KR950702969A - 2-[(4-헤테로사이클-페녹시메틸)페녹시]알카노에이트 제초제(herbicidal 2-[(4-heterocyclic-phenoxymethyl)phenoxy]-alkanoates) - Google Patents
2-[(4-헤테로사이클-페녹시메틸)페녹시]알카노에이트 제초제(herbicidal 2-[(4-heterocyclic-phenoxymethyl)phenoxy]-alkanoates) Download PDFInfo
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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Abstract
본 발명은 제초제 화합물, 이를 함유한 조성물 및 이 조성물의 적용에 의한 잡초의 억제 방법에 관한 것이다.
제초제조성물은 하기 일반식의 2-[(4-헤테로사이클릭-페녹시메틸)페녹시]알카노에이트이다:
상기식에서, A는 알파 탄소에서 페녹시 산소에 결합된 알카노에이트의 유도체이고; Q는 4-디플루오로메틸-4,5-디하이드로-3-메틸-1,2,4-트리아졸-5(1H)-온-1-일, 3,4,5,6-테트라하이드로프탈이미드-1-일, 1-(1-메 틸에틸)이미다졸리딘-2,4-디온-3-일, 1,4-디하이드로-4-(3-플루오르프로필)-5H-테트라졸-5-온-일, 3-클로로-4,5,6,7-테트라하이드로인다졸-2-일, 4-메틸-1, 2, 4-트리아진-3,5-디온-2-일, 8-티아-1,6-디아자비사이클로[4.3.0]-노난-7-온-9-일이미노 또는 1-메틸-6-트리플루오로메틸-2,4-피리미딘디온-3-일이고; X는 수소, 메틸, 불소 또는 염소이고; Y는 수소이고; W는 산소 또는 황이고; Z는 수소, 불소, 염소, 브롬, 저급알킬 또는 메톡시이고; Z′는 수소, 불소 또는 염소이고; AO-그룹은 페닐환의 2,3 또는 4-위치에 있을 수 있다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (20)
- 하기 일반식으로 표시됨을 특징으로 하는 제초제 화합물:상기식에서, A는이고; Q는 4-디플루오로메틸-4,5-디하이드로-3-메틸-1,2,4-트리아졸-5(1H)-온-1-일 또는 1-메틸-6-트리플루오로메틸-2,4-(1H, 3H)-피리미딘디온-3-일이고; R은 각각 하나 이상의 염소 또는 불소로 선택적으로 치환된 수소, M, 저급 알킬, 사이클로 알킬, 저급 알케닐 또는 저급 알키닐이거나, 또는 -[CHR7-(CH2)mO]nR8이고; R′는 수소 또는 메틸이고; R″는 -OR, 아미노, 페닐아미노, 저급 알킬아미노, 저급 알케닐아미노, 저급 알콕시아미노 또는 시아노 이거나, 또는 일반식 -N(저급 알킬) SO2R9또는 -NHSO2R9의 저급알킬-, 저급 할로알킬- 또는 페닐설포닐아미노이고; R7은 H 또는 CH3이고; R8은 저급 알킬이고; R9는 저급 알킬, 저급 할로알킬 또는 페닐이고; X는 수소, 메틸, 불소 또는 염소이고; Y는 수소이고; W는 산소 또는 황이고; Z는 수소, 불소, 염소, 브롬, 저급 알킬 또는 메톡시이고; Z′는 수소, 불소 또는 염소이고; Z 및 Z′는 함께 테트라하이드로나프틸 잔기를 형성하는 -(CH2)4- 일 수 있고; m은 0 내지 2이고; n은 1 내지 6이고; M은 나트륨, 칼륨 또는 암모늄이고; AO- 그룹은 페닐환의 2,3 또는 4-위치에 있을 수 있다.
- 제1항에 있어서, R″가 -OR이고; X가 수소, 불소 또는 염소이고; Z가 수소, 염소 또는 저급 알킬임을 특징으로 하는 화합물.
- 제2항에 있어서, R이 저급 알킬, 저급 클로로알킬 또는 -[CHR7(CH2)mO]nR8이고; R′가 메틸이고; Z가 4-위치에 있고; Z′가 3-위치에서 수소 또는 염소이고; m이 0 또는 1이고; n이 1 내지 3이고; AO-그룹이 페닐환의 2-위치에 있음을 특징으로 하는 화합물.
- 제3항에 있어서, Q가 4-디플루오로메틸-4,5-디하이드로-3-메틸-1,2,4-트리아졸-5-(1H)-온-1-일이고; R이 메틸 또는 CH3O(CH2)2-O-(CH2)2-이고; X가 불소임을 특징으로 하는 화합물.
- 제4항에 있어서, W가 산소이고, Z′가 소소임을 특징으로 하는 화합물.
- 제5항에 있어서, R이 메틸이고, Z가 에틸임을 특징으로 하는 화합물.
- 제5항에 있어서, R이 메틸이고, Z가 2-메틸에틸임을 특징으로 하는 화합물.
- 제5항에 있어서, R 및 Z가 각각 에틸임을 특징으로 하는 화합물.
- 제5항에 있어서, R이 메틸이고, Z가 염소임을 특징으로 하는 화합물.
- 제5항에 있어서, R이 2-(2-메톡시에톡시)에틸이<Z가 메틸임을 특징으로 하는 화합물.
- 제4항에 있어서, R 및 가 각각 메틸이고, W가 황이고, Z′가 수소임을 특징으로 하는 화합물.
- 제3항에 있어서, Q가 1-메틸-6-트리플루오로메틸-2,4-(1H, 3H)-피리미딘-디온-3-일이고; R이 메틸, 2,2,2-트리클로로에틸 또는 CH3O(CH2)2-O-(CH2)2-이고; W가 산소이고; X가 수소 또는 불소이고; Z′가 수소임을 특징으로 하는 화합물.
- 제12항에 있어서, R 및 Z가 각각 메틸이고, X가 수소임을 특징으로 하는 화합물.
- 제12항에 있어서, R이 메틸이고, X가 수소이고, Z가 에틸임을 특징으로 하는 화합물.
- 제12항에 있어서, R 및 Z가 각각 메틸이고, X가 불소임을 특징으로 하는 화합물.
- 제12항에 있어서, R이 메틸이고, X가 불소이고, Z가 에틸임을 특징으로 하는 화합물.
- 제12항에 있어서, R이 2,2,2-트리클로로에틸이고, X가 수소이고, Z가 메틸임을 특징으로 하는 화합물.
- 제12항에 있어서, R이 2,2,2-트리클로로에틸이고, X가 수소이고, Z가 메틸임을 특징으로 하는 화합물.
- 제초적으로 효과적인 양의 제1항의 화합물이 농업적으로 허용가능한 담체와 함께 혼합되어 있음을 특징으로 하는 제초제 조성물.
- 제초척으로 효과적인 양의 제19항의 조성물을 불필요한 식물이 성장하고 있거나 성장이 예측되는 장소에 적용함을 특징으로 하는, 불필요한 시물 성장의 억제 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/935,601 US5262390A (en) | 1992-08-26 | 1992-08-26 | Herbicical 2-[(4-heterocyclic-phenoxymethyl)phenoxy]-alkanoates |
| US07/935601 | 1992-08-26 | ||
| US935601 | 1992-08-26 | ||
| PCT/US1993/007837 WO1994004514A1 (en) | 1992-08-26 | 1993-08-25 | Herbicidal 2-[(4-heterocyclic-phenoxymethyl)phenoxy]-alkanoates |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR950702969A true KR950702969A (ko) | 1995-08-23 |
| KR0178843B1 KR0178843B1 (ko) | 1999-03-20 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019950700838A KR0178843B1 (ko) | 1992-08-26 | 1993-08-25 | 2-[(4-헤테로사이클-페녹시메틸)페녹시]알카노에이트 제초제 |
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| Country | Link |
|---|---|
| US (2) | US5262390A (ko) |
| EP (1) | EP0656892B1 (ko) |
| JP (1) | JP2652084B2 (ko) |
| KR (1) | KR0178843B1 (ko) |
| CN (1) | CN1035434C (ko) |
| AT (1) | ATE202092T1 (ko) |
| AU (1) | AU671311B2 (ko) |
| BG (1) | BG99443A (ko) |
| CA (1) | CA2143323C (ko) |
| CZ (1) | CZ282413B6 (ko) |
| DE (1) | DE69330349D1 (ko) |
| DZ (1) | DZ1710A1 (ko) |
| EC (1) | ECSP930962A (ko) |
| FI (1) | FI950865A (ko) |
| HU (1) | HU218700B (ko) |
| IL (1) | IL106734A (ko) |
| MD (1) | MD930058A (ko) |
| MX (1) | MX9305187A (ko) |
| MY (1) | MY107776A (ko) |
| NO (1) | NO950705L (ko) |
| NZ (1) | NZ255832A (ko) |
| PL (1) | PL172588B1 (ko) |
| RO (1) | RO114254B1 (ko) |
| RU (1) | RU2113434C1 (ko) |
| SI (1) | SI9300448A (ko) |
| SK (1) | SK25995A3 (ko) |
| TN (1) | TNSN93093A1 (ko) |
| TR (1) | TR28387A (ko) |
| TW (1) | TW257754B (ko) |
| UA (1) | UA37219C2 (ko) |
| WO (1) | WO1994004514A1 (ko) |
| YU (1) | YU56793A (ko) |
| ZA (1) | ZA936274B (ko) |
| ZW (1) | ZW11093A1 (ko) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5798316A (en) * | 1992-08-26 | 1998-08-25 | Theodoridis; George | Herbicidal combinations containing 2- (4-heterocyclic-phenoxymethyl)phenoxy!alkanoates |
| US5674810A (en) * | 1995-09-05 | 1997-10-07 | Fmc Corporation | Herbicidal compositions comprising 2- (4-heterocyclic-phenoxymethyl)Phenoxy!-alkanoates |
| JPH0948766A (ja) * | 1995-05-29 | 1997-02-18 | Sumitomo Chem Co Ltd | トリアゾロン誘導体、その用途およびその製造中間体 |
| DE19521162A1 (de) * | 1995-06-09 | 1996-12-12 | Bayer Ag | N-Aryl-1,2,4-triazolin-5-one |
| US5861359A (en) * | 1995-07-25 | 1999-01-19 | Fmc Corporation | Herbicidal phenylmethoxphenyl heterocycles |
| EP1273232B1 (en) * | 1995-08-21 | 2006-06-21 | Fmc Corporation | Process for the preparation of the herbicide ethyl alpha-2-dichloro-5-¬4-(difluoromethyl)-4,5-dihydro-3-methyl-5-oxo-1h-1,2,4-triazol-1-yl|-4-fluorobenzenepropanoate |
| DE19702435A1 (de) * | 1997-01-24 | 1998-07-30 | Bayer Ag | Arylalkylverbindungen |
| DE19715017A1 (de) | 1997-04-11 | 1998-10-15 | Bayer Ag | Substituierte Aryluracile |
| DE19728125A1 (de) * | 1997-07-02 | 1999-01-07 | Bayer Ag | Substituierte Aryluracile |
| US6022830A (en) * | 1997-07-14 | 2000-02-08 | Fmc Corporation | Crop harvesting method using a benzyloxphenyl uracil |
| DE19739638A1 (de) * | 1997-09-10 | 1999-03-11 | Bayer Ag | Substituierte Phenyluracile |
| DE19752748A1 (de) | 1997-11-28 | 1999-06-02 | Bayer Ag | Substituierte Phenyluracile |
| WO2000004774A1 (en) * | 1998-07-21 | 2000-02-03 | Fmc Corporation | Crop harvesting method using a benzyloxyphenyl uracil |
| DE19925593A1 (de) | 1999-06-04 | 2000-12-07 | Bayer Ag | Substituierte 2-Aryl-1,2,4-triazin-3,5-di(thi)one |
| EP2052608A1 (de) | 2007-10-24 | 2009-04-29 | Bayer CropScience AG | Herbizid-Kombination |
| DE102008037631A1 (de) * | 2008-08-14 | 2010-02-18 | Bayer Cropscience Ag | Herbizid-Kombination mit Dimethoxytriazinyl-substituierten Difluormethansulfonylaniliden |
| JP5347072B2 (ja) * | 2010-06-29 | 2013-11-20 | クミアイ化学工業株式会社 | ６−アシル−１，２，４−トリアジン−３，５−ジオン誘導体及び除草剤 |
| RU2489427C1 (ru) * | 2012-07-18 | 2013-08-10 | Владимир Иванович Петров | Пиримидиновые производные бензофенона, обладающие анти-вич-1 активностью |
| US9730448B2 (en) | 2013-08-29 | 2017-08-15 | Sumitomo Chemical Company, Limited | Tetrazolinone compound and use of same |
| WO2015046480A1 (ja) * | 2013-09-25 | 2015-04-02 | 住友化学株式会社 | テトラゾリノン化合物及びその用途 |
| WO2018024695A1 (en) | 2016-08-05 | 2018-02-08 | Basf Se | Method for controlling ppo resistant weeds |
| GB202209303D0 (en) | 2022-06-24 | 2022-08-10 | Redag Crop Prot Ltd | Agricultural chemicals |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5425018B2 (ko) * | 1971-10-30 | 1979-08-24 | ||
| JPS49432A (ko) * | 1972-04-21 | 1974-01-05 | ||
| JPS5426534B2 (ko) * | 1972-07-03 | 1979-09-04 | ||
| JPS6039668B2 (ja) * | 1976-12-13 | 1985-09-06 | 三菱化学株式会社 | ３，４，５，６−テトラヒドロフタルイミド誘導体および除草剤 |
| JPS5419965A (en) * | 1977-07-12 | 1979-02-15 | Mitsubishi Chem Ind Ltd | Preparation of n-substituted phenyl-3,4,5,6-tetrahydro-phthalimide |
| DK366887A (da) * | 1986-07-31 | 1988-05-13 | Hoffmann La Roche | Pyrimidinderivater |
| EP0322413A4 (en) * | 1986-08-20 | 1989-10-04 | Fmc Corp | WEED KILLER. |
| US5084085A (en) * | 1986-08-20 | 1992-01-28 | Fmc Corporation | Herbicidal aryloxyphenyltriazolinones and related compounds |
| US4885025A (en) * | 1986-12-23 | 1989-12-05 | Fmc Corporation | Herbicidal tetrazolinones and use thereof |
| US4816065A (en) * | 1986-12-23 | 1989-03-28 | Fmc Corporation | Herbicides |
| US5165076A (en) * | 1987-06-12 | 1992-11-17 | Canon Kabushiki Kaisha | Ferroelectric liquid crystal device with particular primer alignment, and liquid crystal layers |
| DE3854751T2 (de) * | 1987-06-12 | 1996-06-13 | Canon Kk | Vorrichtung mit einem ferroelektrischen Flüssigkristall. |
| JPH0536708A (ja) * | 1991-07-25 | 1993-02-12 | Sumitomo Electric Ind Ltd | ヘテロ接合バイポーラトランジスタ |
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1992
- 1992-08-26 US US07/935,601 patent/US5262390A/en not_active Expired - Fee Related
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1993
- 1993-08-06 EC EC1993000962A patent/ECSP930962A/es unknown
- 1993-08-17 US US08/107,560 patent/US5344812A/en not_active Expired - Lifetime
- 1993-08-19 IL IL10673493A patent/IL106734A/en not_active IP Right Cessation
- 1993-08-19 TW TW082106660A patent/TW257754B/zh active
- 1993-08-24 MY MYPI93001696A patent/MY107776A/en unknown
- 1993-08-24 DZ DZ930094A patent/DZ1710A1/fr active
- 1993-08-25 WO PCT/US1993/007837 patent/WO1994004514A1/en active IP Right Grant
- 1993-08-25 JP JP6506546A patent/JP2652084B2/ja not_active Expired - Fee Related
- 1993-08-25 NZ NZ255832A patent/NZ255832A/en not_active IP Right Cessation
- 1993-08-25 EP EP93920234A patent/EP0656892B1/en not_active Expired - Lifetime
- 1993-08-25 KR KR1019950700838A patent/KR0178843B1/ko not_active IP Right Cessation
- 1993-08-25 HU HU9500603A patent/HU218700B/hu not_active IP Right Cessation
- 1993-08-25 AT AT93920234T patent/ATE202092T1/de active
- 1993-08-25 PL PL93307728A patent/PL172588B1/pl not_active IP Right Cessation
- 1993-08-25 YU YU56793A patent/YU56793A/sh unknown
- 1993-08-25 SK SK259-95A patent/SK25995A3/sk unknown
- 1993-08-25 RU RU95108542A patent/RU2113434C1/ru not_active IP Right Cessation
- 1993-08-25 CA CA002143323A patent/CA2143323C/en not_active Expired - Fee Related
- 1993-08-25 CZ CZ95518A patent/CZ282413B6/cs unknown
- 1993-08-25 DE DE69330349T patent/DE69330349D1/de not_active Expired - Lifetime
- 1993-08-25 RO RO95-00441A patent/RO114254B1/ro unknown
- 1993-08-25 AU AU50833/93A patent/AU671311B2/en not_active Ceased
- 1993-08-25 TR TR00733/93A patent/TR28387A/xx unknown
- 1993-08-25 UA UA95038232A patent/UA37219C2/uk unknown
- 1993-08-26 CN CN93116971A patent/CN1035434C/zh not_active Expired - Fee Related
- 1993-08-26 SI SI9300448A patent/SI9300448A/sl unknown
- 1993-08-26 TN TNTNSN93093A patent/TNSN93093A1/ar unknown
- 1993-08-26 MD MD93-0058A patent/MD930058A/ro unknown
- 1993-08-26 ZA ZA936274A patent/ZA936274B/xx unknown
- 1993-08-26 MX MX9305187A patent/MX9305187A/es not_active IP Right Cessation
- 1993-12-01 ZW ZW110/93A patent/ZW11093A1/xx unknown
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1995
- 1995-02-20 BG BG99443A patent/BG99443A/xx unknown
- 1995-02-24 NO NO950705A patent/NO950705L/no unknown
- 1995-02-24 FI FI950865A patent/FI950865A/fi not_active Application Discontinuation
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