MX378472B - Soportes de alúmina que contienen sílice, catalizadores elaborados a partir de éstos y procesos que los utilizan. - Google Patents
Soportes de alúmina que contienen sílice, catalizadores elaborados a partir de éstos y procesos que los utilizan.Info
- Publication number
- MX378472B MX378472B MX2014007351A MX2014007351A MX378472B MX 378472 B MX378472 B MX 378472B MX 2014007351 A MX2014007351 A MX 2014007351A MX 2014007351 A MX2014007351 A MX 2014007351A MX 378472 B MX378472 B MX 378472B
- Authority
- MX
- Mexico
- Prior art keywords
- processes
- same
- catalysts made
- made therefrom
- containing alumina
- Prior art date
Links
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 title abstract 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title abstract 4
- 239000003054 catalyst Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 239000000377 silicon dioxide Substances 0.000 title abstract 2
- 239000011148 porous material Substances 0.000 abstract 7
- 239000000203 mixture Substances 0.000 abstract 2
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
- B01J27/19—Molybdenum
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/635—0.5-1.0 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/66—Pore distribution
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0207—Pretreatment of the support
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/12—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Catalysts (AREA)
- Nanotechnology (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Se describen composiciones de soporte de alúmina que contienen al menos 0.1% en peso de sílice. El soporte de alúmina se caracteriza por un volumen de poro mayor de 0.60 cm3/g, una mediana del tamaño de poro que abarca desde aproximadamente 70 hasta aproximadamente 120, una distribución del tamaño de poro para que al menos 90% del volumen de poro total caiga dentro del intervalo de aproximadamente 20 hasta aproximadamente 250, y una amplitud de la distribución del tamaño de poro de no menos de aproximadamente 40. Las composiciones de alúmina de la presente invención exhiben un modo del pico primario en un diámetro de poro menor que la mediana del diámetro de poro. También se proporcionan catalizadores preparados a partir de los soportes de alúmina y los procesos para preparar y utilizar los soportes y los catalizadores.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161579357P | 2011-12-22 | 2011-12-22 | |
| US201261587872P | 2012-01-18 | 2012-01-18 | |
| PCT/US2012/066107 WO2013095856A1 (en) | 2011-12-22 | 2012-11-20 | Silica containing alumina supports, catalysts made therefrom and processes using the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2014007351A MX2014007351A (es) | 2014-11-25 |
| MX378472B true MX378472B (es) | 2025-03-11 |
Family
ID=48669342
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2014007351A MX378472B (es) | 2011-12-22 | 2012-11-20 | Soportes de alúmina que contienen sílice, catalizadores elaborados a partir de éstos y procesos que los utilizan. |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US11090638B2 (es) |
| EP (1) | EP2794088B1 (es) |
| JP (1) | JP6134334B2 (es) |
| KR (1) | KR102041652B1 (es) |
| CN (1) | CN104114273B (es) |
| BR (1) | BR112014015372B1 (es) |
| CA (1) | CA2860166C (es) |
| MX (1) | MX378472B (es) |
| SG (1) | SG11201403322XA (es) |
| TW (1) | TWI641554B (es) |
| WO (1) | WO2013095856A1 (es) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013095856A1 (en) | 2011-12-22 | 2013-06-27 | Advanced Refining Technologies Llc | Silica containing alumina supports, catalysts made therefrom and processes using the same |
| FR3022156B1 (fr) * | 2014-06-13 | 2018-02-23 | Ifp Energies Now | Catalyseur mesoporeux et macroporeux a phase active comalaxee, son procede de preparation et son utilisation en hydrotraitement de residus |
| FR3022158B1 (fr) * | 2014-06-13 | 2018-02-23 | IFP Energies Nouvelles | Catalyseur mesoporeux d'hydroconversion de residus et methode de preparation |
| FR3022255B1 (fr) * | 2014-06-13 | 2016-07-29 | Ifp Energies Now | Procede d'hydrotraitement de coupes distillats utilisant un catalyseur a base d'une alumine mesoporeuse amorphe ayant une connectivite elevee |
| FR3022238B1 (fr) * | 2014-06-13 | 2016-07-29 | Ifp Energies Now | Alumine mesoporeuse amorphe ayant une connectivite elevee et son procede de preparation |
| FR3022160B1 (fr) * | 2014-06-13 | 2021-05-07 | Ifp Energies Now | Catalyseur a phase active de nickel comalaxee mesoporeux et macroporeux ayant un diametre median macroporeux compris entre 50 et 300 nm et son utilisation en hydrogenation |
| FR3022254B1 (fr) * | 2014-06-13 | 2016-07-29 | Ifp Energies Now | Procede d'hydrotraitement de coupes gazoles utilisant un catalyseur a base d'une alumine mesoporeuse amorphe ayant une connectivite elevee |
| US10286386B2 (en) | 2015-05-27 | 2019-05-14 | Jgc Catalysts And Chemicals Ltd. | Hydrotreating catalyst for hydrocarbon oil, process for producing same, and hydrotreating method |
| EP3302790A4 (en) * | 2015-05-29 | 2019-01-16 | Advanced Refining Technologies, LLC | HYDRAULIC CATALYST WITH HIGH HDN SELECTIVITY |
| FR3044677B1 (fr) * | 2015-12-08 | 2018-01-12 | IFP Energies Nouvelles | Procede d'hydrocraquage de charges hydrocarbonees utilisant un catalyseur comprenant une zeolithe et une alumine mesoporeuse amorphe |
| FR3068984B1 (fr) * | 2017-07-13 | 2020-01-17 | IFP Energies Nouvelles | Procede d'hydrogenation des aromatiques mettant en œuvre un catalyseur obtenu par impregnation comprenant un support specifique. |
| WO2019090170A1 (en) | 2017-11-02 | 2019-05-09 | Chevron U.S.A. Inc. | Imms method for petroleum feedstock evaluation |
| EP3883684A2 (en) * | 2018-11-21 | 2021-09-29 | Sasol (USA) Corporation | Silica alumina composition with improved stability and method for making same |
| FR3102069B1 (fr) * | 2019-10-22 | 2021-12-31 | Ifp Energies Now | Procede de preparation d’un support de catalyseur |
| RU2726374C1 (ru) * | 2020-01-17 | 2020-07-13 | Акционерное общество "Газпромнефть - Омский НПЗ" (АО "Газпромнефть - ОНПЗ") | Способ приготовления носителя для катализатора гидроочистки |
| JP7426258B2 (ja) * | 2020-03-03 | 2024-02-01 | テイカ株式会社 | シリカ含有アルミナ粉体及びその製造方法 |
| JP2023536847A (ja) * | 2020-07-28 | 2023-08-30 | シェブロン ユー.エス.エー. インコーポレイテッド | 高活性の第2段階ナフサ水素化分解触媒 |
| KR102300590B1 (ko) | 2020-12-16 | 2021-09-09 | 이성희 | 절개면 보강장치 및 공법 |
| CA3204573A1 (en) | 2021-01-08 | 2022-07-14 | Jifei Jia | High activity hydrotreating catalysts and processes using same |
| KR102358570B1 (ko) | 2021-02-23 | 2022-02-08 | 이성희 | 굴착면 보강을 위한 하향식 콘크리트 타설 보강공법 |
| FR3122585A1 (fr) | 2021-05-04 | 2022-11-11 | Universite Claude Bernard Lyon 1 | Solide mésoporeux pour réguler l’humidité dans les espaces clos |
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| JP3653383B2 (ja) | 1997-12-25 | 2005-05-25 | 触媒化成工業株式会社 | シリカ含有アルミナ成形体の製造方法 |
| JP4778605B2 (ja) | 2000-05-26 | 2011-09-21 | 一般財団法人石油エネルギー技術センター | 軽油留分の水素化脱硫触媒 |
| US6589908B1 (en) | 2000-11-28 | 2003-07-08 | Shell Oil Company | Method of making alumina having bimodal pore structure, and catalysts made therefrom |
| JP2004043579A (ja) | 2002-07-10 | 2004-02-12 | Petroleum Energy Center | 軽油の水素化処理方法 |
| US6872685B2 (en) | 2002-11-08 | 2005-03-29 | Chevron U.S.A. Inc. | Method for preparing a highly homogeneous amorphous silica-alumina composition |
| PL213492B1 (pl) | 2002-12-06 | 2013-03-29 | Albemarle Netherlands Bv | Sposób (HPC) obróbki ciezkiej frakcji weglowodorów wodorem z zastosowaniem mieszaniny katalizatorów |
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| US9376637B2 (en) | 2010-08-13 | 2016-06-28 | Shell Oil Company | Method of making a hydroprocessing catalyst with a single step metal and chelant incorporation, the catalyst, and the use of the catalyst |
| CN103052443B (zh) | 2010-08-13 | 2016-01-20 | 国际壳牌研究有限公司 | 用废催化剂细粉制备的加氢催化剂及其用途 |
| WO2013095856A1 (en) | 2011-12-22 | 2013-06-27 | Advanced Refining Technologies Llc | Silica containing alumina supports, catalysts made therefrom and processes using the same |
-
2012
- 2012-11-20 WO PCT/US2012/066107 patent/WO2013095856A1/en not_active Ceased
- 2012-11-20 MX MX2014007351A patent/MX378472B/es unknown
- 2012-11-20 EP EP12860484.0A patent/EP2794088B1/en active Active
- 2012-11-20 KR KR1020147020001A patent/KR102041652B1/ko active Active
- 2012-11-20 JP JP2014549065A patent/JP6134334B2/ja active Active
- 2012-11-20 US US14/367,449 patent/US11090638B2/en active Active
- 2012-11-20 BR BR112014015372A patent/BR112014015372B1/pt active IP Right Grant
- 2012-11-20 CA CA2860166A patent/CA2860166C/en active Active
- 2012-11-20 SG SG11201403322XA patent/SG11201403322XA/en unknown
- 2012-11-20 CN CN201280070437.1A patent/CN104114273B/zh active Active
- 2012-12-18 TW TW101147971A patent/TWI641554B/zh active
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2021
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Also Published As
| Publication number | Publication date |
|---|---|
| US11090638B2 (en) | 2021-08-17 |
| JP6134334B2 (ja) | 2017-05-24 |
| TWI641554B (zh) | 2018-11-21 |
| EP2794088B1 (en) | 2021-03-31 |
| CN104114273B (zh) | 2018-05-15 |
| CA2860166A1 (en) | 2013-06-27 |
| KR20140106710A (ko) | 2014-09-03 |
| CA2860166C (en) | 2017-08-22 |
| EP2794088A4 (en) | 2015-09-09 |
| WO2013095856A1 (en) | 2013-06-27 |
| US11642664B2 (en) | 2023-05-09 |
| US20140367311A1 (en) | 2014-12-18 |
| EP2794088A1 (en) | 2014-10-29 |
| MX2014007351A (es) | 2014-11-25 |
| BR112014015372A8 (pt) | 2017-06-13 |
| CN104114273A (zh) | 2014-10-22 |
| KR102041652B1 (ko) | 2019-11-06 |
| JP2015508380A (ja) | 2015-03-19 |
| TW201341314A (zh) | 2013-10-16 |
| SG11201403322XA (en) | 2014-07-30 |
| BR112014015372A2 (pt) | 2017-06-13 |
| US20210362137A1 (en) | 2021-11-25 |
| BR112014015372B1 (pt) | 2020-01-14 |
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