KR950701651A - 금속중심 산화를 완화시킨 루이스 산에 의한 부가중합 촉매의 제조방법(preparation of addition polymerization catalystsvia lewis acid mitigated metal center oxidation) - Google Patents

금속중심 산화를 완화시킨 루이스 산에 의한 부가중합 촉매의 제조방법(preparation of addition polymerization catalystsvia lewis acid mitigated metal center oxidation)

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Publication number
KR950701651A
KR950701651A KR1019940704130A KR19940704130A KR950701651A KR 950701651 A KR950701651 A KR 950701651A KR 1019940704130 A KR1019940704130 A KR 1019940704130A KR 19940704130 A KR19940704130 A KR 19940704130A KR 950701651 A KR950701651 A KR 950701651A
Authority
KR
South Korea
Prior art keywords
group
hydrocarbyl
tris
borane
groups
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
KR1019940704130A
Other languages
English (en)
Korean (ko)
Inventor
엔. 닉키아스 피터
제이. 티머즈 프랜시스
디. 데보어 데이빗
케이. 로젠 로버트
디. 무셀 로버트
Original Assignee
스티븐 에스. 그레이스
더 다우 케미칼 캄파니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 스티븐 에스. 그레이스, 더 다우 케미칼 캄파니 filed Critical 스티븐 에스. 그레이스
Publication of KR950701651A publication Critical patent/KR950701651A/ko
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
KR1019940704130A 1993-03-19 1994-02-10 금속중심 산화를 완화시킨 루이스 산에 의한 부가중합 촉매의 제조방법(preparation of addition polymerization catalystsvia lewis acid mitigated metal center oxidation) Withdrawn KR950701651A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/034,434 US5347024A (en) 1993-03-19 1993-03-19 Preparation of addition polymerization catalysts via Lewis acid mitigated metal center oxidation
US08/034.434 1993-03-19
PCT/US1994/001647 WO1994021693A1 (en) 1993-03-19 1994-02-10 Preparation of addition polymerization catalysts via lewis acid mitigated metal center oxidation

Publications (1)

Publication Number Publication Date
KR950701651A true KR950701651A (ko) 1995-04-28

Family

ID=21876391

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019940704130A Withdrawn KR950701651A (ko) 1993-03-19 1994-02-10 금속중심 산화를 완화시킨 루이스 산에 의한 부가중합 촉매의 제조방법(preparation of addition polymerization catalystsvia lewis acid mitigated metal center oxidation)

Country Status (11)

Country Link
US (1) US5347024A (enExample)
EP (1) EP0641360B1 (enExample)
JP (1) JP3547440B2 (enExample)
KR (1) KR950701651A (enExample)
CA (1) CA2134890A1 (enExample)
DE (1) DE69405952T2 (enExample)
ES (1) ES2107201T3 (enExample)
FI (1) FI945435A0 (enExample)
NO (1) NO944420D0 (enExample)
TW (1) TW273557B (enExample)
WO (1) WO1994021693A1 (enExample)

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IT1273753B (it) * 1994-02-11 1997-07-10 Eniriceche Spa Sistema catalitico e processo per la produzione di polidiolefine
US6111020A (en) * 1994-09-02 2000-08-29 The Dow Chemical Company Crosslinked foams from blends of ethylene vinyl acetate and ethylene-styrene interpolymers
FI104825B (fi) 1996-01-26 2000-04-14 Borealis As Olefiinien polymerointikatalysaattorisysteemi, sen valmistus ja käyttö
DE19622207A1 (de) * 1996-06-03 1997-12-04 Hoechst Ag Chemische Verbindung
HU223533B1 (hu) 1996-06-17 2004-08-30 Exxonmobil Chemical Patents Inc. Vegyes átmenetifém katalizátor-rendszer olefinek polimerizálására
US5811379A (en) * 1996-06-17 1998-09-22 Exxon Chemical Patents Inc. Polymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such polymers and additives and use thereof (PT-1267)
US6066603A (en) * 1996-06-17 2000-05-23 Exxon Chemical Patents Inc. Polar monomer containing copolymers derived from olefins useful as lubricant and useful as lubricant and fuel oil additivies process for preparation of such copolymers and additives and use thereof
US5939503A (en) * 1996-08-09 1999-08-17 California Institute Of Technology Group IV zwitterion ansa metallocene (ZAM) catalysts for α-olefin polymerization
ATE325821T1 (de) 1996-08-13 2006-06-15 Basell Polyolefine Gmbh Geträgerte chemische verbindung
DE59703850D1 (de) * 1996-08-13 2001-07-26 Basell Polyolefine Gmbh Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
TW412560B (en) 1996-09-04 2000-11-21 Dow Chemical Co Compositions and adhesives comprising a substantially random interpolymer of at least one vinylidene and at least one vinylidene aromatic monomer or hindered aliphatic vinylidene monomer, and coextruded or laminated multilayer film and tape
DE69711061T2 (de) 1996-09-04 2002-07-18 The Dow Chemical Co., Midland Boden-, wand- oder deckenverkleidung
US6262161B1 (en) 1997-06-26 2001-07-17 The Dow Chemical Company Compositions having improved ignition resistance
US6319969B1 (en) 1997-06-26 2001-11-20 The Dow Chemical Company Interpolymer compositions for use in sound management
US6172015B1 (en) 1997-07-21 2001-01-09 Exxon Chemical Patents, Inc Polar monomer containing copolymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such copolymers and additives and use thereof
AU1085999A (en) 1997-10-17 1999-05-10 Dow Chemical Company, The Compositions of interpolymers of alpha-olefin monomers with one or more vinyl orvinylidene aromatic monomers
EP1062272A1 (en) 1998-03-11 2000-12-27 The Dow Chemical Company Thermoplastic compositions of interpolymers of alpha-olefin monomers with one or more vinyl or vinylidene aromatic monomers and/or one or more hindered aliphatic or cycloaliphatic vinyl or vinylidene monomers blended with engineering thermoplastics
WO2000018808A1 (en) 1998-09-30 2000-04-06 Exxon Chemical Patents Inc. Cationic group 3 catalyst system
US6048909A (en) * 1998-12-04 2000-04-11 The Dow Chemical Company Foams having increased heat distortion temperature made from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers
US5993707A (en) * 1998-12-04 1999-11-30 The Dow Chemical Company Enlarged cell size foams made from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers
US6231795B1 (en) 1998-12-04 2001-05-15 The Dow Chemical Company Soft and flexible foams made from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers
US6187232B1 (en) * 1998-12-04 2001-02-13 The Dow Chemical Company Acoustical insulation foams
BR9916964A (pt) 1998-12-08 2002-05-28 Dow Chemical Co Fibras de polipropileno/etileno ligável por fusão, composição para produzì-la, método para melhorar sua resistência de ligação e processo para produzì-la
US6331597B1 (en) 1999-08-09 2001-12-18 The Dow Chemical Company Azidosilane-modified, moisture-curable polyolefin polymers, process for making, and articles obtained therefrom
US6362270B1 (en) 1999-08-12 2002-03-26 The Dow Chemical Company Thermoplastic compositions for durable goods applications
US6524702B1 (en) 1999-08-12 2003-02-25 Dow Global Technologies Inc. Electrical devices having polymeric members
EP1218444A2 (en) 1999-08-17 2002-07-03 The Dow Chemical Company Free-flowing polymer composition
US6239062B1 (en) 1999-09-02 2001-05-29 Equistar Chemicals, L.P. Olefin polymerization catalysts containing indolyl-amido ligands
WO2001051547A1 (en) 2000-01-07 2001-07-19 Dow Global Technologies Inc. Thermoformable ethylene/styrene interpolymer-based polymer blend film for three-dimensional transfer finish foil
US6160029A (en) * 2000-03-08 2000-12-12 The Dow Chemical Company Olefin polymer and α-olefin/vinyl or α-olefin/vinylidene interpolymer blend foams
US6649671B2 (en) 2000-03-13 2003-11-18 Dow Global Technologies Inc. Concrete and process to make same
WO2002008332A1 (en) 2000-07-20 2002-01-31 Dow Global Technologies Inc. Foam compositions from blend of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic interpolymers
AU2002244184A1 (en) * 2001-02-27 2002-09-12 Dow Global Technologies Inc. Fabricated articles prepared from blends of substantially random ethylene/propylene/vinyl aromatic interpolymers with polypropylene
WO2003013806A1 (en) 2001-08-10 2003-02-20 Dow Global Technologies Inc. Wood treatment composition and method of use
US20040106739A1 (en) * 2002-02-19 2004-06-03 Cheung Yunwa Wilson Blends of substantially random interpolymers with enhanced thermal performance
DE102007057854A1 (de) * 2007-11-28 2009-06-04 Philipps-Universität Marburg Cyclopentadienylphosphazen-Komplexe (CpPN-Komplexe) von Metallen der 3. und 4. Gruppe und der Lanthanoide
JP7499181B2 (ja) 2018-03-30 2024-06-13 ダウ グローバル テクノロジーズ エルエルシー オレフィン重合活性化剤
JP7304880B2 (ja) 2018-03-30 2023-07-07 ダウ グローバル テクノロジーズ エルエルシー 二核オレフィン重合活性化剤
WO2019191440A1 (en) 2018-03-30 2019-10-03 Dow Global Technologies Llc Highly soluble bis-borate as binuclear co-catalysts for olefin polymerizations
US11787880B2 (en) 2018-03-30 2023-10-17 Dow Global Technologies Llc Highly soluble alkyl substituted carbenium borate as co-catalysts for olefin polymerizations
BR112020019547B1 (pt) 2018-03-30 2023-11-28 Dow Global Technologies Llc Processo para polimerizar olefinas

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US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US5189192A (en) * 1991-01-16 1993-02-23 The Dow Chemical Company Process for preparing addition polymerization catalysts via metal center oxidation

Also Published As

Publication number Publication date
ES2107201T3 (es) 1997-11-16
FI945435A7 (fi) 1994-11-18
CA2134890A1 (en) 1994-09-29
EP0641360B1 (en) 1997-10-01
JP3547440B2 (ja) 2004-07-28
TW273557B (enExample) 1996-04-01
FI945435L (fi) 1994-11-18
DE69405952T2 (de) 1998-04-16
FI945435A0 (fi) 1994-11-18
NO944420L (no) 1994-11-18
EP0641360A1 (en) 1995-03-08
US5347024A (en) 1994-09-13
WO1994021693A1 (en) 1994-09-29
JPH07507099A (ja) 1995-08-03
HK1003598A1 (en) 1998-10-30
DE69405952D1 (de) 1997-11-06
NO944420D0 (no) 1994-11-18

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Legal Events

Date Code Title Description
PA0105 International application

Patent event date: 19941118

Patent event code: PA01051R01D

Comment text: International Patent Application

PG1501 Laying open of application
PC1203 Withdrawal of no request for examination
WITN Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid