MX2010006504A - Conversion de carbohidratos a hidroxi-metilfurfural (hmf) y derivado. - Google Patents

Conversion de carbohidratos a hidroxi-metilfurfural (hmf) y derivado.

Info

Publication number
MX2010006504A
MX2010006504A MX2010006504A MX2010006504A MX2010006504A MX 2010006504 A MX2010006504 A MX 2010006504A MX 2010006504 A MX2010006504 A MX 2010006504A MX 2010006504 A MX2010006504 A MX 2010006504A MX 2010006504 A MX2010006504 A MX 2010006504A
Authority
MX
Mexico
Prior art keywords
hmf
organic acid
ester
catalyst
derivatives
Prior art date
Application number
MX2010006504A
Other languages
English (en)
Inventor
Alexandra Sanborn
Stephen Howard
Original Assignee
Archer Daniels Midland Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=40386123&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=MX2010006504(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Archer Daniels Midland Co filed Critical Archer Daniels Midland Co
Publication of MX2010006504A publication Critical patent/MX2010006504A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C07D307/48—Furfural
    • C07D307/50—Preparation from natural products
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/42—Singly bound oxygen atoms
    • C07D307/44—Furfuryl alcohol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C07D307/48—Furfural
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/54—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/68—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Saccharide Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Furan Compounds (AREA)
  • Catalysts (AREA)

Abstract

Un método para producir HMF sustancialmente puro, ésteres de HMF y otros derivados provenientes de una fuente de carbohidratos al poner en contacto la fuente de carbohidratos con un catalizador en fase sólida. La materia prima de carbohidratos se calienta en un solvente en una columna y se hace fluir continuamente a través de un catalizador en fase sólida en la presencia de un ácido orgánico, o se calienta con el ácido orgánico y un catalizador sólido en solución para formar un éster de HMF. El calentamiento sin ácido orgánico forma HMF. El producto resultante se purifica mediante filtración para retirar las materias primas y el catalizador sin reaccionar. El éster de HMF o una mezcla de HMF y éster de HMF pueden oxidarse entonces a ácido 2,5-furandicarboxílico (FDCA) al combinar el éster de HMF con un ácido orgánico, acetato de cobalto, acetato de manganeso y bromuro de sodio bajo presión. Alternativamente, el éster de HMF puede reducirse para formar un diol de furano o de tetrahidrofurano.
MX2010006504A 2007-12-12 2008-12-12 Conversion de carbohidratos a hidroxi-metilfurfural (hmf) y derivado. MX2010006504A (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US99694607P 2007-12-12 2007-12-12
US601207P 2007-12-14 2007-12-14
PCT/US2008/086659 WO2009076627A2 (en) 2007-12-12 2008-12-12 Conversion of carbohydrates to hydroxy-methylfurfural (hmf) and derivatives

Publications (1)

Publication Number Publication Date
MX2010006504A true MX2010006504A (es) 2010-08-31

Family

ID=40386123

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2010006504A MX2010006504A (es) 2007-12-12 2008-12-12 Conversion de carbohidratos a hidroxi-metilfurfural (hmf) y derivado.

Country Status (12)

Country Link
US (1) US20090156841A1 (es)
EP (4) EP2423205B9 (es)
JP (2) JP2011506478A (es)
KR (1) KR101576313B1 (es)
CN (1) CN101896476A (es)
BR (1) BRPI0819406B1 (es)
CA (1) CA2708232C (es)
ES (1) ES2611596T5 (es)
HU (1) HUE032843T2 (es)
MX (1) MX2010006504A (es)
MY (1) MY169437A (es)
WO (1) WO2009076627A2 (es)

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JP2011506478A (ja) 2007-12-12 2011-03-03 アーチャー ダニエルズ ミッドランド カンパニー 炭水化物からヒドロキシメチルフルフラール（ｈｍｆ）への変換及び誘導体
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