MX2018015270A - Proceso para la preparacion de alcoholes 2,3-insaturados. - Google Patents

Proceso para la preparacion de alcoholes 2,3-insaturados.

Info

Publication number
MX2018015270A
MX2018015270A MX2018015270A MX2018015270A MX2018015270A MX 2018015270 A MX2018015270 A MX 2018015270A MX 2018015270 A MX2018015270 A MX 2018015270A MX 2018015270 A MX2018015270 A MX 2018015270A MX 2018015270 A MX2018015270 A MX 2018015270A
Authority
MX
Mexico
Prior art keywords
nerol
inventive process
compound obtainable
preparing
formula
Prior art date
Application number
MX2018015270A
Other languages
English (en)
Inventor
Keller Andreas
Krause Wolfgang
Gralla Gabriele
Zuend Stephan
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of MX2018015270A publication Critical patent/MX2018015270A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8906—Iron and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/009—Preparation by separation, e.g. by filtration, decantation, screening
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00—Essential oils; Perfumes
    • C11B9/0007—Aliphatic compounds
    • C11B9/0015—Aliphatic compounds containing oxygen as the only heteroatom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Fats And Perfumes (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La presente invención proporciona un proceso para preparar un alcohol insaturado de la fórmula OH (1), Donde uno de R' y R2 es preferiblemente alquilo C2-Cio o alquenilo C2-C10 que contiene un enlace doble y el otro es preferiblemente hidrógeno o metilo; R3 es preferiblemente hidrógeno; que comprende someter una composición reactiva que incluye, al menos, 75% en peso de un aldehido insaturado de la fórmula (II) P1, R2 R3 Donde R1. R2 y R3 tienen preferiblemente los significados definidos anteriormente, a una hidrogenación en presencia de un catalizador y una amina terciaria; donde la amina terciaria se utiliza en una cantidad que oscila de 0.001 a 0.7% en peso, con base en la cantidad total de la mezcla de reacción liquida. La invención se refiere, además, al compuesto nerol obtenible por el proceso de la invención, a una composición de sustancias de fragancia o aroma que comprende el compuesto nerol obtenible por el proceso de la invención, a un método para impartir y/o intensificar un aroma o sabor de un producto, y también a productos perfumados o aromatizados que comprenden un compuesto nerol obtenible por el proceso de la invención.
MX2018015270A 2016-06-07 2017-06-06 Proceso para la preparacion de alcoholes 2,3-insaturados. MX2018015270A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP16173352 2016-06-07
PCT/EP2017/063654 WO2017211784A1 (en) 2016-06-07 2017-06-06 Process for preparing 2,3-unsaturated alcohols

Publications (1)

Publication Number Publication Date
MX2018015270A true MX2018015270A (es) 2019-10-07

Family

ID=56112884

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2018015270A MX2018015270A (es) 2016-06-07 2017-06-06 Proceso para la preparacion de alcoholes 2,3-insaturados.

Country Status (8)

Country Link
US (1) US11407700B2 (es)
EP (1) EP3464224B1 (es)
JP (1) JP7146646B2 (es)
CN (1) CN109311789B (es)
BR (1) BR112018074704B1 (es)
ES (1) ES2844182T3 (es)
MX (1) MX2018015270A (es)
WO (1) WO2017211784A1 (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11407700B2 (en) 2016-06-07 2022-08-09 Basf Se Process for preparing 2,3-unsaturated alcohols
CN109503327B (zh) * 2018-12-12 2021-09-07 万华化学集团股份有限公司 一种氢化柠檬醛制备橙花醇和香叶醇的方法
CN111018666B (zh) * 2019-12-12 2022-11-04 万华化学集团股份有限公司 改进的制备橙花醇香叶醇的方法和用于该方法的催化体系
CN115124405B (zh) * 2022-09-01 2022-11-11 山东新和成药业有限公司 一种4-己烯-1-醇异构化制备叶醇的方法及所用的钌基催化剂

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2934251A1 (de) * 1979-08-24 1981-03-26 Basf Ag, 67063 Ludwigshafen Verfahren zur herstellung von ungesaettigten alkoholen.
DE3130805A1 (de) * 1981-08-04 1983-02-24 Basf Ag, 6700 Ludwigshafen Neue ruthenium/kohle-hydrierkatalysatoren, deren herstellung und verwendung zur selektiven hydrierung von ungesaettigten carbonylverbindungen
DE69534903T2 (de) * 1995-08-31 2007-01-18 The Procter & Gamble Company, Cincinnati Verwendung von Allylalkohol als ein Mittel zur Verminderung von schlechten Gerüchen
ES2294075T3 (es) 2001-12-07 2008-04-01 Basf Se Procedimiento para la obtencion de catalizadores de rutenio/hierro sobre soportes de carbono.
DE10160143A1 (de) 2001-12-07 2003-06-18 Basf Ag Verfahren zur selektiven Hydrierung von olefinisch ungesättigten Carbonylverbindungen
EP1930075A1 (en) 2005-09-07 2008-06-11 National University Corporation Nagaoka University Hydrogenation catalyst for carbonyl group, method for producing same, and method for producing unsaturated alcohol by using such catalyst
EP2008989A1 (de) 2007-06-26 2008-12-31 Basf Se Kontinuierliches Verfahren zur Herstellung von Neral in reiner oder angereicherter Form
WO2010067441A1 (ja) 2008-12-11 2010-06-17 高砂香料工業株式会社 アルコール化合物の製造方法
WO2010067442A1 (ja) 2008-12-11 2010-06-17 高砂香料工業株式会社 アルコール化合物の製造方法
CN101747152B (zh) * 2008-12-18 2012-10-24 复旦大学 一种柠檬醛液相加氢合成不饱和醇的方法
EP3019460B1 (en) 2013-07-08 2019-01-30 DSM IP Assets B.V. Selective transfer hydrogenation of citral or ethyl citral
KR20170052631A (ko) 2014-09-12 2017-05-12 바스프 에스이 2＇-o-푸코실락토오스의 제조 방법
CN106715408B (zh) 2014-09-26 2020-06-09 巴斯夫欧洲公司 异构纯或高度异构体富集的顺-或反-(2-异丁基-4-甲基四氢吡喃-4-基)乙酸酯的用途
WO2016097242A1 (de) 2014-12-19 2016-06-23 Basf Se Verfahren zur herstellung optisch aktiver carbonylverbindungen
JP6741687B2 (ja) 2015-05-04 2020-08-19 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ メロナールの調製方法
US11407700B2 (en) 2016-06-07 2022-08-09 Basf Se Process for preparing 2,3-unsaturated alcohols

Also Published As

Publication number Publication date
EP3464224A1 (en) 2019-04-10
CN109311789A (zh) 2019-02-05
WO2017211784A1 (en) 2017-12-14
JP7146646B2 (ja) 2022-10-04
JP2019517543A (ja) 2019-06-24
CN109311789B (zh) 2023-04-04
ES2844182T3 (es) 2021-07-21
BR112018074704A2 (pt) 2019-03-19
EP3464224B1 (en) 2020-10-14
US11407700B2 (en) 2022-08-09
US20190263738A1 (en) 2019-08-29
BR112018074704B1 (pt) 2022-09-27

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