KR960702630A - 보족 표면 한정된 중합체 일렉트로크로믹 물질, 시스템 및 그의 제조방법(complementary surface confined polymer electrochromic materials, systems, and methods of fabrication thereof) - Google Patents

보족 표면 한정된 중합체 일렉트로크로믹 물질, 시스템 및 그의 제조방법(complementary surface confined polymer electrochromic materials, systems, and methods of fabrication thereof)

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KR960702630A
KR960702630A KR1019950704346A KR19950704346A KR960702630A KR 960702630 A KR960702630 A KR 960702630A KR 1019950704346 A KR1019950704346 A KR 1019950704346A KR 19950704346 A KR19950704346 A KR 19950704346A KR 960702630 A KR960702630 A KR 960702630A
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electrochromic
group
bis
phenanthroline
heteroaromatic
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KR1019950704346A
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KR100350602B1 (ko
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레벤티스 니콜라스
시이. 청 영
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리차아드 제이 피텔류우스키
아이젠 인코포레이팃드
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Publication of KR960702630A publication Critical patent/KR960702630A/ko
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
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Abstract

전극 표면 한정된 보족 중합체 일렉트로크로믹 물질을 갖는 일렉트로크로믹 장치(100), 산화에 따라 실질적으로 무색 상태로부터 유색 상태로 변할 수 있는 일렉트로크로믹 물질(20)이 유리 지지체(30)상에 있는 전극(25)상에 표면 한정된다. 투과성 일렉트로크로믹 장치의 경우에는, (25)가 ITO와 같은 투명한 전극인 것이 바람직하다. 반사성 일렉트로크로믹 장치의 경우에는, (25)가 Pt코우팅인 것이 바람직하다. 환원에 따라 실질적으로 무색 상태로부터 유색 상태로 변할 수 있는 일렉트로크로믹 물질(20), 및 일렉트로크로믹 물질(35)은 물리적으로 서로 분리되어 있지만 전극에 의해 이온적으로 연결되어 있다. 두개 유리 지지체(30)는 함께 배치되고 가스켓(45)이 각각의 유리 지지체(30)를 지지하고, 각각의 일렉트로크로믹 물질(20) 및 (30)은 서로 떨어져 있다.

Description

보족 표면 한정된 중합체 일렉트로크로믹 물질, 시스템 및 그의 제조방법 (COMPLEMENTARY SURFACE CONFINED POLYMER ELECTROCHROMIC MATERIALS, SYSTEMS, AND METHODS OF FABRICATION THEREOF)
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제1도는 본 발명의 바람직한 실시양태에 따라 보족 일렉트로크로믹 시스템을 사용하는 조립된 일렉트로크로믹 장치의 개략적인 단면도이다.

Claims (73)

  1. 이온 전도성 용액 내 제1 및 제2전극 표면 한정된 일렉트로크로믹 물질을 포함하는 일렉트로크로믹 장치로서, 상기 제1일렉트로크로믹 물질은 환원에 따라 실질적으로 무색 상태로부터 유색 상태로 변할 수 있는 중합체 일렉트로크로믹 물질을 포함하고 및 상기 제2일렉트로크로믹 물질은 산화에 따라 실질적으로 무색 상태로부터 유색 상태로 변할 수 있는 일렉트로크로믹 물질을 포함하는 일렉트로크로믹 장치.
  2. 제1항에 있어서, 환원에 따라 실질적으로 무색 상태로부터 유색 상태로 변할 수 있는 상기 중합체 일렉트로크로믹 물질이 하나 이상의 사차화된 질소 원자 군을 함유하는 헤테로방향족 물질인 장치.
  3. 제2항에 있어서, 상기 헤테로방향족 물질을 4,4′-비피리딘, 2,2′-비피리딘, 4,9-디아자플루오렌 및 3,7-디아자플루오렌의 군으로부터 얻는 장치.
  4. 제2항에 있어서, 상기 헤테로방향족 물질이 융합된 방향족 고리 폴리방향족 물질인 장치.
  5. 제4항에 있어서, 상기 융합된 방향족 고리 폴리방향족 물질을 1,10-페난트롤린, 1,7-페난트롤린, 4,7-페난트롤린, 3,8-페난트롤린, 2,7-디아자피렌, 및 2,9-디아자페로피렌의 군으로부더 얻는 장치.
  6. 제2항에 있어서, 상기 하나 이상의 사차화된 질소 원자 군이 트리알콕시실릴 기로부터 유도된 하나 이상의 교차-결합제를 포함하는 장치.
  7. 제6항에 있어서, 헤테로방향족 물질이 N,N′-비스[p-(트리메톡시실릴)벤질]-4,4′-비피리디늄 디클로라이드, N,N′-비스[3-(트리메톡시실릴)프로필]-4,4′-비피리디늄 디브로마이드, N,N′-비스[p-(트리메톡시실릴)프로필]-2,7-디아자피레늄디클로라이드 또는 N,N′-비스[3-(트리메톡시실릴)르포릴]-2,7-디아자피레늄 디브로마이드로부터 유도되는 장치.
  8. 제1항에 있어서, 상기 제2일렉트로크로믹 물질이 중합체를 포함하는 장치.
  9. 제8항에 있어서, 상기 중합체가 트리알콕시실릴 기로부터 유도된 하나 이상의 교차-결합제를 포함하는 장치.
  10. 제9항에 있어서, 상기 중합체가 티오닌, 옥사진, 메틸렌블루, 페닐페나지늄 염, 알킬페나지늄 염으로부터 유도되는 장치.
  11. 제10항에 있어서, 상기 제1일렉트로크로믹 물질이 하나 이상의 사차화된 질소 원자 군을 함유하는 헤테로방향족 물질을 포함하는 장치.
  12. 제11항에 있어서, 상기 하나 이상의 사차화된 질소 원자 군이 트리알콕시실릴 기로부터 유도된 하나이상의 교차-결합제를 포함하는 장치.
  13. 제11항에 있어서, 상기 헤테로방향족 물질을 4,4′-비피리딘, 2,2′-비피리딘, 4,9-디아자플루오렌 및 3,7-디아자플루오렌의 군으로부터 얻는 장치.
  14. 제11항에 있어서, 상기 헤테로방향족 물질이 융합된 방향족 고리 폴리방향족 물질인 장치.
  15. 제14항에 있어서, 상기 융합된 방향족 고리 폴리방향족 물질을 1,10-페난트롤린, 1,7-페난트롤린, 4,7-페난트롤린, 3,8-페난트롤린, 2,7-디아자피렌, 및 2,9-디아자페로피렌의 군으로부터 얻는 장치.
  16. 제11항에있어서, 헤테로방향족물질이 N,N′-비스[p-(트리메톡시실릴)벤질]-4,4′-비피리디늄디클로라이드, N,N′-비스[3-(트리메톡시실릴)프로필]-4,4′-비피리디늄 디브로마이드, N,N′-비스[p-(트리메톡시실릴)벤질]-2,7-디아자피레늄 디클로라이드 또는 N,N′-비스[3-(트리메톡시실릴) 프로필]-2,7-디아자피레늄 디브로마이드로부터 유도되는 장치.
  17. 제1항에 있어서, 상기 제2일렉트로크로믹 물질이 금속 염을 포함하는 장치.
  18. 제17항에 있어서, 상기 제2일렉트로크로믹 물질이 감청을 포함하는 장치.
  19. 제18항에 있어서, 상기 제1일렉트로크로믹 물질이 하나 이상의 사차화된 질소 원자 군을 함유하는 헤테로방향족 물질을 포함하고 상기 하나 이상의 사차화된 질소 원자 군이 트리알콕시실릴 기로부터 유도된 하나이상의 교차-결합제를 포함하는 장치.
  20. 제19항에 있어서, 상기 헤테로방향족 물질을 4,4′-비피리딘, 2,2′-비피리딘, 4,9-디아자플루오렌 및 3,7-디아자플루오렌의 군으로부터 얻는 장치.
  21. 제19항에 있어서, 상기 헤테로방향족 물질이 융합된 방향족 고리 폴리방향족 물질인 장치.
  22. 제21항에 있어서, 상기 융합된 방향족 고리 폴리방향족 물질을 1,10-페난트롤린, 1,7-페난트롤린, 4,7-페난트롤린, 3,8-페난트롤린, 2,7-디아자피렌 및 2,9-디아자페로피렌의 군으로부터 얻는 장치.
  23. 제19항에있어서, 헤데로방향족물질이 N,N′-비스[p-(트리메톡시실릴)벤질]-4,4′-비피리디늄디클로라이드, N,N′-비스[3-(트리메톡시실릴)프로필]-4,4′-비피리디늄 디브로마이드, N,N′-비스[p-(트리메톡시실릴)벤질]-2,7-디아자피레늄 디클로라이드 또는 N,N′-비스[3-(트리메톡시실릴)프로필]-2,7-디아자피레늄 디브로마이드로부터 유도되는 장치.
  24. 실질적으로 산화에 따라 실질적으로 무색 상태로부터 유색 상태로 변할 수 있는 일렉트로크로믹 금속염 및 산화에 따라 실질적으로 전도될 수 있는 중합체 일렉트로크로믹 물질을 포함하는 산화에 따라 실질적으로 무색 상태로부터 유색 상태로 변할 수 있는 복합체 물질로 구성되고 전극 상에 한정된 표면인 제1일렉트로크로믹 물질; 환원에 따라 실질적으로 무색 상태로부터 유색 상태로 변할 수 있는 중합체 일렉트로크로믹 물질을 포함하고, 및 전극에 한정된 표면이고 상기 제1일렉트로크로믹 물질로부터 물질적으로 분리된 제2일렉트로크로믹 물질; 및 상기 제1 및 제2일렉트로크로믹 물질을 이온적으로 연결하지만 물리적으로 분리하는 전해질로 구성되는 일렉트로크로믹 장치.
  25. 제24항에 있어서, 상기 제1 및 제2일렉트로크로믹 물질이 동일한 지지체 상에 상면하고 나란하게 놓인 두개의 분리된 전극 상에 한정된 표면인 일렉트로크로믹 장치.
  26. 제24항에 있어서, 상기 제1 및 제2일렉트로크로믹 물질이 상기 사이에 삽입된 상기 전해질과 대항하는 배열 내 배치된 각각의 분리된 제1 및 제2지지체 상 한정된 표면인 일렉트로크로믹 장치.
  27. 제24항에 있어서, 상기 금속 염이 감청인 일렉트로크로믹 장치.
  28. 제24항에 있어서, 산화에 따라 실질적으로 전도할 수 있는 상기 중합체 일렉트로크로믹 물질을 폴리피롤, 폴리(N-메틸)피롤, 폴리(N-페닐)피롤, 폴리N-[3-트리메톡시실릴)프로필]피롤, 폴리아닐린, 폴리티오펜, 폴리(3-메틸)티오펜, 폴리아줄렌, 폴리피렌의 군으로부터 얻는 일렉트로크로믹 장치.
  29. 제24항에 있어서, 환원에 따라 실질적으로 무색 상태로부터 유도색 상태로 변할 수 있는 상기 중합체 일렉트로크로믹 물질이 하나 이상의 사차화된 질소 원자 군을 함유하는 헤테로방향족 물질인 일렉트로크로믹 장치.
  30. 제29항에 있어서, 상기 헤테로방향족물질을 4,4′-비피리딘, 2,2′-비피리딘, 4,9-디아자플루오렌 및 3,7-디아자플루오렌의 군으로부터 얻는 장치.
  31. 제29항에 있어서, 상기 헤테로방향족 물질이 융합된 방향족 고리 폴리방향족 물질인 장치.
  32. 제31항에 있어서, 상기 융합된 방향족 고리 폴리방향족 물질을 1,10-페난트롤린, 1,7-페난트롤린, 4,7-페난트롤린, 3,8-페난트롤린, 2,7-디아자피렌, 및 2,9-디아자페로피렌의 군으로부터 얻는 장치.
  33. 제29항에 있어서, 헤테로방향족 물질의 하나 이상의 사차화된 군이 트리알콕시실릴 기로부터 유도된 하나 이상의 교차-결합제를 포함하는 일렉트로크로믹 장치.
  34. 제33항에 있어서, 중합체일렉트로크로믹물질이 N,N′-비스[p-(트리메톡시실릴)벤질]-4,4′-비피리디늄디클로라이드, N,N′-비스[3-(트리메톡시실릴)프로필]-4,4′-비피리디늄 디브로마이드, N,N′-비스[p-(트리메톡시실릴)벤질]-2,7-디 아자피레늄 디클로라이드 또는 N,N′-비스[3-(트리메톡시실릴)프로필]-2,7-디아자피레늄 디브로마이드로부터 유도되는 일렉트로크로믹 장치.
  35. 실질적으로 중성 pH에서 이온 전도성 용액 내 상기 전도성 지지체상에 중합체 일렉트로크로믹 물질을 전기부착하는 단계로 구성되는, 전도성 지지체 상에 중합체 일렉트로크로믹 물질을 표면 한정시키는 방법.
  36. 제35항에 있어서, pH가 약 5-9 사이의 범위인 방법.
  37. 제35항에 있어서, 중합체 일렉트로크로믹 물질이 하나 이상의 사차화 질소 원자 군을 함유하는 헤테로방향족 물질인 방법.
  38. 제37항에 있어서, 상기 헤테로방향족물질을 4,4′-비피리딘, 2,2′-비피리딘, 4,9-디아자플루오렌 및 3,7-디아자플루오렌의 군으로부터 얻는 방법.
  39. 제37항에 있어서, 상기 헤테로방향족 물질이 융합된 방향족 고리 폴리방향족 물질인 방법.
  40. 제39항에 있어서, 상기 융합뒨 방향족 고리 폴리방향족 물질을 1,10-페난트롤린, 1,7-페난트롤린, 4,7-페난트롤린, 3,8-페난트롤린, 2,7-디아자피렌, 및 2,9-디아자페로피렌의 군으로부터 얻는 방법.
  41. 제37항에 있어서, 헤테로방향족 물질의 하나 이상의 사차화된 군이 트리알콕시실릴 기로부터 유도된 하나의 교차-결합제를 포함하는 방법.
  42. 제37항에 있어서, 중합체 일렉트로크로믹 물질이 N,N′-비스[p-(트리메톡시실릴)벤질]-4.4′-비피리디늄 디클로라이드, N,N′-비스[3-(트리메톡시실릴)프로필]-4,4′-비피리디늄 디브로마이드, N,N′-비스[p-(트리메톡시실릴)벤질]-2,7-디아자피레늄 디클로라이드 또는 N,N′-비스[3-(트리메톡시실릴)프로필]-2,7-디아자피레늄 디브로마이드로부터 유도되는 방법.
  43. 제35항에 있어서, 이온 전도성 용액이 약 7의 범위내로 pH를 조정한 염 M의 수용액으로서, 이매 M을 군 K2SO4, KCl, NaC1, LiCl, NaClO4, LiClO4, CF3SO2Li, KH2PO4/K2HPO4완충액으로부터 얻는 방법.
  44. 제35항에 있어서, 수용액이 0.05몰농도 내지 1.5몰농도 범위내 농도를 갖는 방법.
  45. 적어도 대략 2,000Å의 두께를 갖는 안정하고 강하게 부착된 표면 한정된 4,4′-비피리듐 유도체를 포함하는 전도성 지지체로 구성되는 일렉트로크로믹 장치.
  46. 제45항에 있어서, 상기 한정된 4,4′-비피리듐 유도체가 트리알콕실릴 기를 포함하는 장치.
  47. 제62항에있어서, 물질이 N,N′-비스[p-(트리메톡시실릴)벤질]-4,4′-비피리디늄 디클로라이드 또는 N, N′-비스[3-(트리메톡시실릴)프로필]-4,4′-비피리디늄 디브로마이드로부터 유도되는 장치.
  48. 그위에 금속성 산화물의 층 및 강하게 부착된 전극 표면 한정된 중합체 일렉트로크로믹 물질 층을 갖는 적어도 대략 2,000Å의 두께를 갖는 하나 이상의 지지체, 및 을 포함하는 일렉트로크로믹 장치.
  49. 제48항에 있어서, 상기 중합체 일렉트로크로믹 물질이 하나 이상의 사차화된 질소 원자 군을 함유하는 헤테로방향족 물질인 장치.
  50. 제49항에 있어서, 상기 헤테로방향족물질을 4,4′-비피리딘, 2,2′-비피리딘, 4,9-디아자플루오렌 및 3,7-디아자플루오렌의 군으로부터 얻는 장치.
  51. 제49항에 있어서, 상기 헤테로방향족 물질이 융합된 방향족 고리 폴리방향족 물질인 장치.
  52. 제51항예 있어서, 상기 융합된 방향족 고리 폴리방향족 물질을 1,10-페난트롤린, 1,7-페난트롤린, 4,7-페난트롤린, 3,8-페난트롤린, 2,7-디아자피렌, 및 2,9-디아자페로피렌의 군으로부터 얻는 장치.
  53. 제48항에 있어서, 상기 한정된 중합체 일렉트로크로믹 물질이 트리알콕시실릴 기로부터 유도된 하나 이상의 교차-결합제를 포함하는 장치.
  54. 제53항에 있어서, 한정된 중합체 일렉트로크로믹 물질이 N,N′-비스[p-(트리메톡시실릴)벤질]-4,4′-비피리디늄 디클로라이드, N,N′-비스[3-(트리메톡시실릴)프로필]-4,4′-비피리디늄 디브로마이드, N,N′-비스[p-(트리메톡시실릴)벤질]-2,7-디아자피레늄 디클로라이드 또는 N,N′-비스[3-(트리메톡시실릴)프로필]-2,7-디아자피레늄 디브로마이드로부터 유도되는 장치.
  55. 제48항에 있어서, 상기 일렉트로크로믹 금속성 산화물이 환원에 따라 실질적으로 무색 상태로부터 유색상태로 변할 수 있고 성분으로서 텅스텐, 몰리브데늄, 니오븀, 바나듐 및 티타늄의 군으로부터 얻은 금속을 포함하는 장치.
  56. 제55항에 있어서, 상기 일렉트로크로믹 금속성 산화물이 텅스텐 삼산화물인 장치.
  57. 상기의 산화환원 상태 중 적어도 하나에서 전도성인 일렉트로크로믹 금속성 산화물의 층을 상기 전도성 지지체 상에 부착하고, 및 그리고 나서 중합체 일렉트로크로믹 물질을 이온 전도성 용액 내 상기 금속성 산화물상에 전기부착시키는 단계로 구성되는, 전도성 지지체 상에 다중 층으로 일렉트로크로믹 물질을 표면 한정시키는 방법.
  58. 제57항에 있어서, 상기 일렉트로크로믹 금속성 산화물이 스퍼터링에 의해 부착되는 방법.
  59. 제57항에 있어서, 상기 일렉트로크로믹 금속성 산화물이 환원에 따라 실질적으로 무색 상태로부터 유색상태로 변할 수 있고 성분으로서 텅스텐, 몰리브데늄, 니오븀, 바나듐 및 티타늄의 군으로부터 얻은 금속을 포함하는 방법.
  60. 제59항에 있어서, 상기 일렉트로크로믹 금속성 산화물이 텅스텐 삼산화물인 방법.
  61. 제57항에 있어서, 상기 중합체 일렉트로크로믹 물질이 하나 이상의 사차화된 질소 원자 군을 함유하는 헤테로방향족 물질인 방법.
  62. 제61항에 있어서, 상기 헤테로방향족 물질을 4,4′-비피리딘, 2,2′-비피리딘, 4,9-디아자플루오렌 및 3,7-디아자플루오렌의 군으로부터 얻는 방법.
  63. 제61항에 있어서, 상기 헤테로방향족 물질이 융합된 방향족 고리 폴리방향족 물질인 방법.
  64. 제63항에 있어서, 상기 융합된 방향족 고리 폴리방향족 물질을 1,10-페난트롤린, 1,7-페난트롤린, 4,7-페난트롤린, 3,8-페난트롤린, 2.7-디아자피렌, 및 2,9-디아자페로피렌의 군으로부터 얻는 방법.
  65. 제61항에 있어서, 상기 하나 이상의 사차화된 질소 원자 군이 트리알콕시실릴 기로부터 유도된 하나이상의 교차-결합제를 포함하는 방법.
  66. 제65항에 있어서, 중합체 일렉트로크로믹 물질이 N,N′-비스[p-(트리메톡시실릴)벤질]-4,4′-비피리디늄 디클로라이드, N,N′-비스[3-(트리메톡시실릴)프로필]-4,4′-비피리디늄 디브로마이드, N,N′-비스[p-(트리메톡시실릴)벤질]-2,7-디아자피레늄 디클로라이드 또는 N,N′-비스[3-(트리메톡시실릴)프로필]-2,7-디아자피레늄 디브로마이드로부터 유도되는 방법.
  67. 제57항에 있어서, 이온 전도성 용액이 수성이고 pH를 약 5-9의 범위내로 조정되는 방법.
  68. 제57항에 있어서, 이온 전도성 용액이 약 7의 범위내로 pH를 조정한 염 M의 수용액으로서, 이때 M을 군 K2SO4, KCl, NaCl, LiCl〈 KH2PO4/K2HPO4완충액, NaClO4, LiClO4, CF3SO2Li로부터 얻은 방법.
  69. 제55항에 있어서, 수용액이 0.05 몰농도 내지 1.5 몰농도 범위내 농도를 갖는 방법.
  70. 하나 이상의 부분 투과성 일렉트로크로믹 패널 및 광전지를 구성되는 자기-전력공급 및 자기-조정 일렉트로크로믹 장치로서, 상기 광전지가 기대된 광원으로부터 상기 패널의 반대편 상에 있고 상기 기대된 광원에 직면하도록 배치되고, 상기 광전지가 상기 일렉트로크로믹 패널에 전기적으로 연결되어서 상기 광전지로부터 증가된 전기적 출력이 상기 일렉트로크로믹 패널의 착색 정도를 증가시키는 경향이 있고, 그럼으로써 상기 패널을 통해 상기 광전지 상으로 통과하는 빛의 양을 감소시키는 경향이 있는 자기-전력 공급 및 자기-조정 일렉트로크로믹 장치.
  71. 그위에 일렉트로크로믹 물질의 코우팅을 포함하는 하나 이상의 부분 투과성 렌즈 및 광전지로 구성되는 자기-전력공급 및 자기-조정 일렉트로로크로믹 브안 유리로서, 상기 광전지가 상기 렌즈를 통해 직면해 있는 상기의 후면 상 배치되고 상기 렌즈 상 상기 일렉트로크로믹 물질 코우팅에 전기적으로 연결되어서 상기 광전지로부터 증가된 전기적 출럭이 상기 일렉트로크로믹 물질의 착색 정도를 증가시키는 경향이 있고, 그럼으로써 상기 렌즈를 통해 상기 광전지 상으로 통과하는 빛의 양을 감소시키는 경향이 있는 자기-전력공급 및 자기-조정 일렉트로크로믹 보안 유리.
  72. 그위에 일렉트로크로믹 물질의 코우팅을 포함하는 하나 이상의 부분 투과성 패널 및 광전지로 구성되는 자기-전력공급 및 자기-조정 일렉트로크로믹 창으로서, 상기 광전지가 상기 패널의 내부 상에 배치되어 있고 상기 패널을 통해 기대된 광원에 직면하고 상기 패널 상 상기 일렉트로크로믹 물질 코우팅에 전기적으로 연결되어서 상기 광전지로부터 증가된 전기적 출력이 상기 일렉트로크로믹 물질의 착색 정도를 증가시키는 경향이 있고, 그럼으로써 상기 패널을 통해 상기 광전지 상으로 통과하는 빛의 양을 감소시키는 경향이 있는 자기-전력공급 및 자기-조정 일렉트로크로믹 창.
  73. 하나 이상의 부분 반사 금속성 물질의 코우팅, 일렉트로크로믹 물질의 코우팅을 갖는 하나 이상의 부분 투과성 패널 및 상기 패널 및 상기 일렉트로크로믹 물질의 상기 코우팅의 하나 이상의 부분에서 뒤에 배치되지만 상기 적어도 부분적으로 반사 금속성 물질에 의해 은폐되지 않아서 상기는 상기 일렉트로크로믹 물질 코우팅을 통해 통과하는 빛을 수용할 광전지로 구성되는 자기-전력공급 및 자기-조정 일렉트로크로믹 거울로서, 상기 광전지가 상기 패널 상 상기 일렉트로크로믹 물질 코우팅에 전기적으로 연결되어 상기 광전지로부터 증가된 전기적 출력이 상기 일렉트로크로믹 물질의 착색 정도를 증가시키는 경향이 있고, 그럼으로써 상기 일렉트로크로믹 물질을 통해 및 상기 광전지 상으로 통과하는 빛의 양을 감소시키는 경향이 있는 자기-전력공급 및 자기-조정 일렉트로크로믹 거울.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950704346A 1993-04-05 1994-04-04 상보적으로표면한정된중합체일렉트로크로믹물질,시스템및그의제조방법 KR100350602B1 (ko)

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