MX2016014440A - Espumas de polimero. - Google Patents
Espumas de polimero.Info
- Publication number
- MX2016014440A MX2016014440A MX2016014440A MX2016014440A MX2016014440A MX 2016014440 A MX2016014440 A MX 2016014440A MX 2016014440 A MX2016014440 A MX 2016014440A MX 2016014440 A MX2016014440 A MX 2016014440A MX 2016014440 A MX2016014440 A MX 2016014440A
- Authority
- MX
- Mexico
- Prior art keywords
- polymer composition
- foam
- polyolefin
- lomin
- seconds
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/3442—Mixing, kneading or conveying the foamable material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0052—Organo-metallic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/122—Hydrogen, oxygen, CO2, nitrogen or noble gases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/141—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/12—Melt flow index or melt flow ratio
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/17—Viscosity
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/06—CO2, N2 or noble gases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/16—Unsaturated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2467/04—Polyesters derived from hydroxy carboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0023—Use of organic additives containing oxygen
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Emergency Medicine (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
Una composición de polímero puede incluir poliolefina que tiene una distribución de peso molecular de mayor que o igual a 8 como se mide por GPC y una sal de acrilato metálica. La composición de polímero se puede caracterizar por uno o más de: un gasto de flujo en fusión de 0.1 g/10min a 10 g/10min; una viscosidad de flujo en fusión entre 2,000 Pa.s y 6,000 Pa.s; un hinchamiento en molde de entre 2 y 8; y un tiempo característico de hinchamiento en molde de entre 0.3 segundos y 1.2 segundos. La composición de polímero puede estar en la forma de espuma. Un proceso para formar la espuma puede incluir el suministro de la composición de polímero que incluye la sal de acrilato metálica y la resina de poliolefina, y el mezclado de la composición de polímero con agente espumante. Una espuma puede incluir una composición de polímero que incluye poliolefina y polímero polar y no incluye un ionómero. La espuma puede tener una densidad de espuma de menor que 0.25 g/cc.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14/268,826 US20150315349A1 (en) | 2014-05-02 | 2014-05-02 | Polymer foams |
US201462005613P | 2014-05-30 | 2014-05-30 | |
US14/601,399 US9505906B1 (en) | 2014-05-02 | 2015-01-21 | Polymer foams |
PCT/US2015/028724 WO2015168510A1 (en) | 2014-05-02 | 2015-05-01 | Polymer foams |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2016014440A true MX2016014440A (es) | 2017-02-23 |
Family
ID=54359363
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2016014440A MX2016014440A (es) | 2014-05-02 | 2015-05-01 | Espumas de polimero. |
Country Status (8)
Country | Link |
---|---|
US (1) | US9505906B1 (es) |
EP (1) | EP3137659A4 (es) |
JP (2) | JP2017514977A (es) |
KR (1) | KR102335730B1 (es) |
CN (1) | CN106232881B (es) |
CA (1) | CA2948140C (es) |
MX (1) | MX2016014440A (es) |
WO (1) | WO2015168510A1 (es) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20180089467A (ko) * | 2015-12-03 | 2018-08-08 | 다우 글로벌 테크놀로지스 엘엘씨 | 고다공성 미세기포 폴리에틸렌 |
US20170282410A1 (en) * | 2016-03-31 | 2017-10-05 | Fina Technology, Inc. | Production processing aid |
EP3856832A4 (en) * | 2018-09-26 | 2022-06-01 | ExxonMobil Chemical Patents Inc. | WORK HARDENED POLYPROPYLENE COPOLYMER COMPOSITIONS |
CN112888731A (zh) * | 2018-09-28 | 2021-06-01 | 性能材料北美股份有限公司 | 聚酰胺泡沫的制备 |
Family Cites Families (35)
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US4001172A (en) | 1972-04-03 | 1977-01-04 | Exxon Research And Engineering Company | Polymers with improved properties and process therefor |
IT1157941B (it) * | 1982-05-11 | 1987-02-18 | Bayer Italia Spa | Materiale espanso poliolefinico saldabile dielettricamente |
US6069183A (en) * | 1998-04-07 | 2000-05-30 | Tenneco Packaging Inc. | Foamable composition using high density polyethylene |
JP2001131327A (ja) * | 1999-11-05 | 2001-05-15 | Kanegafuchi Chem Ind Co Ltd | ポリプロピレン系樹脂組成物の型内発泡成形体 |
JP5043252B2 (ja) * | 2000-08-23 | 2012-10-10 | 株式会社プライムポリマー | 改質ポリプロピレン組成物およびそれから得られる発泡体 |
JP4267187B2 (ja) * | 2000-08-10 | 2009-05-27 | 株式会社プライムポリマー | 改質ポリプロピレン系樹脂組成物、その製法およびそれから得られる発泡体 |
KR20020013784A (ko) * | 2000-08-10 | 2002-02-21 | 요시우라 하루끼 | 개질폴리프로필렌, 개질폴리프로필렌의 제조방법,개질폴리프로필렌조성물 및 발포체 |
JP4493821B2 (ja) * | 2000-09-04 | 2010-06-30 | 株式会社プライムポリマー | 改質ポリプロピレンの製造方法および発泡体 |
JP2002105256A (ja) * | 2000-09-28 | 2002-04-10 | Grand Polymer Co Ltd | ポリプロピレン樹脂組成物およびそれから得られる発泡体 |
KR100456392B1 (ko) * | 2001-02-01 | 2004-11-10 | 미쓰이 가가쿠 가부시키가이샤 | 올레핀계 엘라스토머 가교발포체용 엘라스토머 조성물 및그의 용도 |
JP4050520B2 (ja) * | 2001-02-01 | 2008-02-20 | 三井化学株式会社 | オレフィン系エラストマー架橋発泡体用エラストマー組成物およびその用途 |
US6602956B2 (en) * | 2001-11-13 | 2003-08-05 | Solvay Engineered Polymers | Melt strength thermoplastic elastomers and methods for making same |
JP4831647B2 (ja) * | 2002-02-22 | 2011-12-07 | 株式会社ジェイエスピー | ポリプロピレン系樹脂発泡粒子 |
US7629416B2 (en) | 2002-08-12 | 2009-12-08 | Exxonmobil Chemical Patents Inc. | Plasticized polyolefin compositions |
US7256223B2 (en) | 2002-11-26 | 2007-08-14 | Michigan State University, Board Of Trustees | Environmentally friendly polylactide-based composite formulations |
JP2006143769A (ja) * | 2004-11-16 | 2006-06-08 | Prime Polymer:Kk | ポリプロピレン系樹脂組成物及び発泡成形体 |
JP4836472B2 (ja) * | 2005-03-23 | 2011-12-14 | 株式会社プライムポリマー | 発泡成形用ポリプロピレン系組成物及びその成形体 |
CN101248135B (zh) | 2005-06-24 | 2013-03-27 | 埃克森美孚化学专利公司 | 增塑官能化丙烯共聚物粘合剂组合物 |
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EP1940942B1 (en) | 2005-08-24 | 2009-09-30 | Dow Global Technologies Inc. | Polyolefin compositions, articles made therefrom and methods for preparing the same |
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JP2008150474A (ja) * | 2006-12-15 | 2008-07-03 | Sumitomo Chemical Co Ltd | ポリプロピレン系樹脂組成物、その製法およびそれから得られる発泡体 |
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JP2012144692A (ja) | 2010-12-20 | 2012-08-02 | Sumitomo Chemical Co Ltd | 組成物 |
US20120164425A1 (en) | 2010-12-28 | 2012-06-28 | Basf Se | Foam sheet based on styrene polymer-polyolefin mixtures |
US8715449B2 (en) | 2011-06-17 | 2014-05-06 | Berry Plastics Corporation | Process for forming an insulated container having artwork |
JP5914141B2 (ja) * | 2011-07-29 | 2016-05-11 | 日東電工株式会社 | ポリオレフィン系樹脂発泡体用樹脂組成物、ポリオレフィン系樹脂発泡体、発泡体製造方法、及び発泡シール材 |
US9045615B2 (en) * | 2011-08-24 | 2015-06-02 | Fina Technology, Inc. | Metal carboxylate additives for thermoplastics |
JP5893938B2 (ja) * | 2012-01-30 | 2016-03-23 | 株式会社ブリヂストン | 防振ゴム組成物及び防振ゴム |
CA2916531A1 (en) * | 2013-07-23 | 2015-01-29 | Fina Technology, Inc. | Metallic acrylate salts to increase polymer melt strength |
-
2015
- 2015-01-21 US US14/601,399 patent/US9505906B1/en active Active
- 2015-05-01 EP EP15785681.6A patent/EP3137659A4/en active Pending
- 2015-05-01 MX MX2016014440A patent/MX2016014440A/es unknown
- 2015-05-01 CN CN201580021990.XA patent/CN106232881B/zh active Active
- 2015-05-01 WO PCT/US2015/028724 patent/WO2015168510A1/en active Application Filing
- 2015-05-01 CA CA2948140A patent/CA2948140C/en active Active
- 2015-05-01 KR KR1020167030401A patent/KR102335730B1/ko active IP Right Grant
- 2015-05-01 JP JP2017510448A patent/JP2017514977A/ja active Pending
-
2020
- 2020-04-06 JP JP2020068131A patent/JP6960497B2/ja active Active
Also Published As
Publication number | Publication date |
---|---|
KR20170007269A (ko) | 2017-01-18 |
WO2015168510A1 (en) | 2015-11-05 |
EP3137659A1 (en) | 2017-03-08 |
JP2017514977A (ja) | 2017-06-08 |
JP6960497B2 (ja) | 2021-11-05 |
CN106232881A (zh) | 2016-12-14 |
KR102335730B1 (ko) | 2021-12-08 |
US9505906B1 (en) | 2016-11-29 |
EP3137659A4 (en) | 2018-02-14 |
JP2020117719A (ja) | 2020-08-06 |
CN106232881B (zh) | 2020-12-08 |
CA2948140C (en) | 2022-12-06 |
CA2948140A1 (en) | 2015-11-05 |
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