KR940005540A - 카르복시산 유도체 - Google Patents

카르복시산 유도체 Download PDF

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KR940005540A
KR940005540A KR1019930012415A KR930012415A KR940005540A KR 940005540 A KR940005540 A KR 940005540A KR 1019930012415 A KR1019930012415 A KR 1019930012415A KR 930012415 A KR930012415 A KR 930012415A KR 940005540 A KR940005540 A KR 940005540A
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마이엔피쉬 피터
피테르나 토마스
붸게르 만프레트
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베르너 발테크
시바-가이기 아게
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Abstract

본 발명은 유리 형태, 또는 필요한 경우, 염 형태로 존재하며 공지된 방법에 의해 제조될 수 있는 하기 일반식(Ⅰ)의 화합물에 관한 것이다;
상기식에서. A는 산소. 황 또는 -NR1-이고; B는 C2-C6알킬렌이며. D-E는 -0-E, -S-E, -0-CH2-E, -0-C(=0)-E, -0-C(=0)-0-E, -0-C(=0)-N(H)-E. 또는 -0-C(=S)-N(H)-E이고; E는 페닐 할로겐, C1-C4알킬, 할로-C1-C4알킬, C1-C4알콕시, 할로-C1-C4알콕시, 시아노, 니트로 및 메틸렌디옥시로 이루어진 군으로부터 선택된 치환체 1내지 3으로 치환된 페닐; 질소, 산소 및 황으로 이루어진 군으로 부터 선택된 헤테로 원자 1내지 3개를 포함하는 5원 방향족 헤테로싸이클: 질소, 산소 및 황으로 이루어진 군으로 부터 선택된 헤테로 원자 1 내지 3개를 포함하며, 할로겐, C1-C4알킬 및 C1-C4할로알킬로 이루어진 군으로부터 선택된 치환체 1또는 2로 치환된 헤테로 원자 1내지 3개를 포함하는 5원 방향족 헤테로싸이클; 1내지 3의 질소원자를 포함하는 6원 고리 방향족 헤테로싸이클; 또는 1 내지 3의 짙소 원자를 포함하며 할로겐, C1-C4알킬 및 C1-C4할로알킬로 이루어진 군으로부터 선택된 치환체 1또는 2로 치환된 6원 방향족 헤테로사이클이고; L은 할로겐 또는 메틸이며; X는 불소이고; Y는 염소 또는 불소이며; Z는 수소, 불소 또는 메틸이고; m은 숫자 0,1. 2.3,4 또는 5이며; n은 숫자 0,1 또는 2이고; R1은 수소, C1-C4알킬, 페닐티오 또는 톨릴티오이다.

Description

카르복시산 유도체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (25)

  1. 유리 형태, 또는 필용한 경우, 염 형태로 존재하는 하기 일반식(Ⅰ)의 화합물;
    상기식에서. A는 산소, 황 또는 -NR1-이고; B는 C2-C6알킬렌이며. D-E는 -0-E, -S-E, -0-CH2-E, -0-C(=0)-E, -0-C(=0)-0-E, -0-C(=0)-N(H)-E. 또는 -0-C(=S)-N(H)-E이고; E는 페닐, 할로겐, C1-C4알킬, 할로-C1-C4알킬, C1-C4알콕시, 할로-C1-C4알콕시, 시아노, 니트로 및 메틸렌디옥시로 이루어진 군으로부터 선택된 치환체 1내지 3으로 치환된 페닐; 질소, 산소 및 황으로 이루어진 군으로 부터 선택된 헤테로 원자 1내지 3개를 포함하는 5원 방향족 헤테로싸이클: 질소, 산소 및 황으로 이루어진 군으로 부터 선택된 헤테로 원자 1 내지 3개를 포함하며, 할로겐, C1-C4알킬 및 C1-C4할로알킬로 이루어진 군으로부터 선택된 치환체 1또는 2로 치환된 헤테로 원자 1내지 3개를 포함하는 5원 방향족 헤테로싸이클; 1내지 3의 질소원자를 포함하는 6원 고리 방향족 헤테로싸이클; 또는 1 내지 3의 짙소 원자를 포함하며 할로겐, C1-C4알킬 및 C1-C4할로알킬로 이루어진 군으로부터 선택된 치환체 1또는 2로 치환된 6원 방향족 헤테로사이클이고; L은 할로겐 또는 메틸이며; X는 불소이고; Y는 염소 또는 불소이며; Z는 수소, 불소 또는 메틸이고; m은 숫자 0,1,2,3,4 또는 5이며; n은 숫자 0,1 또는 2이고; R1은 수소, C1-C4알킬, 페닐티오 또는 톨릴티오이다.
  2. 제1항에 있어서, A가 산소인 일반식(Ⅰ)의 화합물.
  3. 제1항 또는 제2항에 있어서, B가 에틸렌 브릿지인 일반식(Ⅰ)의 화합물.
  4. 제1항에 있어서, A가 브릿지 -NH-인 일반식(Ⅰ)의 화합물.
  5. 제1항, 제3항 또는 제4항에 있어서, n이 숫자 0인 일반식(Ⅰ)의 화합물.
  6. 제1항 내지 제5항중 어느 하나에 있어서, D가 -0-인 일반식(Ⅰ)의 화합물.
  7. 제1항 내지 제6항중, 어느 하나에 있어서, E가 페닐; 피리딜; 티아디아졸릴; 시아노, 니트로, 할로겐, C1-C4알킬, C1-C4할로알킬로 이루어진 군으로부터 선택된 치환체 1 또는 2에 의해 치환된 페닐; 할로겐; C1-C4알킬 및 할로- C1-C4알킬로 이루어진 군으로부터 선택된 치환체 1 또는 2 에 의해 치환된 피리딜, 또는 C1-C4알킬티아졸릴인 일반식(Ⅰ)의 화합물.
  8. 제1항 내지 제7항중 어느 하나에 있어서, m이 숫자 0, 1 또는 4인 일반식(Ⅰ)의 화합물.
  9. 제1항 내지 제8항중 어느 하나에 있어서, Y가 불소이고 Z가 수소인 일반식(Ⅰ)의 화합물.
  10. 제1항, 3항 내지 제5항 및 제7항 내지 제9항중 어느 하나에 있어서, D가 -O-CH2-인 일반식(Ⅰ)의 화합물.
  11. 제11항 내지 제5항 및 제7항 내지 제9항중 어느 하나에 있어서, D가 -0-CO-또는 -0-CO-인 일반식(Ⅰ)의 화합물.
  12. 제2항에 있어서, n이 숫자 0인 일반식(Ⅰ)의 화합물.
  13. 제12항에 있어서, D가 산소 또는 황인 일반식(Ⅰ)의 화합물.
  14. 제12항에 있어서, D가 -0-CH2-인 일반식(Ⅰ)의 화합물.
  15. 제6항에 있어서, E가 치환된 또는 비치환된 페닐, 티아디아졸릴 또는 피리딜기인 일반식(Ⅰ)의 화합물.
  16. 제3항에 있어서, A가 산소이고, n이 0이며, D가 산소, 황 또는 -O-CH2-이고, E가 페닐, 피리딜, 티아디졸릴, 시아노, 니트로, 할로겐, C1-C4알킬, C1-C4할로알킬로 이루어진 군으로부터 선택된 치환체 1또는 2에 의해 치환된 페닐, 할로겐, C1-C4알킬 및 할로- C1-C4알킬, 또는 C1-C4알킬티아졸릴로 이루어진 군으로부터 선택된 치환체 1또는 2에 의해 치환된 피리딜이며, m이 숫자 0,1 또는 4이고, Y가 불소이며, Z가 수소인 일반식(Ⅰ)의 화합물.
  17. 제16항에 있어서, X가 불소이고, Y가 불소이며, Z가 수소이고, m이 1이며, A가 산소이고, B가 -CH2CH2-이며, n이 0이고, D-E가 -O-CH2-E이며, E가 4-트리플루오로메틸페닐인 일반식(Ⅰ)의 화합물.
  18. 제1항에 있어서, 하기 화합물로 이루어진 군으로부터 선택된 일반식(Ⅰ)의 화합물;
    2-(4-페녹시페녹시)에틸 4,4-디플루오로부트-3-엔오에이트,2-(4-벤질옥기페녹시)에틸4,4-디플루오토부트-3-엔오에이트, 2-〔4-(4-메틸)벤질옥시페녹시〕에틸 4,4-디플루오로부트-3-엔오에이트, 2-(4-페녹시페녹시)에틸 6,6-디플루오로헥스-5-엔오에이트, 2-(4-벤질옥시페녹시)에틸 6,6-디플루오로헥스-5-엔오에이트 , 2-(4-페녹시페녹시)에틸 8,8-디플루오로옥트-7-엔오에이트, 2- (4-벤질옥시페녹시)에틸 8, 8- 디플루오로옥트-7-엔오에이트, 2-(7-페녹시페녹시)에틸 10, 10- 디플루오로도데스-9-엔오에이트, 2-(4-벤질옥시페녹시)에틸 10,10-디플루오로데스-9-엔오에이트, 2-(4-페녹시페녹시)에틸 12,12-디플루오로도데스-11-엔오에이트 및 2-(4-벤질옥시페녹시)에틸 12,12-디플루오로데스-11-엔오에이트.
  19. a)하기 일반식(Ⅲ)의 화합물 또는, 필요한 경우에, 그의 염을 불확성 용매의 존재 또는 부재하에, 그리고 산 결합제의 존재하에 하기 일반식(Ⅱ)의 화합물과 반응시키거나, 또는 b)하기 일반식(Ⅴ)의 화합물을 불활성 용매 및 촉매의 존재 또는 부재하에, 그리고 탈수제의 존재하에 하기 일반식(Ⅲ)의 화합물 또는, 필요한 경우에, 그의 염과 반응시키고, 그리고, 각각의 경우에, 원한다면 본 발명의 방법에 따라 얻을 수 있는 일반식(Ⅰ)의 유리 화합물의 염으로 전환시키거나, 또는 본 발명의 방법을 얻을 수 있는 일반식(Ⅰ)의 화합물의 염을 일반식(Ⅰ)의 유리 화합물 또는 다른 염으로 전환시킴으로써 유리형태, 필요한 경우, 염 형태의 제1항에 따른 일반식(Ⅰ)화합물을 제조하는 방법;
    상기식에서, X, Y, Z, m, A, B, L, D, E및 n은 일반식(Ⅰ)에 정의된 바와 같고, Hal은 염소 또는 브롬이다
  20. 활성 성분으로서 제1항 내지 제18항에 따른 화합물 1이상을 유리 형태, 또는 필요한 경우에는, 농화학적으로 이용 가능한 염 형태로 포함하며 보조제 1이상을 포함하는 살충제 조성물.
  21. 제20항에 있어서, 곤충 및/또는 거미류를 방제하는 방법.
  22. 보조제, 또는 보조제들과 함께 활성 성분을 치밀하게 혼합하는 것을 포함하는, 제20항에 따른 조성물의 제조방법.
  23. 활성 성분으로서, 제1항 내지 18항에 따른 일반식(Ⅰ)의 화합물을 유리 형태, 또는 필요한 경우에는, 농화학적으로 이용 가능한 염 형태로 해충 또는 그의 환경에 도포하는 해충 방제 방법.
  24. 제23항에 있어서, 곤충/및 또는 거미류를 방제하는 방법.
  25. 유리 형태, 또는 필요한 경우, 염 형태로 존재하는 하기 일반식(Ⅳ)의 화합물;
    상기식에서, A,B,L,D,E,m,과 n은 일반식(Ⅰ)에 정의한 바와 같고, Z는 수소 또는 메틸이다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930012415A 1992-06-30 1993-06-30 카르복시산 유도체 KR940005540A (ko)

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