MA64623A1 - Méthode de préparation d'un précurseur de matériau d'électrode positive ayant un grand canal, et son application - Google Patents

Méthode de préparation d'un précurseur de matériau d'électrode positive ayant un grand canal, et son application

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Publication number
MA64623A1
MA64623A1 MA64623A MA64623A MA64623A1 MA 64623 A1 MA64623 A1 MA 64623A1 MA 64623 A MA64623 A MA 64623A MA 64623 A MA64623 A MA 64623A MA 64623 A1 MA64623 A1 MA 64623A1
Authority
MA
Morocco
Prior art keywords
positive electrode
electrode material
sodium
channel
nickel
Prior art date
Application number
MA64623A
Other languages
English (en)
Inventor
Haijun YU
Yinghao XIE
Xuemei Zhang
Changdong LI
Aixia LI
Original Assignee
Guangdong Brunp Recycling Technology Co., Ltd.
Hunan Brunp Recycling Technology Co., Ltd.
Hunan Brunp Ev Recycling Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangdong Brunp Recycling Technology Co., Ltd., Hunan Brunp Recycling Technology Co., Ltd., Hunan Brunp Ev Recycling Co., Ltd. filed Critical Guangdong Brunp Recycling Technology Co., Ltd.
Publication of MA64623A1 publication Critical patent/MA64623A1/fr

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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/40Complex oxides containing nickel and at least one other metal element
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/40Complex oxides containing nickel and at least one other metal element
    • C01G53/42Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • C01G53/502Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2 containing lithium and cobalt
    • C01G53/504Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2 containing lithium and cobalt with the molar ratio of nickel with respect to all the metals other than alkali metals higher than or equal to 0.5, e.g. Li(MzNixCoyMn1-x-y-z)O2 with x ≥ 0.5
    • C01G53/506Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2 containing lithium and cobalt with the molar ratio of nickel with respect to all the metals other than alkali metals higher than or equal to 0.5, e.g. Li(MzNixCoyMn1-x-y-z)O2 with x ≥ 0.5 with the molar ratio of nickel with respect to all the metals other than alkali metals higher than or equal to 0.8, e.g. Li(MzNixCoyMn1-x-y-z)O2 with x ≥ 0.8
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/01Particle morphology depicted by an image
    • C01P2004/03Particle morphology depicted by an image obtained by SEM
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/30Particle morphology extending in three dimensions
    • C01P2004/32Spheres
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/61Micrometer sized, i.e. from 1-100 micrometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/40Electric properties
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M2004/026Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028Positive electrodes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

La présente invention concerne une méthode de préparation d'un précurseur de matériau d'électrode positive ayant un grand canal, et son application. La méthode comprend : le mélange d'une solution aqueuse d'hexanitrocobaltate de sodium, d'une solution de sel mixte de nickel-manganèse, d'une solution d'acide oxalique et d'ammoniac aqueux pour réaction ; la calcination d'un matériau solide ; et le trempage du matériau calciné dans de l'eau pour obtenir un précurseur de matériau d'électrode positive ayant un grand canal. Selon la présente invention, le nickel-cobalt-manganèse et le sodium-ammonium sont co-précipités et frittés, puis le sodium-ammonium est éliminé ; et étant donné que le rayon des ions sodium est supérieur au rayon des ions lithium, un grand canal ionique est laissé dans une structure de précurseur nickel-cobalt-manganèse, ce qui facilite la désintercalation des ions lithium d'un matériau d'électrode positive fritté chimiquement, élargit un canal de diffusion d'ions lithium, et améliore remarquablement la capacité de débit et les performances de cycle du matériau.
MA64623A 2022-01-24 2022-11-30 Méthode de préparation d'un précurseur de matériau d'électrode positive ayant un grand canal, et son application MA64623A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN202210077149.4A CN114436344B (zh) 2022-01-24 2022-01-24 具有大通道的正极材料前驱体的制备方法及其应用
PCT/CN2022/135660 WO2023138220A1 (fr) 2022-01-24 2022-11-30 Méthode de préparation d'un précurseur de matériau d'électrode positive ayant un grand canal, et son application

Publications (1)

Publication Number Publication Date
MA64623A1 true MA64623A1 (fr) 2025-04-30

Family

ID=81368779

Family Applications (1)

Application Number Title Priority Date Filing Date
MA64623A MA64623A1 (fr) 2022-01-24 2022-11-30 Méthode de préparation d'un précurseur de matériau d'électrode positive ayant un grand canal, et son application

Country Status (8)

Country Link
US (1) US20250122098A1 (fr)
CN (1) CN114436344B (fr)
DE (1) DE112022004673T5 (fr)
ES (1) ES2989242R1 (fr)
GB (1) GB2619865A (fr)
HU (1) HUP2400296A1 (fr)
MA (1) MA64623A1 (fr)
WO (1) WO2023138220A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114436344B (zh) * 2022-01-24 2023-07-07 广东邦普循环科技有限公司 具有大通道的正极材料前驱体的制备方法及其应用
CN116102087B (zh) * 2023-02-27 2024-07-30 荆门市格林美新材料有限公司 一种镍锰二元前驱体及其制备方法和应用

Citations (1)

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CN101215011A (zh) * 2008-01-01 2008-07-09 桂林工学院 镍钴锰酸锂的共沉淀-燃烧合成方法

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CN100362681C (zh) * 2005-03-23 2008-01-16 中南大学 一种锂离子电池正极材料锂镍钴锰氧及其制备方法
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CN105742595A (zh) * 2016-03-04 2016-07-06 广东精进能源有限公司 一种含镍富锂锰基正极材料及其制备方法、正极、电池
CN108046231B (zh) * 2017-11-13 2021-03-12 中南大学 一种钠离子电池正极材料及其制备方法
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CN114436344B (zh) * 2022-01-24 2023-07-07 广东邦普循环科技有限公司 具有大通道的正极材料前驱体的制备方法及其应用

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Also Published As

Publication number Publication date
WO2023138220A9 (fr) 2023-08-24
CN114436344B (zh) 2023-07-07
US20250122098A1 (en) 2025-04-17
WO2023138220A1 (fr) 2023-07-27
ES2989242A2 (es) 2024-11-25
GB202314805D0 (en) 2023-11-08
ES2989242R1 (es) 2026-02-13
CN114436344A (zh) 2022-05-06
GB2619865A (en) 2023-12-20
DE112022004673T5 (de) 2024-07-18
HUP2400296A1 (hu) 2024-08-28

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