ES2428442B1 - Deshidrogenación oxidativa de etano a etileno y preparación de catalizador de óxido mezclado multimetálico para tal proceso. - Google Patents
Deshidrogenación oxidativa de etano a etileno y preparación de catalizador de óxido mezclado multimetálico para tal proceso. Download PDFInfo
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- ES2428442B1 ES2428442B1 ES201331144A ES201331144A ES2428442B1 ES 2428442 B1 ES2428442 B1 ES 2428442B1 ES 201331144 A ES201331144 A ES 201331144A ES 201331144 A ES201331144 A ES 201331144A ES 2428442 B1 ES2428442 B1 ES 2428442B1
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- Prior art keywords
- ethylene
- oxidative dehydrogenation
- preparation
- oxide catalyst
- mixed oxide
- Prior art date
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- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title abstract 5
- 239000005977 Ethylene Substances 0.000 title abstract 5
- 239000003054 catalyst Substances 0.000 title abstract 5
- 238000005839 oxidative dehydrogenation reaction Methods 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 2
- 238000002360 preparation method Methods 0.000 title abstract 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 abstract 3
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 238000001027 hydrothermal synthesis Methods 0.000 abstract 1
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8877—Vanadium, tantalum, niobium or polonium
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- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
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- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
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Abstract
Deshidrogenación oxidativa de etano a etileno y preparación de catalizador de óxido mezclado multimetálico para tal proceso.#La deshidrogenación oxidativa de parafinas ligeras, tal como etano, a temperaturas moderadas (<500ºC) para producir etileno sin la formación de productos secundarios como ácido acético y/u otros hidrocarburos oxigenados, es lograda usando catalizadores multimetálicos libres de teluro, poseyendo la fase ortorrómbica M1 y otras estructuras cristalinas que tienen una función importante en la obtención de los catalizadores de alto rendimiento para la deshidrogenación oxidativa del etano a etileno. Tales catalizadores se prepararon usando métodos térmicos e hidrotérmicos.
Description
Claims (1)
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imagen1 imagen2 imagen3 imagen4 imagen5 imagen6 imagen7 imagen8 imagen9 imagen10 imagen11 imagen12 imagen13 imagen14 imagen15 imagen16 imagen17
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201380065588.2A CN104968635B (zh) | 2012-10-19 | 2013-10-04 | 乙烷到乙烯的氧化脱氢和用于此工艺的多金属混合氧化物催化剂的制备 |
PCT/MX2013/000121 WO2014062046A1 (es) | 2012-10-19 | 2013-10-04 | Deshidrogenación oxidativa de etano a etileno y preparación de óxidos mixtos multimetálicos como catalizadores para tal proceso |
CA2888633A CA2888633C (en) | 2012-10-19 | 2013-10-04 | Oxidative dehydrogenation of ethane to ethylene and preparation of multimetallic mixed oxide catalyst for such process |
CA2937242A CA2937242C (en) | 2012-10-19 | 2013-10-04 | Oxidative dehydrogenation of ethane to ethylene and preparation of multimetallic mixed oxide catalyst for such process |
JP2015537654A JP6125023B2 (ja) | 2012-10-19 | 2013-10-04 | エチレンへのエタンの酸化脱水素及びこのようなプロセスのための触媒としての多金属混合酸化物の調製 |
JP2016174950A JP6369817B2 (ja) | 2012-10-19 | 2016-09-07 | エチレンへのエタンの酸化脱水素及びこのようなプロセスのための触媒としての多金属混合酸化物の調製 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/655,620 US9409156B2 (en) | 2012-10-19 | 2012-10-19 | Oxidative dehydrogenation of ethane to ethylene and preparation of multimetallic mixed oxide catalyst for such process |
US13/655,620 | 2012-10-19 |
Publications (3)
Publication Number | Publication Date |
---|---|
ES2428442A2 ES2428442A2 (es) | 2013-11-07 |
ES2428442R1 ES2428442R1 (es) | 2014-02-19 |
ES2428442B1 true ES2428442B1 (es) | 2014-12-04 |
Family
ID=49396977
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES201331144A Active ES2428442B1 (es) | 2012-10-19 | 2013-07-25 | Deshidrogenación oxidativa de etano a etileno y preparación de catalizador de óxido mezclado multimetálico para tal proceso. |
Country Status (8)
Country | Link |
---|---|
US (3) | US9409156B2 (es) |
JP (2) | JP6125023B2 (es) |
CN (1) | CN104968635B (es) |
AR (1) | AR094825A1 (es) |
CA (2) | CA2937242C (es) |
ES (1) | ES2428442B1 (es) |
MX (2) | MX353055B (es) |
TW (1) | TWI653224B (es) |
Families Citing this family (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20150119622A1 (en) * | 2012-05-04 | 2015-04-30 | Shell Oil Company | Catalyst for alkane oxidative dehydrogenation and/or alkene oxidation |
CN106660902B (zh) * | 2014-06-30 | 2019-07-05 | 国际壳牌研究有限公司 | 烷烃氧化脱氢和/或烯烃氧化 |
US11111193B2 (en) * | 2014-06-30 | 2021-09-07 | Shell Oil Company | Treatment of a mixed metal oxide catalyst containing molybdenum, vanadium, niobium and optionally tellurium |
CA3001434C (en) | 2015-10-26 | 2023-10-03 | Shell Internationale Research Maatschappij B.V. | Ethane oxidative dehydrogenation and acetic acid recovery |
EP3378114B1 (en) | 2015-11-16 | 2024-07-31 | Hheli, LLC | Synthesized surface-functionalized, acidified metal oxide materials for energy storage, catalytic, photovoltaic, and sensor applications |
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CA2888633C (en) | 2019-01-08 |
US10058850B2 (en) | 2018-08-28 |
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US9409156B2 (en) | 2016-08-09 |
US9937486B2 (en) | 2018-04-10 |
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