MX353055B - Procedimiento para la preparación de óxidos mixtos multimetálicos y su uso como catalizadores de alto desempeño en la deshidrogenación oxidativa de etano para la producción de etileno, sin formación de ácido acético u otros hidrocarburos oxigenados. - Google Patents

Procedimiento para la preparación de óxidos mixtos multimetálicos y su uso como catalizadores de alto desempeño en la deshidrogenación oxidativa de etano para la producción de etileno, sin formación de ácido acético u otros hidrocarburos oxigenados.

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Publication number
MX353055B
MX353055B MX2015006073A MX2015006073A MX353055B MX 353055 B MX353055 B MX 353055B MX 2015006073 A MX2015006073 A MX 2015006073A MX 2015006073 A MX2015006073 A MX 2015006073A MX 353055 B MX353055 B MX 353055B
Authority
MX
Mexico
Prior art keywords
ethane
ethylene
preparation
oxidative dehydrogenation
oxide catalyst
Prior art date
Application number
MX2015006073A
Other languages
English (en)
Inventor
Sánchez Valente Jaime
De Lourdes Alejandra Guzmán Castillo María
Rodríguez Hernández Andrea
Quintana Solórzano Roberto
Manuel López Nieto José
Armendáriz Herrera Héctor
Massó Ramírez Amada
Ivars Barceló Francisco
Maya Flores Etel
Del Angel Vicente Paz
Original Assignee
Mexicano Inst Petrol
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mexicano Inst Petrol filed Critical Mexicano Inst Petrol
Publication of MX353055B publication Critical patent/MX353055B/es

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/18—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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    • B01J23/22—Vanadium
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/39—Photocatalytic properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
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    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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Abstract

La deshidrogenación oxidativa de parafinas ligeras, tal como etano, a temperaturas moderadas (<500°C) para producir etileno sin la formación de productos secundarios como ácido acético y/u otros hidrocarburos oxigenados, es lograda usando catalizadores multimetálicos libres de teluro, poseyendo la fase ortorrómbica M1 y otras estructuras cristalinas que tienen una función importante en la obtención de los catalizadores de alto rendimiento para la deshidrogenación oxidativa del etano a etileno. Tales catalizadores se prepararon usando métodos térmicos e hidrotérmicos.
MX2015006073A 2012-10-19 2013-06-05 Procedimiento para la preparación de óxidos mixtos multimetálicos y su uso como catalizadores de alto desempeño en la deshidrogenación oxidativa de etano para la producción de etileno, sin formación de ácido acético u otros hidrocarburos oxigenados. MX353055B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US13/655,620 US9409156B2 (en) 2012-10-19 2012-10-19 Oxidative dehydrogenation of ethane to ethylene and preparation of multimetallic mixed oxide catalyst for such process

Publications (1)

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MX353055B true MX353055B (es) 2017-12-11

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MX2015006073A MX353055B (es) 2012-10-19 2013-06-05 Procedimiento para la preparación de óxidos mixtos multimetálicos y su uso como catalizadores de alto desempeño en la deshidrogenación oxidativa de etano para la producción de etileno, sin formación de ácido acético u otros hidrocarburos oxigenados.
MX2013006308A MX345578B (es) 2012-10-19 2013-06-05 Procedimiento para la preparacion de oxidos mixtos multimetalicos y su uso como catalizadores de alto desempeño en la deshidrogenacion oxidativa de etano para la produccion de etileno, sin formacion de acido acetico u otros hidrocarburos oxigenados.

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US (3) US9409156B2 (es)
JP (2) JP6125023B2 (es)
CN (1) CN104968635B (es)
AR (1) AR094825A1 (es)
CA (2) CA2937242C (es)
ES (1) ES2428442B1 (es)
MX (2) MX353055B (es)
TW (1) TWI653224B (es)

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US11111193B2 (en) * 2014-06-30 2021-09-07 Shell Oil Company Treatment of a mixed metal oxide catalyst containing molybdenum, vanadium, niobium and optionally tellurium
CA3001434C (en) 2015-10-26 2023-10-03 Shell Internationale Research Maatschappij B.V. Ethane oxidative dehydrogenation and acetic acid recovery
EP3378114B1 (en) 2015-11-16 2024-07-31 Hheli, LLC Synthesized surface-functionalized, acidified metal oxide materials for energy storage, catalytic, photovoltaic, and sensor applications
CA2936448C (en) * 2016-07-19 2024-02-20 Nova Chemicals Corporation Controlled pressure hydrothermal treatment of odh catalyst
RU2713201C1 (ru) 2016-08-12 2020-02-04 Асахи Касеи Кабусики Кайся Способ получения оксидного катализатора и способ получения ненасыщенного нитрила и ненасыщенной кислоты
US10700349B2 (en) 2016-11-15 2020-06-30 HHeLI, LLC Surface-functionalized, acidified metal oxide material in an acidified electrolyte system or an acidified electrode system
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