MX2017003891A - Proceso para la produccion de 1,3 butadieno a partir de 1,3 butanodiol. - Google Patents
Proceso para la produccion de 1,3 butadieno a partir de 1,3 butanodiol.Info
- Publication number
- MX2017003891A MX2017003891A MX2017003891A MX2017003891A MX2017003891A MX 2017003891 A MX2017003891 A MX 2017003891A MX 2017003891 A MX2017003891 A MX 2017003891A MX 2017003891 A MX2017003891 A MX 2017003891A MX 2017003891 A MX2017003891 A MX 2017003891A
- Authority
- MX
- Mexico
- Prior art keywords
- stream
- optionally
- water
- impurities
- butadiene
- Prior art date
Links
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 title abstract 10
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 title abstract 8
- 238000004519 manufacturing process Methods 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 235000019437 butane-1,3-diol Nutrition 0.000 title 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 7
- 239000012535 impurity Substances 0.000 abstract 6
- 239000003054 catalyst Substances 0.000 abstract 2
- 230000018044 dehydration Effects 0.000 abstract 2
- 238000006297 dehydration reaction Methods 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 238000000746 purification Methods 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 1
- 229920001971 elastomer Polymers 0.000 abstract 1
- 239000000806 elastomer Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/12—Alkadienes
- C07C11/16—Alkadienes with four carbon atoms
- C07C11/167—1, 3-Butadiene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/04—Purification; Separation; Use of additives by distillation
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
- C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
- C12P7/18—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic polyhydric
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Water Supply & Treatment (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Microbiology (AREA)
- Biochemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Biotechnology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
Abstract
Proceso para la producción de 1, 3-butadiendo que comprende: alimentar la mezcla (a) que comprende 1, 3-butadodiol y agua a un evaporador, el agua que se presenta en una cantidad de mayor que o igual a 5% en peso, de manera preferente que varía de 10%en peso a 85%en peso, more de manera preferente que varía de 15% en peso a 30% en peso, con relación al peso total de la mezcla (a), para obtener: (b) una corriente gaseosa que comprende 1,3-butanodiol que sale de la parte superior del evaporador; y, opcionalmente (c) una corriente de purga que sale del fondo del evaporador; alimentar la corriente gaseosa (b) a un primer reactor que contiene al menos un catalizador de deshidratación para obtener (d) una corriente que comprende alquenoles, agua y, opcionalmente, impurezas y/o 1,3-butanodiol sin reaccionar, que sale del primer reactor; opcionalmente, alimentar la corriente (d) a una primera sección de purificación para obtener: (e) una corriente que comprende alquenoles, agua, y, opcionalmente, impurezas; (f) una corriente que comprende agua y, opcionalmente ,impurezas y/o 1,3-butanodiol sin reaccionar; y, opcionalmente, (f') una corriente que comprende impurezas; alimentar la corriente (d) o la corriente (e) a un segundo reactor que contiene al menos un catalizador de deshidratación para obtener (g) una corriente que comprende 1,3-butadieno, agua y, opcionalmente, impurezas y/o alquenoles sin reaccionar, que salen del segundo reactor; alimentar la corriente (g) a una segunda sección de purificación para obtener; (h) una corriente que comprende 1,3-butadiano puro; (i) una corriente que comprende agua y, opcionalmente, alquenoles sin reaccionar; y opcionalmente, (l)una corriente que comprende impurezas. El 1,3-butadieno se puede usar de manera ventajosa como un monómero o compuesto intermedio en la producción de elastómeros y (co) polímeros.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI20142121 | 2014-12-12 | ||
| PCT/EP2015/079378 WO2016092063A1 (en) | 2014-12-12 | 2015-12-11 | Process for the production of 1,3 butadiene from 1,3 butanediol |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2017003891A true MX2017003891A (es) | 2017-08-07 |
Family
ID=52463047
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2017003891A MX2017003891A (es) | 2014-12-12 | 2015-12-11 | Proceso para la produccion de 1,3 butadieno a partir de 1,3 butanodiol. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US10173947B2 (es) |
| EP (1) | EP3230236B1 (es) |
| JP (1) | JP6797110B2 (es) |
| CN (1) | CN107074677B (es) |
| BR (1) | BR112017012500B1 (es) |
| DK (1) | DK3230236T3 (es) |
| FI (1) | FI3230236T3 (es) |
| HU (1) | HUE066687T2 (es) |
| MX (1) | MX2017003891A (es) |
| PL (1) | PL3230236T3 (es) |
| RU (1) | RU2690678C2 (es) |
| SA (1) | SA517381301B1 (es) |
| WO (1) | WO2016092063A1 (es) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6456231B2 (ja) * | 2015-04-27 | 2019-01-23 | 昭和電工株式会社 | ジエン化合物の製造方法 |
| WO2018040058A1 (en) * | 2016-09-02 | 2018-03-08 | Rhodia Operations | Dehydration of diols |
| US11498062B2 (en) | 2016-09-30 | 2022-11-15 | Regents Of The University Of Minnesota | Phosphorus-containing solid catalysts and reactions catalyzed thereby, including synthesis of p-xylene |
| JP7262189B2 (ja) | 2018-08-03 | 2023-04-21 | 国立大学法人千葉大学 | 共役ジエン製造用触媒、前記触媒の製造方法、及び共役ジエンの製造方法 |
| PT3853197T (pt) | 2018-09-21 | 2024-02-22 | Versalis Spa | Processo para purificação de bio-1,3-butanodiol a partir de um caldo de fermentação |
| FR3090393B1 (fr) * | 2018-12-20 | 2021-04-23 | Ifp Energies Now | Procédé de traitement d’une charge alcool pour la production d’oléfines |
| IT201900015069A1 (it) | 2019-08-27 | 2021-02-27 | Versalis Spa | Catalizzatore comprendente coke e procedimento per la produzione di dieni. |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2174280A (en) | 1938-08-25 | 1939-09-26 | Goodrich Co B F | Method of producing butadiene |
| US2310809A (en) * | 1939-04-06 | 1943-02-09 | Reppe Walter | Method of preparing diolefins |
| DE857367C (de) * | 1939-04-07 | 1952-11-27 | Basf Ag | Verfahren zur Herstellung von Diolefinen |
| US2373153A (en) | 1943-04-22 | 1945-04-10 | Air Reduction | Production of butadiene |
| US2426678A (en) | 1943-04-27 | 1947-09-02 | Us Ind Chemicals Inc | Revivification of phosphate catalysts |
| US2444538A (en) * | 1943-08-19 | 1948-07-06 | Celanese Corp | Process for the production of butadiene and catalyst therefor |
| DE1150671B (de) | 1961-12-30 | 1963-06-27 | Huels Chemische Werke Ag | Verfahren zur Herstellung reiner Butenole |
| DE1908620A1 (de) | 1969-02-21 | 1970-09-03 | Basf Ag | Verfahren zur Herstellung modifizierter Polyolefinwachse |
| SU396312A1 (ru) | 1971-02-01 | 1973-08-29 | Г. Д. Закумбаева, Закарина , Д. В. Сокольский | Способ получения виниловых спиртов |
| US4400562A (en) | 1981-07-02 | 1983-08-23 | The United States Of America As Represented By The Secretary Of The Navy | Alkenol synthesis |
| DE3317165A1 (de) * | 1983-05-11 | 1984-11-15 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von olefinen durch wasserabspaltung aus alkoholen |
| JPS63222135A (ja) | 1987-03-11 | 1988-09-16 | Nkk Corp | 不飽和アルコ−ルの製造方法 |
| US5406007A (en) | 1994-07-15 | 1995-04-11 | Eastman Chemical Company | Process for the production of unsaturated alcohols |
| DE19601375C2 (de) * | 1996-01-16 | 1998-09-17 | Linde Ag | Verfahren zur Herstellung von Tetrahydrofuran |
| JP3800205B2 (ja) * | 2002-09-09 | 2006-07-26 | チッソ株式会社 | 不飽和アルコール製造用触媒と不飽和アルコール製造方法 |
| DE10361823A1 (de) * | 2003-12-30 | 2005-08-11 | Basf Ag | Verfahren zur Herstellung von Butadien und 1-Buten |
| DE112007002908B4 (de) | 2006-12-12 | 2022-01-27 | Gkn Sinter Metals, Llc | Gesenkwerkzeug zum formen eines metallpulverschmiedeteils und herstellungsverfahren |
| CA2759994C (en) | 2009-04-30 | 2019-06-11 | Genomatica, Inc. | Organisms for the production of 1,3-butanediol |
| CN102686719A (zh) * | 2009-10-30 | 2012-09-19 | 株式会社大赛璐 | 具有1,3-丁二醇生产功能的基因重组微生物及其应用 |
| WO2012174439A2 (en) * | 2011-06-17 | 2012-12-20 | Invista Technologies S.A R.L. | Methods of producing four carbon molecules |
| WO2012177619A2 (en) * | 2011-06-22 | 2012-12-27 | Genomatica, Inc. | Microorganisms for producing 1,3-butanediol and methods related thereto |
| KR102043381B1 (ko) | 2011-08-19 | 2019-11-11 | 게노마티카 인코포레이티드 | 2,4-펜타디에노에이트, 부타디엔, 프로필렌, 1,3-부탄디올 및 관련 알코올을 생합성하기 위한 미생물과 방법 |
| BR112014005352A2 (pt) | 2011-09-08 | 2017-03-28 | Genomatica Inc | organismos eucarióticos e métodos para aumentar a disponibilidade de acetil-coa citosólico e para produzir 1,3-butanodiol |
| JP5638041B2 (ja) * | 2012-07-25 | 2014-12-10 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物、タイヤ部材、及び空気入りタイヤ |
| FR3001728B1 (fr) * | 2013-02-04 | 2015-11-13 | Adisseo France Sas | Procede de preparation d’une olefine par conversion catalytique d’au moins un alcool |
| ITMI20132069A1 (it) | 2013-12-11 | 2015-06-12 | Versalis Spa | Procedimento per la produzione di zuccheri da biomassa |
| JP5866413B2 (ja) * | 2014-06-30 | 2016-02-17 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物、タイヤ部材、及び空気入りタイヤ |
-
2015
- 2015-12-11 EP EP15808578.7A patent/EP3230236B1/en active Active
- 2015-12-11 RU RU2017110398A patent/RU2690678C2/ru active
- 2015-12-11 JP JP2017516758A patent/JP6797110B2/ja active Active
- 2015-12-11 FI FIEP15808578.7T patent/FI3230236T3/fi active
- 2015-12-11 MX MX2017003891A patent/MX2017003891A/es unknown
- 2015-12-11 PL PL15808578.7T patent/PL3230236T3/pl unknown
- 2015-12-11 US US15/529,778 patent/US10173947B2/en active Active
- 2015-12-11 WO PCT/EP2015/079378 patent/WO2016092063A1/en active Application Filing
- 2015-12-11 BR BR112017012500-5A patent/BR112017012500B1/pt active IP Right Grant
- 2015-12-11 CN CN201580056208.8A patent/CN107074677B/zh active Active
- 2015-12-11 DK DK15808578.7T patent/DK3230236T3/da active
- 2015-12-11 HU HUE15808578A patent/HUE066687T2/hu unknown
-
2017
- 2017-04-13 SA SA517381301A patent/SA517381301B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BR112017012500B1 (pt) | 2022-05-03 |
| JP2017537876A (ja) | 2017-12-21 |
| CN107074677A (zh) | 2017-08-18 |
| US20170313633A1 (en) | 2017-11-02 |
| US10173947B2 (en) | 2019-01-08 |
| SA517381301B1 (ar) | 2020-12-15 |
| PL3230236T3 (pl) | 2024-07-15 |
| RU2017110398A3 (es) | 2019-01-15 |
| DK3230236T3 (da) | 2024-05-13 |
| JP6797110B2 (ja) | 2020-12-09 |
| FI3230236T3 (fi) | 2024-05-28 |
| CN107074677B (zh) | 2021-03-09 |
| RU2690678C2 (ru) | 2019-06-05 |
| HUE066687T2 (hu) | 2024-08-28 |
| BR112017012500A2 (pt) | 2017-12-26 |
| EP3230236A1 (en) | 2017-10-18 |
| EP3230236B1 (en) | 2024-05-01 |
| WO2016092063A1 (en) | 2016-06-16 |
| RU2017110398A (ru) | 2019-01-15 |
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