MX364715B - Procedimiento para la preparacion de espumas duras de poliuretano y espumas duras de poliisocianurato. - Google Patents

Procedimiento para la preparacion de espumas duras de poliuretano y espumas duras de poliisocianurato.

Info

Publication number
MX364715B
MX364715B MX2014011434A MX2014011434A MX364715B MX 364715 B MX364715 B MX 364715B MX 2014011434 A MX2014011434 A MX 2014011434A MX 2014011434 A MX2014011434 A MX 2014011434A MX 364715 B MX364715 B MX 364715B
Authority
MX
Mexico
Prior art keywords
mol
rigid foams
derivatives
polyol
components
Prior art date
Application number
MX2014011434A
Other languages
English (en)
Other versions
MX2014011434A (es
Inventor
Kampf Gunnar
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of MX2014011434A publication Critical patent/MX2014011434A/es
Publication of MX364715B publication Critical patent/MX364715B/es

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C08G18/4211—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
    • C08G18/4219—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols from aromatic dicarboxylic acids and dialcohols in combination with polycarboxylic acids and/or polyhydroxy compounds which are at least trifunctional
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4244—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups
    • C08G18/4247—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids
    • C08G18/4252—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids derived from polyols containing polyether groups and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4288—Polycondensates having carboxylic or carbonic ester groups in the main chain modified by higher fatty oils or their acids or by resin acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014—Use of organic additives
    • C08J9/0019—Use of organic additives halogenated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014—Use of organic additives
    • C08J9/0038—Use of organic additives containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/02—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by the reacting monomers or modifying agents during the preparation or modification of macromolecules
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/08—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/141—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/005—< 50kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00—Foams characterised by the foaming process
    • C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
    • C08J2201/022—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments premixing or pre-blending a part of the components of a foamable composition, e.g. premixing the polyol with the blowing agent, surfactant and catalyst and only adding the isocyanate at the time of foaming
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/10—Water or water-releasing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/12—Organic compounds only containing carbon, hydrogen and oxygen atoms, e.g. ketone or alcohol
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0066—Flame-proofing or flame-retarding additives

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

La invención se refiere a un método para producir espumas rígidas de poliuretano o espumas rígidas de pollisocianurato al hacer reaccionar al menos un poliisocianato A), poliéter éster polioles b) basados en ácidos dicarboxílicos aromáticos, los cuales pueden ser obtenidos mediante esterificación de b1) 10 a 70% mol de una composición de ácido dicarboxílico, comprendiendo b11) 50 a 100% mol con base en la composición de ácido dicarboxílico, de uno o más ácidos dicarboxílicos aromáticos o derivados de los mismos, b12) 0 a 50% mol, con base en la composición de ácido dicarboxílico b1), de uno o más ácidos dicarboxílicos alifáticos o derivados de los mismos, b2) 2 a 30% mol de uno o más ácidos grasos y/o derivados de ácidos grasos, b3) 10 a 79% mol de uno o más dioles alifáticos o cicloalifáticos con 2 a 18 átomos de carbono o alcoxilados de los mismos, b4) 2 a 50% mol de un poliéter poliol teniendo una funcionalidad mayor que o igual a 2, producida por alcoxilación de un poliol teniendo una funcionalidad mayor que o igual a 2 en la presencia de una amina como un catalizador, opcionalmente poliéster polioles adicionales C), los cuales son diferentes de aquél de componentes B), y al menos un poliéter poliol D), en donde la proporción de masa de la suma de los componentes B) y opcionalmente C) a componente D) es al menos 7. La invención también se refiere a las espumas duras resultantes y al uso de las mismas para la producción de elementos de emparedado con capas de cubiertas flxeibles o rígidas. La invención se refiere además a los componentes de polioles subyacentes.
MX2014011434A 2012-03-23 2013-03-19 Procedimiento para la preparacion de espumas duras de poliuretano y espumas duras de poliisocianurato. MX364715B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP12160963 2012-03-23
PCT/EP2013/055675 WO2013139781A1 (de) 2012-03-23 2013-03-19 Verfahren zur herstellung von polyurethan-hartschäumen und polyisocyanurat-hartschäumen

Publications (2)

Publication Number Publication Date
MX2014011434A MX2014011434A (es) 2015-04-14
MX364715B true MX364715B (es) 2019-05-06

Family

ID=47901112

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2014011434A MX364715B (es) 2012-03-23 2013-03-19 Procedimiento para la preparacion de espumas duras de poliuretano y espumas duras de poliisocianurato.

Country Status (13)

Country Link
EP (1) EP2828309B1 (es)
JP (1) JP6227624B2 (es)
KR (1) KR102058227B1 (es)
CN (1) CN104204016B (es)
AU (1) AU2013237561B2 (es)
BR (1) BR112014022421B1 (es)
CA (1) CA2868194A1 (es)
EA (1) EA201491634A1 (es)
ES (1) ES2704402T3 (es)
MX (1) MX364715B (es)
PL (1) PL2828309T3 (es)
TW (1) TW201343700A (es)
WO (1) WO2013139781A1 (es)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9475220B2 (en) 2013-02-13 2016-10-25 Basf Se Process for producing composite elements
EP3310835B1 (de) * 2015-06-18 2022-09-07 Basf Se Verfahren zur herstellung von polyurethan-hartschaumstoffen
CN104974340B (zh) * 2015-06-25 2017-03-29 淄博德信联邦化学工业有限公司 主链中含酯键的高活性聚醚多元醇的制备方法
CN105176054A (zh) * 2015-08-10 2015-12-23 常州仁华化工有限公司 一种阻燃性生物质基聚氨酯泡沫的制备方法
US10975190B2 (en) * 2016-07-21 2021-04-13 Bionanofoam Llc Bio-based and hydrophilic polyurethane prepolymer and foam made therefrom
CN111655805B (zh) * 2018-01-23 2023-01-10 斯蒂潘公司 用于低voc聚氨酯应用的多元醇
CA3096666A1 (en) 2018-04-10 2019-10-17 Stepan Company Polyol blends and rigid foams with improved low-temperature r-values
CN109054024A (zh) * 2018-08-09 2018-12-21 苏州思德新材料科技有限公司 一种聚酯泡沫制备用的有机硅泡沫稳定剂的制备方法
WO2020038755A1 (en) * 2018-08-21 2020-02-27 Huntsman International Llc Catalyst for pir/pur foam production
TW202317655A (zh) 2021-10-18 2023-05-01 德商巴斯夫歐洲公司 依據芳族聚酯多元醇及基於環氧乙烷的聚醚多元醇製備改良的剛性聚異氰脲酸脂發泡體的方法
WO2023194140A1 (en) 2022-04-04 2023-10-12 Basf Se Value chain return process for the recovery of phosphorous ester-based flame retardants from polyurethane rigid foams
WO2024094787A1 (en) 2022-11-03 2024-05-10 Basf Se Value chain return process for the recovery and of polymeric methylene phenylene amine (pmda) as its hci salt from the depolymerization of spend polyurethane and polyisocyanurate rigid foams
WO2024094788A1 (en) 2022-11-03 2024-05-10 Basf Se Value chain return process for the recovery of not bonded additives by extraction from polyurethane or polyisocyanurate rigid foams and depolymerization of the polyurethane rigid foams
EP4424736A1 (de) * 2023-03-02 2024-09-04 Hilti Aktiengesellschaft Nachhaltige polyol-basierte basiszusammensetzung, daraus hergestellte schaumzusammensetzung und daraus hergestellter formkörper für brandschutzzwecke

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1003714B (de) 1956-01-25 1957-03-07 Glanzstoff Ag Verfahren zum Abbau von Polyaethylenterephthalat zu Terephthalsaeuredimethylester
US5051528A (en) 1990-04-24 1991-09-24 Eastman Kodak Company Recovery process for ethylene glycol and dimethylterephthalate
JP3276463B2 (ja) * 1993-07-07 2002-04-22 三井化学株式会社 硬質ポリウレタンフォームの製造法
WO1999042508A1 (en) 1998-02-23 1999-08-26 Stepan Company Low viscosity polyester polyols and methods for preparing same
DE10156014A1 (de) * 2001-11-15 2003-06-05 Basf Ag Verfahren zur Herstellung von Polyetheralkoholen
ZA200709673B (en) * 2006-11-13 2009-09-30 Bayer Materialscience Ag Process for the preparation of polyether-ester polyols
PT2340269E (pt) * 2008-10-15 2012-12-05 Basf Se Poliéster-polióis à base do ácido tereftálico
DE102008051882A1 (de) * 2008-10-16 2010-04-29 Bayer Materialscience Ag Verfahren zur Herstellung von Polyetheresterpolyolen

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Publication number Publication date
PL2828309T3 (pl) 2019-03-29
ES2704402T3 (es) 2019-03-18
BR112014022421B1 (pt) 2021-01-05
CA2868194A1 (en) 2013-09-26
MX2014011434A (es) 2015-04-14
EP2828309B1 (de) 2018-10-10
KR102058227B1 (ko) 2019-12-20
KR20140139061A (ko) 2014-12-04
CN104204016A (zh) 2014-12-10
EP2828309A1 (de) 2015-01-28
EA201491634A1 (ru) 2015-02-27
TW201343700A (zh) 2013-11-01
JP6227624B2 (ja) 2017-11-08
AU2013237561B2 (en) 2016-04-28
JP2015512453A (ja) 2015-04-27
WO2013139781A1 (de) 2013-09-26
CN104204016B (zh) 2017-06-20
AU2013237561A1 (en) 2014-10-09

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