CA2192770A1 - Metallocene compound - Google Patents

Metallocene compound

Info

Publication number
CA2192770A1
CA2192770A1 CA002192770A CA2192770A CA2192770A1 CA 2192770 A1 CA2192770 A1 CA 2192770A1 CA 002192770 A CA002192770 A CA 002192770A CA 2192770 A CA2192770 A CA 2192770A CA 2192770 A1 CA2192770 A1 CA 2192770A1
Authority
CA
Canada
Prior art keywords
olefin
compound
formula
metallocene
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002192770A
Other languages
English (en)
French (fr)
Inventor
Michael Riedel
Thomas Weller
Alexandra Jacobs
Wolfgang Anton Herrmann
Markus Morawietz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Publication of CA2192770A1 publication Critical patent/CA2192770A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C08F4/6428—Component covered by group C08F4/64 with an organo-aluminium compound with an aluminoxane, i.e. a compound containing an Al-O-Al- group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CA002192770A 1995-12-13 1996-12-12 Metallocene compound Abandoned CA2192770A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19546501A DE19546501A1 (de) 1995-12-13 1995-12-13 Metallocenverbindung
DE19546501.6 1995-12-13

Publications (1)

Publication Number Publication Date
CA2192770A1 true CA2192770A1 (en) 1997-06-14

Family

ID=7779983

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002192770A Abandoned CA2192770A1 (en) 1995-12-13 1996-12-12 Metallocene compound

Country Status (11)

Country Link
US (1) US6040469A (enExample)
EP (1) EP0779295B1 (enExample)
JP (1) JP4165720B2 (enExample)
KR (1) KR970042567A (enExample)
CN (2) CN1074421C (enExample)
AT (1) ATE280175T1 (enExample)
AU (1) AU7421896A (enExample)
BR (1) BR9605977A (enExample)
CA (1) CA2192770A1 (enExample)
DE (2) DE19546501A1 (enExample)
NO (1) NO965328L (enExample)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6072014A (en) * 1997-10-17 2000-06-06 Sri International Multimodal polymer compositions prepared using multinuclear metallocene catalysts
US6232256B1 (en) * 1998-01-29 2001-05-15 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for the polymerization of olefins
US6455458B1 (en) 1998-07-10 2002-09-24 Exxonmobil Chemical Patents Inc. Tethered monocyclopentadienyl polymerization catalysts
US6544919B1 (en) 1999-10-06 2003-04-08 Sri International Multinuclear transition metal catalysts for preparation of multimodal polymer compositions

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3566819B2 (ja) * 1996-10-04 2004-09-15 関東化学株式会社 新規な有機遷移金属化合物
ATE222917T1 (de) * 1997-09-15 2002-09-15 Dow Chemical Co Bimetallische komplexe und diese enthaltende polymerisationskatalysatoren
US6284698B1 (en) 1997-09-15 2001-09-04 The Dow Chemical Company Highly activated bimetallic complexes and polymerization process
US6235917B1 (en) 1998-08-28 2001-05-22 The Dow Chemical Company Dinuclear complexes and polymerization catalysts therefrom
US5892079A (en) * 1997-10-17 1999-04-06 Sri International Metallocene catalysts and associated methods of preparation and use
US6096677A (en) * 1997-10-17 2000-08-01 Sri International Supported metallocene catalysts
EP0985677A1 (en) * 1998-09-07 2000-03-15 Industrial Technology Research Institute Dinuclear metallocene catalyst for olefin polymerization
IT1314261B1 (it) * 1999-12-03 2002-12-06 Enichem Spa Composti metallocenici pontati, processo per la loro preparazione eloro uso come catalizzatori per la polimerizzazione di olefine.
JP2002338617A (ja) * 2001-05-22 2002-11-27 Sumitomo Chem Co Ltd ビニル化合物重合用触媒成分、ビニル化合物重合用触媒、ビニル化合物重合体の製造方法および遷移金属化合物の使用方法
WO2004046214A2 (en) 2002-10-15 2004-06-03 Exxonmobil Chemical Patents Inc. Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7541402B2 (en) * 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
US7223822B2 (en) * 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US7550528B2 (en) * 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
CN112552428B (zh) * 2019-09-25 2022-08-05 中国石油天然气股份有限公司 茂金属催化剂及其制备方法与应用

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA844157B (en) 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
US5700749A (en) * 1986-09-24 1997-12-23 Mitsui Petrochemical Industries, Ltd. Process for polymerizing olefins
IL85097A (en) 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5003019A (en) 1987-03-02 1991-03-26 Mitsui Petrochemical Industries, Ltd. Cyclo-olefinic random copolymer, olefinic random copolymer, and process for producing cyclo-olefinic random copolymers
CA2027145C (en) 1989-10-10 2002-12-10 Michael J. Elder Metallocene catalysts with lewis acids and aluminum alkyls
ATE137247T1 (de) 1989-10-30 1996-05-15 Fina Technology Addition von alkylaluminium zum verbessern eines metallocenkatalysators
JP3048653B2 (ja) * 1991-02-07 2000-06-05 三菱化学株式会社 α‐オレフィン重合体の製造
EP0578838A1 (en) 1992-04-29 1994-01-19 Hoechst Aktiengesellschaft Olefin polymerization catalyst, process for its preparation, and its use
EP0567952B1 (en) 1992-04-29 1997-12-03 Hoechst Aktiengesellschaft Olefin polymerization catalyst, process for its preparation, and its use
IT1256603B (it) 1992-10-30 1995-12-12 Enichem Polimeri Catalizzatore e procedimento per (co) polimerizzare le alfa-olefine
IT1273420B (it) * 1994-04-06 1997-07-08 Spherilene Srl Composti metallocenici, procedimento per la preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
US5597935A (en) * 1994-06-01 1997-01-28 University Of Iowa Research Foundation Synthesis of ansa-metallocene catalysts
US5594081A (en) * 1994-07-22 1997-01-14 Mitsubishi Chemical Corporation Catalyst component for the polymerization of α-olefins and a process for preparing α-olefin polymers with use of same

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6072014A (en) * 1997-10-17 2000-06-06 Sri International Multimodal polymer compositions prepared using multinuclear metallocene catalysts
US6232256B1 (en) * 1998-01-29 2001-05-15 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for the polymerization of olefins
US6455458B1 (en) 1998-07-10 2002-09-24 Exxonmobil Chemical Patents Inc. Tethered monocyclopentadienyl polymerization catalysts
US6544919B1 (en) 1999-10-06 2003-04-08 Sri International Multinuclear transition metal catalysts for preparation of multimodal polymer compositions
US6943226B2 (en) 1999-10-06 2005-09-13 Sri International Multinuclear transition metal catalysts for preparation of multimodal polymer compositions

Also Published As

Publication number Publication date
EP0779295A1 (de) 1997-06-18
US6040469A (en) 2000-03-21
KR970042567A (ko) 1997-07-24
DE59611121D1 (de) 2004-11-25
JPH09183788A (ja) 1997-07-15
CN1347921A (zh) 2002-05-08
ATE280175T1 (de) 2004-11-15
DE19546501A1 (de) 1997-06-19
NO965328D0 (no) 1996-12-12
NO965328L (no) 1997-06-16
AU7421896A (en) 1997-06-19
CN1074421C (zh) 2001-11-07
CN1159449A (zh) 1997-09-17
EP0779295B1 (de) 2004-10-20
BR9605977A (pt) 1998-08-25
JP4165720B2 (ja) 2008-10-15

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Legal Events

Date Code Title Description
FZDE Discontinued