MX171232B - Catalizador de plata mejorado - Google Patents

Catalizador de plata mejorado

Info

Publication number
MX171232B
MX171232B MX006343A MX634387A MX171232B MX 171232 B MX171232 B MX 171232B MX 006343 A MX006343 A MX 006343A MX 634387 A MX634387 A MX 634387A MX 171232 B MX171232 B MX 171232B
Authority
MX
Mexico
Prior art keywords
weight
catalyst
silver catalyst
improved silver
alkali metal
Prior art date
Application number
MX006343A
Other languages
English (en)
Inventor
Gosse Boxhoorn
Aan Hendrik Klazinga
Original Assignee
Shell Internationales Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationales Research filed Critical Shell Internationales Research
Publication of MX171232B publication Critical patent/MX171232B/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La presente invención se refiere a un catalizador de plata mejorado, adecuado para uso en la oxidación de etileno a óxido de etileno, caracterizado por a) un soporte de alúmina calcinaco, enriquecido en metal alcalino y b) de 1 a 15 por ciento en peso de plata metálica, basado en el peso del catalizador tal, c) un metal alcalino del grupo constituido por potasio, rubidio y cesio, en la forma de su óxido o hidróxido como activador y d) un anión fluoruro, estando presentes los dos últimos comprendidos en c) y d) cada uno en una cantidad entre 10 y 1000 partes en peso por millón de partes en peso del catalizador total.
MX006343A 1986-05-07 1987-05-06 Catalizador de plata mejorado MX171232B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB868611121A GB8611121D0 (en) 1986-05-07 1986-05-07 Silver catalyst

Publications (1)

Publication Number Publication Date
MX171232B true MX171232B (es) 1993-10-13

Family

ID=10597454

Family Applications (1)

Application Number Title Priority Date Filing Date
MX006343A MX171232B (es) 1986-05-07 1987-05-06 Catalizador de plata mejorado

Country Status (18)

Country Link
US (1) US4742034A (es)
EP (1) EP0244895B1 (es)
JP (1) JP2559038B2 (es)
KR (1) KR960000938B1 (es)
CN (1) CN1008514B (es)
AU (1) AU592431B2 (es)
BR (1) BR8702266A (es)
CZ (1) CZ278266B6 (es)
DE (1) DE3764535D1 (es)
DK (1) DK165104C (es)
GB (1) GB8611121D0 (es)
IN (1) IN176124B (es)
MX (1) MX171232B (es)
PL (1) PL154311B1 (es)
RU (1) RU2034648C1 (es)
SG (1) SG67191G (es)
TR (1) TR23360A (es)
ZA (1) ZA873196B (es)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4950773A (en) * 1988-01-28 1990-08-21 Eastman Kodak Company Selective epoxidation of olefins
CN1009437B (zh) * 1988-02-03 1990-09-05 中国石油化工总公司 乙烯氧化制环氧乙烷高效银催化剂
US4874879A (en) * 1988-07-25 1989-10-17 Shell Oil Company Process for starting-up an ethylene oxide reactor
US5380697A (en) * 1993-09-08 1995-01-10 Shell Oil Company Ethylene oxide catalyst and process
EP0716884B2 (en) * 1994-12-15 2009-09-23 Shell Internationale Researchmaatschappij B.V. Process for preparing ethylene oxide catalysts
US5908942A (en) * 1995-09-15 1999-06-01 Eastman Chemical Company Epoxidation of butadiene using cesium fluoride promoted silver catalyst with enhanced thermal stability under reaction conditions
US5739075A (en) * 1995-10-06 1998-04-14 Shell Oil Company Process for preparing ethylene oxide catalysts
US5801259A (en) * 1996-04-30 1998-09-01 Shell Oil Company Ethylene oxide catalyst and process
US5780656A (en) * 1997-04-14 1998-07-14 Scientific Design Company, Inc. Ethylene oxide catalyst and process
DE69924453T2 (de) * 1998-11-17 2006-02-16 Nippon Shokubai Co., Ltd. Katalysatorträger zur Verwendung in der Herstellung von Ethylenoxid
WO2005023418A1 (en) * 2003-08-22 2005-03-17 Union Carbide Chemicals & Plastics Technology Corporation Improved alumina carriers and silver-based catalysts for the production of alkylene oxides
RU2340607C2 (ru) * 2003-08-22 2008-12-10 Дау Текнолоджи Инвестментс Ллс Модифицированные носители из оксида алюминия и катализаторы на основе серебра для получения алкиленоксидов
CA2541992C (en) 2003-10-16 2013-07-09 Union Carbide Chemicals & Plastics Technology Corporation Catalysts having enhanced stability, efficiency and/or activity for alkylene oxide production
US7528270B2 (en) 2004-06-18 2009-05-05 Shell Oil Company Process for the production of an olefin oxide, a 1, 2-diol, a 1,2-diol ether, or an alkanolamine
JP5106106B2 (ja) * 2004-06-18 2012-12-26 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー オレフィンオキシド、１，２−ジオール、１，２−ジオールエーテル、またはアルカノールアミンの製造方法
WO2006020718A2 (en) * 2004-08-12 2006-02-23 Shell Internationale Research Maatschappij B.V. A method of preparing a shaped catalyst, the catalyst, and use of the catalyst
US8536083B2 (en) 2004-09-01 2013-09-17 Shell Oil Company Olefin epoxidation process, a catalyst for use in the process, a carrier for use in preparing the catalyst, and a process for preparing the carrier
WO2006028940A2 (en) 2004-09-01 2006-03-16 Shell Internationale Research Maatschappij B.V. An olefin epoxidation process, a catalyst for use in the process, a carrier for use in preparing the catalyst, and a process for preparing the carrier
KR20070106772A (ko) * 2005-02-21 2007-11-05 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 올레핀의 에폭시화 방법, 그 방법에 사용하기 위한 촉매,그 촉매를 제조하는데 이용하기 위한 담체, 및 그 담체의제조방법
KR20080034029A (ko) * 2005-08-11 2008-04-17 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 성형 촉매의 제조 방법, 제조된 촉매, 및 촉매의 용도
CN112206798B (zh) * 2020-10-29 2022-03-22 润和催化材料(浙江)有限公司 一种乙烯氧化制环氧乙烷的银催化剂及其制备方法和应用
CN115178252B (zh) * 2021-04-07 2023-09-12 中国石油化工股份有限公司 氧化铝载体及其制备方法和应用以及加氢催化剂

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4356312A (en) * 1972-01-07 1982-10-26 Shell Oil Company Ethylene oxide process
DE2636680C3 (de) * 1976-08-14 1979-04-05 Hoechst Ag, 6000 Frankfurt Verfahren zur Verbesserung der Wirksamkeit von Silber-Trägerkatalysatoren
US4374260A (en) * 1976-08-30 1983-02-15 Texaco Inc. Ethylene oxide production
JPS5929293B2 (ja) * 1977-07-01 1984-07-19 株式会社日本触媒 酸化エチレン製造用銀担持触媒の製造方法
DE3262507D1 (en) * 1981-01-23 1985-04-18 Ici Plc Process for the production of ethylene oxide
JPS57180434A (en) * 1981-04-30 1982-11-06 Mitsubishi Petrochem Co Ltd Silver catalyst for production of ethylene oxide
DE3264712D1 (en) * 1981-02-25 1985-08-22 Mitsubishi Petrochemical Co Silver-based catalyst for production of ethylene oxide
JPS5898144A (ja) * 1981-12-08 1983-06-10 Mitsubishi Petrochem Co Ltd エチレンオキシド製造用銀触媒
US4575494A (en) * 1984-02-08 1986-03-11 The Dow Chemical Company Alumina compositions useful as catalyst supports for ethylene oxidation
JPS60216844A (ja) * 1984-04-13 1985-10-30 Nippon Shokubai Kagaku Kogyo Co Ltd エチレンオキシド製造用銀触媒
JPS6171838A (ja) * 1984-09-14 1986-04-12 Mitsubishi Petrochem Co Ltd 銀触媒の製造法

Also Published As

Publication number Publication date
BR8702266A (pt) 1988-02-17
US4742034A (en) 1988-05-03
TR23360A (tr) 1989-12-28
IN176124B (es) 1996-02-03
CN87103275A (zh) 1987-11-25
JPS62262748A (ja) 1987-11-14
EP0244895A3 (en) 1988-01-07
EP0244895B1 (en) 1990-08-29
AU592431B2 (en) 1990-01-11
DK165104C (da) 1993-03-01
DK229487D0 (da) 1987-05-05
CZ315587A3 (en) 1993-08-11
KR870010900A (ko) 1987-12-18
DE3764535D1 (de) 1990-10-04
PL154311B1 (en) 1991-07-31
AU7249587A (en) 1987-11-12
JP2559038B2 (ja) 1996-11-27
DK229487A (da) 1987-11-08
ZA873196B (en) 1987-10-27
CN1008514B (zh) 1990-06-27
PL265499A1 (en) 1988-08-18
KR960000938B1 (ko) 1996-01-15
EP0244895A2 (en) 1987-11-11
RU2034648C1 (ru) 1995-05-10
DK165104B (da) 1992-10-12
CZ278266B6 (en) 1993-11-17
GB8611121D0 (en) 1986-06-11
SG67191G (en) 1991-09-13

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