MX2019008901A - Sulfuro de litio altamente reactivo, libre de tierra y flujo libre y metodo para su preparacion. - Google Patents

Sulfuro de litio altamente reactivo, libre de tierra y flujo libre y metodo para su preparacion.

Info

Publication number
MX2019008901A
MX2019008901A MX2019008901A MX2019008901A MX2019008901A MX 2019008901 A MX2019008901 A MX 2019008901A MX 2019008901 A MX2019008901 A MX 2019008901A MX 2019008901 A MX2019008901 A MX 2019008901A MX 2019008901 A MX2019008901 A MX 2019008901A
Authority
MX
Mexico
Prior art keywords
free
dust
production
lithium hydroxide
highly reactive
Prior art date
Application number
MX2019008901A
Other languages
English (en)
Inventor
Vitze Hannes
Nickel Vera
Lang Sebastian
Plath Armine
Müller Marc-Christian
Pietzner Sebastian
Original Assignee
Albemarle Germany Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Albemarle Germany Gmbh filed Critical Albemarle Germany Gmbh
Publication of MX2019008901A publication Critical patent/MX2019008901A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/04—Halides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/22—Alkali metal sulfides or polysulfides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/22—Alkali metal sulfides or polysulfides
    • C01B17/38—Dehydration
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/02—Oxides; Hydroxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
    • H01M10/0562—Solid materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/24—Alkaline accumulators
    • H01M10/26—Selection of materials as electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581—Chalcogenides or intercalation compounds thereof
    • H01M4/5815—Sulfides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/14—Cells with non-aqueous electrolyte
    • H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/20—Powder free flowing behaviour
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0068—Solid electrolytes inorganic
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Abstract

La invención se refiere a un polvo de sulfuro de litio altamente reactivo, de alta pureza, de flujo libre y libre de tierra que tiene un tamaño de partícula promedio entre 250 y 1500 µm y áreas de superficie BET entre 1 y 100 m2/g. La invención, además, se refiere a un proceso para su preparación, donde, en una primera etapa, monohidrato de hidróxido de litio se calienta en una unidad de temperatura controlada a una reacción de temperatura entre 150°C y 450°C en ausencia de aire y se hace pasar un gas inerte sobre o a través de este, hasta que el agua residual de contenido de cristalización del hidróxido de litio formado es menor que 5 % en peso y, en una segunda etapa, el hidróxido de litio anhidro formado en la primera etapa se mezcla, se desborda o atraviesa mediante una fuente de azufre gaseoso del grupo que consiste en sulfuro de hidróxido, sulfuro elemental, disulfuro de carbono, mercaptanos o nitruros de azufre.
MX2019008901A 2017-02-03 2018-02-02 Sulfuro de litio altamente reactivo, libre de tierra y flujo libre y metodo para su preparacion. MX2019008901A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102017201772 2017-02-03
PCT/EP2018/052688 WO2018141919A1 (de) 2017-02-03 2018-02-02 Hochreaktives, staubfreies und freifliessendes lithiumsulfid und verfahren zu dessen herstellung

Publications (1)

Publication Number Publication Date
MX2019008901A true MX2019008901A (es) 2020-01-30

Family

ID=61189440

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2019008901A MX2019008901A (es) 2017-02-03 2018-02-02 Sulfuro de litio altamente reactivo, libre de tierra y flujo libre y metodo para su preparacion.

Country Status (13)

Country Link
US (1) US11542162B2 (es)
EP (1) EP3577067A1 (es)
KR (1) KR102485791B1 (es)
CN (1) CN110475745B (es)
AR (1) AR110926A1 (es)
AU (1) AU2018214232B2 (es)
BR (1) BR112019015828A2 (es)
CA (1) CA3050338A1 (es)
IL (1) IL268424B (es)
MX (1) MX2019008901A (es)
TW (1) TWI748052B (es)
WO (1) WO2018141919A1 (es)
ZA (1) ZA201905012B (es)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11749834B2 (en) 2014-12-02 2023-09-05 Polyplus Battery Company Methods of making lithium ion conducting sulfide glass
US10164289B2 (en) 2014-12-02 2018-12-25 Polyplus Battery Company Vitreous solid electrolyte sheets of Li ion conducting sulfur-based glass and associated structures, cells and methods
US10147968B2 (en) 2014-12-02 2018-12-04 Polyplus Battery Company Standalone sulfide based lithium ion-conducting glass solid electrolyte and associated structures, cells and methods
WO2017197039A1 (en) 2016-05-10 2017-11-16 Polyplus Battery Company Solid-state laminate electrode assemblies and methods of making
US10629950B2 (en) 2017-07-07 2020-04-21 Polyplus Battery Company Encapsulated sulfide glass solid electrolytes and solid-state laminate electrode assemblies
US10868293B2 (en) 2017-07-07 2020-12-15 Polyplus Battery Company Treating sulfide glass surfaces and making solid state laminate electrode assemblies
US11631889B2 (en) 2020-01-15 2023-04-18 Polyplus Battery Company Methods and materials for protection of sulfide glass solid electrolytes
CN112125283A (zh) * 2020-08-03 2020-12-25 浙江工业大学 一种利用固液混合加热制备硫化锂的方法
CN112002939B (zh) * 2020-08-31 2021-10-15 成都新柯力化工科技有限公司 一种锂电池固体电解质的清洁制备方法
EP3964480A1 (en) * 2020-09-02 2022-03-09 AMG Lithium GmbH Process for preparing lithium salts
KR102603627B1 (ko) * 2020-12-18 2023-11-16 주식회사 포스코 황화리튬 및 이의 제조방법
CN112939034B (zh) * 2021-03-19 2023-08-15 江西云威新材料有限公司 一种工业级碳酸锂制备电池级无水氢氧化锂的方法
KR20240032052A (ko) 2021-07-07 2024-03-08 스페셜티 오퍼레이션스 프랑스 황화리튬 분말을 수득하는 방법, 및 lps 화합물을 제조하기 위한 이의 용도
WO2023032701A1 (ja) * 2021-09-02 2023-03-09 Ａｇｃ株式会社 硫化リチウムの製造方法
EP4186997A1 (en) * 2021-11-26 2023-05-31 K-UTEC AG Salt Technologies Preparation of lithium hydroxide
CN115535968A (zh) * 2022-10-12 2022-12-30 天津大学 一种硫化锂的制备方法及硫化锂

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JP3816141B2 (ja) * 1996-04-16 2006-08-30 古河機械金属株式会社 硫化リチウムの製造方法
JP3510420B2 (ja) * 1996-04-16 2004-03-29 松下電器産業株式会社 リチウムイオン伝導性固体電解質およびその製造方法
JP4833539B2 (ja) * 2004-11-26 2011-12-07 日本化学工業株式会社 硫化リチウム粒子粉末、その製造方法および無機固体電解質
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GB2464455B (en) * 2008-10-14 2010-09-15 Iti Scotland Ltd Lithium-containing transition metal sulfide compounds
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JP5701808B2 (ja) * 2012-03-30 2015-04-15 三井金属鉱業株式会社 硫化物系固体電解質の製造方法
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Also Published As

Publication number Publication date
KR20190114977A (ko) 2019-10-10
AR110926A1 (es) 2019-05-15
KR102485791B1 (ko) 2023-01-05
US11542162B2 (en) 2023-01-03
CN110475745A (zh) 2019-11-19
CN110475745B (zh) 2023-03-31
WO2018141919A1 (de) 2018-08-09
CA3050338A1 (en) 2018-08-09
TW201840468A (zh) 2018-11-16
ZA201905012B (en) 2021-05-26
AU2018214232A1 (en) 2019-08-29
AU2018214232B2 (en) 2020-06-25
US20200165129A1 (en) 2020-05-28
IL268424A (en) 2019-09-26
EP3577067A1 (de) 2019-12-11
TWI748052B (zh) 2021-12-01
BR112019015828A2 (pt) 2020-03-31
IL268424B (en) 2021-03-25

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