LV10861B - Method for the recovery of betaine from molasses - Google Patents
Method for the recovery of betaine from molasses Download PDFInfo
- Publication number
- LV10861B LV10861B LVP-93-810A LV930810A LV10861B LV 10861 B LV10861 B LV 10861B LV 930810 A LV930810 A LV 930810A LV 10861 B LV10861 B LV 10861B
- Authority
- LV
- Latvia
- Prior art keywords
- molasses
- columns
- column
- water
- betaine
- Prior art date
Links
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 title claims abstract description 187
- 235000013379 molasses Nutrition 0.000 title claims abstract description 165
- 229960003237 betaine Drugs 0.000 title claims abstract description 103
- 238000000034 method Methods 0.000 title claims abstract description 70
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 title claims abstract 17
- 238000011084 recovery Methods 0.000 title description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 115
- 229930006000 Sucrose Natural products 0.000 claims abstract description 76
- 239000005720 sucrose Substances 0.000 claims abstract description 76
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims abstract description 72
- 235000016068 Berberis vulgaris Nutrition 0.000 claims abstract description 23
- 241000335053 Beta vulgaris Species 0.000 claims abstract description 23
- 238000010828 elution Methods 0.000 claims abstract description 18
- 239000012527 feed solution Substances 0.000 claims description 54
- 239000000203 mixture Substances 0.000 claims description 10
- 238000004587 chromatography analysis Methods 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 6
- 239000003729 cation exchange resin Substances 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 239000003463 adsorbent Substances 0.000 claims description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims 2
- 239000012530 fluid Substances 0.000 claims 2
- 238000002347 injection Methods 0.000 claims 2
- 239000007924 injection Substances 0.000 claims 2
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 229960004793 sucrose Drugs 0.000 description 65
- 239000000047 product Substances 0.000 description 30
- 238000000926 separation method Methods 0.000 description 15
- 239000000243 solution Substances 0.000 description 13
- 239000003480 eluent Substances 0.000 description 12
- 239000011347 resin Substances 0.000 description 9
- 229920005989 resin Polymers 0.000 description 9
- 239000000126 substance Substances 0.000 description 6
- 230000002378 acidificating effect Effects 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 235000000346 sugar Nutrition 0.000 description 3
- 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 239000005715 Fructose Substances 0.000 description 2
- 235000021536 Sugar beet Nutrition 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 238000005341 cation exchange Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005194 fractionation Methods 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 238000004886 process control Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229940001593 sodium carbonate Drugs 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- 150000008163 sugars Chemical class 0.000 description 2
- HRSYWPMGIIAQIW-UHFFFAOYSA-N 5-bromo-2,3-dihydro-1,4-benzodioxine-7-carbaldehyde Chemical compound O1CCOC2=C1C=C(C=O)C=C2Br HRSYWPMGIIAQIW-UHFFFAOYSA-N 0.000 description 1
- 101150116295 CAT2 gene Proteins 0.000 description 1
- 101100326920 Caenorhabditis elegans ctl-1 gene Proteins 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- 230000005526 G1 to G0 transition Effects 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000827875 Nanger Species 0.000 description 1
- 101100126846 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) katG gene Proteins 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
- -1 beet molasses Chemical compound 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 238000013375 chromatographic separation Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 235000008504 concentrate Nutrition 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 1
- 238000001739 density measurement Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229920001542 oligosaccharide Polymers 0.000 description 1
- 150000002482 oligosaccharides Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000011020 pilot scale process Methods 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920003053 polystyrene-divinylbenzene Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical group OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13B—PRODUCTION OF SUCROSE; APPARATUS SPECIALLY ADAPTED THEREFOR
- C13B35/00—Extraction of sucrose from molasses
- C13B35/02—Extraction of sucrose from molasses by chemical means
- C13B35/06—Extraction of sucrose from molasses by chemical means using ion exchange
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
- C07C227/38—Separation; Purification; Stabilisation; Use of additives
- C07C227/40—Separation; Purification
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13B—PRODUCTION OF SUCROSE; APPARATUS SPECIALLY ADAPTED THEREFOR
- C13B20/00—Purification of sugar juices
- C13B20/14—Purification of sugar juices using ion-exchange materials
- C13B20/148—Purification of sugar juices using ion-exchange materials for fractionating, adsorption or ion exclusion processes combined with elution or desorption of a sugar fraction
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Fertilizers (AREA)
- Saccharide Compounds (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Steroid Compounds (AREA)
- Medicines Containing Antibodies Or Antigens For Use As Internal Diagnostic Agents (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
- Fodder In General (AREA)
- On-Site Construction Work That Accompanies The Preparation And Application Of Concrete (AREA)
- Underground Or Underwater Handling Of Building Materials (AREA)
Claims (16)
- LV 10861 METODE BET AINA IZDALĪŠANAI NO MELASES PATENTA FORMULA 1. Metode betaīna un saharozes izdalīšanai no biešu melases pseido-kustīga slāņa hromatogrāfijas sistēmas, kas satur vismaz trīs hromatogrāfijas kolonas, kas saslēgtas sērijā un piemērotas šķidruma tecēšanai vienā virzienā caur kolonām, viena un tā paša cikla laikā, minētais cikls ietver melases pievadīšanas stadiju, kas satur melases barošanas šķīduma ievadīšanu vienā no minētām kolonām un būtībā vienlaicīgu eluēšanas ūdens ievadīšanu citā no minētām kolonām, eluēšanas ūdens pievadīšanas stadiju, kas satur ūdens ievadīšanu vienā no minētām kolonām, cirkulācijas stadiju, kas satur minētā melases barošanas šķīduma un minētā ūdens cirkulāciju caur minētām kolonām, un produkta frakciju eluēšanu minēto stadiju laikā, kas izdalītas no grupas, kas sastāv no melases atlikuma frakcijas, betaīna frakcijas, sekojošas aiz melases atlikuma frakcijas, un saharozes frakcijas, sekojošas aiz betaīna frakcijas, un minēto stadiju atkārtošanu 1 līdz 6 reizes viena cikla laikā.
- 2. Metode, saskaņā ar 1. punktu, kas bez tam satur saharozes un betaīna frakciju eluēšanu pēc kārtas no vienas no minētām kolonām.
- 3. Metode, saskaņā ar 1. vai 2. punktu, kur minētā melases ievadīšanas stadija un minētā ūdens ievadīšanas stadija bez tam satur divu vai trīs produkta frakciju, kas izdalītas no grupas, kas 2 satur saharozi, melases atlikumu un betaīnu, eluēšanu no vienas no minētām kolonām.
- 4. Metode, saskaņā ar 3. punktu, kurā minēto betaīnu eluē minētās ūdens ievadīšanas stadijas laikā no kolonas, kas ir aiz kolonas, kurā ūdens ir ievadīts.
- 5. Metode, saskaņā ar 3. punktu, kas bez tam satur minētā melases atlikuma eluēšanu kā būtībā atsevišķu frakciju papildus minētam betaīnam minētās ūdens ievadīšanas stadijas laikā.
- 6. Metode, saskaņā ar 1. punktu, kas bez tam satur minētā betaīna un minētā melases atlikuma eluēšanu vienu aiz otra no vienas un tās pašas kolonas.
- 7. Metode, saskaņā ar 1. punktu, kas bez tam satur apgādi ar no 3 līdz aptuveni 14, labāk no 4 līdz aptuveni 8, hromatogrāfijas kolonām, kas saslēgtas sērijā.
- 8. Metode, saskaņā ar 1. punktu, kurā minētajās hromatogrāfijas kolonās kā adsorbents ir izmantoti stipras skābes katjonu apmaiņas sveķi.
- 9. Metode, saskaņā ar 8. punktu, kurā minētie stipras skābes katjonu apmaiņas sveķi ir vienvērtīgā formā, labāk nātrija vai kālija formā, vai minēto formu maisījums.
- 10. Metode, saskaņā ar 1. punktu, kurā šķidruma plūsmas ātrums minētajās kolonās ir no aptuveni 0.5 līdz aptuveni 10 m^/h/m^.
- 11. Metode, saskaņā ar 1. punktu, kurā minētā cirkulējošā barošanas šķīduma un ūdens temperatūra ir no aptuveni 40° līdz aptuveni 85°C. 3 LV 10861
- 12. Metode betaīna un saharozes izdalīšanai no biešu melases no pseidokustīga slāņa hromatogrāfijas sistēmas ar vismaz trim hromatogrāfijas kolonām, kas saslēgtas sērijā un piemērotas šķidruma tecēšanai vienā virzienā caur kolonām, kas sekojoši satur ( 1 ) melases barošanas šķīduma ievadīšanu vienā no minētām kolonām un melases atlikuma frakcijas eluēšanu no kolonas, kas ir aiz minētās kolonas, kurā ievadīts minētais melases barošanas šķīdums; ( 2 ) ūdens ievadīšanu vienā no minētām kolonām aiz kolonas, kurā ievadīts minētais melases barošanas šķīdums, būtībā vienā un tajā pašā laikā, kā minētā melases barošanas šķīduma ievadīšana, un produkta frakciju eluēšanu, kas satur saharozes frakciju, kas seko betaīna frakcijai no kolonas aiz minētās kolonas, kurā ievadīts ūdens; ( 3 ) minētā melases barošanas šķīduma un ūdens cirkulēšanu plūsmas virzienā caur minētām kolonām; ( 4 ) ūdens ievadīšanu vienā no minētām kolonām un melases atlikuma eluēšanu no kolonas aiz minētās kolonas, kurā ievadīts ūdens; ( 5 ) minētā melases barošanas šķīduma un ūdens cirkulēšanu plūsmas virzienā caur minētām kolonām; ( 6 ) ūdens ievadīšanu vienā no minētām kolonām un melases atlikuma eluēšanu no kolonas aiz minētās kolonas, kurā ievadīts ūdens; un ( 7 ) minētā melases barošanas šķīduma un ūdens cirkulēšanu plūsmas virzienā caur minētām kolonām.
- 13. Metode, saskaņā ar 12. punktu, kas bez tam satur stadiju 1 - 7 atkārtošanu, sākot ar melases barošanas šķīduma ievadīšanu kolonā aiz minētās kolonas, kurā minētais melases barošanas šķīdums tika ievadīts iepriekšējā cikla laikā.
- 14. Metode betaīna un saharozes izdalīšanai no biešu melases, izmantojot pseidokustīga slāņa hromatogrāfijas sistēmu ar vismaz trim hromatogrāfijas kolonām, kas saslēgtas sērijā un piemērotas šķidruma tecēšanai vienā virzienā caur kolonām, kas sekojoši satur 4 ( 1 ) melases barošanas šķīduma ievadīšanu vienā no minētām kolonām un melases atlikuma frakcijas eluēšanu no kolonas, kas ir aiz minētās kolonas, kurā ievadīts minētais melases barošanas šķīdums; ( 2 ) ūdens ievadīšanu vienā no minētām kolonām aiz kolonas, kurā ievadīts minētais melases barošanas šķīdums, būtībā vienā un tajā pašā laikā, kā minētā melases barošanas šķīduma ievadīšana, un produkta frakciju eluēšanu, izdalot no grupas, kas satur saharozi, betaīnu un saharozes frakciju, kas seko betaīna frakcijai no kolonas aiz minētās kolonas, kurā ievadīts ūdens-; ( 3 ) minētā melases barošanas šķīduma un ūdens cirkulēšanu plūsmas virzienā caur minētām kolonām; ( 4 ) ūdens ievadīšanu vienā no minētām kolonām un melases atlikuma eluēšanu no kolonas aiz minētās kolonas, kurā ievadīts ūdens; ( 5 ) minētā melases barošanas šķīduma un ūdens cirkulēšanu plūsmas virzienā caur minētām kolonām; ( 6 ) ūdens ievadīšanu vienā no minētām kolonām un betaīna eluēšanu no kolonas aiz kolonas, kurā ievadīts ūdens; un ( 7 ) minētā melases barošanas šķīduma un ūdens cirkulēšanu plūsmas virzienā caur minētām kolonām.
- 15. Metode, saskaņā ar 1., 2., 12. vai 14. punktu, kas bez tam satur minētā cikla atkārtošanu pēc līdzsvara sasniegšanas.
- 16. Metode, saskaņā ar 15. punktu, kas bez tam satur stadiju 1 - 7 atkārtošanu, sākot ar melases barošanas šķīduma ievadīšanu kolonā aiz minētās kolonas, kurā minētais melases barošanas šķīdums bija ievadīts iepriekšējā cikla laikā.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI882740A FI86416C (fi) | 1988-06-09 | 1988-06-09 | Foerfarande foer tillvaratagande av betain ur melass. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| LV10861A LV10861A (lv) | 1995-10-20 |
| LV10861B true LV10861B (en) | 1996-08-20 |
Family
ID=8526611
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| LVP-93-810A LV10861B (en) | 1988-06-09 | 1993-06-30 | Method for the recovery of betaine from molasses |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US5127957A (lv) |
| EP (1) | EP0345511B1 (lv) |
| JP (1) | JP2619530B2 (lv) |
| AT (1) | ATE126543T1 (lv) |
| AU (1) | AU3500289A (lv) |
| CA (1) | CA1326850C (lv) |
| DE (1) | DE68923821T2 (lv) |
| DK (1) | DK175303B1 (lv) |
| ES (1) | ES2078225T3 (lv) |
| FI (1) | FI86416C (lv) |
| GR (1) | GR3017252T3 (lv) |
| IE (1) | IE68037B1 (lv) |
| LT (1) | LT3704B (lv) |
| LV (1) | LV10861B (lv) |
| MA (1) | MA21562A1 (lv) |
| NO (1) | NO174849C (lv) |
| RU (1) | RU2054045C1 (lv) |
| UA (1) | UA8282A (lv) |
| ZA (1) | ZA893914B (lv) |
Families Citing this family (53)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7109005B2 (en) | 1990-01-15 | 2006-09-19 | Danisco Sweeteners Oy | Process for the simultaneous production of xylitol and ethanol |
| FI86440C (fi) | 1990-01-15 | 1992-08-25 | Cultor Oy | Foerfarande foer samtidig framstaellning av xylitol och etanol. |
| DE4231149C1 (de) * | 1992-09-17 | 1993-12-16 | Amino Gmbh | Verfahren zur Weiterverarbeitung von technischen Restabläufen der melasseverarbeitenden Industrie |
| FI96225C (fi) * | 1993-01-26 | 1996-05-27 | Cultor Oy | Menetelmä melassin fraktioimiseksi |
| US6663780B2 (en) | 1993-01-26 | 2003-12-16 | Danisco Finland Oy | Method for the fractionation of molasses |
| FI932108A (fi) * | 1993-05-10 | 1994-11-11 | Xyrofin Oy | Menetelmä sulfiittikeittoliemen fraktioimiseksi |
| US6265626B1 (en) | 1993-09-29 | 2001-07-24 | Regents Of The University Of Minnesota | Simulated countercurrent moving bed chromatographic reactor and method for use thereof |
| US5556546A (en) * | 1993-12-27 | 1996-09-17 | Mitsubishi Kasei Engineering Company | Method of separation into three components using a simulated moving bed |
| US5795398A (en) | 1994-09-30 | 1998-08-18 | Cultor Ltd. | Fractionation method of sucrose-containing solutions |
| US5760078A (en) * | 1996-03-08 | 1998-06-02 | Gist-Brocades B.V. | Process for the fractioning and recovery of valuable compounds from vinasse produced in fermentations |
| FI962204A0 (fi) * | 1996-05-24 | 1996-05-24 | Cultor Oy | Foerfarande foer fraktionering av en loesning |
| US6224776B1 (en) * | 1996-05-24 | 2001-05-01 | Cultor Corporation | Method for fractionating a solution |
| AU715541B2 (en) * | 1996-07-03 | 2000-02-03 | Tennessee Valley Authority | Exclusion chromatographic separation of ionic from nonionic solutes |
| EP0815911B1 (en) * | 1996-07-05 | 2004-10-06 | Tennessee Valley Authority | Exclusion chromatographic separation of ionic from nonionic solutes |
| DE69841418D1 (de) | 1997-01-07 | 2010-02-11 | Amalgamated Res Inc | Nderbett |
| US6379554B1 (en) | 1997-01-29 | 2002-04-30 | Amalgamated Research Inc. | Method of displacement chromatography |
| FI105048B (fi) * | 1997-05-22 | 2000-05-31 | Xyrofin Oy | Menetelmä isomaltuloosin ja muiden tuotteiden valmistamiseksi |
| JP3478325B2 (ja) | 1997-12-25 | 2003-12-15 | オルガノ株式会社 | クロマト分離方法 |
| FR2787576B1 (fr) | 1998-12-22 | 2001-01-12 | Inst Francais Du Petrole | Procede et dispositif d'analyse integree pour la caracterisation d'hydrocarbures, par simulation de distillation |
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-
1988
- 1988-06-09 FI FI882740A patent/FI86416C/fi active IP Right Grant
-
1989
- 1989-05-16 IE IE158089A patent/IE68037B1/en not_active IP Right Cessation
- 1989-05-19 DE DE68923821T patent/DE68923821T2/de not_active Expired - Lifetime
- 1989-05-19 AT AT89109081T patent/ATE126543T1/de not_active IP Right Cessation
- 1989-05-19 EP EP89109081A patent/EP0345511B1/en not_active Expired - Lifetime
- 1989-05-19 AU AU35002/89A patent/AU3500289A/en not_active Abandoned
- 1989-05-19 ES ES89109081T patent/ES2078225T3/es not_active Expired - Lifetime
- 1989-05-24 ZA ZA893914A patent/ZA893914B/xx unknown
- 1989-05-24 MA MA21813A patent/MA21562A1/fr unknown
- 1989-06-07 JP JP1145042A patent/JP2619530B2/ja not_active Expired - Lifetime
- 1989-06-08 NO NO892362A patent/NO174849C/no not_active IP Right Cessation
- 1989-06-08 UA UA4614225A patent/UA8282A/uk unknown
- 1989-06-08 DK DK198902806A patent/DK175303B1/da not_active IP Right Cessation
- 1989-06-08 CA CA000602195A patent/CA1326850C/en not_active Expired - Lifetime
- 1989-06-08 RU SU894614225A patent/RU2054045C1/ru active
-
1990
- 1990-11-30 US US07/622,392 patent/US5127957A/en not_active Expired - Lifetime
-
1993
- 1993-06-30 LV LVP-93-810A patent/LV10861B/en unknown
- 1993-12-03 LT LTIP1522A patent/LT3704B/lt not_active IP Right Cessation
-
1995
- 1995-08-30 GR GR950402367T patent/GR3017252T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JPH03209354A (ja) | 1991-09-12 |
| NO892362D0 (no) | 1989-06-08 |
| EP0345511A2 (en) | 1989-12-13 |
| UA8282A (uk) | 1996-03-29 |
| FI882740A (fi) | 1989-12-10 |
| NO174849B (no) | 1994-04-11 |
| ZA893914B (en) | 1990-02-28 |
| FI882740A0 (fi) | 1988-06-09 |
| NO174849C (no) | 1994-07-20 |
| GR3017252T3 (en) | 1995-11-30 |
| DK280689A (da) | 1989-12-11 |
| CA1326850C (en) | 1994-02-08 |
| MA21562A1 (fr) | 1989-12-31 |
| LT3704B (en) | 1996-02-26 |
| FI86416C (fi) | 1992-08-25 |
| DK280689D0 (da) | 1989-06-08 |
| EP0345511A3 (en) | 1991-04-03 |
| EP0345511B1 (en) | 1995-08-16 |
| JP2619530B2 (ja) | 1997-06-11 |
| ES2078225T3 (es) | 1995-12-16 |
| DK175303B1 (da) | 2004-08-16 |
| US5127957A (en) | 1992-07-07 |
| DE68923821D1 (de) | 1995-09-21 |
| LV10861A (lv) | 1995-10-20 |
| IE68037B1 (en) | 1996-05-15 |
| LTIP1522A (en) | 1995-06-26 |
| FI86416B (fi) | 1992-05-15 |
| ATE126543T1 (de) | 1995-09-15 |
| NO892362L (no) | 1989-12-11 |
| DE68923821T2 (de) | 1995-12-21 |
| IE891580L (en) | 1989-12-09 |
| AU3500289A (en) | 1989-12-14 |
| RU2054045C1 (ru) | 1996-02-10 |
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