MX9602168A - Composicion para producir gas que contiene fosfino. - Google Patents

Composicion para producir gas que contiene fosfino.

Info

Publication number
MX9602168A
MX9602168A MX9602168A MX9602168A MX9602168A MX 9602168 A MX9602168 A MX 9602168A MX 9602168 A MX9602168 A MX 9602168A MX 9602168 A MX9602168 A MX 9602168A MX 9602168 A MX9602168 A MX 9602168A
Authority
MX
Mexico
Prior art keywords
phosphine
metal phosphide
composition
mixture
carrier gas
Prior art date
Application number
MX9602168A
Other languages
English (en)
Inventor
Franziskus Horn Feja
Christoph Reichmuth
Original Assignee
Degesch De Chile Ltda
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Degesch De Chile Ltda filed Critical Degesch De Chile Ltda
Publication of MX9602168A publication Critical patent/MX9602168A/es

Links

Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • A23L3/34Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
    • A23L3/3409Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B9/00Preservation of edible seeds, e.g. cereals
    • A23B9/16Preserving with chemicals
    • A23B9/18Preserving with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • A23L3/34Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
    • A23L3/3454Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
    • A23L3/358Inorganic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00Feed or outlet devices; Feed or outlet control devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J7/00Apparatus for generating gases
    • B01J7/02Apparatus for generating gases by wet methods
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00Phosphorus; Compounds thereof
    • C01B25/06Hydrogen phosphides
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00Phosphorus; Compounds thereof
    • C01B25/08Other phosphides
    • C01B25/081Other phosphides of alkali metals, alkaline-earth metals or magnesium
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00Phosphorus; Compounds thereof
    • C01B25/08Other phosphides
    • C01B25/082Other phosphides of boron, aluminium, gallium or indium
    • C01B25/085Other phosphides of boron, aluminium, gallium or indium of aluminium
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/141Feedstock
    • Y02P20/145Feedstock the feedstock being materials of biological origin

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Food Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Catching Or Destruction (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)

Abstract

Se expone una composicion de fosfuro de metal para generar una mezcla de fosfino y gas(es) diluyente(es), presentada lista para su utilizacion en un aparato o proceso de hidrolisis en la forma de un material de fosfuro de metal de fluidez libre compuesto por partículas sueltas de dicho fosfuro metálico esencialmente exentas de polvo, agentes retardantes de hidrolisis y sustancias hidrofobicas en la forma de revestimientos o aditivos hidrofobizantes. En uso, el fosfuro metálico hidrolizable, de preferencia fosfuro de magnesio, es liberado directamente dentro de agua líquida, en una atmosfera de gas inerte ante el fosfino. La mezcla generada de fosfino y gas portador inerte, tal como, por ejemplo, CO2, es utilizada como tal o es diluida en una cámara para mezcla de gases con aire, hasta alcanzar una concentracion inferior al límite de ignicion antes de que se lo emplee en fumigacion. La composicion de fosfuro de metal es fabricada haciendo reaccionar un metal, seleccionado del grupo consistente en aluminio, calcio y magnesio, dividido finamente, con un fosforo amarillo en una atmosfera de gas inerte y en presencia de un catalizador. Por toda la tanda de reaccion y durante la totalidad del proceso, una vez que ha comenzado la reaccion, la temperatura es mantenida dentro del intervalo de 350 a 550 degree C. El fosfuro de metal es removido como un material en partículas de fluidez libre y es envasado en un recipiente expendedor hermético a gases, listo para su utilizacion en la generacion de fosfina en tal condicion de fluidez libre, esencialmente exento de polvo de fosfuro metálico, de agentes retardadores de la hidrolisis y de sustancias hidrofobas en forma de revestimientos o aditivos hidrofobizantes.
MX9602168A 1995-06-07 1996-06-05 Composicion para producir gas que contiene fosfino. MX9602168A (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GBGB9511495.5A GB9511495D0 (en) 1995-06-07 1995-06-07 Composition, process and apparatus for producing phosphine - containing gas

Publications (1)

Publication Number Publication Date
MX9602168A true MX9602168A (es) 1997-06-28

Family

ID=10775648

Family Applications (2)

Application Number Title Priority Date Filing Date
MX9602168A MX9602168A (es) 1995-06-07 1996-06-05 Composicion para producir gas que contiene fosfino.
MX9602167A MX9602167A (es) 1995-06-07 1996-06-05 Proceso y aparato para producir gas que contiene fosfino.

Family Applications After (1)

Application Number Title Priority Date Filing Date
MX9602167A MX9602167A (es) 1995-06-07 1996-06-05 Proceso y aparato para producir gas que contiene fosfino.

Country Status (19)

Country Link
US (3) US5820840A (es)
EP (2) EP0747320B1 (es)
JP (1) JP4282776B2 (es)
CN (2) CN1080702C (es)
AR (2) AR002386A1 (es)
AT (2) ATE403629T1 (es)
AU (2) AU711520B2 (es)
BR (2) BR9602717A (es)
CA (2) CA2178542C (es)
DE (2) DE69637623D1 (es)
DK (1) DK0747319T3 (es)
ES (2) ES2313724T3 (es)
GB (1) GB9511495D0 (es)
IL (1) IL118592A (es)
MX (2) MX9602168A (es)
PT (1) PT747319E (es)
RU (1) RU2238905C2 (es)
UA (1) UA49798C2 (es)
ZA (1) ZA964713B (es)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9511495D0 (en) 1995-06-07 1995-08-02 Degesch De Chile Ltda Composition, process and apparatus for producing phosphine - containing gas
US5916856A (en) * 1996-10-16 1999-06-29 Lever Brothers Company Pourable cast melt bar compositions comprising low levels of water and minimum ratios of polyol to water
AU1997799A (en) 1997-12-23 1999-07-12 Gary B Carman Dynamic ox biological burden reduction
US6334979B1 (en) 1997-12-23 2002-01-01 Cosmed Group, Inc. Gaseous blend of Ox and its use for biological burden reduction
US6955786B2 (en) * 1997-12-23 2005-10-18 Cosmed Group, Inc. Gaseous blend of CO2 and Ox and its use for biological burden reduction
DE19839385A1 (de) * 1998-08-28 2000-03-23 Horn Pedro Miguel Verfahren und Vorrichtung zur Verdünnung von Phosphorwasserstoff mit Luft ohne Entzündungsgefahr
US6627758B2 (en) 1999-03-19 2003-09-30 San Diego State University Foundation Compositions and methods for hydration of terminal alkynes
US6380393B1 (en) 1999-03-19 2002-04-30 San Diego State University Foundation Ligands, transition metal complexes and methods of using same
JP2001070471A (ja) * 1999-07-07 2001-03-21 Teijin Chem Ltd リン化金属化合物製剤残渣の除害方法および除害システム
DE10062564A1 (de) * 2000-12-15 2002-06-20 Linde Ag Schutzgas und Verfahren zum Lichtbogenschweißen
DE10062563A1 (de) * 2000-12-15 2002-06-20 Linde Ag Schutzgas und Verfahren zum Lichtbogenschweißen
US7556785B2 (en) * 2003-05-12 2009-07-07 United Phosphorus, Ltd. Apparatus and method for rapid and continuous generation of phosphine gas
US20060013745A1 (en) * 2004-07-16 2006-01-19 Yi-Rong Chen Enhanced PFC waste-gas treating system
US7621668B2 (en) * 2006-11-14 2009-11-24 Rensselaer Polytechnic Institute Methods and apparatus for handling or treating particulate material
US8235577B2 (en) * 2006-11-14 2012-08-07 Rensselaer Polytechnic Institute Methods and apparatus for coating particulate material
GB2454902B (en) * 2007-11-22 2012-12-05 Ct Fa R Angewandte Nanotechnologie Can Gmbh A method for the manufacture of III-V particles
RU2395220C2 (ru) * 2008-07-17 2010-07-27 Людмила Александровна Тихонова Способ выработки газа фумиганта и устройство для его осуществления (варианты)
JP5124521B2 (ja) * 2009-04-28 2013-01-23 池田興業株式会社 燻蒸装置および燻蒸方法
CN102217585B (zh) * 2011-05-18 2012-11-21 山东省农作物种质资源中心 磷化氢发生器
CN102351158B (zh) * 2011-07-14 2013-02-13 马文忠 利用黄磷生产磷化铝同时回收副产品的工艺方法
CN110097989B (zh) * 2018-01-31 2022-11-18 中国辐射防护研究院 一种用于球床高温气冷堆的去石墨粉尘污染方法
AR115373A1 (es) * 2018-04-27 2021-01-13 Gasapps Australia Pty Ltd Sistema de suministro de gas
CN109270209B (zh) * 2018-10-16 2024-02-09 中国科学技术大学 磷化氢气体熏蒸环境下粮食多因素耦合引燃机理研究实验平台
AU2019415246A1 (en) * 2018-12-27 2021-05-27 Nippon Chemical Industrial Co., Ltd. Phosphine for fumigation, method for producing same, and fumigation method

Family Cites Families (18)

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Publication number Priority date Publication date Assignee Title
GB291897A (en) * 1927-03-17 1928-06-14 John Haworth Improvements in apparatus for the generation of acetylene gas under low or high pressure
GB472970A (en) * 1936-04-01 1937-10-01 John Haworth Improvements in acetylene gas generation
US2246734A (en) * 1939-01-26 1941-06-24 Kleijn Adrianus Apparatus for charging a current of air with a volatile substance
GB776070A (en) * 1953-07-07 1957-06-05 Union Carbide & Carbon Corp Improved method and apparatus for generating gas
US3179378A (en) * 1962-12-26 1965-04-20 Ducon Co Apparatus for mixing and transporting finely divided solids
GB1175511A (en) * 1966-01-10 1969-12-23 Albright & Wilson Mfg Ltd Manufacture of Metal Phosphides
DE1567520B2 (de) * 1966-04-07 1973-01-04 Freyberg, Werner, Dr., 6149 Kirschhausen Verfahren zur Herstellung von Magnesiumphosphid
DE2945647C2 (de) * 1979-11-12 1990-01-04 Degesch Gmbh, 6000 Frankfurt Verfahren zur Herstellung von Aluminiumphosphid und/oder Magnesiumphosphid
DE3117393A1 (de) * 1981-05-02 1982-11-11 Degesch Gmbh, 6000 Frankfurt Verfahren zur herstellung der phosphide von aluminium oder magnesium
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GB9511495D0 (en) 1995-06-07 1995-08-02 Degesch De Chile Ltda Composition, process and apparatus for producing phosphine - containing gas

Also Published As

Publication number Publication date
EP0747320A3 (en) 1997-02-26
EP0747319B1 (en) 2009-09-30
EP0747320B1 (en) 2008-08-06
ZA964713B (en) 1997-12-08
CA2178545A1 (en) 1996-12-08
CN1150939A (zh) 1997-06-04
BR9602718A (pt) 1998-04-22
EP0747319A3 (en) 1997-04-16
US6315965B1 (en) 2001-11-13
AU5584896A (en) 1996-12-19
IL118592A0 (en) 1996-10-16
DK0747319T3 (da) 2010-01-04
IL118592A (en) 2000-07-26
AU712536B2 (en) 1999-11-11
ES2333920T3 (es) 2010-03-02
AU5585496A (en) 1996-12-19
AR002386A1 (es) 1998-03-11
CA2178545C (en) 2001-10-09
PT747319E (pt) 2009-12-09
US5820840A (en) 1998-10-13
US6027667A (en) 2000-02-22
DE69638039D1 (de) 2009-11-12
CN1153741A (zh) 1997-07-09
BR9602717A (pt) 1998-04-22
CN1163408C (zh) 2004-08-25
CN1080702C (zh) 2002-03-13
AR002387A1 (es) 1998-03-11
AU711520B2 (en) 1999-10-14
MX9602167A (es) 1997-06-28
JPH09165209A (ja) 1997-06-24
ES2313724T3 (es) 2009-03-01
UA49798C2 (uk) 2002-10-15
RU2238905C2 (ru) 2004-10-27
CA2178542C (en) 2000-08-01
JP4282776B2 (ja) 2009-06-24
CA2178542A1 (en) 1996-12-08
DE69637623D1 (de) 2008-09-18
EP0747320A2 (en) 1996-12-11
ATE444260T1 (de) 2009-10-15
GB9511495D0 (en) 1995-08-02
ATE403629T1 (de) 2008-08-15
EP0747319A2 (en) 1996-12-11

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