KR960041416A - 실리콘 산화물층의 증착 방법 - Google Patents

실리콘 산화물층의 증착 방법 Download PDF

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Publication number
KR960041416A
KR960041416A KR1019960013434A KR19960013434A KR960041416A KR 960041416 A KR960041416 A KR 960041416A KR 1019960013434 A KR1019960013434 A KR 1019960013434A KR 19960013434 A KR19960013434 A KR 19960013434A KR 960041416 A KR960041416 A KR 960041416A
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KR
South Korea
Prior art keywords
gas flow
teos
ozone
silicon oxide
oxide layer
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KR1019960013434A
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English (en)
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KR100385003B1 (ko
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츠보니미르 가브릭
오스발트 슈핀들러
Original Assignee
알베르트 발도르프·롤프 옴케
지멘스 악티엔게젤샤프트
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Publication of KR960041416A publication Critical patent/KR960041416A/ko
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Publication of KR100385003B1 publication Critical patent/KR100385003B1/ko

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
    • C23C16/45523—Pulsed gas flow or change of composition over time
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/40—Oxides
    • C23C16/401—Oxides containing silicon
    • C23C16/402—Silicon dioxide

Abstract

본 발명에서는 테트라 에틸 오르토 실리케이트 (TEOS)를 사용한 오존 활성화 기상 증착 방법에 의해 실리콘 산화물층을 증착하는 방법이 제공된다. 상기 방법에서 TEOS 대 오존의 초기의 높은 가스 흐름 비율은 점차적으로 낮은 고정 비율로 변동된다. 그럼으로써 균질의 실리콘 산화물층이 형성된다.

Description

실리콘 산화물층의 증착 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 테트라 에틸 오르토 실리케이트 (TEOS)를 사용한 오존 활성화된 기상 증착 방법에 의해 실리콘 산화물층을 증착하는 방법에 있어서, TEOS 대 오존의 초기의 높은 가스 흐름 비율이 점차적으로 낮은 고정 비율로 변화되도록구성된 실리콘 산화물층의 증착 방법.
  2. 제1항에 있어서, 초기에는 TEOS가스 흐름이 오존 가스 흐름의 수배이고, 고정 비율일 때는 오존 가스흐름이 TEOS 가스 흐름의 수배인 것을 특징으로 하는 실리콘 산화물층의 증착 방법.
  3. 제1항 또는 2항에 있어서, 초기의 조건으로부터 TEOS가스 흐름이 감소되고 오존 가스 흐름이 증가되는 것을 특징으로 하는 실리콘 산화물층의 증착 방법.
  4. 제1항 또는 2항에 있어서, 초기 비율로부터 먼저 오존 함유 가스 흐름이 증가하고 TEOS 가스 흐름이 일정하게 유지되는 것을 특징으로 하는 실리콘 산화물층의 증착 방법.
  5. 제1항 내지 4항 중 어느 한 항에 있어서, 가스 흐름의 고정 비율은 대략 1분 30초 후에 얻어지는 것을 특징으로 하는 실리콘 산화물층의 증착 방법.
  6. 제1항 내지 5항 중 어느 한 항에 있어서, TEOS 대 오존의 가스흐름 비율의 변동이 연속적으로 이루어지는 것을 특징으로 하는 실리콘 산화물층의 증착 방법.
  7. 제1항 내지 5항중 어느 한 항에 있어서, TEOS 대 오존의 가스 흐름 비율의 변동이 단계적으로 이루어지는 것을 특징으로 하는 실리콘 산화물층의 증착 방법
  8. 제1항 내지 7항 중 어느 한 항에 있어서, 가스 흐름 비율의 변동이 초기에는 천천히 이루어지고, 그 다음에는 비선형으로 증가하는 것을 특징으로 하는 실리콘 산화물층의 증착 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960013434A 1995-05-05 1996-04-29 실리콘산화물층의증착방법 KR100385003B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19516669A DE19516669A1 (de) 1995-05-05 1995-05-05 Verfahren zur Abscheidung einer Siliziumoxidschicht
DE19516669.8 1995-05-05

Publications (2)

Publication Number Publication Date
KR960041416A true KR960041416A (ko) 1996-12-19
KR100385003B1 KR100385003B1 (ko) 2003-08-06

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KR1019960013434A KR100385003B1 (ko) 1995-05-05 1996-04-29 실리콘산화물층의증착방법

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Country Link
US (1) US5965203A (ko)
EP (1) EP0741196B1 (ko)
JP (1) JP3502504B2 (ko)
KR (1) KR100385003B1 (ko)
AT (1) ATE182926T1 (ko)
DE (2) DE19516669A1 (ko)
TW (1) TW424116B (ko)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR0144228B1 (ko) * 1995-03-04 1998-08-17 김주용 다층 금속배선의 층간 절연막 형성 방법
JP4498503B2 (ja) * 1999-10-29 2010-07-07 アプライド マテリアルズ インコーポレイテッド 薄膜形成装置及び薄膜形成方法
US6541369B2 (en) * 1999-12-07 2003-04-01 Applied Materials, Inc. Method and apparatus for reducing fixed charges in a semiconductor device
US6429092B1 (en) 2000-06-19 2002-08-06 Infineon Technologies Ag Collar formation by selective oxide deposition
TW479315B (en) * 2000-10-31 2002-03-11 Applied Materials Inc Continuous depostiton process
US7335609B2 (en) * 2004-08-27 2008-02-26 Applied Materials, Inc. Gap-fill depositions introducing hydroxyl-containing precursors in the formation of silicon containing dielectric materials
US6905940B2 (en) * 2002-09-19 2005-06-14 Applied Materials, Inc. Method using TEOS ramp-up during TEOS/ozone CVD for improved gap-fill
US7456116B2 (en) * 2002-09-19 2008-11-25 Applied Materials, Inc. Gap-fill depositions in the formation of silicon containing dielectric materials
US7141483B2 (en) * 2002-09-19 2006-11-28 Applied Materials, Inc. Nitrous oxide anneal of TEOS/ozone CVD for improved gapfill
US7431967B2 (en) * 2002-09-19 2008-10-07 Applied Materials, Inc. Limited thermal budget formation of PMD layers
CN100445423C (zh) * 2002-09-30 2008-12-24 凸版印刷株式会社 薄膜成膜方法、薄膜成膜装置和薄膜成膜过程的监视方法
JP4794800B2 (ja) * 2002-09-30 2011-10-19 凸版印刷株式会社 薄膜成膜方法および薄膜成膜装置
US7241703B2 (en) 2003-05-30 2007-07-10 Matsushita Electric Industrial Co., Ltd. Film forming method for semiconductor device
US7528051B2 (en) * 2004-05-14 2009-05-05 Applied Materials, Inc. Method of inducing stresses in the channel region of a transistor
US7642171B2 (en) 2004-08-04 2010-01-05 Applied Materials, Inc. Multi-step anneal of thin films for film densification and improved gap-fill
US9018108B2 (en) 2013-01-25 2015-04-28 Applied Materials, Inc. Low shrinkage dielectric films

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR870000750A (ko) * 1985-06-14 1987-02-20 이마드 마하윌리 이산화실리콘 필름을 화학적으로 증기피복하는 방법
DE3683039D1 (de) * 1986-04-04 1992-01-30 Ibm Deutschland Verfahren zum herstellen von silicium und sauerstoff enthaltenden schichten.
US5000113A (en) * 1986-12-19 1991-03-19 Applied Materials, Inc. Thermal CVD/PECVD reactor and use for thermal chemical vapor deposition of silicon dioxide and in-situ multi-step planarized process

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Publication number Publication date
JP3502504B2 (ja) 2004-03-02
DE59602585D1 (de) 1999-09-09
EP0741196A1 (de) 1996-11-06
EP0741196B1 (de) 1999-08-04
US5965203A (en) 1999-10-12
DE19516669A1 (de) 1996-11-07
JPH08306685A (ja) 1996-11-22
KR100385003B1 (ko) 2003-08-06
TW424116B (en) 2001-03-01
ATE182926T1 (de) 1999-08-15

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