MX2017006073A - Procedimiento para la produccion de ciclohexanona a partir de fenol. - Google Patents

Procedimiento para la produccion de ciclohexanona a partir de fenol.

Info

Publication number
MX2017006073A
MX2017006073A MX2017006073A MX2017006073A MX2017006073A MX 2017006073 A MX2017006073 A MX 2017006073A MX 2017006073 A MX2017006073 A MX 2017006073A MX 2017006073 A MX2017006073 A MX 2017006073A MX 2017006073 A MX2017006073 A MX 2017006073A
Authority
MX
Mexico
Prior art keywords
phenol
cyclohexanone
production
hydrogenation reactor
charged
Prior art date
Application number
MX2017006073A
Other languages
English (en)
Inventor
Thomas Tinge Johan
Daguenet Corinne
Rudolf Maria Martens Wilhelmus
Jan Korte De Robert
Wilhelmus Theodorus Maria BRANDS Roeland
Verschuren Iris
Original Assignee
Cap Iii Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cap Iii Bv filed Critical Cap Iii Bv
Publication of MX2017006073A publication Critical patent/MX2017006073A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/006—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by hydrogenation of aromatic hydroxy compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/19—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds in six-membered aromatic rings
    • C07C29/20—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds in six-membered aromatic rings in a non-condensed rings substituted with hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C35/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C35/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic
    • C07C35/08—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic containing a six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
    • C07C39/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring monocyclic with no unsaturation outside the aromatic ring
    • C07C39/04—Phenol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/002—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by dehydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/385—Saturated compounds containing a keto group being part of a ring
    • C07C49/403—Saturated compounds containing a keto group being part of a ring of a six-membered ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/00033—Continuous processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Se describe un procedimiento continuo a escala industrial para la producción y recuperación de ciclohexanona a partir de fenol e hidrógeno, dicho procedimiento comprendiendo: hidrogenar fenol en un reactor de hidrogenación de fenol; separar ciclohexanona a partir de una corriente de producto hidrogenado en una sección de separación y purificación [II] que comprende por lo menos 4 secciones de destilación; en donde por lo menos parte del calor de reacción producido en la sección de reacción de hidrogenación de fenol [I] se aplica para la producción de vapor; y en donde la relación molar de ciclohexanona a fenol que es cargada a dicho reactor de hidrogenación de fenol es de 0.02 a 0.10; y/o en donde la relación molar de ciclohexanol a fenol que es cargada a dicho reactor de hidrogenación de fenol es de 0.001 a 0.10.
MX2017006073A 2014-11-10 2015-11-06 Procedimiento para la produccion de ciclohexanona a partir de fenol. MX2017006073A (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP14192423 2014-11-10
EP2015075113 2015-10-29
PCT/EP2015/075951 WO2016075047A1 (en) 2014-11-10 2015-11-06 Process for the production of cyclohexanone from phenol

Publications (1)

Publication Number Publication Date
MX2017006073A true MX2017006073A (es) 2018-01-11

Family

ID=55953768

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2017006073A MX2017006073A (es) 2014-11-10 2015-11-06 Procedimiento para la produccion de ciclohexanona a partir de fenol.

Country Status (12)

Country Link
US (1) US10301243B2 (es)
EP (1) EP3218338B1 (es)
JP (1) JP6249467B1 (es)
KR (1) KR101820639B1 (es)
CN (1) CN107124881B (es)
EA (1) EA031615B1 (es)
ES (1) ES2803082T3 (es)
MX (1) MX2017006073A (es)
PL (1) PL3218338T3 (es)
SA (1) SA517381498B1 (es)
UA (1) UA122897C2 (es)
WO (1) WO2016075047A1 (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110563564B (zh) * 2018-06-06 2022-02-01 中国石油化工股份有限公司 苯酚加氢制备环己酮的方法
CN108816223B (zh) * 2018-07-09 2021-08-20 江苏凌飞科技股份有限公司 一种制备壬基环己醇聚氧乙烯醚用的催化剂及其制备方法
CN110372462A (zh) * 2019-08-06 2019-10-25 吉林凯莱英医药化学有限公司 连续化合成-纯化一体装置及含有其的连续化反应系统
JP2024505299A (ja) 2021-02-04 2024-02-05 セーアーペー ドリー ベスローテン ヴェンノーツハップ フェノールの水素化のためのプロセス制御

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2829166A (en) 1933-04-04 1958-04-01 Allied Chem & Dye Corp Hydrogenation of phenol
US5015787A (en) 1989-04-10 1991-05-14 Allied-Signal Inc. Process for production cyclohexanol
CN101945845B (zh) * 2007-12-20 2013-09-18 帝斯曼知识产权资产管理有限公司 具有经改进的后蒸馏的环己酮生产方法
WO2009080618A1 (en) 2007-12-20 2009-07-02 Dsm Ip Assets B.V. Cyclohexanone production process with impurities removal
KR20100099304A (ko) 2007-12-20 2010-09-10 디에스엠 아이피 어셋츠 비.브이. 다중 후-증류에 의한 사이클로헥사논의 제조방법
WO2014001461A1 (en) 2012-06-28 2014-01-03 Dsm Ip Assets B.V. Process for the production of a mixture comprising cyclohexanone and cyclohexanol from phenol
CN105073700A (zh) * 2013-04-05 2015-11-18 三井化学株式会社 环己酮化合物的制造方法
US20160368844A1 (en) 2013-07-24 2016-12-22 Exxonmobil Chemical Patents Inc. Process for Producing Mixtures of Cyclohexanone and Cyclohexanol
SG11201701429SA (en) * 2014-09-30 2017-04-27 Exxonmobil Chemical Patents Inc Process for making cyclohexanone

Also Published As

Publication number Publication date
EA201791013A1 (ru) 2017-12-29
SA517381498B1 (ar) 2020-09-03
CN107124881B (zh) 2019-04-19
JP2018501301A (ja) 2018-01-18
EP3218338B1 (en) 2020-06-10
ES2803082T3 (es) 2021-01-22
WO2016075047A1 (en) 2016-05-19
PL3218338T3 (pl) 2020-09-21
US10301243B2 (en) 2019-05-28
JP6249467B1 (ja) 2017-12-20
EA031615B1 (ru) 2019-01-31
KR101820639B1 (ko) 2018-01-19
CN107124881A (zh) 2017-09-01
KR20170077249A (ko) 2017-07-05
EP3218338A1 (en) 2017-09-20
US20180290955A1 (en) 2018-10-11
UA122897C2 (uk) 2021-01-20

Similar Documents

Publication Publication Date Title
MX2013012674A (es) Proceso integrado para la produccion de 1 - cloro - 3, 3, 3 - trifluoropropeno.
MY170550A (en) Production of higher alcohols
MY182714A (en) Method for the production of butadiene and hydrogen from ethanol in two low-water-and low-energy-consumption reaction steps
MX2013005514A (es) Proceso para producir 2,3,3,3-tetrafluoropropeno.
MX2017006073A (es) Procedimiento para la produccion de ciclohexanona a partir de fenol.
UA104324C2 (ru) Способ получения муравьиной кислоты
SA115360430B1 (ar) عملية لإنتاج هكسا ميثيلين داي أمين من مواد تتضمن كربوهيدرات ومركبات وسيطة منها
MX2012008927A (es) Proceso para recuperar etanol.
MX2017007339A (es) Proceso para la producción de 2,5-bis-hidroximetilfurano, 2,5-bis-hidroximetiltetrahidrofurano, 1,6-hexanodiol y 1,2,6-hexanotriol a partir de 5-hidroximetilfurfural.
MX2017007011A (es) Metodo e instalacion para producir hidrocarburos.
MX2012008937A (es) Proceso para producir etanol utilizando una columna de destilacion por extraccion.
MX2018010305A (es) Proceso para preparar terpinen-4-ol.
MX2017003891A (es) Proceso para la produccion de 1,3 butadieno a partir de 1,3 butanodiol.
EP4249458A3 (en) Methods for recovering chlorinated hydrocarbons
MY186375A (en) Process
MX2016012851A (es) Un metodo para producir 1,1,2,3-tetracloropropeno con alto rendimiento.
MX2012008928A (es) Proceso de purificar etanol.
WO2012149156A3 (en) Process to reduce ethanol recycled to acetic acid hydrogenation reactor
AR108423A1 (es) Método para producir ácido acético de alta pureza
MX2017009714A (es) Metodos para producir compuesto de pirazin carboxamida e intermediario sintetico del mismo.
IN2014DN08226A (es)
MX2017007808A (es) Un procedimiento para construir una planta para la produccion de ciclohexanona.
MY189114A (en) Process and plant for producing fatty alcohols
SE1500125A1 (en) Process for production of a butanal
WO2011104634A3 (pt) Produção de propilenoglicol a partir de glicerina