MX172437B - Un procedimiento para preparar composiciones a base de particulas de oxido de zinc pigmentario - Google Patents
Un procedimiento para preparar composiciones a base de particulas de oxido de zinc pigmentarioInfo
- Publication number
- MX172437B MX172437B MX018693A MX1869389A MX172437B MX 172437 B MX172437 B MX 172437B MX 018693 A MX018693 A MX 018693A MX 1869389 A MX1869389 A MX 1869389A MX 172437 B MX172437 B MX 172437B
- Authority
- MX
- Mexico
- Prior art keywords
- zinc oxide
- slurry
- metal oxide
- hydrated metal
- pigment zinc
- Prior art date
Links
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 title abstract 12
- 239000000203 mixture Substances 0.000 title abstract 6
- 239000011787 zinc oxide Substances 0.000 title abstract 6
- 239000002245 particle Substances 0.000 title abstract 3
- 239000002002 slurry Substances 0.000 abstract 9
- 229910044991 metal oxide Inorganic materials 0.000 abstract 8
- 150000004706 metal oxides Chemical class 0.000 abstract 8
- 239000000049 pigment Substances 0.000 abstract 7
- 239000007771 core particle Substances 0.000 abstract 4
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical group [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 abstract 4
- 238000000576 coating method Methods 0.000 abstract 3
- 239000011248 coating agent Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 230000008021 deposition Effects 0.000 abstract 2
- 239000002243 precursor Substances 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000005300 metallic glass Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/02—Ingredients treated with inorganic substances
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/04—Compounds of zinc
- C09C1/043—Zinc oxide
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/06—Treatment with inorganic compounds
- C09C3/063—Coating
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
- C01P2002/84—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by UV- or VIS- data
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Nanotechnology (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Composite Materials (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Cosmetics (AREA)
- Compounds Of Unknown Constitution (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
La presente invención se refiere a un procedimiento para preparar composiciones químicamente inertes absorbentes de luz ultravioleta, constituidas por particulas que tienen nucleos de óxido de zinc pigmentario, cuyos nucleos tienen, depositados sobre los mismos, revestimientos separados y distintos de 2 óxidos metálicos hidratados diferentes, caracterizado porque comprende las etapas de: - formar una lechada acuosa de partículas de nucleo de óxido de zinc pigmentario químicamente reactivo; - calentar dicha lechada a una temperatura elevada; - añadir a dicha lechada caliente un primer compuesto precursor de un óxido metálico hidratado, al tiempo que se mantiene el pH de la lechada caliente en un valor de por lo menos 9 aproximadamente para efectuar la deposición de un primer revestimiento de un primer óxido metálico amorfo hidratado sobre dichas partículas de núcleo de óxido de zinc pigmentario; - ajustar el pH de la lechada caliente de las partículas de núcleo de óxido de zinc pigmentario revestidas con dicho primer óxido metálico hidratado, a un valor de 6,5 o menos aproximadamente; - añadir a dicha lechada caliente de las partículas de óxido de zinc pigmentario revestidas con el primer óxido metálico hidratado, al tiempo que se mantiene el pH de la lechada caliente en 6,5 o menos aproximadamente, un segundo compuesto precursor de un óxido metálico hidratado, para efectuar la deposición sobre dichas partículas de núcleo de óxido de zinc pigmentario, revestidas con el primer óxido metálico hidratado, de un segundo revestimiento de un segundo óxido metálico hidratado, para producir así una lechada que contiene una composici composición de óxido de zinc pigmentario, químicamente inerte; - curar dicha composición de óxido de zinc pigmentario químicamente inerte; y - recuerar dicha composición de óxido de zinc pigmentario, químicamente inerte, curada, de dicha lechada, practicamente como se produce.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/284,628 US4923518A (en) | 1988-12-15 | 1988-12-15 | Chemically inert pigmentary zinc oxides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX172437B true MX172437B (es) | 1993-12-16 |
Family
ID=23090920
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX018693A MX172437B (es) | 1988-12-15 | 1989-12-13 | Un procedimiento para preparar composiciones a base de particulas de oxido de zinc pigmentario |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US4923518A (es) |
| EP (1) | EP0449888B1 (es) |
| JP (2) | JP2501663B2 (es) |
| CN (1) | CN1029686C (es) |
| AR (1) | AR245758A1 (es) |
| AU (1) | AU619432B2 (es) |
| BR (1) | BR8907829A (es) |
| CA (1) | CA2000962A1 (es) |
| DE (1) | DE68921220T2 (es) |
| ES (1) | ES2018995A6 (es) |
| FI (1) | FI910817A0 (es) |
| MX (1) | MX172437B (es) |
| MY (1) | MY106029A (es) |
| PH (1) | PH25822A (es) |
| WO (1) | WO1990006974A1 (es) |
| ZA (1) | ZA898230B (es) |
Families Citing this family (55)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9121143D0 (en) * | 1991-10-04 | 1991-11-13 | Tioxide Chemicals Limited | Dispersions |
| GB9121153D0 (en) * | 1991-10-04 | 1991-11-13 | Tioxide Chemicals Ltd | Method of preparing sunscreens |
| EP0698275A4 (en) * | 1993-04-28 | 1996-09-04 | Mark Mitchnick | CONDUCTIVE POLYMERS |
| US5441726A (en) * | 1993-04-28 | 1995-08-15 | Sunsmart, Inc. | Topical ultra-violet radiation protectants |
| JP2943056B2 (ja) * | 1994-12-30 | 1999-08-30 | ミキ アメリカ インコーポレイテド | 粒状複合材料、その製造法および粒状複合材料を含む化粧品 |
| JPH09227779A (ja) * | 1995-12-22 | 1997-09-02 | Toto Ltd | 建築用ゴム部材及びその表面の親水性付与方法 |
| US5922403A (en) * | 1996-03-12 | 1999-07-13 | Tecle; Berhan | Method for isolating ultrafine and fine particles |
| GB9616978D0 (en) * | 1996-08-13 | 1996-09-25 | Tioxide Specialties Ltd | Zinc oxide dispersions |
| US6159600A (en) | 1997-02-14 | 2000-12-12 | Reliance Electric Technologies, Llc | Oxygen plasma resistant polymer for electrical devices |
| US5780525A (en) * | 1997-02-14 | 1998-07-14 | Reliance Electric Industrial Company | Photocurable composition for electrical insulation |
| US6169119B1 (en) | 1997-02-14 | 2001-01-02 | Reliance Electric Technologies, Llc | Metal oxide sols and process for making the same |
| DE19732954A1 (de) * | 1997-07-31 | 1999-02-18 | Beiersdorf Ag | Lichtschutzzubereitungen mit einem Gehalt an anorganischen Pigmenten, welche oberflächlich mit UV-Filtersubstanzen beschichtet sind |
| US5891237A (en) * | 1997-10-08 | 1999-04-06 | Millennium Inorganic Chemicals, Ltd. | Production of free flowing spheres using partially neutralized fatty acid |
| KR100592832B1 (ko) * | 2001-05-18 | 2006-06-26 | 쇼와 덴코 가부시키가이샤 | 코팅된 산화 아연 입자, 및 그의 제조 방법 및 용도 |
| JP4224290B2 (ja) * | 2002-11-28 | 2009-02-12 | 三菱樹脂株式会社 | 剥離性フィルム |
| US20060042512A1 (en) * | 2004-08-30 | 2006-03-02 | Craig Daniel H | Surface-treated pigments |
| US20060047022A1 (en) * | 2004-08-30 | 2006-03-02 | Craig Daniel H | Thermoplastic compositions including inorganic particulates |
| US20060042513A1 (en) * | 2004-08-30 | 2006-03-02 | Craig Daniel H | Process for manufacturing thermoplastic materials containing inorganic particulates |
| US20060047020A1 (en) * | 2004-08-30 | 2006-03-02 | Craig Daniel H | Thermoplastic compositions including inorganic particulates |
| US20060047021A1 (en) * | 2004-08-30 | 2006-03-02 | Craig Daniel H | Thermoplastic compositions including inorganic particulates |
| US20060047023A1 (en) * | 2004-08-30 | 2006-03-02 | Craig Daniel H | Process for manufacturing thermoplastic materials containing inorganic particulates |
| US20060042511A1 (en) * | 2004-08-30 | 2006-03-02 | Craig Daniel H | Surface-treated pigments |
| US20060046058A1 (en) * | 2004-08-30 | 2006-03-02 | Craig Daniel H | Process for manufacturing thermoplastic materials containing inorganic particulates |
| US20060045841A1 (en) * | 2004-08-30 | 2006-03-02 | Craig Daniel H | Process for making titanium dioxide and resulting product |
| US20060048677A1 (en) * | 2004-09-07 | 2006-03-09 | Craig Daniel H | Process for manufacturing thermoplastic materials containing inorganic particulates |
| US7138011B2 (en) * | 2004-09-07 | 2006-11-21 | Tronox Llc | Surface treated pigments |
| US6958091B1 (en) | 2004-09-07 | 2005-10-25 | Kerr-Mcgee Chemical Llc | Surface-treated pigments |
| US20060051503A1 (en) * | 2004-09-07 | 2006-03-09 | Craig Daniel H | Process for manufacturing thermoplastic materials containing inorganic particulates |
| US20060048674A1 (en) * | 2004-09-07 | 2006-03-09 | Craig Daniel H | Process for manufacturing thermoplastic materials containing inorganic particulates |
| US6946028B1 (en) | 2004-09-07 | 2005-09-20 | Kerr-Mcgee Chemical Llc | Surface-treated pigments |
| US20060052482A1 (en) * | 2004-09-07 | 2006-03-09 | Craig Daniel H | Thermoplastic compositions including inorganic particulates |
| US20060052484A1 (en) * | 2004-09-07 | 2006-03-09 | Craig Daniel H | Thermoplastic compositions including inorganic particulates |
| US20060051504A1 (en) * | 2004-09-07 | 2006-03-09 | Craig Daniel H | Process for manufacturing thermoplastic materials containing inorganic particulates |
| US20060052485A1 (en) * | 2004-09-07 | 2006-03-09 | Craig Daniel H | Thermoplastic compositions including inorganic particulates |
| US20060052483A1 (en) * | 2004-09-07 | 2006-03-09 | Craig Daniel H | Thermoplastic compositions including inorganic particulates |
| KR100645649B1 (ko) * | 2004-11-03 | 2006-11-15 | 주식회사 엘지화학 | 염화비닐 수지 조성물 및 그 제조방법 |
| CN101522569B (zh) * | 2006-10-06 | 2012-02-15 | 堺化学工业株式会社 | 超微粒氧化锌及其制造方法 |
| TWI327556B (en) * | 2006-10-19 | 2010-07-21 | Ind Tech Res Inst | Ultraviolet absorber formulation |
| DE102007062774A1 (de) | 2007-12-27 | 2009-07-02 | Baerlocher Gmbh | Leicht suspendierbare Hydrophobierungsmittel |
| US20090170992A1 (en) * | 2007-12-28 | 2009-07-02 | Saint-Gobain Performance Plastics Corporation | Etch resistant polymer composition |
| WO2010066768A2 (de) | 2008-12-12 | 2010-06-17 | Basf Se | Dispersionen enthaltend funktionalisierte oxidische nanopartikel |
| WO2010066640A1 (de) * | 2008-12-12 | 2010-06-17 | Basf Se | Silan-modifizierte nanopartikel aus metalloxiden |
| WO2011023266A1 (en) | 2009-08-28 | 2011-03-03 | Basf Se | Modified nanoparticles |
| ES2950865T3 (es) * | 2011-08-03 | 2023-10-16 | Sakai Chemical Industry Co | Polvo compuesto y método para producir el mismo |
| WO2013062781A1 (en) * | 2011-10-28 | 2013-05-02 | E. I. Du Pont De Nemours And Company | Treated inorganic pigments having improved dispersability and use thereof in coating compositions |
| DE102012004138B3 (de) * | 2011-12-06 | 2012-09-27 | Ley & Co. Farbenwerke Wunsiedel KG | Verwendung einer zinkoxidhaltigen Fritte als UV-Schutzpigment |
| DE102012002824B4 (de) * | 2012-02-11 | 2017-01-12 | Ley & Co. Farbenwerke Wunsiedel KG | Verwendung von säurefest gecoateten Pigmenten in PVC sowie PVC-Kunststoff mit säurefest gecoateten Pigmenten |
| KR101334145B1 (ko) * | 2013-01-08 | 2013-11-28 | 주식회사 케이엠티알 | 슈퍼 옥사이드 생성 조성물의 제조방법 및 이 방법에 의해 제조된 슈퍼 옥사이드 생성 조성물 |
| US20150257341A1 (en) * | 2014-03-13 | 2015-09-17 | Nursery Supplies, Inc. | System for protecting a growing container |
| JP6477173B2 (ja) * | 2015-04-02 | 2019-03-06 | 堺化学工業株式会社 | 表面被覆酸化亜鉛粒子の製造方法 |
| US9765222B2 (en) | 2015-05-06 | 2017-09-19 | Viavi Solutions Inc. | Method of encapsulating pigment flakes with a metal oxide coating |
| CN109081946B (zh) * | 2017-06-14 | 2022-10-14 | 张家港康得新光电材料有限公司 | 光吸收材料组合物以及应用其的产品 |
| CN110305524A (zh) * | 2018-03-20 | 2019-10-08 | 常州格林感光新材料有限公司 | 一种含有改性颜料的辐射固化组合物及其应用 |
| CN108690375A (zh) * | 2018-05-24 | 2018-10-23 | 陈红玲 | 纳米TiO2表面疏水修饰工艺 |
| US10934175B1 (en) | 2019-12-02 | 2021-03-02 | King Saud University | Method of making zinc oxide nanoparticles using red sand |
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| US27818A (en) * | 1860-04-10 | Artificial slate | ||
| US2068066A (en) * | 1932-06-14 | 1937-01-19 | Glidden Co | Process of coating pigments |
| US1997925A (en) * | 1932-08-10 | 1935-04-16 | American Zinc Lead & Smelting | Process for making pigments |
| US1946055A (en) * | 1932-10-21 | 1934-02-06 | Sandura Company Inc | Pigment |
| US2118511A (en) * | 1933-02-10 | 1938-05-24 | Du Pont | Coating compositions and process of preparing same |
| US2303329A (en) * | 1940-07-06 | 1942-12-01 | New Jersey Zinc Co | Zinc oxide |
| US2785990A (en) * | 1954-02-08 | 1957-03-19 | American Zinc Lead & Smelting | Method of surface treating zinc oxide |
| US2913419A (en) * | 1956-04-18 | 1959-11-17 | Du Pont | Chemical process and composition |
| US2885366A (en) * | 1956-06-28 | 1959-05-05 | Du Pont | Product comprising a skin of dense, hydrated amorphous silica bound upon a core of another solid material and process of making same |
| US3042539A (en) * | 1959-01-15 | 1962-07-03 | Csonka Lajos | Process for the preparation of zinc oxide pigments |
| US3083113A (en) * | 1960-04-07 | 1963-03-26 | Dorst W | Zinc oxide pigments and their production |
| GB1046723A (en) * | 1963-01-02 | 1966-10-26 | Lajos Csonka | Process for preparing surface treated pigments |
| US3576656A (en) * | 1968-03-11 | 1971-04-27 | Nasa | Stabilized zinc oxide coating compositions |
| US3846148A (en) * | 1971-09-20 | 1974-11-05 | Hammond Lead Prod Inc | Novel composite pigments |
| US3852087A (en) * | 1972-03-22 | 1974-12-03 | J Nordyke | Composite pigment for blocking tannin |
| USRE27818E (en) | 1972-06-02 | 1973-11-27 | Titanium dioxide pigment coated with silica and alumina | |
| US4130442A (en) * | 1977-06-06 | 1978-12-19 | Frederick G. Schwarzmann | Method for renewing grout |
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| US4619995A (en) * | 1984-12-24 | 1986-10-28 | Nova Chem Limited | N,O-carboxymethyl chitosan and preparative method therefor |
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-
1988
- 1988-12-15 US US07/284,628 patent/US4923518A/en not_active Expired - Fee Related
-
1989
- 1989-10-17 MY MYPI89001428A patent/MY106029A/en unknown
- 1989-10-18 CA CA002000962A patent/CA2000962A1/en not_active Abandoned
- 1989-10-20 PH PH39390A patent/PH25822A/en unknown
- 1989-10-30 ZA ZA898230A patent/ZA898230B/xx unknown
- 1989-11-20 FI FI910817A patent/FI910817A0/fi not_active Application Discontinuation
- 1989-11-20 AU AU48043/90A patent/AU619432B2/en not_active Ceased
- 1989-11-20 DE DE68921220T patent/DE68921220T2/de not_active Expired - Fee Related
- 1989-11-20 BR BR898907829A patent/BR8907829A/pt not_active Application Discontinuation
- 1989-11-20 JP JP2501261A patent/JP2501663B2/ja not_active Expired - Lifetime
- 1989-11-20 WO PCT/US1989/005186 patent/WO1990006974A1/en not_active Ceased
- 1989-11-20 EP EP90900702A patent/EP0449888B1/en not_active Expired - Lifetime
- 1989-12-12 AR AR89315652A patent/AR245758A1/es active
- 1989-12-12 CN CN89109235A patent/CN1029686C/zh not_active Expired - Fee Related
- 1989-12-13 MX MX018693A patent/MX172437B/es unknown
- 1989-12-15 ES ES8904238A patent/ES2018995A6/es not_active Expired - Fee Related
-
1995
- 1995-08-30 JP JP7222042A patent/JPH08104823A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JPH08104823A (ja) | 1996-04-23 |
| JP2501663B2 (ja) | 1996-05-29 |
| CA2000962A1 (en) | 1990-06-15 |
| AR245758A1 (es) | 1994-02-28 |
| BR8907829A (pt) | 1991-12-10 |
| EP0449888A1 (en) | 1991-10-09 |
| CN1043515A (zh) | 1990-07-04 |
| ES2018995A6 (es) | 1991-05-16 |
| AU619432B2 (en) | 1992-01-23 |
| DE68921220D1 (de) | 1995-03-23 |
| CN1029686C (zh) | 1995-09-06 |
| US4923518A (en) | 1990-05-08 |
| FI910817A7 (fi) | 1991-02-20 |
| PH25822A (en) | 1991-11-05 |
| MY106029A (en) | 1995-02-28 |
| EP0449888B1 (en) | 1995-02-15 |
| ZA898230B (en) | 1991-01-30 |
| AU4804390A (en) | 1990-07-10 |
| WO1990006974A1 (en) | 1990-06-28 |
| FI910817A0 (fi) | 1991-02-20 |
| DE68921220T2 (de) | 1995-06-14 |
| JPH04506674A (ja) | 1992-11-19 |
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