-02 | 주식회사 엘지화학 | 신규한 리간드 화합물 및 전이금속 화합물 |
| US10759886B2 (en) | 2015-06-05 | 2020-09-01 | Exxonmobil Chemical Patents Inc. | Single reactor production of polymers in gas or slurry phase |
| US10294316B2 (en) | 2015-06-05 | 2019-05-21 | Exxonmobil Chemical Patents Inc. | Silica supports with high aluminoxane loading capability |
| US10280235B2 (en) | 2015-06-05 | 2019-05-07 | Exxonmobil Chemical Patents Inc. | Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers |
| WO2016196331A1 (en) | 2015-06-05 | 2016-12-08 | Exxonmobil Chemical Patents Inc. | Supported metallocene catalyst systems for polymerization |
| US9809664B2 (en) | 2015-06-05 | 2017-11-07 | Exxonmobil Chemical Patents Inc. | Bimodal propylene polymers and sequential polymerization |
| EP3885373A1 (de) | 2015-06-05 | 2021-09-29 | ExxonMobil Chemical Patents Inc. | Herstellung von heterophasischen polymeren in gas- oder schlämmephase |
| US10280233B2 (en) | 2015-06-05 | 2019-05-07 | Exxonmobil Chemical Patents Inc. | Catalyst systems and methods of making and using the same |
| US10329360B2 (en) | 2015-06-05 | 2019-06-25 | Exxonmobil Chemical Patents Inc. | Catalyst system comprising supported alumoxane and unsupported alumoxane particles |
| US11059918B2 (en) | 2016-05-27 | 2021-07-13 | Exxonmobil Chemical Patents Inc. | Metallocene catalyst compositions and polymerization process therewith |
| JP7248405B2 (ja) * | 2018-09-27 | 2023-03-29 | 三井化学株式会社 | 遷移金属化合物、オレフィン重合用触媒およびオレフィン重合体の製造方法 |
| KR102624685B1 (ko) * | 2019-01-28 | 2024-01-11 | 주식회사 엘지화학 | 전이 금속 화합물, 촉매 조성물 및 이를 이용한 폴리프로필렌의 제조 방법 |
| US11472828B2 (en) | 2019-10-11 | 2022-10-18 | Exxonmobil Chemical Patents Inc. | Indacene based metallocene catalysts useful in the production of propylene polymers |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2072598T3 (es) | 1990-01-02 | 1995-07-16 | Exxon Chemical Patents Inc | Catalizadores ionicos de metaloceno soportados para la polimerizacion de olefinas. |
| ATE188972T1 (de) | 1994-06-24 | 2000-02-15 | Exxon Chemical Patents Inc | Polymerisationskatalysatorsystem, ihre herstellung und gebrauch |
| CA2164461C (en) * | 1994-12-06 | 2000-08-08 | Tatsuya Tanizaki | Polypropylene composition and uses thereof |
| WO1997040075A1 (fr) * | 1996-04-22 | 1997-10-30 | Japan Polyolefins Co., Ltd. | Procede de production de polyolefine et catalyseur approprie |
| AU7332398A (en) | 1997-03-07 | 1998-09-29 | Targor Gmbh | Method for producing olefin polymers with a higher melting point |
| DE19757563A1 (de) * | 1997-03-07 | 1999-07-08 | Targor Gmbh | Geträgertes Katalysatorsystem, Verfahren zur Herstellung und seine Verwendung zur Polymerisation von Olefinen |
| DE19733017A1 (de) | 1997-07-31 | 1999-02-04 | Hoechst Ag | Chemische Verbindung |
| DE19813656A1 (de) | 1998-03-27 | 1999-09-30 | Aventis Res & Tech Gmbh & Co | Übergangsmetallverbindung |
| DE19813657A1 (de) | 1998-03-27 | 1999-09-30 | Aventis Res & Tech Gmbh & Co | Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
| JPH11349617A (ja) * | 1998-06-04 | 1999-12-21 | Mitsubishi Chemical Corp | α−オレフィン重合用触媒成分、触媒およびα−オレフィン重合体の製造方法 |
| JPH11349618A (ja) * | 1998-06-04 | 1999-12-21 | Mitsubishi Chemical Corp | α−オレフィン重合用触媒成分、触媒およびα−オレフィン重合体の製造方法 |
| DE19833170A1 (de) * | 1998-07-23 | 2000-01-27 | Targor Gmbh | Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators oder einer Trägerkatalysatorkomponente durch Tränkung einer Trägersubstanz |
| DE19903306A1 (de) * | 1999-01-28 | 2000-08-03 | Targor Gmbh | Organometallverbindung, Katalysatorsystem enthaltend diese Organometallverbindung und seine Verwendung |
| UA57864C2 (uk) | 1998-10-08 | 2003-07-15 | Бп Кемікалз Лімітед | Спосіб полімеризації олефінів з використанням місточкових металевих комплексів |
| HUP0104654A3 (en) | 1998-10-08 | 2003-08-28 | Univ Michigan Ann Arbor | Bridged metal complexes |
| AU1863201A (en) | 1999-12-21 | 2001-07-03 | Basell Polyolefine Gmbh | Partly crystalline propylene polymerisate composition for production of biaxial-stretched polypropylene films |
| CN100575324C (zh) | 1999-12-23 | 2009-12-30 | 巴塞尔聚烯烃有限公司 | 过渡金属化合物，配体体系，催化剂体系及其在烯烃的聚合反应和共聚反应中的用途 |
| DE19962905A1 (de) * | 1999-12-23 | 2001-07-12 | Basell Polyolefine Gmbh | Übergangsmetallverbindung, Ligandensystem, Katalysatorsystem und seine Verwendung zur Polymerisation und Copolymerisation von Olefinen |
| US6492465B1 (en) | 2000-02-08 | 2002-12-10 | Exxonmobil Chemical Patents, Inc. | Propylene impact copolymers |
| EP1294733B1 (de) | 2000-06-30 | 2004-02-25 | ExxonMobil Chemical Patents Inc. | Verbrückte bisindenyl substituierte metallocen-verbindungen |
| JP2004502699A (ja) | 2000-06-30 | 2004-01-29 | エクソンモービル・ケミカル・パテンツ・インク | 架橋ビス（インデニル）メタロセン化合物 |
| US6784305B2 (en) | 2000-08-29 | 2004-08-31 | Basell Polyolefine Gmbh | Method for producing alkyl-bridged ligand systems and transition metal compounds |
| GB0111020D0 (en) * | 2001-05-04 | 2001-06-27 | Borealis Tech Oy | Process |
| DE10126265A1 (de) | 2001-05-29 | 2002-12-05 | Basell Polyolefine Gmbh | Verfahren zur Abreicherung von anorganischen Nebenprodukten und organometallischen Nebenprodukten bei der Herstellung von Metallocenen sowie der wirtschaftlichen Rückgewinnung der eingesetzten Edukte |
| JP2005522406A (ja) | 2001-06-29 | 2005-07-28 | エクソンモービル・ケミカル・パテンツ・インク | メタロセン及び該メタロセン由来の触媒組成物 |
-
2001
- 2001-11-30 DE DE10158656A patent/DE10158656A1/de not_active Withdrawn
-
2002
- 2002-11-26 JP JP2003547045A patent/JP4416507B2/ja not_active Expired - Lifetime
- 2002-11-26 AU AU2002358541A patent/AU2002358541A1/en not_active Abandoned
- 2002-11-26 US US10/496,142 patent/US7109278B2/en not_active Expired - Lifetime
- 2002-11-26 EP EP02792805A patent/EP1455938B1/de not_active Expired - Lifetime
- 2002-11-26 AT AT02792805T patent/ATE494954T1/de not_active IP Right Cessation
- 2002-11-26 WO PCT/EP2002/013296 patent/WO2003045551A1/en active Application Filing
- 2002-11-26 DE DE60238939T patent/DE60238939D1/de not_active Expired - Lifetime
- 2002-11-29 AR ARP020104606A patent/AR037470A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU2002358541A1 (en) | 2003-06-10 |
| DE10158656A1 (de) | 2003-06-26 |
| EP1455938A1 (de) | 2004-09-15 |
| JP4416507B2 (ja) | 2010-02-17 |
| AR037470A1 (es) | 2004-11-10 |
| EP1455938B1 (de) | 2011-01-12 |
| JP2005510546A (ja) | 2005-04-21 |
| US20040260107A1 (en) | 2004-12-23 |
| DE60238939D1 (de) | 2011-02-24 |
| WO2003045551A1 (en) | 2003-06-05 |
| US7109278B2 (en) | 2006-09-19 |
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| RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |