MX2013006308A - Procedimiento para la preparacion de oxidos mixtos multimetalicos y su uso como catalizadores de alto desempeño en la deshidrogenacion oxidativa de etano para la produccion de etileno, sin formacion de acido acetico u otros hidrocarburos oxigenados. - Google Patents

Procedimiento para la preparacion de oxidos mixtos multimetalicos y su uso como catalizadores de alto desempeño en la deshidrogenacion oxidativa de etano para la produccion de etileno, sin formacion de acido acetico u otros hidrocarburos oxigenados.

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Publication number
MX2013006308A
MX2013006308A MX2013006308A MX2013006308A MX2013006308A MX 2013006308 A MX2013006308 A MX 2013006308A MX 2013006308 A MX2013006308 A MX 2013006308A MX 2013006308 A MX2013006308 A MX 2013006308A MX 2013006308 A MX2013006308 A MX 2013006308A
Authority
MX
Mexico
Prior art keywords
ethane
ethylene
preparation
oxidative dehydrogenation
oxide catalyst
Prior art date
Application number
MX2013006308A
Other languages
English (en)
Other versions
MX345578B (es
Inventor
Paz Del Angel Vicente
Andrea Rodríguez Hernández
María De Lourdes Alejandra Guzmán Castillo
Héctor Armendáriz Herrera
Jaime Sánchez Valente
Roberto Quintana Solórzano
José Manuel López Nieto
Amada Massó Ramírez
Francisco Ivars Barceló
Etel Maya Flores
Original Assignee
Inst Mexicano Del Petróleo
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inst Mexicano Del Petróleo filed Critical Inst Mexicano Del Petróleo
Priority to CA2888633A priority Critical patent/CA2888633C/en
Priority to PCT/MX2013/000121 priority patent/WO2014062046A1/es
Priority to CA2937242A priority patent/CA2937242C/en
Priority to JP2015537654A priority patent/JP6125023B2/ja
Priority to CN201380065588.2A priority patent/CN104968635B/zh
Publication of MX2013006308A publication Critical patent/MX2013006308A/es
Priority to JP2016174950A priority patent/JP6369817B2/ja
Publication of MX345578B publication Critical patent/MX345578B/es

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
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    • B01J23/18—Arsenic, antimony or bismuth
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
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    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
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    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
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Abstract

La deshidrogenación oxidativa de parafinas ligeras, tal como etano, a temperaturas moderadas (<500°C) para producir etileno sin la formación de productos secundarios como ácido acético y/u otros hidrocarburos oxigenados, es lograda usando catalizadores multimetálicos libres de teluro, poseyendo la fase ortorrómbica M1 y otras estructuras cristalinas que tienen una función importante en la obtención de los catalizadores de alto rendimiento para la deshidrogenación oxidativa del etano a etileno. Tales catalizadores se prepararon usando métodos térmicos e hidrotérmicos.
MX2013006308A 2012-10-19 2013-06-05 Procedimiento para la preparacion de oxidos mixtos multimetalicos y su uso como catalizadores de alto desempeño en la deshidrogenacion oxidativa de etano para la produccion de etileno, sin formacion de acido acetico u otros hidrocarburos oxigenados. MX345578B (es)

Priority Applications (6)

Application Number Priority Date Filing Date Title
CA2888633A CA2888633C (en) 2012-10-19 2013-10-04 Oxidative dehydrogenation of ethane to ethylene and preparation of multimetallic mixed oxide catalyst for such process
PCT/MX2013/000121 WO2014062046A1 (es) 2012-10-19 2013-10-04 Deshidrogenación oxidativa de etano a etileno y preparación de óxidos mixtos multimetálicos como catalizadores para tal proceso
CA2937242A CA2937242C (en) 2012-10-19 2013-10-04 Oxidative dehydrogenation of ethane to ethylene and preparation of multimetallic mixed oxide catalyst for such process
JP2015537654A JP6125023B2 (ja) 2012-10-19 2013-10-04 エチレンへのエタンの酸化脱水素及びこのようなプロセスのための触媒としての多金属混合酸化物の調製
CN201380065588.2A CN104968635B (zh) 2012-10-19 2013-10-04 乙烷到乙烯的氧化脱氢和用于此工艺的多金属混合氧化物催化剂的制备
JP2016174950A JP6369817B2 (ja) 2012-10-19 2016-09-07 エチレンへのエタンの酸化脱水素及びこのようなプロセスのための触媒としての多金属混合酸化物の調製

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US13/655,620 US9409156B2 (en) 2012-10-19 2012-10-19 Oxidative dehydrogenation of ethane to ethylene and preparation of multimetallic mixed oxide catalyst for such process

Publications (2)

Publication Number Publication Date
MX2013006308A true MX2013006308A (es) 2014-04-24
MX345578B MX345578B (es) 2017-01-25

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Family Applications (2)

Application Number Title Priority Date Filing Date
MX2015006073A MX353055B (es) 2012-10-19 2013-06-05 Procedimiento para la preparación de óxidos mixtos multimetálicos y su uso como catalizadores de alto desempeño en la deshidrogenación oxidativa de etano para la producción de etileno, sin formación de ácido acético u otros hidrocarburos oxigenados.
MX2013006308A MX345578B (es) 2012-10-19 2013-06-05 Procedimiento para la preparacion de oxidos mixtos multimetalicos y su uso como catalizadores de alto desempeño en la deshidrogenacion oxidativa de etano para la produccion de etileno, sin formacion de acido acetico u otros hidrocarburos oxigenados.

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MX2015006073A MX353055B (es) 2012-10-19 2013-06-05 Procedimiento para la preparación de óxidos mixtos multimetálicos y su uso como catalizadores de alto desempeño en la deshidrogenación oxidativa de etano para la producción de etileno, sin formación de ácido acético u otros hidrocarburos oxigenados.

Country Status (8)

Country Link
US (3) US9409156B2 (es)
JP (2) JP6125023B2 (es)
CN (1) CN104968635B (es)
AR (1) AR094825A1 (es)
CA (2) CA2888633C (es)
ES (1) ES2428442B1 (es)
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