MX345578B - Procedimiento para la preparacion de oxidos mixtos multimetalicos y su uso como catalizadores de alto desempeño en la deshidrogenacion oxidativa de etano para la produccion de etileno, sin formacion de acido acetico u otros hidrocarburos oxigenados. - Google Patents

Procedimiento para la preparacion de oxidos mixtos multimetalicos y su uso como catalizadores de alto desempeño en la deshidrogenacion oxidativa de etano para la produccion de etileno, sin formacion de acido acetico u otros hidrocarburos oxigenados.

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Publication number
MX345578B
MX345578B MX2013006308A MX2013006308A MX345578B MX 345578 B MX345578 B MX 345578B MX 2013006308 A MX2013006308 A MX 2013006308A MX 2013006308 A MX2013006308 A MX 2013006308A MX 345578 B MX345578 B MX 345578B
Authority
MX
Mexico
Prior art keywords
ethane
ethylene
preparation
oxidative dehydrogenation
oxide catalyst
Prior art date
Application number
MX2013006308A
Other languages
English (en)
Other versions
MX2013006308A (es
Inventor
Del Angel Vicente Paz
Rodríguez Hernández Andrea
De Lourdes Alejandra Guzmán Castillo María
Armendáriz Herrera Héctor
Sánchez Valente Jaime
Quintana Solórzano Roberto
Manuel López Nieto José
Massó Ramírez Amada
Ivars Barceló Francisco
Maya Flores Etel
Original Assignee
Inst Mexicano Del Petróleo
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inst Mexicano Del Petróleo filed Critical Inst Mexicano Del Petróleo
Priority to CN201380065588.2A priority Critical patent/CN104968635B/zh
Priority to PCT/MX2013/000121 priority patent/WO2014062046A1/es
Priority to CA2888633A priority patent/CA2888633C/en
Priority to CA2937242A priority patent/CA2937242C/en
Priority to JP2015537654A priority patent/JP6125023B2/ja
Publication of MX2013006308A publication Critical patent/MX2013006308A/es
Priority to JP2016174950A priority patent/JP6369817B2/ja
Publication of MX345578B publication Critical patent/MX345578B/es

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/18—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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    • B01J23/88—Molybdenum
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
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    • B01J35/39—Photocatalytic properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
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    • B01J37/10—Heat treatment in the presence of water, e.g. steam
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
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    • C07C11/04—Ethylene
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    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
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    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
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    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
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    • C07—ORGANIC CHEMISTRY
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    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
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    • C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
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  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
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Abstract

La deshidrogenación oxidativa de parafinas ligeras, tal como etano, a temperaturas moderadas (<500°C) para producir etileno sin la formación de productos secundarios como ácido acético y/u otros hidrocarburos oxigenados, es lograda usando catalizadores multimetálicos libres de teluro, poseyendo la fase ortorrómbica M1 y otras estructuras cristalinas que tienen una función importante en la obtención de los catalizadores de alto rendimiento para la deshidrogenación oxidativa del etano a etileno. Tales catalizadores se prepararon usando métodos térmicos e hidrotérmicos.
MX2013006308A 2012-10-19 2013-06-05 Procedimiento para la preparacion de oxidos mixtos multimetalicos y su uso como catalizadores de alto desempeño en la deshidrogenacion oxidativa de etano para la produccion de etileno, sin formacion de acido acetico u otros hidrocarburos oxigenados. MX345578B (es)

Priority Applications (6)

Application Number Priority Date Filing Date Title
CN201380065588.2A CN104968635B (zh) 2012-10-19 2013-10-04 乙烷到乙烯的氧化脱氢和用于此工艺的多金属混合氧化物催化剂的制备
PCT/MX2013/000121 WO2014062046A1 (es) 2012-10-19 2013-10-04 Deshidrogenación oxidativa de etano a etileno y preparación de óxidos mixtos multimetálicos como catalizadores para tal proceso
CA2888633A CA2888633C (en) 2012-10-19 2013-10-04 Oxidative dehydrogenation of ethane to ethylene and preparation of multimetallic mixed oxide catalyst for such process
CA2937242A CA2937242C (en) 2012-10-19 2013-10-04 Oxidative dehydrogenation of ethane to ethylene and preparation of multimetallic mixed oxide catalyst for such process
JP2015537654A JP6125023B2 (ja) 2012-10-19 2013-10-04 エチレンへのエタンの酸化脱水素及びこのようなプロセスのための触媒としての多金属混合酸化物の調製
JP2016174950A JP6369817B2 (ja) 2012-10-19 2016-09-07 エチレンへのエタンの酸化脱水素及びこのようなプロセスのための触媒としての多金属混合酸化物の調製

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US13/655,620 US9409156B2 (en) 2012-10-19 2012-10-19 Oxidative dehydrogenation of ethane to ethylene and preparation of multimetallic mixed oxide catalyst for such process

Publications (2)

Publication Number Publication Date
MX2013006308A MX2013006308A (es) 2014-04-24
MX345578B true MX345578B (es) 2017-01-25

Family

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Family Applications (2)

Application Number Title Priority Date Filing Date
MX2015006073A MX353055B (es) 2012-10-19 2013-06-05 Procedimiento para la preparación de óxidos mixtos multimetálicos y su uso como catalizadores de alto desempeño en la deshidrogenación oxidativa de etano para la producción de etileno, sin formación de ácido acético u otros hidrocarburos oxigenados.
MX2013006308A MX345578B (es) 2012-10-19 2013-06-05 Procedimiento para la preparacion de oxidos mixtos multimetalicos y su uso como catalizadores de alto desempeño en la deshidrogenacion oxidativa de etano para la produccion de etileno, sin formacion de acido acetico u otros hidrocarburos oxigenados.

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MX2015006073A MX353055B (es) 2012-10-19 2013-06-05 Procedimiento para la preparación de óxidos mixtos multimetálicos y su uso como catalizadores de alto desempeño en la deshidrogenación oxidativa de etano para la producción de etileno, sin formación de ácido acético u otros hidrocarburos oxigenados.

Country Status (8)

Country Link
US (3) US9409156B2 (es)
JP (2) JP6125023B2 (es)
CN (1) CN104968635B (es)
AR (1) AR094825A1 (es)
CA (2) CA2937242C (es)
ES (1) ES2428442B1 (es)
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Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150119622A1 (en) * 2012-05-04 2015-04-30 Shell Oil Company Catalyst for alkane oxidative dehydrogenation and/or alkene oxidation
CN106660902B (zh) * 2014-06-30 2019-07-05 国际壳牌研究有限公司 烷烃氧化脱氢和/或烯烃氧化
US11111193B2 (en) * 2014-06-30 2021-09-07 Shell Oil Company Treatment of a mixed metal oxide catalyst containing molybdenum, vanadium, niobium and optionally tellurium
CA3001434C (en) 2015-10-26 2023-10-03 Shell Internationale Research Maatschappij B.V. Ethane oxidative dehydrogenation and acetic acid recovery
EP3378114B1 (en) 2015-11-16 2024-07-31 Hheli, LLC Synthesized surface-functionalized, acidified metal oxide materials for energy storage, catalytic, photovoltaic, and sensor applications
CA2936448C (en) * 2016-07-19 2024-02-20 Nova Chemicals Corporation Controlled pressure hydrothermal treatment of odh catalyst
RU2713201C1 (ru) 2016-08-12 2020-02-04 Асахи Касеи Кабусики Кайся Способ получения оксидного катализатора и способ получения ненасыщенного нитрила и ненасыщенной кислоты
US10700349B2 (en) 2016-11-15 2020-06-30 HHeLI, LLC Surface-functionalized, acidified metal oxide material in an acidified electrolyte system or an acidified electrode system
CN108114730A (zh) * 2016-11-26 2018-06-05 中国科学院大连化学物理研究所 钼钒碲铌催化剂组合物
CN108114733A (zh) * 2016-11-26 2018-06-05 中国科学院大连化学物理研究所 钼钒碲铌复合催化剂
US10464864B2 (en) 2016-12-20 2019-11-05 Exxonmobil Research And Engineering Company Upgrading ethane-containing light paraffins streams
WO2018118440A1 (en) 2016-12-20 2018-06-28 Exxonmobil Research And Engineering Company Upgrading ethane-containing light paraffins streams
EP3559169A1 (en) 2016-12-20 2019-10-30 ExxonMobil Research and Engineering Company Upgrading ethane-containing light paraffins streams
WO2018148145A1 (en) 2017-02-07 2018-08-16 Sabic Global Technologies, B.V. A process for catalytic oxidative dehydrogenation of ethane to ethylene in the presence of chlorine intermediates
CN106861567B (zh) * 2017-02-17 2019-03-05 山东理工大学 一种铁磁性BiFeO3-α-Fe2O3核-壳结构纳米颗粒的制备方法
EP3610526A4 (en) 2017-04-10 2020-12-16 Hheli, LLC BATTERY WITH NEW ELEMENTS
CN110870102B (zh) 2017-05-17 2023-06-30 氢氦锂有限公司 具有酸化阴极和锂阳极的电池
WO2018213616A2 (en) 2017-05-17 2018-11-22 HHeLI, LLC Battery cell with novel construction
US10978731B2 (en) 2017-06-21 2021-04-13 HHeLI, LLC Ultra high capacity performance battery cell
EP3685458A4 (en) 2017-09-22 2021-07-07 Hheli, LLC CONSTRUCTION OF VERY HIGH CAPACITY PERFORMANCE BATTERY ELEMENTS
CA3008612A1 (en) * 2018-06-18 2019-12-18 Nova Chemicals Corporation Removing and cleaning dehydrogenation catalysts
US11230512B2 (en) * 2018-07-19 2022-01-25 Nova Chemicals (International) S.A. Catalysts for the oxidative dehydrogenation of alkanes
CA3050720A1 (en) * 2018-08-03 2020-02-03 Nova Chemicals Corporation Oxidative dehydrogenation catalyst compositions
WO2020049462A1 (en) * 2018-09-05 2020-03-12 Sabic Global Technologies B.V. Vanadium oxide supported catalyst for alkane dehydrogenation
CA3112390A1 (en) 2018-09-10 2020-03-19 HHeLI, LLC Methods of use of ultra high capacity performance battery cell
CN111085211B (zh) * 2018-10-24 2023-03-21 中国科学院青岛生物能源与过程研究所 一种用于乙烷氧化脱氢反应的介孔氧化铝基双功能催化剂及制备和应用
CA3115731A1 (en) 2018-11-02 2020-04-16 Shell Internationale Research Maatschappij B.V. Separation of ethane oxidative dehydrogenation effluent
BR102018076221B1 (pt) * 2018-12-17 2021-10-13 Petróleo Brasileiro S.A. - Petrobras Método de preparo do catalisador, catalisador e, processo de desidrogenação oxidativa de propano
BR112022005484A2 (pt) 2019-09-24 2022-06-14 Nova Chem Int Sa Geração de vapor em desidrogenação oxidativa
CN110882689B (zh) * 2019-12-11 2022-08-02 中国天辰工程有限公司 一种用于环己烷脱氢制环己烯的催化剂的制备及其应用
WO2021250495A1 (en) * 2020-06-09 2021-12-16 Nova Chemicals (International) S.A. Limiting acetic acid production in ethane odh process
ZA202106756B (en) 2020-09-17 2022-08-31 Indian Oil Corp Ltd An integrated oxidative alkane dehydrogenation and hydrogen generation process
CN114618474B (zh) * 2020-12-14 2023-08-18 中国科学院大连化学物理研究所 一种用于干气中乙烷制乙烯的钼钒锑氧催化剂及其制备方法
JP2024532841A (ja) * 2021-08-23 2024-09-10 ダウ グローバル テクノロジーズ エルエルシー アルカンからオレフィンへの脱水素のための触媒及びプロセス

Family Cites Families (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4250346A (en) 1980-04-14 1981-02-10 Union Carbide Corporation Low temperature oxydehydrogenation of ethane to ethylene
US4524236A (en) * 1984-06-28 1985-06-18 Union Carbide Corporation Process for oxydehydrogenation of ethane to ethylene
US4568790A (en) 1984-06-28 1986-02-04 Union Carbide Corporation Process for oxydehydrogenation of ethane to ethylene
GB8518820D0 (en) * 1985-07-25 1985-08-29 British Petroleum Co Plc Chemical process
US5162578A (en) 1987-06-12 1992-11-10 Union Carbide Chemicals & Plastics Technology Corporation Acetic acid from ethane, ethylene and oxygen
EP0294846A3 (en) 1987-06-12 1990-06-20 Union Carbide Corporation Preparation of organic acids from alkanols
IT1252093B (it) * 1991-11-26 1995-06-01 Eniricerche Spa Catalizzatore e procedimento per la deidrogenazione ossidativa di etano ad etilene
JPH10175885A (ja) * 1996-04-25 1998-06-30 Mitsubishi Chem Corp エチレンの製造方法
JPH1017523A (ja) 1996-07-01 1998-01-20 Mitsubishi Chem Corp 酢酸の製造方法
DE19630832A1 (de) 1996-07-31 1998-02-05 Hoechst Ag Verfahren zur selektiven Herstellung von Essigsäure
US5821192A (en) 1996-09-23 1998-10-13 The Standard Oil Company Method of improving the attrition resistance of V/SB oxide based catalyst
FR2754817B1 (fr) 1996-10-21 2000-03-17 Toagosei Co Ltd Procede de production d'acide acrylique a partir de propane et d'oxygene gazeux
US5866502A (en) * 1997-03-27 1999-02-02 The Standard Oil Co. Process for the preparation of antimonate catalysts for (AMM) oxidation of alkanes and alkenes
JPH1143314A (ja) * 1997-07-25 1999-02-16 Mitsubishi Chem Corp 複合酸化物の製造方法
US6013597A (en) 1997-09-17 2000-01-11 Saudi Basic Industries Corporation Catalysts for the oxidation of ethane to acetic acid processes of making same and, processes of using same
US6030920A (en) 1997-12-24 2000-02-29 Saudi Basic Industries Corporation Catalysts for producing acetic acid from ethane oxidation, processes of making same and method of using same
JPH11285637A (ja) * 1998-04-03 1999-10-19 Toagosei Co Ltd アクリル酸製造用触媒およびその製造方法ならびに該触媒を用いるアクリル酸の製造方法
US6514902B1 (en) 1998-08-28 2003-02-04 Asahi Kasei Kogyo Kabushiki Kaisha Method for producing an oxide catalyst for use in producing acrylonitrile or methacrylonitrile from propane or isobutane
US6436871B1 (en) 1999-02-22 2002-08-20 Symyx Technologies, Inc. Catalysts for oxidative dehydrogenation
JP4247565B2 (ja) 1999-03-10 2009-04-02 東亞合成株式会社 アクリル酸製造用の触媒およびそれを用いたアクリル酸の製造方法
US6531631B1 (en) 2000-04-28 2003-03-11 Saudi Basic Industries Corporation Oxidation of ethane to acetic acid and ethylene using molybdenum and vanadium based catalysts
AU2001287622A1 (en) * 2000-07-18 2002-01-30 Basf Aktiengesellschaft Method for producing acrylic acid by the heterogeneously catalysed gas-phase oxidation of propane
KR100407528B1 (ko) 2000-09-18 2003-11-28 아사히 가세이 가부시키가이샤 산화 또는 가암모니아산화용 산화물 촉매의 제조 방법
JP4530595B2 (ja) 2000-12-13 2010-08-25 旭化成ケミカルズ株式会社 酸化またはアンモ酸化用酸化物触媒
TW574071B (en) 2001-06-14 2004-02-01 Rohm & Haas Mixed metal oxide catalyst
ES2192983B1 (es) 2002-01-31 2004-09-16 Universidad Politecnica De Valencia. Un catalizador para la deshidrogenacion oxidativa de etano a eteno.
WO2004024665A1 (fr) 2002-09-10 2004-03-25 Arkema Procede de fabrication d'acide acrylique a partir de propane
US6864384B2 (en) 2002-11-27 2005-03-08 The Standard Oil Company Preparation of vanadium antimony oxide based catalysts using nano-scale iron
FR2855516B1 (fr) * 2003-05-27 2005-07-08 Atofina Oxydation du propane en acide acrylique par utilisation de catalyseurs en melange de phases cristallines
BRPI0500615B1 (pt) 2004-03-10 2015-07-14 Rohm & Haas Catalisador modificado, e, sistema de catalisador modificado
EP1598110A1 (en) 2004-04-22 2005-11-23 Rohm and Haas Company Structured oxidation catalysts
EP1755779A1 (de) * 2004-06-09 2007-02-28 Basf Aktiengesellschaft Verfahren zur herstellung einer multimetalloxidmasse
EP1704919A1 (en) * 2005-03-25 2006-09-27 Arkema France Process for preparing improved catalysts for selective oxidation of propane into acrylic acid
US7807601B2 (en) 2006-12-27 2010-10-05 Exxonmobil Research And Engineering Company Mixed metal oxide catalysts and processes for their preparation and use
US20080248947A1 (en) 2007-04-03 2008-10-09 Zajac Gerry W Mixed metal oxide catalysts and catalytic processes for conversions of lower alkane hydrocarbons
US8697596B2 (en) * 2007-04-03 2014-04-15 Ineos Usa Llc Mixed metal oxide catalysts and catalytic conversions of lower alkane hydrocarbons
US8658817B2 (en) 2008-08-01 2014-02-25 Ineos Usa Llc Method of making mixed metal oxide catalysts for ammoxidation and/or oxidation of lower alkane hydrocarbons
CA2655841C (en) 2009-02-26 2016-06-21 Nova Chemicals Corporation Supported oxidative dehydrogenation catalyst
US8105971B2 (en) 2009-04-02 2012-01-31 Lummus Technology Inc. Process for making catalysts useful for the conversion of paraffins to olefins
US8519210B2 (en) 2009-04-02 2013-08-27 Lummus Technology Inc. Process for producing ethylene via oxidative dehydrogenation (ODH) of ethane
CA2699836A1 (en) 2010-03-31 2011-09-30 Nova Chemicals Corporation Oxidative dehydrogenation of paraffins
CA2701089A1 (en) 2010-03-31 2011-09-30 Nova Chemicals Corporation Pulsed oxidative dehydrogenation process
WO2012134898A2 (en) 2011-03-25 2012-10-04 Rohm And Haas Company Steam re-calcination of mixed metal oxide catalysts

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