RS54603B1 - Method for producing polyurethane hard foams and polyisocyanurate hard foams - Google Patents

Method for producing polyurethane hard foams and polyisocyanurate hard foams

Info

Publication number
RS54603B1
RS54603B1 RS20160100A RSP20160100A RS54603B1 RS 54603 B1 RS54603 B1 RS 54603B1 RS 20160100 A RS20160100 A RS 20160100A RS P20160100 A RSP20160100 A RS P20160100A RS 54603 B1 RS54603 B1 RS 54603B1
Authority
RS
Serbia
Prior art keywords
mol
dicarboxylic acids
optionally
hard foams
composition
Prior art date
Application number
RS20160100A
Other languages
Serbian (sr)
Inventor
Gunnar Kampf
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of RS54603B1 publication Critical patent/RS54603B1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C08G18/4211—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
    • C08G18/4219—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols from aromatic dicarboxylic acids and dialcohols in combination with polycarboxylic acids and/or polyhydroxy compounds which are at least trifunctional
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4244—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups
    • C08G18/4247—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids
    • C08G18/4252—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids derived from polyols containing polyether groups and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4288—Polycondensates having carboxylic or carbonic ester groups in the main chain modified by higher fatty oils or their acids or by resin acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/08—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/141—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/02—CO2-releasing, e.g. NaHCO3 and citric acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/18—Binary blends of expanding agents
    • C08J2203/184—Binary blends of expanding agents of chemical foaming agent and physical blowing agent, e.g. azodicarbonamide and fluorocarbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C08J2375/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C08J2375/08—Polyurethanes from polyethers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Laminated Bodies (AREA)

Abstract

Postupak za dobijanje čvrstih poliuretanskih pena koji obuhvata reakcijuA) bar jednog poliizocijanata,B) bar jednog polietarester poliola koji se može dobiti esterifikacijomb1) 10 do 70 mol. % kompozicije dikarboksilnih kiselina koji obuhvatab11) 50 do 100 mol. %, bazirano na kompoziciji dikarboksilnih kiselina, jedne ili više aromatičnih dikarboksilnih kiselina ili njihovih derivata,b12) 0 do 50 mol. %, bazirano na pomenutoj kompoziciji dikarboksilnih kiselina b1), jedne ili više alifatičnih dikarboksilnih kiselina ili njihovih derivata,b2) 2 do 30 mol. % jedne ili više masnih kiselina i/ili derivata masnih kiselina,b3) 10 do 70 mol. % jednog ili više alifatičnih ili cikloalifatičnih diola koji imaju 2 do 18 atoma ugljenika ili njihovih alkoksilata,b4) 2 do 50 mol. % polietar poliola koji ima funkcionalnost ne manju od 2 i OH broj od 300-1250 mg KOH/g, a dobijen je alkoksilacijom poliola koji ima funkcionalnost veću od 2,bazirano na ukupnoj količini komponenata b1) do b4), pri čemu se komponente b1) do b4) dodaju do 100 mol %,C) opciono drugih poliester poliola, koji se razlikuju od komponente B),D) bar jednog polietar poliola, iE) opciono usporivača plamena,F) jednog ili više agenasa za stvaranje pene,G) katalizatora, iH) opciono drugih pomoćnih ili drugih dodatnih agenasa.pri čemu maseni odnos sume komponenti B) i opciono C) prema komponenti D) iznosi najmanje 7.Prijava sadrži još 13 patentnih zahteva.A process for the production of solid polyurethane foams comprising the reaction A) at least one polyisocyanate, B) at least one polyether ester polyol that can be obtained by esterification with 1) 10 to 70 mol. % composition of dicarboxylic acids comprising 11) 50 to 100 mol. %, based on the composition of dicarboxylic acids, one or more aromatic dicarboxylic acids or their derivatives, b12) 0 to 50 mol. %, based on said composition of dicarboxylic acids b1), one or more aliphatic dicarboxylic acids or their derivatives, b2) 2 to 30 mol. % of one or more fatty acids and / or fatty acid derivatives, b3) 10 to 70 mol. % of one or more aliphatic or cycloaliphatic diols having 2 to 18 carbon atoms or their alkoxylates, b4) 2 to 50 mol. % polyether polyol having a functionality of not less than 2 and an OH number of 300-1250 mg KOH / g, obtained by alkoxylation of a polyol having a functionality greater than 2, based on the total amount of components b1) to b4), wherein components b1 ) to b4) add up to 100 mol%, C) optionally other polyester polyols, which differ from component B), D) at least one polyether polyol, and E) optionally a flame retardant, F) one or more foaming agents, G) catalyst, iH) optionally other auxiliary or other auxiliary agents. wherein the mass ratio of the sum of the components B) and optionally C) to the component D) is at least 7. The application contains 13 more claims.

RS20160100A 2012-01-02 2012-12-13 Method for producing polyurethane hard foams and polyisocyanurate hard foams RS54603B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12150016 2012-01-02
EP12160927 2012-03-23
PCT/EP2012/075347 WO2013102540A1 (en) 2012-01-02 2012-12-13 Method for producing polyurethane hard foams and polyisocyanurate hard foams

Publications (1)

Publication Number Publication Date
RS54603B1 true RS54603B1 (en) 2016-08-31

Family

ID=47501145

Family Applications (1)

Application Number Title Priority Date Filing Date
RS20160100A RS54603B1 (en) 2012-01-02 2012-12-13 Method for producing polyurethane hard foams and polyisocyanurate hard foams

Country Status (19)

Country Link
EP (1) EP2800769B1 (en)
JP (2) JP2015504113A (en)
KR (1) KR102018406B1 (en)
CN (1) CN104039856B (en)
AU (1) AU2012364369B2 (en)
BR (1) BR112014016275B1 (en)
CA (1) CA2862774C (en)
EA (1) EA027089B1 (en)
ES (1) ES2560968T3 (en)
HU (1) HUE027908T2 (en)
IN (1) IN2014CN04925A (en)
MX (1) MX339548B (en)
MY (1) MY167781A (en)
PH (1) PH12014501409A1 (en)
PL (1) PL2800769T3 (en)
RS (1) RS54603B1 (en)
SG (1) SG11201403796RA (en)
WO (1) WO2013102540A1 (en)
ZA (1) ZA201405619B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8895636B2 (en) 2012-01-02 2014-11-25 Basf Se Producing rigid polyurethane foams and rigid polyisocyanurate foams
BR112014017049A8 (en) * 2012-01-18 2017-07-04 Basf Se process for preparing rigid polyurethane foams or rigid polyisocyanurate foams, rigid polyurethane or polyisocyanurate foam, use of rigid polyurethane or polyisocyanurate foam, and polyol component
US9475220B2 (en) 2013-02-13 2016-10-25 Basf Se Process for producing composite elements
KR102243756B1 (en) * 2013-08-20 2021-04-23 바스프 에스이 Improved rigid-polyurethane and rigid-polyisocyanurate foams based on fatty-acid-modified polyether polyols
CA2934128A1 (en) 2013-12-16 2015-06-25 Rockwool International A/S Polyisocyanurate foam composites and their production and use
MX367477B (en) * 2014-02-11 2019-08-23 Basf Se Method for producing polyurethane rigid foams and polyisocyanurate rigid foams.
CN104448186A (en) * 2014-11-20 2015-03-25 镇江拜因诺生物科技有限公司 Bio-based polyurethane foam insulation material
DK3268406T3 (en) * 2015-03-12 2019-07-22 Huntsmann Advanced Mat Licensing Switzerland Gmbh POLYOL COMPONENT FOR MANUFACTURING PUR FOAM TYPES
KR20180041665A (en) * 2015-08-17 2018-04-24 코베스트로 도이칠란트 아게 Modification method of isocyanate using cyclic ammonium salt as catalyst
CN113728028A (en) * 2019-05-16 2021-11-30 陶氏环球技术有限责任公司 Compatible blends of terephthalate polyols and hydrocarbon blowing agents
CN114127146A (en) * 2019-07-22 2022-03-01 陶氏环球技术有限责任公司 Polyurethane composition, product prepared by using same and preparation method of product
TW202317655A (en) 2021-10-18 2023-05-01 德商巴斯夫歐洲公司 Process for producing improved rigid polyisocyanurate foams based on aromatic polyester polyols and ethylene oxide-based polyether polyols
CN116925317B (en) * 2023-09-19 2023-11-28 南京赛弗尼电气有限公司 Polyurethane resin composition for lifting ground and preparation method thereof

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1003714B (en) 1956-01-25 1957-03-07 Glanzstoff Ag Process for the degradation of polyethylene terephthalate to dimethyl terephthalate
DE1097671B (en) * 1959-05-23 1961-01-19 Bayer Ag Process for the production of rigid foams containing urethane groups
US3399154A (en) * 1965-10-22 1968-08-27 Witco Chemical Corp Rigid polyurethane foams and polyesters for use therein
US5051528A (en) 1990-04-24 1991-09-24 Eastman Kodak Company Recovery process for ethylene glycol and dimethylterephthalate
EP1058701B2 (en) 1998-02-23 2011-03-16 Stepan Company Low viscosity polyester polyols and methods for preparing same
DE102005041763A1 (en) * 2005-09-01 2007-03-08 Basf Ag Polyisocyanurate rigid foam and process for the preparation
MX2011003903A (en) * 2008-10-15 2011-04-28 Basf Se Terephthalic acid-based polyester polyols.
EP2492297A1 (en) * 2011-02-23 2012-08-29 Basf Se Polyester polyols on the basis of aromatic dicarbon acids and polyurethane rigid foams obtained therefrom
BR112014017049A8 (en) * 2012-01-18 2017-07-04 Basf Se process for preparing rigid polyurethane foams or rigid polyisocyanurate foams, rigid polyurethane or polyisocyanurate foam, use of rigid polyurethane or polyisocyanurate foam, and polyol component

Also Published As

Publication number Publication date
MY167781A (en) 2018-09-25
JP2018111818A (en) 2018-07-19
ZA201405619B (en) 2015-12-23
SG11201403796RA (en) 2014-11-27
PH12014501409A1 (en) 2014-09-22
CA2862774C (en) 2020-08-18
ES2560968T3 (en) 2016-02-23
AU2012364369A1 (en) 2014-07-24
BR112014016275A8 (en) 2017-07-04
IN2014CN04925A (en) 2015-09-18
EP2800769B1 (en) 2015-12-09
CA2862774A1 (en) 2013-07-11
BR112014016275A2 (en) 2017-06-13
HUE027908T2 (en) 2016-11-28
CN104039856A (en) 2014-09-10
EA201491312A1 (en) 2014-11-28
JP2015504113A (en) 2015-02-05
KR20140109475A (en) 2014-09-15
KR102018406B1 (en) 2019-10-21
EA027089B1 (en) 2017-06-30
JP6567709B2 (en) 2019-08-28
CN104039856B (en) 2017-03-01
MX339548B (en) 2016-05-30
PL2800769T3 (en) 2016-06-30
BR112014016275B1 (en) 2020-10-27
AU2012364369B2 (en) 2016-01-14
MX2014007821A (en) 2014-09-01
EP2800769A1 (en) 2014-11-12
WO2013102540A1 (en) 2013-07-11

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