MX342580B - Metodo para recuperar rutenio a partir de un catalizador residual a base de rutenio soportado sobre oxido de aluminio. - Google Patents
Metodo para recuperar rutenio a partir de un catalizador residual a base de rutenio soportado sobre oxido de aluminio.Info
- Publication number
- MX342580B MX342580B MX2014010726A MX2014010726A MX342580B MX 342580 B MX342580 B MX 342580B MX 2014010726 A MX2014010726 A MX 2014010726A MX 2014010726 A MX2014010726 A MX 2014010726A MX 342580 B MX342580 B MX 342580B
- Authority
- MX
- Mexico
- Prior art keywords
- ruthenium
- obtaining
- waste catalyst
- aluminum oxide
- h3ruc16
- Prior art date
Links
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 title abstract 9
- 229910052707 ruthenium Inorganic materials 0.000 title abstract 9
- 239000003054 catalyst Substances 0.000 title abstract 4
- 239000002699 waste material Substances 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 title abstract 3
- 239000007789 gas Substances 0.000 abstract 4
- 229910001927 ruthenium tetroxide Inorganic materials 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 239000012530 fluid Substances 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 230000001590 oxidative effect Effects 0.000 abstract 2
- 239000000843 powder Substances 0.000 abstract 2
- 238000006722 reduction reaction Methods 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 abstract 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 235000019270 ammonium chloride Nutrition 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 239000012065 filter cake Substances 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 230000001737 promoting effect Effects 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 229910001925 ruthenium oxide Inorganic materials 0.000 abstract 1
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/06—Chloridising
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/02—Obtaining noble metals by dry processes
- C22B11/021—Recovery of noble metals from waste materials
- C22B11/026—Recovery of noble metals from waste materials from spent catalysts
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/04—Obtaining noble metals by wet processes
- C22B11/042—Recovery of noble metals from waste materials
- C22B11/048—Recovery of noble metals from waste materials from spent catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
Un método para recuperar rutenio a partir de un catalizador residual a base de rutenio soportado sobre óxido de aluminio, que comprende los siguientes pasos: secar, tostar y enfriar el catalizador residual a base de rutenio soportado sobre óxido de aluminio; moler el polvo negro que contiene óxido de rutenio; colocar el polvo negro en un reactor de lecho fluidizado, introducir hidrógeno y realizar la reacción de reducción, obteniendo de este modo el Ru metálico; introducir una mezcla gaseosa de oxígeno y ozono en el reactor de lecho fluidizado y oxidar al catalizador residual, obteniéndose de este modo gas RuO4 introducir el gas RuO4 en una solución de ácido clorhídrico suficiente para disolver el gas RuO4, obteniendo de este modo una solución de H3RuCl6 adicionar de forma excesiva el oxidante en la solución de H3RuCl6 y promover que la solución de H3RuCl6 se oxide totalmente, generando así hexacloro ácido de rutenio (IV); adicionar NH4Cl en exceso, hacer reaccionar, filtrar y limpiar la torta de filtración, por lo que se obtiene hexacloro de rutenio (IV) de amonio sólido; y, finalmente, realizar el tratamiento de reducción con hidrógeno sobre el hexacloro de rutenio (IV) de amonio sólido, obteniéndose de este modo el rutenio metálico. El método es simple en operación, de bajo costo, con una recuperación en un periodo corto y un alto promedio de recuperación.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012100558061A CN102560128B (zh) | 2012-03-05 | 2012-03-05 | 氧化铝负载钌废催化剂中回收钌的方法 |
| PCT/CN2013/072114 WO2013131453A1 (zh) | 2012-03-05 | 2013-03-04 | 氧化铝负载钌废催化剂中回收钌的方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2014010726A MX2014010726A (es) | 2014-10-13 |
| MX342580B true MX342580B (es) | 2016-10-03 |
Family
ID=46406726
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2014010726A MX342580B (es) | 2012-03-05 | 2013-03-04 | Metodo para recuperar rutenio a partir de un catalizador residual a base de rutenio soportado sobre oxido de aluminio. |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US9758844B2 (es) |
| EP (1) | EP2824201B1 (es) |
| JP (1) | JP5891316B2 (es) |
| KR (1) | KR101613258B1 (es) |
| CN (1) | CN102560128B (es) |
| AP (1) | AP2014007988A0 (es) |
| AU (1) | AU2013230405B2 (es) |
| BR (1) | BR112014021850B1 (es) |
| CA (1) | CA2866191C (es) |
| DK (1) | DK2824201T3 (es) |
| HR (1) | HRP20181285T1 (es) |
| HU (1) | HUE038818T2 (es) |
| IN (1) | IN2014MN01925A (es) |
| MX (1) | MX342580B (es) |
| MY (1) | MY175018A (es) |
| RU (1) | RU2580580C1 (es) |
| SG (1) | SG11201405385XA (es) |
| WO (1) | WO2013131453A1 (es) |
| ZA (1) | ZA201407148B (es) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102560128B (zh) * | 2012-03-05 | 2013-10-09 | 武汉凯迪工程技术研究总院有限公司 | 氧化铝负载钌废催化剂中回收钌的方法 |
| DE102015118279A1 (de) * | 2015-10-27 | 2017-04-27 | Max-Planck-Institut Für Eisenforschung GmbH | Verfahren zur Gewinnung von Edelmetallen |
| EP3243914B1 (de) * | 2016-05-13 | 2018-10-17 | Heraeus Deutschland GmbH & Co. KG | Verfahren zur herstellung von partikulärem ruthenium |
| WO2018065127A1 (de) * | 2016-10-07 | 2018-04-12 | Heraeus Deutschland GmbH & Co. KG | Verfahren zur abtrennung von edelmetall aus partikulärem edelmetallhaltigem refraktärmaterial |
| CN106282581B (zh) * | 2016-11-01 | 2018-02-06 | 福州大学 | 一种活性炭负载钌催化剂中钌的回收方法 |
| CN107166403B (zh) * | 2017-07-04 | 2019-03-05 | 于向真 | 一种贵金属碳催化剂焚烧炉及焚烧工艺 |
| DE102018208043A1 (de) * | 2018-05-23 | 2019-11-28 | Robert Bosch Gmbh | Verfahren und Vorrichtung zur Gewinnung von Gold, Silber und Platinmetallen |
| DE102018208079A1 (de) * | 2018-05-23 | 2019-11-28 | Robert Bosch Gmbh | Verfahren und Vorrichtung zur Gewinnung von Gold, Silber und Platinmetallen |
| CN109161698B (zh) * | 2018-09-13 | 2020-11-17 | 陈永福 | 一种在富集铂族金属及金的工艺中优先吸收钌的方法 |
| CN111100999B (zh) * | 2018-10-26 | 2021-11-05 | 贵研资源（易门）有限公司 | 废催化剂钌的回收方法 |
| CN111100997B (zh) * | 2018-10-26 | 2021-11-05 | 贵研资源（易门）有限公司 | 从失效氯化氢氧化制氯气催化剂回收钌的方法 |
| CN110919019A (zh) * | 2019-12-02 | 2020-03-27 | 河南东微电子材料有限公司 | 一种高纯钌粉的制备方法 |
| CN111744560A (zh) * | 2020-07-28 | 2020-10-09 | 安徽东至广信农化有限公司 | 一种加氢催化剂的回收方法 |
| DE102020209886A1 (de) * | 2020-08-05 | 2022-02-10 | Robert Bosch Gesellschaft mit beschränkter Haftung | Verfahren und Vorrichtung zur Gewinnung von Gold und/oder Silber und/oder mindestens einem Platinmetall |
| CN116203184B (zh) * | 2021-12-01 | 2024-09-24 | 中国科学院大连化学物理研究所 | 一种钴钌/氧化铝催化剂中钴钌含量的检测方法 |
| CN114934180B (zh) * | 2022-04-12 | 2023-01-24 | 中南大学 | 一种富集氧化铝基废载钌催化剂中钌的方法 |
| DE102022111440B3 (de) | 2022-05-09 | 2022-08-25 | Technische Universität Bergakademie Freiberg, Körperschaft des öffentlichen Rechts | Verfahren zur Rückgewinnung von Ruthenium aus einem Ruthenium-haltigem Material |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09227965A (ja) * | 1996-02-19 | 1997-09-02 | Mitsubishi Materials Corp | 精製金属ルテニウム粉末とその製造方法 |
| US6458183B1 (en) * | 1999-09-07 | 2002-10-01 | Colonial Metals, Inc. | Method for purifying ruthenium and related processes |
| RU2239666C1 (ru) * | 2003-04-24 | 2004-11-10 | Институт неорганической химии им. А.В. Николаева СО РАН (статус государственного учреждения) | Способ получения концентрата родия, палладия и рутения из азотнокислых растворов |
| JP2005272917A (ja) * | 2004-03-24 | 2005-10-06 | Jfe Steel Kk | Ｍｏ含有廃触媒の処理方法 |
| DE102005061954A1 (de) * | 2005-12-23 | 2007-07-05 | Basf Ag | Verfahren zur Wiedergewinnung von Ruthenium aus gebrauchten Rutheniumoxid-haltigen Katalysatoren |
| DE102007020142A1 (de) * | 2007-04-26 | 2008-10-30 | Bayer Materialscience Ag | Verfahren zur Rückgewinnung von Ruthenium aus einem rutheniumhaltigen geträgerten Katalysatormaterial |
| CN101270420A (zh) * | 2008-05-19 | 2008-09-24 | 中国科学院山西煤炭化学研究所 | 一种钴基费托合成催化剂中钴的回收方法 |
| JP5408993B2 (ja) * | 2008-12-24 | 2014-02-05 | 山本貴金属地金株式会社 | 白金族元素の回収方法 |
| WO2010076297A2 (de) * | 2008-12-30 | 2010-07-08 | Basf Se | Verfahren zur wiedergewinnung von ruthenium aus gebrauchten rutheniumoxidhaltigen katalysatoren |
| CN101700913B (zh) * | 2009-11-17 | 2011-05-18 | 中南民族大学 | 利用费托合成用氧化铝负载钴基废催化剂制备高纯硝酸钴 |
| CN101797649B (zh) * | 2010-01-19 | 2012-09-05 | 兰州大学 | 一种制备高纯钌的方法及装置 |
| US7935173B1 (en) * | 2010-07-23 | 2011-05-03 | Metals Recovery Technology Inc. | Process for recovery of precious metals |
| CN102108444B (zh) * | 2011-04-01 | 2013-04-17 | 开滦能源化工股份有限公司 | 从负载型钌金属或氧化钌催化剂中回收钌的方法 |
| CN102560128B (zh) * | 2012-03-05 | 2013-10-09 | 武汉凯迪工程技术研究总院有限公司 | 氧化铝负载钌废催化剂中回收钌的方法 |
-
2012
- 2012-03-05 CN CN2012100558061A patent/CN102560128B/zh not_active Expired - Fee Related
-
2013
- 2013-03-04 WO PCT/CN2013/072114 patent/WO2013131453A1/zh not_active Ceased
- 2013-03-04 HR HRP20181285TT patent/HRP20181285T1/hr unknown
- 2013-03-04 HU HUE13758628A patent/HUE038818T2/hu unknown
- 2013-03-04 IN IN1925MUN2014 patent/IN2014MN01925A/en unknown
- 2013-03-04 MX MX2014010726A patent/MX342580B/es active IP Right Grant
- 2013-03-04 JP JP2014560230A patent/JP5891316B2/ja not_active Expired - Fee Related
- 2013-03-04 KR KR1020147027916A patent/KR101613258B1/ko not_active Expired - Fee Related
- 2013-03-04 EP EP13758628.5A patent/EP2824201B1/en not_active Not-in-force
- 2013-03-04 AU AU2013230405A patent/AU2013230405B2/en not_active Ceased
- 2013-03-04 DK DK13758628.5T patent/DK2824201T3/en active
- 2013-03-04 SG SG11201405385XA patent/SG11201405385XA/en unknown
- 2013-03-04 MY MYPI2014002569A patent/MY175018A/en unknown
- 2013-03-04 RU RU2014140155/02A patent/RU2580580C1/ru not_active IP Right Cessation
- 2013-03-04 BR BR112014021850-1A patent/BR112014021850B1/pt not_active IP Right Cessation
- 2013-03-04 AP AP2014007988A patent/AP2014007988A0/xx unknown
- 2013-03-04 CA CA2866191A patent/CA2866191C/en not_active Expired - Fee Related
-
2014
- 2014-09-05 US US14/479,268 patent/US9758844B2/en not_active Expired - Fee Related
- 2014-10-02 ZA ZA2014/07148A patent/ZA201407148B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN102560128A (zh) | 2012-07-11 |
| JP5891316B2 (ja) | 2016-03-22 |
| ZA201407148B (en) | 2016-01-27 |
| MX2014010726A (es) | 2014-10-13 |
| MY175018A (en) | 2020-06-02 |
| KR101613258B1 (ko) | 2016-04-29 |
| US9758844B2 (en) | 2017-09-12 |
| KR20140130549A (ko) | 2014-11-10 |
| HUE038818T2 (hu) | 2018-11-28 |
| BR112014021850B1 (pt) | 2019-05-28 |
| HRP20181285T1 (hr) | 2018-10-05 |
| RU2580580C1 (ru) | 2016-04-10 |
| AP2014007988A0 (en) | 2014-10-31 |
| CA2866191C (en) | 2017-01-03 |
| US20140373682A1 (en) | 2014-12-25 |
| JP2015511885A (ja) | 2015-04-23 |
| AU2013230405B2 (en) | 2015-11-05 |
| EP2824201B1 (en) | 2018-05-16 |
| SG11201405385XA (en) | 2014-11-27 |
| EP2824201A1 (en) | 2015-01-14 |
| CN102560128B (zh) | 2013-10-09 |
| EP2824201A4 (en) | 2015-12-09 |
| DK2824201T3 (en) | 2018-08-27 |
| CA2866191A1 (en) | 2013-09-12 |
| IN2014MN01925A (es) | 2015-07-10 |
| AU2013230405A1 (en) | 2014-10-16 |
| WO2013131453A1 (zh) | 2013-09-12 |
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