MX2019014263A - Capsulas de poliurea o poliuretano. - Google Patents
Capsulas de poliurea o poliuretano.Info
- Publication number
- MX2019014263A MX2019014263A MX2019014263A MX2019014263A MX2019014263A MX 2019014263 A MX2019014263 A MX 2019014263A MX 2019014263 A MX2019014263 A MX 2019014263A MX 2019014263 A MX2019014263 A MX 2019014263A MX 2019014263 A MX2019014263 A MX 2019014263A
- Authority
- MX
- Mexico
- Prior art keywords
- poiyurea
- polyurethane
- compositions
- capsule
- capsules
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/11—Encapsulated compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3225—Polyamines
- C08G18/3228—Polyamines acyclic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3225—Polyamines
- C08G18/3253—Polyamines being in latent form
- C08G18/3256—Reaction products of polyamines with aldehydes or ketones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/64—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
- C08G18/6415—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63 having nitrogen
- C08G18/6423—Polyalkylene polyamines; polyethylenimines; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/64—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
- C08G18/6415—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63 having nitrogen
- C08G18/6446—Proteins and derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/7806—Nitrogen containing -N-C=0 groups
- C08G18/7818—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
- C08G18/7831—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing biuret groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/794—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aromatic isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
- C08G18/8006—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32
- C08G18/8009—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203
- C08G18/8022—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203 with polyols having at least three hydroxy groups
- C08G18/8029—Masked aromatic polyisocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/02—Polyureas
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
- C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/10—General cosmetic use
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Dispersion Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Dermatology (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Cosmetics (AREA)
Abstract
Se describen composiciones de cápsulas de poliurea o poliuretano; un subgrupo de estas composiciones contiene una pluralidad de cápsulas y un auxiliar de formación de cápsula, en donde cada una de las cápsulas contiene una pared de poliurea o poliuretano y un núcleo de aceite; la pared de poliurea o poliuretano se forma de un producto de reacción de un poliisocianato y un agente de entrelazamiento en presencia del auxiliar de formación de cápsula; y el núcleo de aceite contiene un material activo; se describen en la presente el poliisocianato, el agente de entrelazamiento y el auxiliar de formación de cápsula; también se describen métodos para preparar composiciones de cápsulas de poliurea o poliuretano, así como productos de consumo que contienen una de estas composiciones.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/967,800 US11311467B2 (en) | 2009-09-18 | 2013-08-15 | Polyurea capsules prepared with a polyisocyanate and cross-linking agent |
US13/968,862 US10226405B2 (en) | 2009-09-18 | 2013-08-16 | Purified polyurea capsules, methods of preparation, and products containing the same |
US13/969,038 US9687424B2 (en) | 2009-09-18 | 2013-08-16 | Polyurea capsules prepared with aliphatic isocyanates and amines |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2019014263A true MX2019014263A (es) | 2020-01-23 |
Family
ID=52468832
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2016002041A MX361658B (es) | 2013-08-15 | 2014-08-15 | Capsulas de poliurea o poliuretano. |
MX2019014263A MX2019014263A (es) | 2013-08-15 | 2016-02-15 | Capsulas de poliurea o poliuretano. |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2016002041A MX361658B (es) | 2013-08-15 | 2014-08-15 | Capsulas de poliurea o poliuretano. |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP3033066B1 (es) |
CN (1) | CN105722495B (es) |
BR (2) | BR122019023314B1 (es) |
MX (2) | MX361658B (es) |
WO (1) | WO2015023961A1 (es) |
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US10537503B2 (en) * | 2015-03-06 | 2020-01-21 | International Flavors & Fragrances Inc. | Microcapsule compositions with high performance |
WO2016162381A1 (en) * | 2015-04-07 | 2016-10-13 | Firmenich Sa | Process for preparing polyurea microcapsules |
US10993466B2 (en) | 2015-04-24 | 2021-05-04 | International Flavors & Fragrances Inc. | Delivery systems and methods of preparing the same |
US10900002B2 (en) | 2015-06-05 | 2021-01-26 | Firmenich Sa | Microcapsules with high deposition on surfaces |
CN107708853B (zh) * | 2015-10-27 | 2021-12-07 | 恩盖普有限公司 | 包封 |
SG11201803900UA (en) * | 2015-12-15 | 2018-06-28 | Firmenich & Cie | Process for preparing polyurea microcapsules with improved deposition |
US20180015009A1 (en) * | 2015-12-30 | 2018-01-18 | International Flavors & Fragrances Inc. | Microcapsule compositions with improved deposition |
US9974720B2 (en) | 2015-12-30 | 2018-05-22 | International Flavors & Fragrances Inc. | Compositions containing microcapsules coated with deposition proteins |
MX2018009997A (es) * | 2016-02-18 | 2019-02-07 | Int Flavors & Fragrances Inc | Composiciones de cápsulas de poliurea. |
MX2018011341A (es) | 2016-03-18 | 2019-07-04 | Int Flavors & Fragrances Inc | Microcápsulas de sílice y métodos para prepararlas. |
BR112018072391A2 (pt) * | 2016-05-03 | 2019-02-19 | International Flavors & Fragrances Inc. | microcápsula, composição de microcápsula, método para preparar uma composição de microcápsula, e, produto destinado ao consumidor. |
US20190184364A1 (en) * | 2016-05-03 | 2019-06-20 | International Flavors & Fragrances Inc. | Fragrance compositions containing microcapsules |
BR112018076803B1 (pt) | 2016-07-01 | 2022-05-03 | International Flavors & Fragrances Inc | Composição estável de microcápsula, e, produto de consumo |
EP3512625B1 (en) | 2016-09-16 | 2023-04-26 | International Flavors & Fragrances Inc. | Microcapsule compositions stabilized with viscosity control agents |
EP3295929A1 (en) * | 2016-09-19 | 2018-03-21 | S.P.C.M. Sa | Use of an ampholyte copolymer as colloidal stabilizer in a process of encapsulating fragrance |
US20180085291A1 (en) | 2016-09-28 | 2018-03-29 | International Flavors & Fragrances Inc. | Microcapsule compositions containing amino silicone |
US11471396B2 (en) | 2016-10-28 | 2022-10-18 | Conopco, Inc. | Personal care compositions comprising surface-modified particles and non-volatile funcationalised silicone |
CN109862945B (zh) | 2016-10-28 | 2022-03-08 | 联合利华知识产权控股有限公司 | 包含颗粒的个人护理组合物 |
CN108299438B (zh) * | 2017-01-13 | 2022-05-17 | 国家纳米科学中心 | pH响应性近红外荧光探针化合物及其制备方法和应用 |
US20180346648A1 (en) | 2017-05-30 | 2018-12-06 | International Flavors & Fragrances Inc. | Branched polyethyleneimine microcapsules |
WO2019027632A1 (en) * | 2017-07-31 | 2019-02-07 | Dow Global Technologies Llc | ENCAPSULATION METHOD |
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EP3470134B1 (en) * | 2017-10-13 | 2020-06-03 | Agfa Nv | A composition comprising solvent and heat resistant capsules |
CN108066165A (zh) * | 2017-12-22 | 2018-05-25 | 江山 | 一种牙膏颗粒及其制备方法和在牙膏中的应用 |
WO2019179939A1 (en) * | 2018-03-19 | 2019-09-26 | Firmenich Sa | Process for the preparation of microcapsules |
CN112004852B (zh) * | 2018-04-24 | 2023-04-04 | 西姆莱斯有限公司 | 以直链和环状脂肪族多异氰酸酯制备的核壳胶囊 |
CN112423875B (zh) * | 2018-05-25 | 2023-07-21 | 国际香料和香精公司 | 表面改性的微胶囊 |
CN109679055B (zh) * | 2018-12-12 | 2020-12-08 | 中国农业科学院农业质量标准与检测技术研究所 | 一种抗紫外改性的可降解微胶囊材料及其制备方法与应用 |
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EP3897525A4 (en) | 2018-12-18 | 2023-05-10 | International Flavors & Fragrances Inc. | COMPOSITIONS OF MICROCAPSULES PREPARED FROM POLYSACCHARIDES |
WO2020164705A1 (de) * | 2019-02-13 | 2020-08-20 | Symrise Ag | Verfahren zur herstellung von mikrokapseln |
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KR20220076455A (ko) * | 2019-10-03 | 2022-06-08 | 가부시끼가이샤 도꾸야마 | 마이크로 벌룬의 제조 방법 |
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CN112900146A (zh) * | 2021-03-03 | 2021-06-04 | 东莞市贝辉装饰材料有限公司 | 一种带有香味的浸渍胶膜纸及其制备方法 |
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-
2014
- 2014-08-15 MX MX2016002041A patent/MX361658B/es active IP Right Grant
- 2014-08-15 WO PCT/US2014/051309 patent/WO2015023961A1/en active Application Filing
- 2014-08-15 BR BR122019023314-4A patent/BR122019023314B1/pt active IP Right Grant
- 2014-08-15 EP EP14836237.9A patent/EP3033066B1/en active Active
- 2014-08-15 BR BR112016003137-7A patent/BR112016003137B1/pt active IP Right Grant
- 2014-08-15 CN CN201480057739.4A patent/CN105722495B/zh active Active
-
2016
- 2016-02-15 MX MX2019014263A patent/MX2019014263A/es unknown
Also Published As
Publication number | Publication date |
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CN105722495B (zh) | 2020-02-28 |
BR112016003137A2 (pt) | 2017-09-12 |
BR122019023314B1 (pt) | 2020-10-06 |
EP3033066A4 (en) | 2017-05-03 |
CN105722495A (zh) | 2016-06-29 |
EP3033066A1 (en) | 2016-06-22 |
MX361658B (es) | 2018-12-13 |
BR112016003137B1 (pt) | 2020-10-27 |
EP3033066B1 (en) | 2023-07-12 |
MX2016002041A (es) | 2016-09-13 |
WO2015023961A1 (en) | 2015-02-19 |
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