MX2017003132A - Un proceso para la preparacion de un material zeolitico de mww que comprende boro y titanio. - Google Patents

Un proceso para la preparacion de un material zeolitico de mww que comprende boro y titanio.

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Publication number
MX2017003132A
MX2017003132A MX2017003132A MX2017003132A MX2017003132A MX 2017003132 A MX2017003132 A MX 2017003132A MX 2017003132 A MX2017003132 A MX 2017003132A MX 2017003132 A MX2017003132 A MX 2017003132A MX 2017003132 A MX2017003132 A MX 2017003132A
Authority
MX
Mexico
Prior art keywords
boron
titanium
zeolitic material
preparation
mww
Prior art date
Application number
MX2017003132A
Other languages
English (en)
Inventor
Müller Ulrich
Uhl Georg
Henrique Teles Joaquim
Parvulescu Andrei-Nicolae
Riedel Dominic
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of MX2017003132A publication Critical patent/MX2017003132A/es

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/009—Preparation by separation, e.g. by filtration, decantation, screening
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/086—Decomposition of an organometallic compound, a metal complex or a metal salt of a carboxylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
    • C01B39/085—Group IVB- metallosilicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/12—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least boron atoms
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/82—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by IR- or Raman-data
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/86—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by NMR- or ESR-data

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Un proceso para la preparación de un material zeolítico que tiene una estructura marco de MWW y que comprende boro y titanio. El proceso comprende (i) proporcionar una mezcla de síntesis acuosa que comprende una fuente de sílice, una fuente de boro, una fuente de titanio y un agente que sirve de modelo para MWW; (ii) calentar la mezcla de síntesis acuosa a una temperatura en el rango de 160 a 190 °C; (iii) someter la mezcla de síntesis (ii) a condiciones de síntesis hidrotérmicas, lo que obtiene, en su licor madre, un precursor del material zeolítico; (iv) separar el precursor de su licor madre; (v) calcinar el precursor separado, lo que obtiene el material zeolítico que tiene una estructura marco de MWW y que comprende boro y titanio.
MX2017003132A 2014-09-09 2015-09-08 Un proceso para la preparacion de un material zeolitico de mww que comprende boro y titanio. MX2017003132A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP14184111 2014-09-09
PCT/EP2015/070488 WO2016038030A1 (en) 2014-09-09 2015-09-08 A process for the preparation of an mww zeolitic material comprising boron and titanium

Publications (1)

Publication Number Publication Date
MX2017003132A true MX2017003132A (es) 2017-06-14

Family

ID=51518608

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2017003132A MX2017003132A (es) 2014-09-09 2015-09-08 Un proceso para la preparacion de un material zeolitico de mww que comprende boro y titanio.

Country Status (16)

Country Link
US (1) US10300468B2 (es)
EP (1) EP3191404B1 (es)
JP (1) JP6775491B2 (es)
KR (1) KR102469448B1 (es)
CN (1) CN107074567B (es)
BR (1) BR112017004074B1 (es)
ES (1) ES2727604T3 (es)
HU (1) HUE043211T2 (es)
MX (1) MX2017003132A (es)
MY (1) MY183916A (es)
PL (1) PL3191404T3 (es)
RU (1) RU2698832C2 (es)
SA (1) SA517381056B1 (es)
SG (1) SG11201701622TA (es)
WO (1) WO2016038030A1 (es)
ZA (1) ZA201702330B (es)

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EP3256422B1 (en) 2015-02-12 2022-04-06 Basf Se Process for the preparation of a dealuminated zeolitic material having the bea framework structure
JP6741687B2 (ja) 2015-05-04 2020-08-19 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ メロナールの調製方法
CN107848929A (zh) 2015-07-15 2018-03-27 巴斯夫欧洲公司 制备芳基丙烯的方法
WO2017009458A1 (en) 2015-07-15 2017-01-19 Basf Se Process for preparing an arylpropene
CA2991075A1 (en) 2015-07-22 2017-01-26 Basf Se Process for preparing furan-2,5-dicarboxylic acid
EP3170828A1 (de) 2015-11-23 2017-05-24 Basf Se Verfahren zur herstellung von verbindungen mit 16-oxabicyclo[10.3.1]pentadecengerüst und deren folgeprodukten
KR20180088679A (ko) 2015-11-27 2018-08-06 바스프 에스이 금속-유기 골격의 초고속 시공간 합성
EP3178788A1 (en) 2015-12-08 2017-06-14 Basf Se A tin-containing zeolitic material having a bea framework structure
JP7039472B2 (ja) 2015-12-08 2022-03-22 ビーエーエスエフ ソシエタス・ヨーロピア Ｂｅａ骨格構造を有するスズ含有ゼオライト材料
WO2017133995A1 (de) 2016-02-01 2017-08-10 Basf Se Verfahren zur herstellung von c4-c15-lactamen
ES2867052T3 (es) 2016-06-29 2021-10-20 Basf Se Procedimiento de preparación de aldehídos alfa, beta insaturados por oxidación de alcoholes en presencia de una fase líquida
JP6986063B2 (ja) 2016-07-08 2021-12-22 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se 有機スルホンの製造方法
CN110072618B (zh) 2016-12-20 2022-12-30 巴斯夫欧洲公司 制备包含具有mww骨架类型的含钛沸石材料的可挤出组合物的方法
CN109231233B (zh) * 2018-10-23 2022-09-09 福州大学 一种Ti-MWW分子筛的绿色合成方法及应用
CN110203947B (zh) * 2019-07-03 2022-07-26 浙江师范大学 一种钛硅分子筛Ti-MWW的制备方法

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JP2002102709A (ja) * 2000-09-29 2002-04-09 Showa Denko Kk 酸化化合物製造用結晶性ｍｗｗ型チタノシリケート触媒、該触媒の製造方法、及び該触媒を用いた酸化化合物の製造方法
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EP2604590A4 (en) * 2010-08-12 2015-12-16 Mitsui Chemicals Inc METHOD FOR PRODUCING UNSATURATED HYDROCARBONS AND DEHYDRATION CATALYST USED IN THIS PROCESS
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Also Published As

Publication number Publication date
EP3191404A1 (en) 2017-07-19
SA517381056B1 (ar) 2021-03-29
KR20170052651A (ko) 2017-05-12
JP6775491B2 (ja) 2020-10-28
KR102469448B1 (ko) 2022-11-21
CN107074567B (zh) 2020-01-03
WO2016038030A1 (en) 2016-03-17
BR112017004074A2 (pt) 2017-12-05
EP3191404B1 (en) 2019-02-20
PL3191404T3 (pl) 2019-08-30
RU2017111855A3 (es) 2019-02-22
RU2698832C2 (ru) 2019-08-30
ZA201702330B (en) 2019-07-31
SG11201701622TA (en) 2017-03-30
US20170246620A1 (en) 2017-08-31
US10300468B2 (en) 2019-05-28
ES2727604T3 (es) 2019-10-17
RU2017111855A (ru) 2018-10-10
CN107074567A (zh) 2017-08-18
JP2017530078A (ja) 2017-10-12
MY183916A (en) 2021-03-17
BR112017004074B1 (pt) 2022-03-03
HUE043211T2 (hu) 2019-08-28

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