MA61499A1 - Procédé d'extraction sélective de lithium à partir d'une batterie usagée et application du procédé - Google Patents

Procédé d'extraction sélective de lithium à partir d'une batterie usagée et application du procédé

Info

Publication number
MA61499A1
MA61499A1 MA61499A MA61499A MA61499A1 MA 61499 A1 MA61499 A1 MA 61499A1 MA 61499 A MA61499 A MA 61499A MA 61499 A MA61499 A MA 61499A MA 61499 A1 MA61499 A1 MA 61499A1
Authority
MA
Morocco
Prior art keywords
lithium
ion
divalent manganese
positive electrode
electrode material
Prior art date
Application number
MA61499A
Other languages
English (en)
Inventor
Dingshan Ruan
Changdong Li
Ruokui Chen
Yanchao Qiao
Bo Li
Donglian Bao
Original Assignee
Guangdong Brunp Recycling Technology Co Ltd
Hunan Brunp Recycling Tech Co Ltd
Hunan Brunp Ev Recycling Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangdong Brunp Recycling Technology Co Ltd, Hunan Brunp Recycling Tech Co Ltd, Hunan Brunp Ev Recycling Co Ltd filed Critical Guangdong Brunp Recycling Technology Co Ltd
Publication of MA61499A1 publication Critical patent/MA61499A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
    • C22B26/10—Obtaining alkali metals
    • C22B26/12—Obtaining lithium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00—Preliminary treatment of ores or scrap
    • C22B1/005—Preliminary treatment of scrap
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00—Preliminary treatment of ores or scrap
    • C22B1/02—Roasting processes
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00—Preliminary treatment of ores or scrap
    • C22B1/02—Roasting processes
    • C22B1/06—Sulfating roasting
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00—Preliminary treatment of ores or scrap
    • C22B1/14—Agglomerating; Briquetting; Binding; Granulating
    • C22B1/24—Binding; Briquetting ; Granulating
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/001—Dry processes
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/006—Wet processes
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/006—Wet processes
    • C22B7/007—Wet processes by acid leaching
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/006—Wet processes
    • C22B7/008—Wet processes by an alkaline or ammoniacal leaching
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/54—Reclaiming serviceable parts of waste accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/84—Recycling of batteries or fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Geology (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Metallurgy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Inorganic Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Primary Cells (AREA)

Abstract

Sont divulgués ici un procédé d'extraction sélective de lithium à partir d'une batterie usagée et une application du procédé. Selon le procédé, sur la base d'un effet d'échange d'ions entre un ion manganèse divalent et un ion lithium, un matériau d'électrode positive et un sel de manganèse divalent sont mélangés selon une certaine proportion et préparés de sorte à former une suspension, et le sel de manganèse divalent et le matériau d'électrode positive sont entièrement mélangés au moyen d'un processus de broyage à boulets, de sorte qu'une structure maillée du matériau d'électrode positive est efficacement endommagée, ce qui permet de réduire l'énergie d'activation de l'échange de l'ion manganèse divalent et de l'ion lithium et de réduire considérablement l'énergie de réaction requise par un processus d'extraction de lithium de sous-séquence. Un matériau mélangé après broyage à boulets est calciné à une température inférieure de sorte que le manganèse bivalent dans le sel de manganèse occupe une position de lithium dans une structure en couches, et le remplacement du manganèse-lithium est effectué directement pour obtenir une solution de lixiviation contenant du lithium pur. Le présent procédé améliore considérablement le taux de lixiviation et la sélectivité vis-à-vis du lithium. La présente invention utilise un mode consistant à réaliser d'abord un mélange par broyeur à boulets et à réaliser ensuite une calcination, et présente ainsi une faible consommation d'énergie, une sécurité élevée, un bon taux de lixiviation et une bonne sélectivité vis-à-vis du lithium, et de vastes perspectives d'application.
MA61499A 2021-07-22 2022-06-06 Procédé d'extraction sélective de lithium à partir d'une batterie usagée et application du procédé MA61499A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN202110831643.0A CN113684374B (zh) 2021-07-22 2021-07-22 从退役电池中选择性提锂的方法及其应用
PCT/CN2022/097178 WO2023000843A1 (fr) 2021-07-22 2022-06-06 Procédé d'extraction sélective de lithium à partir d'une batterie usagée et application du procédé

Publications (1)

Publication Number Publication Date
MA61499A1 true MA61499A1 (fr) 2023-11-30

Family

ID=78577714

Family Applications (1)

Application Number Title Priority Date Filing Date
MA61499A MA61499A1 (fr) 2021-07-22 2022-06-06 Procédé d'extraction sélective de lithium à partir d'une batterie usagée et application du procédé

Country Status (8)

Country Link
US (1) US12136714B2 (fr)
CN (1) CN113684374B (fr)
DE (1) DE112022000241B4 (fr)
ES (1) ES2950430R1 (fr)
GB (1) GB2622492A (fr)
MA (1) MA61499A1 (fr)
MX (1) MX2023014936A (fr)
WO (1) WO2023000843A1 (fr)

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CN113684374B (zh) 2021-07-22 2022-11-15 广东邦普循环科技有限公司 从退役电池中选择性提锂的方法及其应用
CN115275415A (zh) * 2022-08-05 2022-11-01 华中科技大学 一种从退役锂电池中回收锂并再生正极材料的方法
US20240240284A1 (en) * 2023-01-12 2024-07-18 Changwon National University Industry Academy Cooperation Corps Method for extracting lithium from cathod active materials in spent lithium-ion batteries using neutral aqueous solution and method for selectively extracting lithium from cathod active materials in spent lithium-ion batteries using carbonated water
CN116281918B (zh) * 2023-03-09 2024-03-29 中国科学院广州能源研究所 一种退役磷酸铁锂黑粉全组分精细分离回收的方法
CN117548097B (zh) * 2023-09-26 2025-11-04 中山大学 一种利用废旧锰酸锂电池制备整体式催化剂及其制备方法与应用

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Also Published As

Publication number Publication date
US12136714B2 (en) 2024-11-05
ES2950430A2 (es) 2023-10-09
GB2622492A (en) 2024-03-20
GB202316044D0 (en) 2023-12-06
CN113684374B (zh) 2022-11-15
US20240039068A1 (en) 2024-02-01
CN113684374A (zh) 2021-11-23
ES2950430R1 (es) 2024-07-10
DE112022000241T5 (de) 2023-08-31
WO2023000843A1 (fr) 2023-01-26
DE112022000241B4 (de) 2024-04-18
MX2023014936A (es) 2024-04-05

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