MX339548B - Metodo para producir espumas rigidas de poliuretano y espumas rigidas de poliisocianurato. - Google Patents

Metodo para producir espumas rigidas de poliuretano y espumas rigidas de poliisocianurato.

Info

Publication number
MX339548B
MX339548B MX2014007821A MX2014007821A MX339548B MX 339548 B MX339548 B MX 339548B MX 2014007821 A MX2014007821 A MX 2014007821A MX 2014007821 A MX2014007821 A MX 2014007821A MX 339548 B MX339548 B MX 339548B
Authority
MX
Mexico
Prior art keywords
mol
hard foams
derivatives
polyol
acid composition
Prior art date
Application number
MX2014007821A
Other languages
English (en)
Other versions
MX2014007821A (es
Inventor
Gunnar Kampf
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of MX2014007821A publication Critical patent/MX2014007821A/es
Publication of MX339548B publication Critical patent/MX339548B/es

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/10Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/4009Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C08G18/4211Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
    • C08G18/4219Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols from aromatic dicarboxylic acids and dialcohols in combination with polycarboxylic acids and/or polyhydroxy compounds which are at least trifunctional
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4244Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups
    • C08G18/4247Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids
    • C08G18/4252Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids derived from polyols containing polyether groups and polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4288Polycondensates having carboxylic or carbonic ester groups in the main chain modified by higher fatty oils or their acids or by resin acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/08Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing carbon dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/141Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00Foam properties
    • C08G2110/0025Foam properties rigid
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/02CO2-releasing, e.g. NaHCO3 and citric acid
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/14Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/18Binary blends of expanding agents
    • C08J2203/184Binary blends of expanding agents of chemical foaming agent and physical blowing agent, e.g. azodicarbonamide and fluorocarbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04Polyurethanes
    • C08J2375/06Polyurethanes from polyesters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04Polyurethanes
    • C08J2375/08Polyurethanes from polyethers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Laminated Bodies (AREA)

Abstract

La invención se refiere a un método para la producción de espumas rígidas de poliuretano o espumas rígidas de poliisocianurato por reacción de por lo menos un poliisocianato A), poliéter éster polioles B) a base de ácidos dicarboxílicos aromáticos que pueden obtenerse por esterificación de B1) de 10 a 70% molar de una composición de ácido dicarboxílico que contiene b11) de 50 a 100% molar, en relación a la composición de ácido dicarboxílico, de uno o más ácidos dicarboxílicos aromáticos o derivados de los mismos, b12) de 0 a 50% molar, en relación a la composición de ácido dicarboxílico b1), de uno o un ácidos dicarboxílicos alifáticos o más derivados de los mismos, b2) de 2 a 30% molar de uno o más ácidos grasos y/o derivados de ácidos grasos, b3) de 10 a 70% molar de uno o más dioles alifáticos o cicloalifáticos con 2 a 18 átomos de C o alcoxilatos de la misma, b4) de 2 a 50% molar de un poliol de poliéter que tiene una funcionalidad mayor que o igual a 2, producido por alcoxilación de un poliol que tiene una funcionalidad mayor que 2, donde polioles de poliéster adicionales necesarios C), que se diferencian de los del componente B), y por lo menos un poliol de poliéter D), en donde la relación de masa de la suma de los componentes B) y, en su caso, C) al componente D) es de por lo menos 7. La invención también se refiere a la fuerza espumas que puede obtenerse en dicha manera y para el uso de los mismos para la producción de elementos emparedados con capas de cobertura rígidas o flexibles. La invención se refiere además a los componentes básicos de poliol.
MX2014007821A 2012-01-02 2012-12-13 Metodo para producir espumas rigidas de poliuretano y espumas rigidas de poliisocianurato. MX339548B (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12150016 2012-01-02
EP12160927 2012-03-23
PCT/EP2012/075347 WO2013102540A1 (de) 2012-01-02 2012-12-13 Verfahren zur herstellung von polyurethan-hartschäumen und polyisocyanurat-hartschäumen

Publications (2)

Publication Number Publication Date
MX2014007821A MX2014007821A (es) 2014-09-01
MX339548B true MX339548B (es) 2016-05-30

Family

ID=47501145

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2014007821A MX339548B (es) 2012-01-02 2012-12-13 Metodo para producir espumas rigidas de poliuretano y espumas rigidas de poliisocianurato.

Country Status (19)

Country Link
EP (1) EP2800769B1 (es)
JP (2) JP2015504113A (es)
KR (1) KR102018406B1 (es)
CN (1) CN104039856B (es)
AU (1) AU2012364369B2 (es)
BR (1) BR112014016275B1 (es)
CA (1) CA2862774C (es)
EA (1) EA027089B1 (es)
ES (1) ES2560968T3 (es)
HU (1) HUE027908T2 (es)
IN (1) IN2014CN04925A (es)
MX (1) MX339548B (es)
MY (1) MY167781A (es)
PH (1) PH12014501409A1 (es)
PL (1) PL2800769T3 (es)
RS (1) RS54603B1 (es)
SG (1) SG11201403796RA (es)
WO (1) WO2013102540A1 (es)
ZA (1) ZA201405619B (es)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8895636B2 (en) 2012-01-02 2014-11-25 Basf Se Producing rigid polyurethane foams and rigid polyisocyanurate foams
MY165909A (en) * 2012-01-18 2018-05-18 Basf Se Method for producing rigid polyurethane foams
US9475220B2 (en) 2013-02-13 2016-10-25 Basf Se Process for producing composite elements
ES2655510T3 (es) * 2013-08-20 2018-02-20 Basf Se Espumas rígidas de poliuretano y poliisocianurato mejoradas a base de polioles de poliéter modificados por ácidos grasos
CA2934128A1 (en) * 2013-12-16 2015-06-25 Rockwool International A/S Polyisocyanurate foam composites and their production and use
EP3105274B1 (de) * 2014-02-11 2018-03-14 Basf Se Verfahren zur herstellung von polyurethan-hartschäumen und polyisocyanurat-hartschäumen
CN104448186A (zh) * 2014-11-20 2015-03-25 镇江拜因诺生物科技有限公司 一种生物基聚氨酯泡沫保温材料
CA2973777C (en) 2015-03-12 2023-09-26 Huntsman Advanced Materials Licensing (Switzerland) Gmbh Polyol component for the production of pur foams
KR20180041665A (ko) * 2015-08-17 2018-04-24 코베스트로 도이칠란트 아게 촉매로서 시클릭 암모늄 염을 사용하는 이소시아네이트의 개질 방법
WO2020231603A1 (en) * 2019-05-16 2020-11-19 Dow Global Technologies Llc Compatibilized blends of terephalate ester polyols and hydrocarbon blowing agents
US20220315690A1 (en) * 2019-07-22 2022-10-06 Dow Global Technologies Llc Polyurethane compositions, products prepared with same and preparation methods thereof
WO2023066838A1 (de) 2021-10-18 2023-04-27 Basf Se Verfahren zur herstellung von verbesserten polyisocyanurat-hartschaumstoffen auf basis von aromatischen polyesterpolyolen und ethylenoxid basierten polyetherpolyolen
CN116925317B (zh) * 2023-09-19 2023-11-28 南京赛弗尼电气有限公司 一种地面抬升用聚氨酯树脂组合物及其制备方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1003714B (de) 1956-01-25 1957-03-07 Glanzstoff Ag Verfahren zum Abbau von Polyaethylenterephthalat zu Terephthalsaeuredimethylester
DE1097671B (de) 1959-05-23 1961-01-19 Bayer Ag Verfahren zur Herstellung von Urethangruppen enthaltenden harten Schaumstoffen
US3399154A (en) * 1965-10-22 1968-08-27 Witco Chemical Corp Rigid polyurethane foams and polyesters for use therein
US5051528A (en) 1990-04-24 1991-09-24 Eastman Kodak Company Recovery process for ethylene glycol and dimethylterephthalate
EP1058701B2 (en) 1998-02-23 2011-03-16 Stepan Company Low viscosity polyester polyols and methods for preparing same
DE102005041763A1 (de) * 2005-09-01 2007-03-08 Basf Ag Polyisocyanurat Hartschaum und Verfahren zur Herstellung
WO2010043624A2 (de) * 2008-10-15 2010-04-22 Basf Se Polyesterpolyole auf basis von terephthalsäure
EP2492297A1 (de) * 2011-02-23 2012-08-29 Basf Se Polyesterpolyole auf Basis aromatischer Dicarbonsäuren und daraus hergestellte Polyurethanhartschäume
MY165909A (en) * 2012-01-18 2018-05-18 Basf Se Method for producing rigid polyurethane foams

Also Published As

Publication number Publication date
BR112014016275A8 (pt) 2017-07-04
JP6567709B2 (ja) 2019-08-28
PL2800769T3 (pl) 2016-06-30
WO2013102540A1 (de) 2013-07-11
CN104039856B (zh) 2017-03-01
EP2800769A1 (de) 2014-11-12
ZA201405619B (en) 2015-12-23
CA2862774A1 (en) 2013-07-11
MY167781A (en) 2018-09-25
CA2862774C (en) 2020-08-18
MX2014007821A (es) 2014-09-01
JP2018111818A (ja) 2018-07-19
EA027089B1 (ru) 2017-06-30
KR20140109475A (ko) 2014-09-15
CN104039856A (zh) 2014-09-10
AU2012364369B2 (en) 2016-01-14
SG11201403796RA (en) 2014-11-27
BR112014016275A2 (pt) 2017-06-13
EP2800769B1 (de) 2015-12-09
HUE027908T2 (en) 2016-11-28
JP2015504113A (ja) 2015-02-05
KR102018406B1 (ko) 2019-10-21
EA201491312A1 (ru) 2014-11-28
ES2560968T3 (es) 2016-02-23
RS54603B1 (en) 2016-08-31
AU2012364369A1 (en) 2014-07-24
IN2014CN04925A (es) 2015-09-18
BR112014016275B1 (pt) 2020-10-27
PH12014501409A1 (en) 2014-09-22

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