KR960017710A - 코어 관능화된 성상 블록 공중합체 - Google Patents

코어 관능화된 성상 블록 공중합체 Download PDF

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KR960017710A
KR960017710A KR1019950040446A KR19950040446A KR960017710A KR 960017710 A KR960017710 A KR 960017710A KR 1019950040446 A KR1019950040446 A KR 1019950040446A KR 19950040446 A KR19950040446 A KR 19950040446A KR 960017710 A KR960017710 A KR 960017710A
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core
block copolymer
functional group
block
polymer
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KR1019950040446A
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KR100401300B1 (ko
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제임즈 헉스마이어 로널드
조오지 사우스윅 제프리
앤 스펜스 브리지트
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알베르루스 빌헬무스·요아네스 쩨스트라텐
셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/18—Introducing halogen atoms or halogen-containing groups

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Lubricants (AREA)

Abstract

본 발명은 i)적어도 한 블록의 비닐 방향족 탄화수소, 및/또는 ii)적어도 한 블록의 컨쥬게이트 디엔 및 iii)폴리알케닐 방향족 커플링제로 형성된 코어 관능화된 성상 블록 공중합체를 제공한다. 여기서, 코어 관능화는, 비대칭 이-또는 다관능의 캡핑제와 성상 중합체 코어를 반응시키므로써 제공된다.

Description

코어 관능화된 성상 블록 공중합체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. i)적어도 한 블록의 비닐 방향족 탄화수소, 및/또는 ii)적어도 한 블록의 컨쥬게이트 디엔 및 iii)폴리알케닐 방향족 커플링제로 형성된 코어 관능화된 성상 블록 공중합체로서, 상기 코어 관능화가, 중합체 코어와 반응하고 제2관능기를 통해 코어에 캡핑제 분자를 부착시킬 제2유형의 관능기 및 코어로부터 뻗어있는 제1유형의 관능기를 혼입하는 비대칭 이-또는 다관능의 캡핑제와 성상 중합체 코어를 반응시키므로써 제공되는 블록 공중합체.
  2. 제1항에 있어서, 캡핑제가 퍼플루오로알데히드, 퍼플루오로케톤, 퍼플루오로알카노일클로라이드, 퍼플루오로에스테르, 퍼플루오로에스테르에스테르, 포르밀에스테르, 폴리옥시알케닐렌 에스테르, 아미노알데히드, 메탈로센 알데히드, 알데히드의 에폭시드, 케톤의 디에폭시드, 및 실란의 에폭시드 유도체로 구성되는 군으로부터 선택된 블록 공중합체.
  3. 제1 또는 제2항에 있어서, 0.05∼10중량%의 제1유형의 관능기를 함유하는 블록 공중합체.
  4. 제1∼3항 중 어느 한 항에 있어서, 비닐 방향족 탄화수소가 스티렌인 블록 공중합체.
  5. 제1∼4항 중 어느 한 항에 있어서, 컨쥬게이트 디엔이 이소프렌 또는 부타디엔인 블록 공중합체.
  6. 제1∼5항 중 어느 한 항에 있어서, 50중량% 이하의 비닐 방향족 탄화수소를 포함하는 블록 공중합체.
  7. (a) 음이온성 중합에 의해 적어도 한 블록의 비닐 방향족 탄화수소 및/또는 적어도 한 블록의 컨쥬게이트 디엔의 적어도 한 세트의 중합체 아암을 제조하고, (b) 폴리알케닐 방향족 커플링제와 중합체 아암을 커플링하고, 커플링 반응을 종결하지 않고, (c) 제2관능기를 통해 코어에 캡핑제 분자를 부착하기 위해 중합체 코어와 반응하는 제2유형의 관능기 및 코어로부터 뻗어있는 제1유형의 관능기를 혼입하는 비대칭 이-또는 다관능의 캡핑제와 리빙 성상 중합체의 코어를 반응시키므로써 리빙 성상 중합체의 코어를 캡핑하며, (d) 캡핑 반응을 종결시키고, 중합체를 회수하는 것으로 구성되는 코어 관능화된 성상 블록 공중합체 제조 방법.
  8. 제7항에 있어서, 캡핑제가 퍼플루오로알데히드, 퍼플루오로케톤, 퍼플루오로알카노이를로라이드, 퍼플루오로에스테르, 퍼플루오로에테르에스테르, 포르밀에스테르, 폴리옥시알케닐렌 에스테르, 아미노알데히드, 메탈로센 알데히드, 알데히드의 에폭시드, 케톤의 디에폭시드 및 실란의 에폭시드 유도체로 구성되는 군으로부터 선택되는 방법.
  9. 제7 또는 제8항에 있어서, 0.05∼10중량% 의 캡핑제가 단계 (c)에서 사용되는 방법.
  10. 제7∼9항 중 어느 한 항에 있어서, 단계 (b)에서 적용되는 온도가 25∼95℃범위인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950040446A 1994-11-10 1995-11-09 코어관능화된성상블록공중합체 KR100401300B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/336,965 US5461116A (en) 1994-11-10 1994-11-10 Core functionalized star block copolymers
US336965 1994-11-10

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KR960017710A true KR960017710A (ko) 1996-06-17
KR100401300B1 KR100401300B1 (ko) 2003-12-18

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US (1) US5461116A (ko)
EP (1) EP0711789B1 (ko)
JP (1) JP3578848B2 (ko)
KR (1) KR100401300B1 (ko)
CN (1) CN1068346C (ko)
BR (1) BR9505119A (ko)
DE (1) DE69515102T2 (ko)
ES (1) ES2142450T3 (ko)
MX (1) MX9504681A (ko)
TR (1) TR199501404A2 (ko)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5830986A (en) * 1996-10-28 1998-11-03 Massachusetts Institute Of Technology Methods for the synthesis of functionalizable poly(ethylene oxide) star macromolecules
US6184422B1 (en) 1998-02-26 2001-02-06 Hoffman-La Roche Inc. Cyclohexanediol derivatives
FR2779728B1 (fr) * 1998-06-10 2001-04-13 Inst Francais Du Petrole Polymeres sequences greffes contenant au moins une sequence polyolefinique ou polydienique comportant un cycle succinimide substitue sur l'azote par un groupement reactif
DE19910810C2 (de) * 1999-03-11 2001-06-28 Bayer Ag Hydrophilierbare Blockcopolymere, Verfahren zu ihrer Herstellung und deren Verwendung
DE19910811C2 (de) * 1999-03-11 2002-11-14 Sunyx Surface Nanotechnologies Hydrophilierbare Blockcopolymere
ES2366577T3 (es) * 2001-07-18 2011-10-21 Asahi Kasei Chemicals Corporation Copolímero de bloques modificado.
KR100595336B1 (ko) * 2001-07-18 2006-06-30 아사히 가세이 케미칼즈 가부시키가이샤 개질 블록 공중합체
JP5594994B2 (ja) * 2009-08-31 2014-09-24 ダイキン工業株式会社 星形ポリマー
US8999905B2 (en) * 2010-10-25 2015-04-07 Afton Chemical Corporation Lubricant additive
CN103570851A (zh) * 2012-08-01 2014-02-12 中国石油化工股份有限公司 一种终止共轭二烯烃均聚反应的方法
CN103570874A (zh) * 2012-08-01 2014-02-12 中国石油化工股份有限公司 一种终止共轭二烯烃与乙烯基芳烃的共聚反应的方法
JP7484719B2 (ja) * 2018-11-30 2024-05-16 日本ゼオン株式会社 ブロック共重合体、ブロック共重合体組成物、ホットメルト粘接着剤組成物および粘接着剤組成物

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3692874A (en) * 1970-09-02 1972-09-19 Ralph C Farrar Process of coupling alkali metal-terminated polymers with silicic compound in presence of conjugated dienes
US4010226A (en) 1975-07-17 1977-03-01 Shell Oil Company Block polymers and their preparation
US4244862A (en) * 1976-02-05 1981-01-13 Denki Kagaku Kogyo Kabushiki Kaisha Compositions for paints and printing inks
US4141847A (en) * 1977-05-11 1979-02-27 Shell Oil Company Star-shaped polymer reacted with dicarboxylic acid and amine as dispersant viscosity index improver
US4222882A (en) * 1978-02-08 1980-09-16 Rhone-Poulenc Industries Polymers bearing groups derived from N-substituted lactams and their use as lubricating oil additives
US4229308A (en) * 1978-02-08 1980-10-21 Rhone-Poulenc Industries Polymer lubricating oil additives bearing nitrogen groups and their use as additives for lubricating oils
US4497748A (en) * 1981-07-13 1985-02-05 The General Tire & Rubber Company Preparation of lithium initiator for the preparation of star polymers
US4417029A (en) * 1981-08-03 1983-11-22 Atlantic Richfield Company Derivatization of star-block copolymers
US4409357A (en) * 1981-09-10 1983-10-11 Atlantic Richfield Company Footwear-compounds from derivatized star-block copolymers
US4391949A (en) 1981-11-12 1983-07-05 Shell Oil Company Asymmetric block copolymers and corresponding adhesive formulations
US4444953A (en) 1981-11-12 1984-04-24 Shell Oil Company Assymetric block copolymers and corresponding adhesive formulations
US4427834A (en) * 1981-12-21 1984-01-24 Shell Oil Company Dispersant-VI improver product
GB2144430B (en) * 1983-08-04 1986-11-19 Shell Int Research Hydrogenated modified star-shaped polymers
ATE67770T1 (de) * 1985-08-16 1991-10-15 Shell Int Research Modifizierte blockcopolymere, diese copolymere enthaltende zusammensetzungen und verfahren zur herstellung dieser copolymere.
IT1196517B (it) * 1986-07-17 1988-11-16 Montedipe Spa Copolimeri a blocco radiali e bimodali aventi ottime proprieta' ottiche e reistenza agli urti e processo per la loro preparazione
CA1281449C (en) * 1986-08-29 1991-03-12 Clyde S. Hutchins Hybrid acrylic star polymers and preparation
CA1335614C (en) * 1987-10-30 1995-05-16 Ronald James Hoxmeier Method for preparing asymmetric radial copolymers
US5104921A (en) 1988-02-17 1992-04-14 Shell Oil Company Radiation cured polymer composition
US4970265A (en) * 1989-03-27 1990-11-13 Shell Oil Company Functionalized polymers and process for modifying unsaturated polymers
JPH03190944A (ja) * 1989-12-20 1991-08-20 Nippon Zeon Co Ltd 耐摩耗性ゴム組成物
GB9002804D0 (en) * 1990-02-08 1990-04-04 Secr Defence Anionic polymerisation
US5212249A (en) * 1991-10-28 1993-05-18 Shell Oil Company Method for preparing asymmetric radial polymers
US5344887A (en) * 1992-12-21 1994-09-06 Shell Oil Company Star polymers of dienes, vinylarenes and alkyl methacrylates as modiied viscosity index improvers
US5369175A (en) * 1993-11-09 1994-11-29 Shell Oil Company Method for preparing asymmetric radial copolymers having four first arms and two second arms

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Publication number Publication date
JPH08208780A (ja) 1996-08-13
CN1129713A (zh) 1996-08-28
EP0711789A3 (en) 1996-07-31
BR9505119A (pt) 1997-09-09
TR199501404A2 (tr) 1996-06-21
US5461116A (en) 1995-10-24
DE69515102D1 (de) 2000-03-23
CN1068346C (zh) 2001-07-11
JP3578848B2 (ja) 2004-10-20
DE69515102T2 (de) 2000-09-28
ES2142450T3 (es) 2000-04-16
MX9504681A (es) 1997-04-30
KR100401300B1 (ko) 2003-12-18
EP0711789B1 (en) 2000-02-16
TR199501404A3 (ko) 1996-06-21
EP0711789A2 (en) 1996-05-15

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