NO965328L - Metallocenforbindelser - Google Patents

Metallocenforbindelser

Info

Publication number
NO965328L
NO965328L NO965328A NO965328A NO965328L NO 965328 L NO965328 L NO 965328L NO 965328 A NO965328 A NO 965328A NO 965328 A NO965328 A NO 965328A NO 965328 L NO965328 L NO 965328L
Authority
NO
Norway
Prior art keywords
formula
polyolefins
metallocene
compounds
catalysts
Prior art date
Application number
NO965328A
Other languages
English (en)
Other versions
NO965328D0 (no
Inventor
Michael Riedel
Thomas Weller
Alexandra Jacobs
Wolfgang Anton Herrmann
Markus Morawietz
Original Assignee
Hoechst Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst Ag filed Critical Hoechst Ag
Publication of NO965328D0 publication Critical patent/NO965328D0/no
Publication of NO965328L publication Critical patent/NO965328L/no

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642Component covered by group C08F4/64 with an organo-aluminium compound
    • C08F4/6428Component covered by group C08F4/64 with an organo-aluminium compound with an aluminoxane, i.e. a compound containing an Al-O-Al- group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Metallocenforbindelser En metallocenforblndelse med formel I, hvor Cp betyr en usubstituert eller substituert cyklopentadienylgruppe, Ind er en usuhstituert eller substituert Indyl, M er et flreverdig metall, R^, R^, r3 og R^ er uavhengig av hverandre Ilke eller forskjel- lige og er et hydrogenatom eller en Cj^-C2o-hydrokarbon- rest, r5 og R^ er uavhengig av hverandre Ilke eller forskjellige og er et hydrogenatom eller en C2-C20- hydrokarbonrest og m er Ilk 1 eller 2, Idet når m er Ilk 1 er k og 1 Ilk 1 og når m er Ilk 2, er k og 1 Ilk null, er beskrevet. Metallocenforbindelsene egner seg som katalysatorkomponenter for olefinpolymerisasjon.
NO965328A 1995-12-13 1996-12-12 Metallocenforbindelser NO965328L (no)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19546501A DE19546501A1 (de) 1995-12-13 1995-12-13 Metallocenverbindung

Publications (2)

Publication Number Publication Date
NO965328D0 NO965328D0 (no) 1996-12-12
NO965328L true NO965328L (no) 1997-06-16

Family

ID=7779983

Family Applications (1)

Application Number Title Priority Date Filing Date
NO965328A NO965328L (no) 1995-12-13 1996-12-12 Metallocenforbindelser

Country Status (11)

Country Link
US (1) US6040469A (no)
EP (1) EP0779295B1 (no)
JP (1) JP4165720B2 (no)
KR (1) KR970042567A (no)
CN (2) CN1074421C (no)
AT (1) ATE280175T1 (no)
AU (1) AU7421896A (no)
BR (1) BR9605977A (no)
CA (1) CA2192770A1 (no)
DE (2) DE19546501A1 (no)
NO (1) NO965328L (no)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3566819B2 (ja) * 1996-10-04 2004-09-15 関東化学株式会社 新規な有機遷移金属化合物
US6235917B1 (en) 1998-08-28 2001-05-22 The Dow Chemical Company Dinuclear complexes and polymerization catalysts therefrom
US6284698B1 (en) 1997-09-15 2001-09-04 The Dow Chemical Company Highly activated bimetallic complexes and polymerization process
KR20010024020A (ko) * 1997-09-15 2001-03-26 그래햄 이. 테일러 2-금속 착체 및 이로부터 제조된 중합 촉매
US5892079A (en) * 1997-10-17 1999-04-06 Sri International Metallocene catalysts and associated methods of preparation and use
US6096677A (en) * 1997-10-17 2000-08-01 Sri International Supported metallocene catalysts
US5986024A (en) * 1997-10-17 1999-11-16 Sri International Preparation of multimodal polymer compositions using multinuclear metallocene catalysts
EP0933383A1 (en) * 1998-01-29 1999-08-04 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for the polymerization of olefins
WO2000002891A1 (en) 1998-07-10 2000-01-20 Exxon Chemical Patents Inc. Tethered monocyclopentadienyl polymerization catalysts
EP0985677A1 (en) * 1998-09-07 2000-03-15 Industrial Technology Research Institute Dinuclear metallocene catalyst for olefin polymerization
US6544919B1 (en) 1999-10-06 2003-04-08 Sri International Multinuclear transition metal catalysts for preparation of multimodal polymer compositions
IT1314261B1 (it) * 1999-12-03 2002-12-06 Enichem Spa Composti metallocenici pontati, processo per la loro preparazione eloro uso come catalizzatori per la polimerizzazione di olefine.
JP2002338617A (ja) * 2001-05-22 2002-11-27 Sumitomo Chem Co Ltd ビニル化合物重合用触媒成分、ビニル化合物重合用触媒、ビニル化合物重合体の製造方法および遷移金属化合物の使用方法
US7541402B2 (en) * 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
US7550528B2 (en) * 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7223822B2 (en) * 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
CA2499951C (en) 2002-10-15 2013-05-28 Peijun Jiang Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
CN112552428B (zh) * 2019-09-25 2022-08-05 中国石油天然气股份有限公司 茂金属催化剂及其制备方法与应用

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA844157B (en) 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
US5700749A (en) * 1986-09-24 1997-12-23 Mitsui Petrochemical Industries, Ltd. Process for polymerizing olefins
IL85097A (en) 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5003019A (en) 1987-03-02 1991-03-26 Mitsui Petrochemical Industries, Ltd. Cyclo-olefinic random copolymer, olefinic random copolymer, and process for producing cyclo-olefinic random copolymers
ES2087145T3 (es) 1989-10-10 1996-07-16 Fina Technology Catalizadores metalocenos con acidos de lewis y alkilo-aluminios.
ES2086397T5 (es) 1989-10-30 2005-07-16 Fina Technology, Inc. Adicion de alkiloaluminio para un catalizador metaloceno mejorado.
JP3048653B2 (ja) * 1991-02-07 2000-06-05 三菱化学株式会社 α‐オレフィン重合体の製造
EP0578838A1 (en) 1992-04-29 1994-01-19 Hoechst Aktiengesellschaft Olefin polymerization catalyst, process for its preparation, and its use
EP0567952B1 (en) 1992-04-29 1997-12-03 Hoechst Aktiengesellschaft Olefin polymerization catalyst, process for its preparation, and its use
IT1256603B (it) 1992-10-30 1995-12-12 Enichem Polimeri Catalizzatore e procedimento per (co) polimerizzare le alfa-olefine
IT1273420B (it) * 1994-04-06 1997-07-08 Spherilene Srl Composti metallocenici, procedimento per la preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
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Also Published As

Publication number Publication date
AU7421896A (en) 1997-06-19
EP0779295A1 (de) 1997-06-18
CA2192770A1 (en) 1997-06-14
DE59611121D1 (de) 2004-11-25
BR9605977A (pt) 1998-08-25
EP0779295B1 (de) 2004-10-20
ATE280175T1 (de) 2004-11-15
KR970042567A (ko) 1997-07-24
CN1347921A (zh) 2002-05-08
DE19546501A1 (de) 1997-06-19
JP4165720B2 (ja) 2008-10-15
US6040469A (en) 2000-03-21
CN1159449A (zh) 1997-09-17
CN1074421C (zh) 2001-11-07
NO965328D0 (no) 1996-12-12
JPH09183788A (ja) 1997-07-15

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