MX362519B - Composiciones a base de propileno con aspecto mejorado y excelente fluidez en el molde. - Google Patents

Composiciones a base de propileno con aspecto mejorado y excelente fluidez en el molde.

Info

Publication number
MX362519B
MX362519B MX2013007072A MX2013007072A MX362519B MX 362519 B MX362519 B MX 362519B MX 2013007072 A MX2013007072 A MX 2013007072A MX 2013007072 A MX2013007072 A MX 2013007072A MX 362519 B MX362519 B MX 362519B
Authority
MX
Mexico
Prior art keywords
gels
compositions
molded parts
propylene
compositions exhibit
Prior art date
Application number
MX2013007072A
Other languages
English (en)
Other versions
MX2013007072A (es
Inventor
William C Thurston
Antonios K Doufas
Edward Catalina
Rita Majewski
Original Assignee
Braskem America Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=46235194&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=MX362519(B) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Braskem America Inc filed Critical Braskem America Inc
Publication of MX2013007072A publication Critical patent/MX2013007072A/es
Publication of MX362519B publication Critical patent/MX362519B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/02—Ziegler natta catalyst

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)

Abstract

La presente invención se refiere a una clase de composiciones de copolímero de polipropileno de impacto (ICP) que exhiben la ventajosa combinación de excelente comportamiento de formación de rayas de tigre (marcas de flujo) en piezas moldeadas grandes/largas, muy bajo recuento de geles y excepcional fluidez en el-molde (alto MFR), a pesar de la alta razón de viscosidades (por ejemplo, > 4) entre las fases de caucho y de matriz a base de propileno; además, se ha encontrado sorprendentemente que las composiciones inventivas están asociadas con un bajo recuento de geles aun cuando se use un tamiz de malla de alambre bastante gruesa, por ejemplo, un tamiz de malla de alambre 60, independiente del tipo de tornillos, por ejemplo un solo tornillo o doble tornillo; finalmente, las composiciones inventivas exhiben niveles significativamente reducidos de compuestos volátiles y excelente equilibrio de rigidez-impacto cuando se usan como materiales independientes o en compuestos rellenados; el número significativamente reducido de geles grandes lleva a excelente aspecto superficial y pintabilidad de las piezas moldeadas; la composición de la presente invención se fabrica con un proceso en un reactor a granel/gas (o sea, un proceso que no es en lechada/no es en solvente) que tiene la ventaja de simplicidad del proceso, eficiencia del proceso y simplicidad de la estructura de la composición, con respecto a la complejidad en la estructura y proceso de fabricación de las composiciones en el arte previo.
MX2013007072A 2010-12-20 2011-12-16 Composiciones a base de propileno con aspecto mejorado y excelente fluidez en el molde. MX362519B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201061424762P 2010-12-20 2010-12-20
PCT/US2011/065555 WO2012087832A1 (en) 2010-12-20 2011-12-16 Propylene-based compositions of enhanced appearance and excellent mold flowability

Publications (2)

Publication Number Publication Date
MX2013007072A MX2013007072A (es) 2013-07-29
MX362519B true MX362519B (es) 2019-01-21

Family

ID=46235194

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2013007072A MX362519B (es) 2010-12-20 2011-12-16 Composiciones a base de propileno con aspecto mejorado y excelente fluidez en el molde.

Country Status (12)

Country Link
US (2) US20120157599A1 (es)
EP (1) EP2655505B1 (es)
JP (2) JP5851519B2 (es)
CN (1) CN103429656B (es)
BR (1) BR112013015505B8 (es)
CA (1) CA2820359C (es)
CL (1) CL2013001775A1 (es)
CO (1) CO6761303A2 (es)
ES (1) ES2692860T3 (es)
MX (1) MX362519B (es)
PL (1) PL2655505T3 (es)
WO (1) WO2012087832A1 (es)

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CN105849179B (zh) 2013-12-20 2019-11-12 沙特基础工业公司 多相丙烯共聚物
EP3083819B1 (en) 2013-12-20 2019-01-30 Saudi Basic Industries Corporation Polyolefin composition
MX2016008440A (es) * 2013-12-23 2017-02-23 Braskem America Inc Composiciones a base de propileno de apariencia y fluidez mejoradas.
WO2016022922A1 (en) 2014-08-08 2016-02-11 Braskem America, Inc. Composition comprising polypropylene and polyol, and method of making the same
MX2017009858A (es) 2015-01-30 2017-11-15 Braskem America Inc Polipropileno modificado y mezclas de polimero del mismo.
CN108219266B (zh) * 2016-12-13 2019-11-26 金发科技股份有限公司 一种消除聚丙烯组合物虎皮纹缺陷的方法及其制备的聚丙烯组合物
IL257637B (en) * 2018-02-20 2021-10-31 Carmel Olefins Ltd Impact strength polypropylene copolymers with low volatile emissions
EP3722364B1 (en) 2019-04-12 2024-01-24 Thai Polyethylene Co., Ltd. High flow and high stiffness impact copolymer polypropylene
US11725100B2 (en) 2019-05-13 2023-08-15 Braskem S.A. Proplylene-based copolymer product
WO2021080803A1 (en) 2019-10-22 2021-04-29 Exxonmobil Chemical Patents Inc. Impact copolymer compositions
WO2024058800A1 (en) * 2022-09-12 2024-03-21 Formosa Plastics Corporation, U.S.A. High ductility, high modulus and phthalate free impact resistant propylene copolymer

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Also Published As

Publication number Publication date
BR112013015505A2 (pt) 2016-10-11
JP6527454B2 (ja) 2019-06-05
ES2692860T3 (es) 2018-12-05
PL2655505T3 (pl) 2019-03-29
US20120157599A1 (en) 2012-06-21
CN103429656A (zh) 2013-12-04
JP2014500389A (ja) 2014-01-09
MX2013007072A (es) 2013-07-29
EP2655505B1 (en) 2018-07-25
CL2013001775A1 (es) 2013-12-06
JP5851519B2 (ja) 2016-02-03
CA2820359C (en) 2019-10-22
CN103429656B (zh) 2016-06-29
EP2655505A4 (en) 2016-08-10
CO6761303A2 (es) 2013-09-30
WO2012087832A1 (en) 2012-06-28
US20160194488A1 (en) 2016-07-07
EP2655505A1 (en) 2013-10-30
JP2016029192A (ja) 2016-03-03
BR112013015505B8 (pt) 2020-04-22
CA2820359A1 (en) 2012-06-28

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