KR970042567A - 메탈로센 화합물 - Google Patents
메탈로센 화합물 Download PDFInfo
- Publication number
- KR970042567A KR970042567A KR1019960064293A KR19960064293A KR970042567A KR 970042567 A KR970042567 A KR 970042567A KR 1019960064293 A KR1019960064293 A KR 1019960064293A KR 19960064293 A KR19960064293 A KR 19960064293A KR 970042567 A KR970042567 A KR 970042567A
- Authority
- KR
- South Korea
- Prior art keywords
- formula
- compound
- catalyst
- polyolefins
- metallocene compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 150000001875 compounds Chemical class 0.000 title claims abstract 12
- 239000003054 catalyst Substances 0.000 claims abstract 9
- 229920000098 polyolefin Polymers 0.000 claims abstract 6
- 150000001336 alkenes Chemical class 0.000 claims abstract 4
- 238000004519 manufacturing process Methods 0.000 claims abstract 4
- 238000000034 method Methods 0.000 claims abstract 4
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 claims abstract 3
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims abstract 3
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 claims abstract 3
- 229910052751 metal Inorganic materials 0.000 claims abstract 3
- 239000002184 metal Substances 0.000 claims abstract 3
- 229910052782 aluminium Inorganic materials 0.000 claims abstract 2
- 150000001639 boron compounds Chemical class 0.000 claims abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 4
- 229930195733 hydrocarbon Natural products 0.000 claims 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 3
- 238000006116 polymerization reaction Methods 0.000 claims 2
- -1 aluminum compound Chemical class 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 239000004411 aluminium Substances 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
- C08F4/6428—Component covered by group C08F4/64 with an organo-aluminium compound with an aluminoxane, i.e. a compound containing an Al-O-Al- group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19546501A DE19546501A1 (de) | 1995-12-13 | 1995-12-13 | Metallocenverbindung |
| DE19546501.6 | 1995-12-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR970042567A true KR970042567A (ko) | 1997-07-24 |
Family
ID=7779983
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019960064293A Withdrawn KR970042567A (ko) | 1995-12-13 | 1996-12-11 | 메탈로센 화합물 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6040469A (enExample) |
| EP (1) | EP0779295B1 (enExample) |
| JP (1) | JP4165720B2 (enExample) |
| KR (1) | KR970042567A (enExample) |
| CN (2) | CN1074421C (enExample) |
| AT (1) | ATE280175T1 (enExample) |
| AU (1) | AU7421896A (enExample) |
| BR (1) | BR9605977A (enExample) |
| CA (1) | CA2192770A1 (enExample) |
| DE (2) | DE19546501A1 (enExample) |
| NO (1) | NO965328L (enExample) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3566819B2 (ja) * | 1996-10-04 | 2004-09-15 | 関東化学株式会社 | 新規な有機遷移金属化合物 |
| BR9812308A (pt) * | 1997-09-15 | 2000-09-05 | Dow Chemical Co | Complexos bimetálicos, catalisadores feitos destes |
| US6284698B1 (en) | 1997-09-15 | 2001-09-04 | The Dow Chemical Company | Highly activated bimetallic complexes and polymerization process |
| US6235917B1 (en) | 1998-08-28 | 2001-05-22 | The Dow Chemical Company | Dinuclear complexes and polymerization catalysts therefrom |
| US5892079A (en) * | 1997-10-17 | 1999-04-06 | Sri International | Metallocene catalysts and associated methods of preparation and use |
| US6096677A (en) * | 1997-10-17 | 2000-08-01 | Sri International | Supported metallocene catalysts |
| US5986024A (en) * | 1997-10-17 | 1999-11-16 | Sri International | Preparation of multimodal polymer compositions using multinuclear metallocene catalysts |
| EP0933383A1 (en) * | 1998-01-29 | 1999-08-04 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst composition for the polymerization of olefins |
| CA2336811A1 (en) | 1998-07-10 | 2000-01-20 | Joann M. Canich | Tethered monocyclopentadienyl polymerization catalysts |
| EP0985677A1 (en) * | 1998-09-07 | 2000-03-15 | Industrial Technology Research Institute | Dinuclear metallocene catalyst for olefin polymerization |
| US6544919B1 (en) | 1999-10-06 | 2003-04-08 | Sri International | Multinuclear transition metal catalysts for preparation of multimodal polymer compositions |
| IT1314261B1 (it) * | 1999-12-03 | 2002-12-06 | Enichem Spa | Composti metallocenici pontati, processo per la loro preparazione eloro uso come catalizzatori per la polimerizzazione di olefine. |
| JP2002338617A (ja) * | 2001-05-22 | 2002-11-27 | Sumitomo Chem Co Ltd | ビニル化合物重合用触媒成分、ビニル化合物重合用触媒、ビニル化合物重合体の製造方法および遷移金属化合物の使用方法 |
| US7550528B2 (en) * | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| US7223822B2 (en) * | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US7541402B2 (en) * | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| EP2261292B1 (en) | 2002-10-15 | 2014-07-23 | ExxonMobil Chemical Patents Inc. | Polyolefin adhesive compositions |
| CN112552428B (zh) * | 2019-09-25 | 2022-08-05 | 中国石油天然气股份有限公司 | 茂金属催化剂及其制备方法与应用 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA844157B (en) | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
| US5700749A (en) * | 1986-09-24 | 1997-12-23 | Mitsui Petrochemical Industries, Ltd. | Process for polymerizing olefins |
| IL85097A (en) | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
| PL276385A1 (en) | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
| US5003019A (en) | 1987-03-02 | 1991-03-26 | Mitsui Petrochemical Industries, Ltd. | Cyclo-olefinic random copolymer, olefinic random copolymer, and process for producing cyclo-olefinic random copolymers |
| EP0427697B1 (en) | 1989-10-10 | 1996-05-08 | Fina Technology, Inc. | Metallocene catalysts with Lewis acids and aluminum alkyls |
| DE69026679T3 (de) | 1989-10-30 | 2005-10-06 | Fina Technology, Inc., Houston | Addition von Alkylaluminium zum Verbessern eines Metallocenkatalysators |
| JP3048653B2 (ja) * | 1991-02-07 | 2000-06-05 | 三菱化学株式会社 | α‐オレフィン重合体の製造 |
| EP0578838A1 (en) | 1992-04-29 | 1994-01-19 | Hoechst Aktiengesellschaft | Olefin polymerization catalyst, process for its preparation, and its use |
| EP0567952B1 (en) | 1992-04-29 | 1997-12-03 | Hoechst Aktiengesellschaft | Olefin polymerization catalyst, process for its preparation, and its use |
| IT1256603B (it) | 1992-10-30 | 1995-12-12 | Enichem Polimeri | Catalizzatore e procedimento per (co) polimerizzare le alfa-olefine |
| IT1273420B (it) * | 1994-04-06 | 1997-07-08 | Spherilene Srl | Composti metallocenici, procedimento per la preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine |
| US5597935A (en) * | 1994-06-01 | 1997-01-28 | University Of Iowa Research Foundation | Synthesis of ansa-metallocene catalysts |
| EP0693502B1 (en) * | 1994-07-22 | 1997-11-05 | Mitsubishi Chemical Corporation | Catalyst component for the polymerization of alpha-olefins and a process for preparing alpha-olefin polymers with use of same |
-
1995
- 1995-12-13 DE DE19546501A patent/DE19546501A1/de not_active Withdrawn
-
1996
- 1996-12-06 AU AU74218/96A patent/AU7421896A/en not_active Abandoned
- 1996-12-10 DE DE59611121T patent/DE59611121D1/de not_active Expired - Lifetime
- 1996-12-10 AT AT96119752T patent/ATE280175T1/de not_active IP Right Cessation
- 1996-12-10 EP EP96119752A patent/EP0779295B1/de not_active Expired - Lifetime
- 1996-12-11 KR KR1019960064293A patent/KR970042567A/ko not_active Withdrawn
- 1996-12-12 CA CA002192770A patent/CA2192770A1/en not_active Abandoned
- 1996-12-12 US US08/764,526 patent/US6040469A/en not_active Expired - Fee Related
- 1996-12-12 NO NO965328A patent/NO965328L/no not_active Application Discontinuation
- 1996-12-12 BR BR9605977A patent/BR9605977A/pt not_active Application Discontinuation
- 1996-12-13 JP JP33367396A patent/JP4165720B2/ja not_active Expired - Fee Related
- 1996-12-13 CN CN96121557A patent/CN1074421C/zh not_active Expired - Fee Related
-
2001
- 2001-03-09 CN CN01110987A patent/CN1347921A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| CN1159449A (zh) | 1997-09-17 |
| CN1074421C (zh) | 2001-11-07 |
| ATE280175T1 (de) | 2004-11-15 |
| DE59611121D1 (de) | 2004-11-25 |
| DE19546501A1 (de) | 1997-06-19 |
| EP0779295B1 (de) | 2004-10-20 |
| JP4165720B2 (ja) | 2008-10-15 |
| NO965328D0 (no) | 1996-12-12 |
| NO965328L (no) | 1997-06-16 |
| JPH09183788A (ja) | 1997-07-15 |
| CA2192770A1 (en) | 1997-06-14 |
| CN1347921A (zh) | 2002-05-08 |
| EP0779295A1 (de) | 1997-06-18 |
| US6040469A (en) | 2000-03-21 |
| AU7421896A (en) | 1997-06-19 |
| BR9605977A (pt) | 1998-08-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR970042567A (ko) | 메탈로센 화합물 | |
| US5324800A (en) | Process and catalyst for polyolefin density and molecular weight control | |
| EP0129368B2 (en) | Process and catalyst for polyolefin density and molecular weight control | |
| US4542199A (en) | Process for the preparation of polyolefins | |
| KR0137960B1 (ko) | 가스상 중합에 의한 폴리에틸렌 왁스의 제조방법 | |
| JP2775069B2 (ja) | シリカゲル担持メタロセンアルモキサン触媒の製法 | |
| US5001244A (en) | Metallocene, hydrocarbylaluminum and hydrocarbylboroxine olefin polymerization catalyst | |
| US5373072A (en) | Supported catalyst for 1-olefin(s) (co)polymerization | |
| US5580939A (en) | Process and catalyst for polyolefin density and molecular weight control | |
| JP2892968B2 (ja) | ポリオレフィンの製造方法 | |
| US6992035B2 (en) | Metallocenes, polymerization catalyst systems, their preparation, and use | |
| KR970065549A (ko) | 치환 인데닐 언브리지드 메탈로센 | |
| KR910007971A (ko) | 신디오택틱 중합체의 제조방법 및 이에 사용되는 촉매 | |
| US6262199B1 (en) | Process and catalyst for producing isotactic polyolefins | |
| EP0324856A4 (en) | POLYMERIZATION PROCESS FOR OLEFINS. | |
| JPH0791328B2 (ja) | 幅広い分子量分布を有するポリエチレンの製造方法及びその触媒 | |
| DE69322139T2 (de) | Katalysator und Verfahren zur Olefinpolymerisation | |
| KR100186779B1 (ko) | 메탈로센 촉매반응을 이용하여 조절된 형태학적 특성을 갖는 폴리올레핀 플러프를 제조하는 방법 | |
| ATE248848T1 (de) | Verbrückte metallocene für die (co)polymerisation von olefinen | |
| US5453475A (en) | Process for preparing low density ethylene copolymers | |
| US5457171A (en) | Catalyst systems for the polymerization of C2 -C10 -alkenes | |
| EP0550075A1 (en) | Use of methylene-bridged derivatives of cyclopentadienyl dicarbollide complexes of titanium, zirconium and hafnium as polymerization catalysts | |
| KR100548104B1 (ko) | 알크-1-엔의 (공)중합용 촉매 조성물 | |
| RU2126424C1 (ru) | Каталитическая композиция для использования при полимеризации олефинов | |
| JP2968499B2 (ja) | アンカー鎖によってキャリアと連結したメタロセンを有する触媒系 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0109 | Patent application |
Patent event code: PA01091R01D Comment text: Patent Application Patent event date: 19961211 |
|
| PG1501 | Laying open of application | ||
| PC1203 | Withdrawal of no request for examination | ||
| WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |